SKC SIR ORGANIC CHEMISTRY

EXERCISE-1 (CONCEPTUAL QUESTIONS)

BIOMOLECULES
1. Which of the following statement is not correct for maltose.
(1) It is a disaccharide (2) It undergoes mutarotation
(3) It is reducing sugar (4) It does not have hemiacetal group

2. Identify the correct statement about lactose.

(1) It consists of one galactose and one glucose unit.
(2) Mutarotation is not possible.
(3) Anomeric carbon of galactose is attached to 4’ carbon of glucose which is -1, 4’-glycoside bond.
(4) Lactose is used to cleave the -1,4’-glycoside bond.

3. Mutarotation involve -
(1) Racemisation (2) Diastereomerisation
(3) Optical resolution (4) Conformational inversion

4. Peptide linkage is -

(1) (2) (3) (4)

5. The monomer of nucleic acids are held together by :

(1) Phosphoester linkage (2) Amide linkage
(3) Glycosidic linkage (4) Ester linkage

6. Carbohydrates may be :
(1) Sugars (2) Starch
(3) Polyhydroxy aldehyde/ ketones (4) All

7. Select the correct statement.

(1) Proteins upon hydrolysis gives -amino acid only.
(2) Except glycine, all other naturally occurring -amino acids are optically active.
(3) In fibrous proteins polypeptide chains are held together by hydrogen and disulphide bonds.
(4) All

8. Which of the following carbohydrates developes blue colour on treatment with iodine solution ?
(1) Glucose (2) Amylose (3) Starch (4) Both (2) & (3)

9. (+)–Glucose and (–)-Fructose can be differentiated by :

(1) Tollen’s reagent (2) Benedict solution (3) Bromine water (4) None of these

10. Sucrose on hydrolysis gives :

(1) Glucose and galactose (2) Maltose and galactose
(3) Glucose and fructose (4) None of these

11. Hydrolysis of sucrose is called :

(1) Saponification (2) Hydration (3) Inversion (4) esterification

12. The number of chiral carbons in -D(+)–glucose is :

(1) 5 (2) 6 (3) 3 (4) 4

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13. Glucose reacts with methyl alcohol to give :
(1) -methyl glucoside (2) -methyl glucoside (3) Both (1) and (2) (4) None of these

14. Cellulose is a :
(1) monosaccharide (2) disaccharide (3) polysaccharide (4) None of these

15. Lactose has the same molecular formula as :

(1) Glucose (2) maltose (3) Fructose (4) galactose

16. Dihydroxy acetone (CH2OH CO CH2OH) has the general formula of carbohydrate but not included in this
class because :
(1) It does not contain polyhydroxy group (2) It does not contain aldehyde group
(3) It is not optically active (4) All of the above

17. The intermediate compound in the conversion of starch to glucose is :

(1) lactose (2) maltose (3) fructose (4) sucrose

18. Which statement about ribose is incorrect ?

(1) A polyhydroxy compound (2) An aldehyde sugar
(3) Has six carbon atoms (4) Exhibits optical activity

19. Mannose is ......... epimer of glucose.

(1) C5 (2) C2 (3) C4 (4) C3

20. When glucose is heated with nitric acid, the product is :

(1) Gluconic acid (2) Saccharic acid (3) Glycolic acid (4) Oxalic acid

21. Complete hydrolysis of cellulose gives :

(1) D-glucose (2) L-glucose (3) D-fructose (4) D-ribose

22. Lactose is made of :

(1) -D-glucose only (2) -D-galactose and -D-glucose
(3) -D-galactose and -D-glucose (4) -D-galactose and -D-glucose

23. The change in optical rotation with time of freshly prepared solutions of sugar is known as :
(1) Specific rotation (2) Inversion (3) Rotatory motion (4) Mutarotation

24. Which of the following -amino acids is not optically active ?

(1) Alanine (2) Glycine (3) Phenylalanine (4) Cysteine

25. Biuret test is not given by :

(1) Proteins (2) urea (3) Polypeptide (4) carbohydrates

26. The force of attraction between the neighbouring peptide chains is :

(1) van der Waals force (2) Covalent bond (3) Hydrogen bond (4) Peptide linkage

27. Consider the following compounds :

(I) Glycine (II) Sulphanilic acid (III) Anthranilic acid
Which can form dipolar (Zwitter) ion ?
(1) I and II (2) I, II and III (3) II and III (4) I and III

28. Which of the following bases is not present in DNA ?

(1) Cytosin (2) Gaunine (3) Uracil (4) Adenine

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29. Which of the following is not a fat soluble vitamin?
(1) Vitamin A (2) Vitamin K (3) B9 (4) Vitamin E

30. Vitamin B1 is chemically known as :

(1) Ascorbic acid (2) Riboflavin (3) Pyridoxine (4) Thiamine

31. DNA and RNA are chiral molecule due to the presence of :
(1) Chiral bases (2) Phosphate ester unit
(3) D–sugar component (4) L–sugar component

32. Which of the following monosaccharides is a pentose :

(1) Glucose (2) Fructose (3) Ribose (4) Galactose

33. Ring structure of glucose is due to formation of hemiacetal and ring formation between :
(1) C1 and C5 (2) C1 and C4 (3) C1 and C3 (4) C2 and C4

34. The pH value of the solution in which a particular amino acid does not migrate under the influence of electric
field is called its :
(1) Eutectic point (2) Neutralisation point (3) Isoelectric point (4) Effusion point

35. Secondary structure of proteins refers to :

(1) Mainly denatured proteins and structure of prosthetic group
(2) Three dimensional structure specially the bond between amino acid residues that are distant from each
other in polypeptide chain
(3) Linear sequence of amino acid residue in the polypeptide chain
(4) Regular folding patterns of continuous portion of the polypeptide chain

36. The main structural feature of proteins is :

(1) An ester linkage (2) An ether linkage (3) The peptide linkage (4) All

37. -Helical structure refers to the :

(1) Primary structure of protein (2) Secondary structure of protein
(3) Tertiary structure of protein (4) Quaternary structure of proteins

38. Mark the globular protein in the following :

(1) Collagen (2) Myoglobin (3) Myosin (4) Fibroin

39. The base present in RNA but not found in DNA is:
(1) Thymine (2) Uracil (3) Adenine (4) Guanine

40. Which of the following is an essential amino acid?

(1) Serine (2) Cysteine (3) Glycine (4) Phenylalanine

41. Which pairing is found in DNA :

(1) Adenine with thymine (2) Thymine with guanine
(3) Guanine with adenine (4) Uracil with adenine

42. The acidic characters of DNA and RNA are due to:
(1) purine bases (2) sugar molecules
(3) pyrimidine bases (4) phosphoric group

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43. DNA molecule is formed of :
(1) Pentose sugar, pyrimidines and purines
(2) Pentose sugar: Phosphoric acid, pyrimidines and purines
(3) Pentose sugar,phosphoric acid, and purines
(4) Chloridepentose sugar, phosphoric acid and pyrimidines

44. Which of the following is not a reducing sugar-

(1) Sucrose (2) Galactose (3) Glucose (4) Lactose

45. Sucrose, a common table sugar, is composed of:

(1) glucose + fructose (2) glucose + galactose (3) fructose + galactose (4) none of these

46. Chemical nature of cellulose is :

(1) polypeptide (2) disaccharide (3) polynucleotide (4) polysaccharide

47. Lactose is composed of :

(1) Glucose + Glucose (2) Glucose + Fructose
(3) Glucose + Galactose (4) Fructose + Galactose

48. Cellulose is a polymer of:

(1) - 1 - glucose (2)  - D - glucose (3)  - D - glucose (4)  - 1 - glucose

49. All the following are composed exclusively of glucose except:

(1) lactose (2) amylose (3) cellulose (4) maltose
50. Benedict’s solution is not reduced by:
(1) Glucose (2) Fructose (3) Maltose (4) Sucrose

51. Nonessential amino acid is :

(1) not needed in the diet (2) not essential for growth
(3) not required for protein synthesis (4) not synthesized in the body

52. The number of asymmetric carbon atom in the glucose molecule is :

(1) One (2) Two (3) Four (4) Six

53. Which of the following is a ketohexose :

(1) Glucose (2) Fructose (3) Sucrose (4) Starch

54. Glucose is a/an :

(1) Oxidising sugar (2) Reducing sugar
(3) Reducing & oxidising sugar (4) None of the above

55. Alpha–glucose & beta–glucose are called :

(1) Isomers (2) Anomers (3) Tautomers (4) Epimers

56. A disaccharides which give only glucose on hydrolysis :

(1) Lactose (2) Fructose (3) Sucrose (4) Maltose

57. D – (+)– glucose reacts with hydroxyl amine and yields an oxime. the structure of the oxime would be :

CH = NOH CH=N—OH CH=NOH

CH=NOH
H—C—OH HO—C—H H—C—OH
HO—C—H
HO—C—H HO—C—H HO—C—H
(1) (2) (3) H—C—OH (4)
HO—C—H H—C—OH H—C—OH
HO—C—H
H—C—OH H—C—OH H—C—OH
H—C—OH
CH2OH CH2OH CH2OH
CH2OH
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58. Select the incorrect statement.
(1) Coiling of polypeptide chain form fibrous protein.
(2) Quarternary structure of protein also exist.
(3) Lysine is an amino acid with basic side chain.
(4) The absolute configuration of

H3 N CH  CH2 OH COO  (L  serine) is S.

POLYMERS
59. Select the incorrect statement.
(1) Manufacture of paints require glyptal (2) Water pipes are made up of PVC

(3) Bakelite has free carbonyl group (4) Polystyrene is

60. Select the incorrect statement about Nylon-2-nylon-6.

(1) It is a copolymer
(2) It is biodegradable
(3) It is an alternating polyamide
(4) It is made up of and H2N(CH2)5COOH.

61. The process of vulcanisation makes rubber

(1) Soluble in water (2) Elastic (3) Hard (4) Soft

62. Orlon is a polymer of :

(1) Styrene (2) Tetrafluoro ethylene (3) Vinyl chloride (4) Acrylonitrile

63. Neoprene is a polymer of :

(1) Propene (2) Vinyl chloride (3) Chloroprene (4) Butadiene

64. Which one of the following is not a condensation polymer ?

(1) Nylon-6,6 (2) Nylon-6 (3) Dacron (4) Buna-S

65. In Buna-S symbol ‘Bu’ stands for :

(1) 1-butene (2) 2-butene (3) n-butene (4) butadiene

66. Which is an example of thermosetting polymer ?

(1) Polythene (2) PVC (3) Teflon (4) Bakelite
67. Which of the following is a semisynthetic polymer ?
(1) Silk (2) Wood (3) Rayon (4) Natural rubber

68. Which of the following rubber is not a polydiene ?

(1) Polysisoprene (2) Polychloroprene (3) Nylon 6 (4) Nitrile rubber

69. Which of the following is fully fluorinated polymer ?

(1) Telfon (2) Neoprene (3) Buna-S (4) PVC

70. The polymer containing strong intermolecular forces, e.g., hydrogen bonding is :
(1) natural rubber (2) Teflon (3) nylon-6,6 (4) Polystyrene

71. Natural polymer among the following is :

(1) Nylon (2) Glyptal (3) Cellulose (4) Terylene

72. Which of the following is a biodegradable polymer ?

(1) Polythene (2) PVC (3) Bakelite (4) PHBV

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73. ‘Rayon’ is :
(1) Natural silk (2) Artificial silk
(3) Natural plastic or rubber (4) Synthetic plastic

74. Nylon-6,6 is a :
(1) Natural polymer (2) Condensation polymer
(3) Addition polymer (4) Substitution polymer

75. A condensation polymer among the following polymers is :

(1) PVC (2) Teflon (3) Decron (4) Polystyrene

76. Which of the following is not a natural polymer ?

(1) Cellulose (2) Protein (3) PVC (4) Nucleic acid

77. Which of the following is used in vulcanization of rubber ?

(1) SF6 (2) CF4 (3) Cl2F2 (4) C2F2

78. Which one of the following is an example of copolymer ?

(1) Teflon (2) Buna-S (3) PVC (4) Polypropylene
79. Which one of the following in used to make ‘non-stick’ cookware ?
(1) PVC (2) Polystyrene
(3) Polyethylene terephthalate (4) Polytetrafluoroethylene

80. Which of the following is not a polymer ?

(1) Silk (2) DNA (3) DDT (4) Starch

81. Bakelites are

(1) Rubber (2) Rayon (3) Resins (4) Plasticisers

82. Which of the following is a step-growth polymer?

(1) Polyisoprene (2) Polythene (3) Nylon (4) Polyacrylonitrile

83. Which of the following is not polyamide ?

(1) Nylon-66 (2) Protein (3) Glyptal (4) Nylon-6

84. Which of the following is a copolymer formed by condensation polymerization ?

(1) Buna-S rubber (2) Buna-N (3) Neoprene (4) Terylene

85. Dacron is an example of :

(1) Polyamide (2) Polypropylene (3) Polyurethane (4) Polyester

86. Which of the following is a thermosetting polymer ?

(1) Nylon-6 (2) Nylon-6,6 (3) Bakelite (4) SBR

87. High density polyethylene (HDPE) can be prepared from ethylene by :

(1) Ziegler- Natta process (2) Heating with peroxides

(3) Condensing in sealed tubes (4) Condensing with styrenes

88. Polymerisation in which two or more chemically different monomers take part is called :
(1) Addition polymerisation (2) Copolymerisation (3) Chain polymerisation (4) Homopolymerisation

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89. Chemical name of melamine is :
(1) 2,4-Diamino-1,3,5-triazine (2) 2-Amino-1,3,5-triazine
(3) 2,4,6 -Triamino-1,3,5-triazine (4) 1,3,5-Triamino-2,4,6-triazine

90. Carprolactum is used to prepare which of the polymer :

(1) Nylon – 66 (2) Melamine (3) Nylon – 6 (4) Teflon

91. The fibre obtained by the condensation of hexamethylene diamine and adipic acid is :
(1) Dacron (2) Nylon 66 (3) Rayon (4) Teflon

92. Of the following which is a step growth polymer:

(1) Bakelite (2) Polyethylene (3) Teflon (4) PVC

93. Nylon-6, 6 is made by the polycondensation of:

(1) Adipic acid + Hexamethylene diamine (2) Phthalic acid + Glycerol
(3) Phenol + Formaldehyde (4) Urea + Formaldehyde

94. Peptide bond is a key feature in :

(1) Polysaccharide (2) Proteins (3) Nucleotide (4) Vitamins

95. Neoprene rubber is obtained by the polymerization of :

(1) 1, 3-Butadiene (2) 2- Methyl -1, 3-butadiene
(3) 2- Chloro -1, 3 butadiene (4) Styrene and butadiene

96 The example of thermosetting plastic and thermoplastic polymer respectively is :

(1) Polystyrene, polyvinyl chloride (2) Bakelite, polystyrene
(3) Polythene, polyacrylonitrile (4) Polystyrene, urea formaldehyde resin

97. Which of the following is wrong:

(1) Buna-S is a elastomer (2) PTFE is called teflon
(3) SBR is called natural rubber (4) LDPE is called low density polyethylene

98. Which is not a rubber polymer :

(1) Neoprene (2) Gutta percha (3) Buna-S (4) P.V.C.

99. Match List – I [polymers] with List – II [monomers] and choose the correct answer from the codes given
below the list :
List–I [Polymer] List–II [Monomer]
A. P.A.N. a. Chloroethene
B. Natural rubber b. Caprolactum
C. Nylon–6 c. Isoprene
D. P.V.C. d. Acrylonitrile
Code is -
A B C D
(1) d c b a
(2) a b c d
(3) c d a b
(4) b a c d

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100. Formaldehyde is not used in the manufacture of the following polymer :
(1) Bakelite (2) Nylon-6 (3) Urea resin (4) Melamine resin

101. Which one of the following pairs is not correctly matched :

(1) Terylene-condensation polymer of terephthalic acid and ethylene glycol
(2) Teflon-thermally stable cross linked polymer of phenol and formaldehyde
(3) Novolac - linear polymer of phenol and formaldehyde
(4) Synthetic rubber-A copolymer of butadiene and styrene

102. In vulcanisation of rubber :

(1) Sulphur reacts to form new compound
(2) Sulphur cross-links are introduced
(3) Sulphur forms a very thin protective layer over rubber
(4) All of the statements are correct

103. Glyptal polymer is obtained from glycol by reacting with :

(1) Malonic acid (2) Phthalic acid (3) Maleic acid (4) Acetic acid

104. Which one of the following is not an example of chain growth polymer :
(1) Neoprene (2) Buna-S (3) Natural rubber (4) Glyptal

105. P.V.C. is formed by polymerisation of :

(1) 1-Chloroethene (2) Ethene (3) Propene (4) 1-Chloropropene

106. Which of the following polymers do not involve cross linkages :

(1) Melamine (2) Bakelite (3) Polythene (4) Vulcanised rubber

107. Which of the following is not correctly matched?

O
(1) Neoprene; (2) Nylon -6; ||
–NH–(CH2)6 –NH–CO–(CH2)4–C– n

O O C6H5
||
(3) Terylene; –OCH –CH –O–C || (4) Polystyrene
C CH2 – CH
2 2
n n

108. Match list-I (Monomer) with list-II (Polymer) and select the correct answer using the codes given below the
lists :
List-I List-II
(I) Hexamethylenediamine A. Bakelite
(II) Phenol B. Dacron
(III) Phthalic acid C. Glyptal
(IV) Terephthalic acid D. Melamine
E. Nylon 6,6
Codes :
(1) I–E, II–A, III–B, IV–C (2) I–E, II–A, III–C, IV–B
(3) I–D, II–C, III–A, IV–B (4) I–D, II–C, III–A, IV–B

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SKC SIR ORGANIC CHEMISTRY
CHEMISTY IN EVERY DAY LIFE
109. Which of the following is not a narcotic :
(1) Codeine (2) Brown Sugar (3) Diclofenac (4) Morphine
110. Which of the following medicine is required for malaria :
(1) Aspirin (2) Penicillin (3) Chloroquine (4) paracetamol

111. Streptomycin is an example of :

(1) Antibiotic (2) Analgesic (3) Antipyretic (4) Anaesthetic.

112. Chloroxylenol is an important component of :

(1) Soap (2) Antibiotics (3) Dettol (4) Pain killing ointments

113. Which of the following is used as pain killers :

(1) Bromopheniramine (2) Paracetamol (3) Aminoglycoside (4) Penicillin-G

114. Penicillin is an :
(1) Antibiotic (2) Antipyretic (3) Hormone (4) Vitamin

115. Aspirin is an :
(1) Antipyretic (2) Antiseptic (3) Antimalarial (4) Narotic.

116. Which of the following can be used as an analgesic :

(1) Aspirin (2) Penicillin (3) Chloremphenicol (4) Streptomycin.

117. Veronal, a barbituric drug is used as a :

(1) Anaesthetic (2) Sedative (3) Antiseptic (4) Antipyretic.

118. Which of the following is a hypnotic drug :

(1) Catechol (2) Luminal (3) Phenol (4) Tincture iodine

119. Morphine is used as an :

(1) Antipyretic (2) Antiseptic (3) Narcotic Analgesic (4) Insecticide.

120. A substance which can act both as an analgesic and antipyretic is :

(1) Quinine (2) Aspirin (3) Penicillin (4) Insulin.

121. Soap is :
(1) Sodium stearate (2) Calcium stearate (3) Sodium acetate (4) Sodium benzoate

122. The polar head of sodium stearate is :

(1) Na+ (2) H+ (3) –COO– (4) CH3(CH2)16

123. Detergents......the surface tension of water:

(1) Reduces (2) Increases (3) Keeps constant (4) Slightly increases

124. Which among the following is a broad spectrum antibiotic :

(1) Paracetamol (2) Penicillin-G (3) Aspirin (4) Ofloxacin

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125. 1 % solution of phenol is used as a :
(1) Antiseptic (2) Disinfectant (3) Both (4) None.

126. Which of the following is used as an antiseptic :

(1) Dettol (2) Iodoform (3) Bithional (4) All the above

127. The drug used as an antidepressant is :

(1) Luminal (2) Terfenadine (3) Aspirin (4) Sulphadiazine

128. The drug given during hypertension is :

(1) Streptomycin (2) Chloroxylenol (3) Equanil (4) Aspirin

129. Which of the following is used as sedative :

(1) Paracetamol (2) Chloroquine (3) Bithional (4) Barbituric acid derivatives

130. Traquilizers are used for the treatment of :

(1) Cancer (2) AIDS (3) Mental diseases (4) Physical disorders

131. Drug which helps to reduce anxiety and brings about calmness is :
(1) Tranquilizer (2) Diuretic (3) Analgesic (4) Antihistamine

132. Dettol consist of :

(1) Xylenol + Terpeneol (2) Chlroxylenol + Terpeneol
(3) Cresol + ethnol (4) None

133. Which of the following is an antidiabetic drug :

(1) insulin (2) penicillin (3) chloroquine (4) aspirin

134. 2-Acetoxybenzoic acid is called :

(1) antiseptic (2) aspirin (3) antibiotic (4) mordant dye

ANSWER KEY [EXERCISE-I]

Que . 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 4 1 2 3 1 4 4 4 3 3 3 1 3 3 2
Que . 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 3 2 3 2 2 1 2 4 2 4 3 2 3 3 4
Que . 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 3 3 1 3 4 3 2 2 2 4 1 4 2 1 1
Que . 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 4 3 3 1 4 1 3 2 2 2 4 4 1 3 4
Que . 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. 3 4 3 4 4 4 3 3 1 3 3 4 2 2 3
Que . 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans. 3 1 2 4 3 3 3 3 4 4 3 1 2 3 3
Que . 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105
Ans. 2 1 1 2 3 2 3 4 1 2 2 2 2 4 1
Que . 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. 3 2 2 3 3 1 3 2 1 1 1 2 2 3 2
Que . 121 122 123 124 125 126 127 128 129 130 131 132 133 134
Ans. 1 3 1 4 2 4 1 3 4 3 1 2 1 2
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EXERCISE-2 (PREVIOUS YEAR QUESTIONS)
AIPMT - 2006
1. Which one of the following is a peptide hormone:
(1) Glucagon (2) Testosterone (3) Thyroxin (4) Adrenaline

2. During the process of digestion, the proteins present in food materials are hydrolysed to amino acids. The
two enzymes involved in the process:
Proteins 
Enzyme ( A )
 Polypeptides 
Enzyme (B)
 Amino acids, are respectively :
(1) Amylase and Maltase (2) Diastase and Lipase
(3) Pepsin and Trypsin (4) Invertase and Zymase

AIIMS - 2006
3. The pair in which both species have iron is :
(1) Nitrogenase, cytochromes (2) Carboxypeptidase, haemoglobin
(3) Haemocyanin, nitrogenase (4) Haemoglobin, cytochromes

4. Thymine is :
(1) 5-Methyluracil (2) 4-Methyluracil (3) 3-Methyluracil (4) 1-Methyluracil

5. Lysine is least soluble in water in the pH range :

(1) 3 to 4 (2) 5 to 6 (3) 6 to 7 (4) 8 to 9

6. Methyl--D-glucoside and methyl--D-glucoside are :

(1) Epimers (2) Anomers
(3) Enantiomers (4) Conformational diastereomers

AIPMT - 2007
7. Which one of the following vitamins is water soluble :
(1) Vitamin A (2) Vitamin B (3) Vitamin E (4) Vitamin K

8. RNA and DNA are chiral molecules, their chirality is due to :

(1) D - sugar component (2) L - sugar component
(3) Chiral bases (4) Chiral phosphate ester units

9. Which one of the following polymer is prepared by condensation polymerization :

(1) Styrene (2) Nylon-66 (3) Teflon (4) Rubber

AIPMT - 2008
10. In DNA, the complimentary bases are :
(1) Adenine and thymine; guanine and uracil (2) Adenine and guanine; thymine and cytosine
(3) Uracil and adenine; cytosine and guanine (4) Adenine and thymine; guanine and cytosine

11. Which one of the following is an amine hormone:

(1) Oxypurin (2) Insulin (3) Progesterone (4) Thyroxine

12. Which of the following statement is not true :

(1) Natural rubber has the trans-configuration at every double bond.
(2) Buna-S is a copolymer of butadiene and styrene
(3) Natural rubber is a 1, 4-polymer of isoprene
(4) In vulcanization, the formation of sulphur bridges between different chains make rubber harder and stronger.

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13. Green chemistry means such reaction which :
(1) Reduce the use and production of hazardous chemicals.
(2) Are related to the depletion of ozone layer
(3) Study the reaction in plants
(4) Produce colour during reactions
AIPMT - 2009
14. Which one of the following is employed as a transquilizer ?
(1) Chlorpheninamine (2) Equanil (3) Naproxen (4) Tetracycline

15. Structures of some common polymers are given. Which one is not correctly presented ?

(1) Nylon 66 –[ NH(CH2)6NHCO(CH2)4 – CO –]n (2) Teflon –( CF2 – CF2 –)n

 CH2  C  CH – CH2  CH2 – 

(3) Neoprene  |  (4) Terylene –( OC COOCH2–CH2–O)-n
 Cl 
 n

16. The segment of DNA which acts as the instrumental manual for the synthesis of the protein is :

(1) Nucleoside (2) Nucleotide (3) Ribose (4) Gene

17. Which of the following hormones contains iodine?

(1) Thyroxine (2) Insulin (3) Testosterone (4) Adrenaline

AIPMT - 2010
18. Which one of the following does not exhibit the phenomenon of mutarotation ?

(1) (–) Fructose (2) (+) Sucrose (3) (+) Lactose (4) (+) Maltose

19. Which of the following structures represents Neoprene polymer ?

(1) ( CH  CH2 )n (2) ( CH2  C  CH  CH2 )n

| |
C6H5 Cl

CN Cl
| |
(3) ( CH2  CH)n (4) ( CH2  CH)n

AIPMT Mains - 2010

20. Fructose reduces Tollen’s reagent due to :
(1) Primary alcoholic group
(2) Secondary alcoholic group
(3) Enolisation of fructose followed by conversion to aldehyde by base.
(4) Asymmetric carbons.

AIIMS - 2010
21. The most basic -amino acid is :
(1) Lysine (2) Histidine (3) Glutamine (4) Glycine

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SKC SIR ORGANIC CHEMISTRY
22. Units of lactose are :
(1) -D Glucose and -D-Glucose (2) -D Glucose and -D Galactose
(3) -D Glucose and -D Galactose (4) -D Glucose and -D Galactose

AIPMT Pre. - 2011

23. Which one of the following statements is not true regarding (+) Lactose ?
(1) On hydrolysis (+) Lactose gives equal amount of D(+) glucose and D(+) galactose
(2) (+) Lactose is a -glycoside formed by the union of a molecule of D(+) glucose and a molecule of D(+)
galactose
(3) (+) Lactose is a reducing sugar and does not exhibit mutarotation
(4) (+) Lactose, C12H22O11 contains 8-OH groups

24. Which one of the following is employed as Antithistamine ?

(1) Chloramphenicol (2) diphenyl hydramine
(3) Norethindrone (4) Omeparazole

25. Of the following which one is classified as polyester polymer ?

(1) Terylene (2) Bakelite (3) Malamine (4) Nylon-66

AIPMT Mains - 2011

26. Which of the following is not a fat soluble vitamin?
(1) Vitamin A (2) Vitamin B complex (3) Vitamin D (4) Vitamin E

27. Which of the statements about “Denaturation” given below are correct ?
Statements
(a) Denaturation of proteins causes loss of secondary and tertiary structures of the protein
(b) Denaturation leads to the conversion of double strand of DNA into single strand.
(c) Denaturation affects primary structure which gets distorted.
Options :
(1) (a), (b) and (c) (2) (b) and (c) (3) (a) and (c) (4) (a) and (b)

AIIMS - 2011
28. Find the hydrolysis product when a phosphodiester bonds of nucleotide breaks :
(1) 3-OH-deoxyribose-5 PO43– (2) 5-OH-deoxyribose-3-PO43–
(3) 2-OH-deoxyribose-2-PO43– (4) 4-OH-deoxyribose-2-PO43–

29. Find the hydrolysis product of maltose :

(1) -D Glucose + -D-Glucose (2) -D Glucose + -D-Fructose
(3) -D Glucose + -D-Galactose (4) -D Fructose + -D-Galactose

AIPMT Pre. - 2012

30. Deficiency of vitamin B1 causes the disease :

(1) Cheilosis (2) Sterility (3) Convulsions (4) Beri-Beri

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SKC SIR ORGANIC CHEMISTRY
31. Which one of the following sets of monosaccharides forms sucrose ?

(1) -D Glucopyranose and -D-fructofuranose (2) -D Glucopyranose and -D fructopyranose

(3) -D Galactopyranose and -D glucopyranose (4) -D Glucopyranose and -D fructofuranose

32. Which one of the following is not a condensation polymer ?

(1) Dacron (2) Neoprene (3) Melamine (4) Glyptal

33. Which of the following statements is false ?

(1) The repeat unit in natural rubber is isoprene (2) Both starch and cellulose are polymers of glucose

(3) Artificial silk is derived from cellulose (4) Nylon-66 is an example of elastomer

AIPMT Mains - 2012

34. Which one of the following sets forms the biodegradable polymer ?

(1) HO–CH2–CH2–OH & HOOC COOH (2) CH=CH2 & CH2=CH–CH=CH2

(3) CH2=CH–CN & CH2=CH–CH=CH2 (4) H2N–CH2–COOH & H2N–(CH2)5–COOH

35. Chloroamphenicol is an :
(1) Antiseptic and disinfectant (2) Antibiotic broad spectrum
(3) Antifertility drug (4) Antithistaminic

NEET (UG) - 2013

36. Nylon is an example of :
(1) Polythene (2) Polyester (3) Polysaccharide (4) Polyamide

37. Antiseptics and disinfectants either kill or prevent growth of microganisms. Identify which of the following
statements is not true :
(1) Disinfectants harm the living tissues
(2) A 0.2% solution of phenol is an antiseptic while 1% solution acts as a disinfectant
(3) Chlorine and Iodine are used as strong disinfectants
(4) Dilute solutions of Boric acid and Hydrogen Peroxide are strong antiseptics.

38. Which is the monomer of Neoprene in the following?

(1) CH2=CH–CCH (2) CH2=CH–CH=CH2

(3) CH2  C  CH  CH2 (4) CH2  C  CH  CH2

| |
CH3 Cl

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SKC SIR ORGANIC CHEMISTRY
AIIMS - 2013
39. Which of the following is non reducing sugar :
(1) Sucrose (2) Maltose (3) Lactose (4) Mannose

40. Artifical sweetner which is stable under cold conditions only is :-

(1) Saccharine (2) Sucralose (3) Aspartame (4) Alitame
AIPMT - 2014
41. D(+) glucose reacts with hydroxylamine and yields an oxime. The structure of the oxime would be :

CH  NOH CH  NOH
| | CH  NOH CH  NOH
H  C  OH HO  C  OH | |
| | HO  C  H H  C  OH
HO  C  H HO  C  H | |
(1) | (2) | (3) H  C  OH (4) HO  C  H
HO  C  H H  C  OH | |
| | HO  C  H H  C  OH
H  C  OH H  C  OH | |
| | H  C  OH H  C  OH
CH2 OH CH2 OH | |
CH2 OH CH2 OH

42. Which one of the following is an example of a thermosetting polymer ?

(1) ( CH2  C  CH  CH2 )n (2) ( CH2  CH)n

| |
Cl Cl

H H O O
| | || ||
(3) (N  (CH2 )6  N  C  (CH2 )4  C )n (4)

43. Which of the following organic compounds polymerizes to form the polyester Dacron ?
(1) Propylene and para HO–(C6H4)–OH (2) Benzoic acid and ethanol
(3) Terephthalic acid and ethylene glycol (4) Benzoic acid and para HO–(C6H4)–OH

AIIMS - 2014
44. “Maltose” is made up of ?

(1) -D Glucose + -D-Glucose (2) -D Glucose + -D-Glucose

(3) -D Glucose + -D-Fructose (4) -D Glucose + -D-Galactose

45. Nylon 2-Nylon 6 is the copolymer of :

(1) Glycine + Adipic acid (2) Glycine + Amino caproic acid

(3) Adipic acid + Hexamethylene diamine (4) Amino caproic acid + Alanine

46. RNA and DNA are made up of :

(1) Sugar, Phosphate and vitamin A (2) Sugar, Phosphate and bases

(3) Nucleic Acid, Vitamins and sugar (4) Sugar, Amino acid and Phosphate

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SKC SIR ORGANIC CHEMISTRY
Re-AIPMT - 2015
47. Caprolactam is used for the manufacture of :
(1) Terylene (2) Nylon - 6, 6 (3) Nylon - 6 (4) Teflon

AIPMT - 2015
48. Bithional is generally added to the soaps as an additive to function as a/an :
(1) Dryer (2) Buffering agent (3) Antiseptic (4) Softner

49. Biodegradable polymer which can be produced from glycine and aminocaproic acid is :
(1) PHBV (2) Buna-N (3) Nylon 6, 6 (4) Nylon 2 - nylon 6
NEET(I) - 2016
50. In a protein molecule various amino acids are linked together by
(1) -glycosidic bond (2) -glycosidic bond (3) peptide bond (4) dative bond

51. Natural rubber has

(1) all cis-configuration (2) all trans-configuration
(3) alternate cis-and trans-configuration (4) random cis-and trans-configuration

52. Which of the following is an analgesic?

(1) Novalgin (2) Penicillin (3) Streptomycin (4) Chloromycetin

53. The correct statement regarding RNA and DNA, respectively is

(1) The sugar component in RNA is arabinose and the sugar component in DNA is 2’-deoxyribose.
(2) The sugar component in RNA is ribose and the sugar component in DNA is 2-deoxyribose.
(3) The sugar component in RNA is arabinose and the sugar component in DNA is ribose.
(4) The sugar component in RNA is 2’-deoxyribose and the sugar component in DNA is arabinose.

54. Which one given below is a non-reducing sugar?

(1) Maltose (2) Lactose (3) Glucose (4) Sucrose
NEET(II) - 2016
55. Which one of the following represents nylon 6,6 polymer?

(1) (2)

(3) (4)

56. The central dogma of molecular genetics states that the genetic information flows from
(1) DNA  Carbohydrates  Proteins (2) DNA  RNA  Proteins
(3) DNA  RNA  Carbohydrates (4) Amino acids  Proteins  DNA

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SKC SIR ORGANIC CHEMISTRY
57. The correct corresponding order of names of four aldoses with configuration given below

respectively, is
(1) D-threose, D-erythrose, L-threose, L-erythrose
(2) L-erythrose, L-threose, D-erythrose, D-threose
(3) D-erythrose, D-threose, L-erythrose, L-threose
(4) L-erythrose, L-threose, L-erythrose,D-threose

NEET- 2017

58. Mixture of chloroxylenol and terpineol acts as :

(1) analgesic (2) antiseptic (3) antipyretic (4) antibiotic

59. Which of the following statements is not correct?

(1) Insulin maintains sugar level in the blood of a human body
(2) Ovalbumin is a simple food reserve in eggwhite
(3) Blood proteins thrombin and fibrinogen are involved in blood clotting
(4) Denaturation makes the proteins more active.

NEET- 2018
60. The difference between amylose and amylopectin is
(1) Amylopectin have 1  4 -linkage and 1  6 -linkage
(2) Amylose have 1  4 -linkage and 1  6 -linkage
(3) Amylopectin have 1  4 -linkage and 1  6 -linkage
(4) Amylose is made up of glucose and galactose

61. Which of the following compounds can form zwitterion ?

(1) Aniline (2) Acetanilide (3) Benzoic acid (4) Glycine

62. Regarding cross-linked or network polymers,which of the following statements is incorrect?

(1) They contain covalent bonds between various linear polymer chains.
(2) They are formed from bi- and tri-functional monomers.
(3) Examples are bakelite and melamine
(4) They contain strong covalent bonds in their polymer chains.

AIIMS - 2018

63. Which is incorrect statement (Exact)

(1) Amyeopectin is insoluble in water (2) Fructose is reducing sugar
(3) Cellulose is the polymer -D-glucose (4) D-ribose sugar present in DNA

64. Match the following

(i) Biodegaradble (p) 3-Hydroxybutanoic polymer acid
(ii) Bakelite (q) phenol
(iii) Neoprene (r) 2-chlorobuta-1,3-diene
(iv) Glyptal (s) phthalic acid
(1) i – p; ii – q ; iii – r; iv – s (2) i – q; ii – p ; iii – r; iv – s
(3) i – p; ii – q ; iii – s; iv – r (4) i – s; ii – r ; iii – p; iv – q

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SKC SIR ORGANIC CHEMISTRY
65. Which of the following have maximum pH?
(1) Black coffee (2) blood (3) Gastric juice (4) Saliva

66. Which is incorrect :

(1) Novestrol — Antifertility (2) Serotonine — Tranquilizer
(3) Narrow spectrum — Chloromphenicol (4) Rentac — antacid

67. Structure of Guanine is :

(1) (2)

(3) (4) None

68. Monomers of Natural Rubber and Neoprene are Respectively :

(1) CH3 — C = CH — CH3 , CH3 — C = CH — CH3 (2) ,

CH3 Cl

(3) , CH2 = CH — Cl (4) CH2 = C — CH = CH2 , CH2 = C — CH = CH2

Cl CH3

ANSWER KEY [EXERCISE-II]

Que . 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 1 3 4 1 4 2 2 1 2 4 4 1 1 2 3
Que . 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 4 1 2 2 3 1 4 3 2 1 2 4 1 1 4
Que . 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 4 2 4 4 2 4 4 4 1 3 4 4 3 1 2
Que . 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 2 3 3 4 3 1 1 2 4 3 2 3 2 4 1
Que . 61 62 63 64 65 66 67 68
Ans. 4 4 4 1 2 2 1 2

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SKC SIR ORGANIC CHEMISTRY
EXERCISE-3 (ANALYTICAL QUESTIONS)
1. Which of the following carbohydrates would be most abundant in the diet of strict vegetarian ?
(1) Amylose (2) Glycogen (3) Cellulose (4) Maltose

2. Consider the given process.

 

OH
 
 
OH
 

HO2 HO 2

and identify the incorrect statement.

(1) Configuration at C-2 is lost on enolisation.
(2) I and III are epimers.

(3) Proton transfer from water to C-1 converts ene diol to an aldose.

(4) D-glucose can isomerise to D-fructose through enol intermediate.

3. Select the incorrect statement.

(1) Starch is a homopolymer of glucose forming an -glycosidic chain.

(2) Maltose and Lactose are disaccharides.

(3) Cellulose has only -D-glucose unit which are joined by glycosidic linkage between C1 of one glucose unit
and C4 of another glucose unit.

(4) The structure of glycogen is similar to amylose.

4. When methyl D-glucopyranoside is treated with HIO4 its number of mole consumed per mole of the sugar is
(1) 2 (3) 3 (3) 4 (4) 5

5. Same osazone derivatives is obtained in case of D-glucose, D-Mannose and D-Fructose due to :
(1) The same configuration at C-5.
(2) The same constitution
(3) The same constitution at C-1 and C-2.
(4) The same constitution and its configuration at C-3, C-4,C-5 and C-6 but different constitution and
configuration at C-1 and C-2 which becomes identical by osazone formation.

6. The polymer formed as a result of following sequence of reaction is :

Cu2Cl2 HCl(1eq.)
2HC CH HC CH – CH = CH2 CH2 = C–CH=CH2
NH4Cl
Cl
Polymerisation

[CH2–C = CH – CH2]
Cl

(1) Saran (2) PVC (3) Neoprene (4) Chloroprene

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SKC SIR ORGANIC CHEMISTRY
7. Select the correct statement :
(1) S-glyceraldehyde is also known as L-glyceradehyde
(2) The Configuration of the stereocenter most distant from the carbonyl group determines whether a
monosaccharide is D or L.
(3) Glucose and all naturally occurring sugars are D-sugars.
(4) All

8. All disaccharides may have

(1) One acetal (2) Two acetal
(3) One acetal and One hemiacetal (4) All

9. Starch molecules are polymer with repeating glucose units. Select the correct statement(s).
(1) Glucose units are joined through -glycosidic linkage.
(2) The branches of amylopectin are linked to the chain with -1,6’-glycosidic linkages.
(3) Amylose has an unbranched skeleton of glucose molecules with -1,4’ glycosidic linkages.
(4) All

10. Buna–N synthetic rubber is a copolymer if :

Cl
|
(1) H2 C  CH  C  CH2 and H2C = CH–CH = CH2

(2) H2C = CH – CN = CH2 and H5H6 – CH = CH2

(3) H2C = CH – CN and H2C = CH–CH = CH2

Cl
|
(4) H2C = CH – CN and H2 C  CH  C  CH2

11. Given the polymers,

A = Nylon-6,6; B = Buna-S; C = Polythene
Arrange these in decreasing order of their intermolecular forces :
(1) C < B > A (2) B > C > A (3) B < C < A (4) C < A < B

12. The monomeric units of terylene are glycol and which of the following :

(1) (2)

(3) (4)

13. Neoprene, a synthetic rubber contains which of the following element besides C and H
(1) N (2) O (3) Cl (4) F

14. Which of the following is not correct regarding terylene ?

(1) Step- growth polymer (2) Synthetic fibre
(3) Thermosetting polymer (4) It is also called decron

15. Which of the following statements is not correct?

(1) Caprolactam is the monomer of nylon-6 (2) Terylene is a polyester polymer
(3) Phenol formaldehyde resin is known as bakelite (4) The monomer of natural rubber is butadiene

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SKC SIR ORGANIC CHEMISTRY
16. Polythene is :
(1) Thermoplastic (2) Thermosetting (3) Both (1) & (2) (4) None of these

17. Among cellulose, poly vinyl chloride, nylon and natural rubber, the polymer in which the intermolecular force
of attraction is weakest is :
(1) nylon (2) poly vinyl chloride (3) cellulose (4) natural rubber

18. Which of the nitrogen of histidine is first protonated ?

(1)  (2)  (3) Both (4) None

19. In osazone formation, glucose reacts with three molecules of phenylhydrazine. Which statement is true
regarding this ?
(1) All the three molecules react in similar fashion.
(2) Two molecules react in similar manner, while the third reacts in different way.
(3) All the three molecules react in different ways
(4) None of the above is true

20. The compound required for the formation of a thermosetting polymer with methanal is :
(1) Benzene (2) Phenyl amine
(3) Benzaldehyde (4) Phenol

21. The following carbohydrate is :

(1) a ketohexose (2) An aldohexose

(3) an  - furanose (4) an - pyranose

22. Sulpha drugs are derivatives of :

(1) Benzene sulphonic acid (2) Sulphanilic acid
(3) Sulphanilamide (4) P- Aminobenzoic acid

23. Which of the following statements is not true :

(1) Some disinfectant can be used antiseptics at low concentration
(2) Sulphadiazine is a synthetic antibacterial
(3) Ampicillin is natural antibiotic
(4) Aspirin is analgesic and antipyretic both.

24. Which of the following drugs combination is not correct :

(1) Bithionol - Tranquilizer (2) Chloremphenicol- antibiotics
(3) Equanil -Antidepressant (4) Phenacetin - Antipyretic.

25. Match list with list II and salect the correct answer using the codes given below the lists :
List I List II
(I) Iodoform (A) Antibiotic
(II) Novestrol (B) Antiseptic
(III) Chloroquine (C) Antimalarial
(IV) Aminoglycosides (D) Antifertility
Codes :
(1) I -B, II -D, III - C, IV- A (2) I -D, II -B, III - A, IV- C
(3) I -B, II -D, III - A, IV- C (4) I -C, II -A, III - D, IV- B
SKCLIVE Page # 21
SKC SIR ORGANIC CHEMISTRY
26. Match the column :
(1) Antimalarial (P) 0.2 % phenol
(2) Antibiotic (Q) lansoprazole
(3) Antiseptic (R) chloroquine
(4) Antiacid (S) ofloxacin
a b c d
(1) P Q R S
(2) R S P Q
(3) S R Q P
(4) R Q P S

ANSWER KEY [EXERCISE-II]

Que . 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 3 4 1 4 3 4 4 4 3 3 3 3 3 4
Que . 16 17 18 19 20 21 22 23 24 25 26
Ans. 1 4 2 2 4 2 3 3 1 1 2

Page # 22 SKCLIVE