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Preparation of Soap
Preparation of Soap
SIGN OF PRINCIPAL::
ACKNOWLEDGEMENT
SIGNATURE OF STUDENT::
INTRODUCTION
In chemistry, soap is a salt of a fatty acid. Soap are
mainly used as surfactants for washing, bathing,
cleaning .
Fats and oils are composed or triglycerides; three
molecules of fatty acids are attached to a single
molecules of glycerol. The alkaline solution, which is
often called lye, brings about a chemical reaction as
saponification .
They have a polar end which is hydrophilic (water
loving) and a long non-polar chain which is
hydrophobic (water hating). As a consequence, they
can form emulsion by suspending oil in water.
FATTY END OF WATER SOLUBLE END
CH3-(CH2)n-COONa
Soaps are useful for cleaning because soap molecules
have both a hydrophilic end, which dissolves in water,
as well as hydrophobic end, which is able to dissolve
non-polar grease molecules.
MICELLE
Micelles is an aggregate of surfactant molecules
disperse in a liquid colloid.
In an aqueous solution, molecules having polar or
charged or group and non polar regions (amphiphilic
molecules) from aggregate called micelle. In a micelle,
polar or ionic heads from an outer shell in contact with
water, while non-polar tails are sequestered in the
interior.
PROPERTIES
WASHING PROPERTIES
Take a small amount of soap and try to wash your hands with
it. It should lather rather easily if soft water or deionized
water
EMULSIFICATION
Put 5-10 drops of kerosene in test tube containing 10ml
water shake to mix. Emulsification or suspension of tiny oil
droplets in water from formed ..let this stand for a few
minutes.
Prepare a another test tube with the same ingredients and
also add a small portion (1/2 gm)of your soap. Shake to mix,
compare the relative stability of the two emulsion.
HARD WATER REACTION
Take 1g of your soap and warm it with 150ml of water in a
100ml beaker.
When you have obtained a reasonably clear solution. Pour
about 15ml into each of three test tubes.
Test one of the three test tubes with 10 drops of 5% CaCl2
solution, one with 10 drops of 5% MgCl2 solution and one
with 10 drops 5% FeCl3 solution.
Let these solution stand, then make your observation.
BASICITY:- Soap with free alkali can be very damaging to
skin, silk or wool.
It’s test
Dissolve a small piece of your soap in 15ml of ethanol and
then add two drops of phenolphthalein. It the indicators
turns red, the presence of free alkali is indicated.
It the indicators turns red, the presence of free alkali is
indicator.
Fats and oils are hydrolyzed with a high pressure
to yield crude fatty acids and glycerols.
The fatty acid are then purified by distillation and
neutralized with an alkali to produce soap and
water.
Fatty acid + NaOH > glycerol + sodium soap
Sodium soaps are “hard” soap
The more saturated the oil (tropical vegetables oils
such as coconut oil), the harder the soap.
Fatty acid + KOH > glycerol + potassium soap
I. slideshare.com
II. wikipedia.org
III. icbse.co.in
IV. scribd.com