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Determination of Diffusivity of Steel....
Determination of Diffusivity of Steel....
Determination of Diffusivity of Steel....
Abstract: A numerical method, with which experimental results were processed, was adopted to measure the total emissivity of mild steel
specimens at high temperatures. This method is derived from considering the transient thermal energy equilibrium between a steel specimen
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and its surrounding heating environment. As a first step to validate this method, the results obtained at a low temperature were compared with
those using infrared thermographic techniques, and a good correlation of 87% was achieved. The numerical model was then extended to high
temperatures to investigate the variation of emissivity of steel with temperatures. The convective heat transfer coefficient used in the numeri-
cal model was examined in great detail using results obtained from transient high temperature tests. The emissivity of steel obtained from this
study shows that steel emissivity varies over a range of temperatures and the variation becomes more abrupt between 400 and 500°C. For-
mulation for the emissivity of steel at rising temperatures is recommended for steel design in fire. DOI: 10.1061/(ASCE)MT.1943-5533
.0000607. © 2013 American Society of Civil Engineers.
CE Database subject headings: Structural steel; Temperature effects; Heat transfer; Radiation; Material properties.
Author keywords: Emissivity; Steel; Temperature; Heat transfer; Convection; Radiation.
the fire test. Therefore, it was limited to a minimum temperature of where g = acceleration of gravity (9.81 m=s2 ); and β = volumetric
approximately 150°C and reliable results were not possible below this thermal expansion coefficient (K−1 ), and can be assumed as
temperature, because the constant temperature regime was disturbed
when the furnace door was opened for installing the test specimens. 1
β ¼ ðT ð4Þ
Good agreements were found between this method and another op- s þT f Þ
2 þ 273
tical method at 200°C conducted for two types of stainless steel; how-
ever, this was not the case for carbon steel specimens. Moreover, in ν = momentum diffusivity; α = thermal diffusivity; and Pr =
these experiments, the constant temperature was kept at 700°C, giving Prandtl number, which is the ratio of the momentum and thermal
a very high heating rate for the test specimens. diffusivities of the furnace medium; T s and T f = specimen and fur-
In the current study, the method to find the emissivity of carbon nace temperatures (°C), respectively. The thermophysical proper-
steel surfaces is similar to that used by Paloposki and Liedquist ties of the air as a function of temperature were taken from
(2006). The process of heating the specimens was modified, and Moran et al. (2003). The values of these parameters were used
in this instance, the specimen was placed in the furnace before to find the coefficient of heat convection for the furnace by apply-
the test so that both the furnace and the specimen temperatures were ing Eqs. (1–4).
continuously and simultaneously monitored and measured without The convective heat transfer from the heated environment in the
any disturbance. As a first step to validate this method, the results furnace to the specimen is given by
obtained at a low temperature were compared with those using in-
frared (IR) thermographic techniques, as recommended by ASTM
qconv ¼ hc ðT f − T s Þ ð5Þ
(2005), and a good correlation was achieved. The sensitivity of this
method against variables was also investigated, including the size
of the time interval taken to solve the energy equation and the con- Radiation Heat Transfer Coefficient
vective heat transfer coefficient. The numerical procedure is
adopted from a previous study by Wong and Ghojel (2003b). The radiation exchange between a heated object, such as a small
Finally, a formulation for the emissivity of steel is recommended steel specimen, at temperature T s , and a large isothermal surround-
for use in high temperature steel design. ing, such as the furnace walls at temperature T f , is represented by
the net radiation equation:
qnet rad: ¼ α · σ · T 4f − ε · σ · T 4s ð6Þ
Methodology
where α = total absorptivity; ε = total emissivity of the specimen
Convection Heat Transfer Coefficient surface; and σ = Stefan Boltzmann constant (5.67×
10−8 W=m2 K4 ). One of the essential assumptions of gray surfaces
Three primary factors influence the convection heat transfer coeffi- is that the total emissivity is equal to the total absorptivity and both
cient. These are the geometry of the surface on which heat energy is are independent of the wavelength. Hence:
incident, the conditions of the heat flow, and the temperature between
the specimen and its environment (Moran et al. 2003). By knowing qnet rad: ¼ ε · σðT 4f − T 4s Þ ð7Þ
the geometry of the surface and identifying the flow condition as free
or forced convection, or laminar or turbulent flow along the surface, In general, it is a practical assumption that insulated walls in
appropriate dimensionless correlations can be obtained to find the furnaces are treated as gray surfaces to simplify the analysis process
convective coefficient. The important parameters in establishing such (Moran et al. 2003). The net radiative heat flux given in Eq. (7) is a
correlations are the Nusselt (NuL ), Reynolds (RL ), Prandtl (Pr), and special case of the general equation accounting for the view factor
Rayleigh (RaL ) numbers. For the characterization of free convection, between the two surfaces. Eq. (7) is applicable when the surface
Grashof number (GrL ) is also used. area of the object is smaller than the area of the enclosure (Moran
The Nusselt number represents the slope of the temperature at et al. 2003), as is the case in the current study.
the surface of the object and directly correlates the surface convec- If an object is placed in a furnace, the change of energy storage
tion coefficient, as shown in Eq. (1): due to the temperature change is equal to the energy flow due to
convection and net radiation. Thus:
NuL k
hc ¼ ð1Þ Est ¼ Ein − Eout ¼ q•net ð8Þ
L
where hc and L = convective heat transfer coefficient and the where Est = rate of increase or decrease in the internal energy of
characteristic length of the surface, respectively, for rectangular the object, usually corresponding to an increase or decrease in
εðTÞ ¼ ð11Þ
σðT 4f − T 4s Þ
IR Camera
where ρ and V = density and volume of the tested specimen, An NEC Thermo Tracer TH9260 thermal camera from NEC Avio
respectively. Infrared Technologies was used to measure the emissivity in this
study. This camera operates in the medium-long wavelength IR spec-
tral band between 8 and 13 μm. It has a thermal sensitivity of 0.06°C
Experimental Procedures at 30°C. The measurement accuracy is 2°C or 2% of the reading at
ambient temperature of 0 ∼40°C. The detectable measurement is up
High Temperature Test to 30 frames per second. This detector has an uncooled focal plane
array (FPA) microbolometer detector with 640 ðhorizontalÞ ×
Eq. (11) can be used to obtain the variation of steel emissivity with 480 ðverticalÞ pixels. The minimum detectable area that this imager
temperature if a set of values for T f and T s are available over a can detect is 0.18 mm2 . The emissivity input correction is between
practical range of temperatures. Thus, a high temperature test 0.1 and 1.0. The detector is provided with ambient temperature cor-
was performed on a steel rod. rection, background temperature correction, and distance from object
An electrical furnace with 800 × 350 × 350 mm internal dimen- correction. The camera was calibrated by the manufacturer. The cam-
sions was used for the high temperature test, as shown in Fig. 1. To era is supported with many image processing functions; it can read
verify the validity of Eq. (1) for the evaluation of the convective temperatures for different points and provides the IR reading with
heat transfer coefficient, a comparative test was first performed. different shapes as regions of interest. The data can be recorded with
Two rod specimens, one made of nickel titanium (NiTi) alloy real time interval measuring.
and the other of carbon steel, were prepared with identical dimen- According to Planck’s Law, because objects with high temper-
sions of 10 mm in diameter and 200 mm in length. The purpose of ature emit radiation in short wavelengths, a detector with long
using specimens with different materials was to examine the effects wavelength receives radiation with minimal atmospheric effects.
of different thermal properties on the convective coefficient. Two For that, the TH9260 IR detector showed minimum noisy images.
thermocouples were used for each specimen, one to monitor the The obtained data was digitized and displayed as shades of color
surface temperature and the other to monitor the temperature of or gray with many different patterns. The controlling of these dis-
the surrounding environment in the vicinity of the specimen. played patterns can enormously affect the detection process. Cooler
Special care was taken to mount the thermocouple onto the speci- or hotter regions of interest are identified by a different shading
men surface to minimize the effect of the heat flux intercepted color than the neighboring areas.
directly by the thermocouple sensor. This was done by covering
the thermocouple with ceramic fiber tape as an insulation material,
as shown in Fig. 1. Test Setup
The NEC camera was positioned at 1 m from the specimen. To con-
firm that the temperature differences in the IR records are not attrib-
utable to the reflections on the steel surface, a digital video camera
was used in parallel with the TH9260 IR detector to provide a record
Fig. 1. Interior view of the furnace with NiTi alloy and carbon steel
specimens Fig. 2. Steel specimen with portion of the painted surface
body was input into the IR software for the modified steel portion.
Fig. 4. Temperature–time response of NiTi alloy and mild steel
The emissivity of the original steel surface was obtained by adjust-
specimens
ing the input value of the emissivity until the IR camera detected
the same temperature of the modified steel surface. This process
was repeated three times and the average emissivity reading was
thermocouples, Furnace (steel) and Furnace (NiTi), for each of
recorded.
the specimens, although they were placed relatively close to each
other. This implies that there was a small temperature gradient
in the space of the furnace. Nevertheless, for analysis purposes,
Results and Discussions the environment temperature for each specimen was measured
separately according to the temperature recorded by the adjacent
IR Test thermocouple.
Also, Fig. 4 shows that the furnace does not follow the standard
To obtain a valid image using the IR imaging technique, the steel
ISO 834 (ISO 834-8 2002) fire curve, which has a higher heating
specimen needed to be at least 10°C hotter or cooler than the
rate and may not be ideal for the current study. As a result of the
ambient temperature (ASTM 2005). A tungsten halogen light lamp
different thermal properties for the NiTi and mild steel materials,
from IANIRO was used to provide this difference between the
temperature histories of steel and NiTi specimens were not the
specimen and the ambient temperatures. The maximum capacity
same, although they had the same geometry and were simultane-
of the light was 2,000 W.
ously exposed to a similar environment. In Fig. 4, both the NiTi
Fig. 3 shows the IR image for the steel specimen. As illustrated
alloy and the steel temperature–time curves possess a small plateau
in the diagram, the thermograms show differences in temperatures
where the temperatures do not significantly increase. It is at approx-
between specimen and ambient and between the modified and
imately 100°C for the NiTi alloy and 700°C for the steel. The reason
original surfaces of the specimen. The emissivity of the steel
behind this phenomenon is that NiTi alloy and steel experience
specimen was measured at 60.3°C and the readings were between
solid to solid phase transformation at approximately 100 and
0.29 and 0.32. This process was repeated five times and the average
700°C, respectively, and most of the incident heat energy is con-
emissivity reading was found to be 0.3.
sumed by the transformation.
calculated from NiTi alloy and mild steel specimens show noises arising from the inconsistency in the heat energy below this
acceptable agreement, especially at temperatures from 25 to approx- temperature, and only part of the data are presented in Table 2 to
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imately 400°C, although there was a noticeable difference in their demonstrate how the calculation is conducted.
surface temperatures over this range during the test. The NiTi alloy Fig. 6 depicts the variation of the calculated total emissivity with
produced an average convective coefficient of 10.5 W=m2 K and the the specimen temperature. When compared with the result from the
mild steel specimen produced an average of 10.8 W=m2 K. The con- IR test at 60.3°C, this method slightly underestimates the total
vective coefficient does not usually have a constant value, because it emissivity, but generally agrees well. Table 3 compares the results
is, among other conditions, a function of the temperature difference obtained from the two methods at 60.3°C, at which the method
between the specimen and the furnace environment. based on Eq. (11) agrees with the IR method to 87%. Fig. 6 shows
the variation of the total emissivity between 50 and 600°C of the
Emissivity of Steel specimen temperature. This range of temperatures was selected
from a practical point of view because steel loses most of its
To obtain the total emissivity, ε, of carbon steel, the temperature strength at temperatures above 600°C.
data of the tested steel rod were used. The specific heat variation Fig. 6 also shows that the method is not sensitive to the mag-
of the steel with temperature was assumed as recommended in nitude of the time interval. There are two temperature ranges within
Eurocode 3 (CEN 2005) and the convective heat transfer coefficient which the total emissivity is almost a constant. One is from 50 to
obtained from the previous section was used in this analysis. The approximately 400°C and the other is from 500 to 600°C. However,
spreadsheet method was adopted to solve the energy equilibrium a rapid increase in the total emissivity occurs from 400 to 500°C.
equation at time steps of 10 and 20 s. Table 2 shows the steps that The reason for such a rapid increase is that the specimen surface
are required to calculate the steel emissivity using the measured starts to oxidize and changes surface roughness, causing a change
steel and environment temperatures, the convective coefficients of the total emissivity from approximately 0.28 at 50°C to approx-
obtained from Table 1, and Eq. (11). Once again, the calculations imately 0.7 at 600°C. According to the literature, the total emissiv-
start at steel temperatures above 49°C to avoid any numerical ity of carbon mild steel with a freshly rolling surface is usually in
the realm of 0.2–0.32 at room temperature (Croft and Stone 1977;
Tanaka et al. 1989).
Recommendations
References
ASTM. (2005). “Standard test method for measuring and compensating for
emissivity using infrared imaging radiometers.” E1933-99a, West
Conshohocken, PA.
Conroy, C., Guthrie, J., Sharkins, A., Sparr, B., Crocombe, R., and
Curbelo, R. (1987). “An infrared accessory for studying the emissivity
of aluminum surfaces.” Appl. Spectrosc., 41(4), 688–692.
Fig. 7. Total emissivity values of steel using constant and variable con-
Croft, D., and Stone, J. (1977). Heat transfer calculations using finite dif-
vective coefficients
ference equations, Applied Science Publishers, Barking, UK.
(2), 187–201.
Heat Trans., 21(1), 128. Wong, M. B., and Ghojel, J. (2003b). “Spreadsheet method for temperature
Moran, M., Shapiro, H., Munson, B., and DeWitt, D. (2003). Introduction calculation of unprotected steelwork subject to fire.” Struct. Des. Tall
to thermal systems engineering, Wiley, New York. Special Build., 12(2), 83–92.