1 Online JEE Main Chemistry Solved Papers July Attempt 2022

29 JULY 2022, SHIFT-I

1. (b) Odd electron species are those molecules in which total 7. (c) Lithium nitrate on heating produces Li 2O and NO2 with
number of valence electrons is an odd number. O2 gas.
Among the given molecules NO is an odd electron species. D
4LiNO3 ¾® 2Li 2O + 4NO2 + O2
It contains 15 electrons. The structure of NO is as follows.
- Sodium nitrate on heating produces NaNO2 and O2.
+ ··
·N == O ·· D
·· 2NaNO3 ¾® 2NaNO2 + O2
Expanded octet molecule contains more than eight 8. (b) Structure of SCl 2,
electrons in their valence shell. SF6 , PCl5 and H2SO4 are S
examples of expanded octet molecules. Cl Cl
F Cl O (Number of lone pairs of electron on central atom, S = 2)
F F Cl
S , Cl—P , HO—S—OH Structure of O3 ,
F F Cl O
F Cl O
O O
(12 e–) (10 e–) (12 e–)
Number of lone pairs = 1

BCl3 is an electron deficient molecule, i.e. it contains less Structure of ClF3 ,

than 8 electrons in its valence shell. Cl
2. (c) N2 ( g ) + 3H2 ( g ) - 2NH ( g) 3 F F F
(20 g) (5g)
Number of lone pairs = 2
20
Moles of N2 = mol Structure of SF6 ,
28 F
5 F F
Moles of H2 = mol S
2
Number of moles F F
Limiting reagent = F
Stoichiometric coefficient Number of lone pairs = 0
20
For NH3 = 9. (a) d 0 and d10 electronic configurations are colourless in
28 aqueous solution.
5 5
For H2 = = (A) Sc3 + ¾® 3d 0 4s0 , colourless as no transition possible
2´3 6
20 5 Zn 2+ ¾® 3d10 4s0 , colourless
Clearly, < so, N2 is a limiting reagent. (B) Ti 4+ ¾® 3d 0 4s0 , colourless
28 6
1 mole of N2 forms 2 mole of NH3 . Cu 2+ ¾® 3d 9 4s0 , coloured
20 20 20 10 (C) V2+ ¾® 3d3 4s0 , coloured
So, mole of N2 forms = 2 ´ = = = 142
. mol.
28 28 14 7 Ti3 + ¾® 3d1 4s0 , coloured
3. (a) Lyophilic sol can be obtained by stirring albumin in 5% (D) Zn 2+ ¾® 3d10 4s0 , colourless
(w/V) solution NaCl in water. This sol obtained is very stable Mn 2+ ¾® 3d5 4s0 , coloured
and is unaffected by the traces of impurities present in it.
10. (d) The reaction involved in neutral or faintly alkaline
4. (c) On moving left to right across a period, ionisation medium is
energy increases as Z eff increases. +7 +4 -
So, Si has highest whereas Na has lowest ionisation energy. 8MnO4- + 3S2O32- + H2O ¾® 8MnO2 + 6SO24- + 2O H
Mg has a fully-filled electronic configuration. Thus, it has So, change in oxidation state of Mn is 7 - 4 = 3
high ionisation energy than Al. So, the order is
11. (d) Herbicides are chemical compounds that are used to
Na < Al < Mg < Si control the growth of undesired plants also known as
Ionisation energy of Al lies in between Na (496 kJ/mol) and weeds.
Mg (738 kJ/mol). Thus, correct answer is 577 kJ/mol. Among the given chemical compounds sodium chlorate
5. (a) Gangue is an unwanted / undesired material or impurity (NaClO3 ) and sodium arsinite (Na3 AsO3 ) are herbicides.
that is present in an ore. e.g. sand, rocks, stones, etc. 12. (d) Bronsted base are chemical species which can easily
6. (d) NaOH reacts with Zn to form Zn(OH)2. donate their lone pair of electrons.
Zn( s) + 2NaOH( aq) ¾® Zn(OH)2( s) + 2Na Out of compounds a, b, c and d, d is the strongest Bronsted
base as its lone pair of electrons are directed on one side.
Zn(OH)2 is amphoteric in nature and reacts with excess of
Thus, it can easily donate these electrons to capture a
NaOH to form [ZnO2 ]2- ion.
proton. While compound c is weakest Bronsted base as lone
Zn(OH)2 + 2OH- ¾® ZnO22- + 2H2O
pair of N are participating in resonance.
 July Attempt 2022 Online JEE Main Chemistry Solved Papers 2

CH3 CH3
s
r NaCN
N N + NaCl¯
Cl C2H5OH–H2O CN
(B )
s

13. (c) The given compounds and their products are as follows. AgCN is covalent in nature and nitrogen is free to donate
electron pair forming isocyanide as the main product.
CH3
O O O O Ag CN
r s
(a)
O3/Zn/H2O Cl C2H5OH–H2O N C + AgCl¯
2CH3 C C H + H C C H
(A )
CH3
15. (d) Reaction mechanism
CH3 1. Electrophilic substitution reaction (Bromination) As
O O O O ¾ OH group is ortho, para directing, so bromination occurs
O3 at ortho-position.
2CH3 C C H + H C C H OH OH
Zn/H2O
CH3 Br Br
Br2
CH3

CHO CHO
(A )
O O O O
CH3 O3 2. Hydroxylamine (NH2OH) reacts with carbonyl group to
2CH3 C C H + H C C H
(b) CH3 Zn/H2O form oximes.
OH OH
Br Br Br Br
NH2OH

CH3
C H HC N
CH3
O (B ) OH
CH3 O O O O
O3 (Oxime)
(c) CH3 C C CH3 + 2H C C H
Zn/H2O 3. P2O5 is a dehydrating agent and upon heating, it removes
water from ¾ CH== NOH to form cyanide group.
CH3
O O O O OH OH
CH3
O3 Br Br Br Br
2CH3 C C H + H C C H P2O5
Zn/H2O
D
CH3
HC NOH C N
O O O O (C )

O3 OH
(d) CH3 C C H + 2H C C H
CH3 Zn/H2O Br Br
Hence, the final product C is

CN
CH3 CH3
16. (c) Reaction mechanism
CH3 CH3 ··
Hence, give different 1. Addition-elimination reaction NH3 attacks on
and
products on ozonolysis. carbonyl carbon and eliminates Cl to form amide.
-
14. (c) NaCN is ionic and provides cyanide ion (CN ) in
solution. The attack (nucleophilic) takes place mainly
through carbon atom and not through nitrogen atom.
3 Online JEE Main Chemistry Solved Papers July Attempt 2022

– r
O O N NCl
s
OH
+ NaOH
C Cl C—NH3 +
NH3
–HCl Cl (A )
Cl N N
Cl
OH
CH3 O CH3 O
(A)
C8H6Cl2O C C
–
NH2 Cl +
H—N—H Red-orange dye
–HCl
Cl H 18. (b) Reaction mechanism
Cl
CH3 CH3 1. DIBAL-H i.e. (AlH(i - Bu)2 ) reagent is used to convert CN
(B ) group to aldehyde group.
C8H8ClNO
NH2 NH2
2. Hoffmann bromamide degradation Amide with X 2 in
presence of NaOH undergoes Hoffmann bromamide (i) AlH—(i-Bu)2
degradation to form amine. (ii) H2O
O O

C N H
s CN CHO
s C N
H OH (A)
H Br Br
–Brs 2. Cross aldol condensation
Cl
Cl
CH3 NH2
CH3
H O O
O O s
s
OH
CH2 C H CH2 C H+
C N H s C N
OH
Br O C H
Cl Cl NH2 NH2 NH2
CH3 CH3
Nitrene
HOH D

O
N C O –
H2 O H H O—C—H HC CH C H CH CHCHO
Rearrangement (B)
r
O CH2—C—H OH H a,b-unsaturated
Cl s aldehyde
CH3 N C O O
Isocyanate
19. (b)
Cl (a) Seldane is an antihistamine used for treatment of
CH3 allergic conditions.
OH
OH
NH C O Ph
NH2
C N CH2 CH2 CH2 CH
+ CO2 Ph
OH
Cl Cl
(b) Amytal is a barbiturate derivative and used for hypnotic
CH3 CH3
purposes.
17. (a) Diazonium salts react with b- naphthol to form H
O N OsNar
azo-compounds which are orange red dyes.
N

O
 July Attempt 2022 Online JEE Main Chemistry Solved Papers 4

(c) Aspartame is a artificial non-saccharide sweetener. It is L1 129 ´ 103 ´ 50 ´ 2

= =1
200 times sweeter than sucrose. L2 100 ´ 129 ´ 103
L1
= 1 = 1000 ´ 10-3 .
L2
O 22. (566) In cubic close packing, the arrangement of atoms
OCH3
O along the edge is as
N
H O
OH NH2

(d) Prontosil is an antibacterial drug.

NH2 So, edge length a = 2 [r + rB - ]
O A+
= 2(102 + 181)
H2N S N N NH2
= 2(283)
O = 566 pm

20. (b) Phenol is acidic in nature as after removing H ion, + 23. (548) Uncertainty in position, Dx = 2a0 = 2 ´ 52.9 pm
phenoxide ion is stablised by resonance. = 2 ´ 52.9 ´ 10-12 m
OH Os Using Heisenberg uncertainity equation,
h
Dx × Dv =
+ Hr 4pm
h
=
(X ) Stable due 4pmDx
to resonance
6.63 ´ 10-34
=
Phenol is although acidic but it is not soluble in NaHCO3 4 ´ 314 . ´ 10-31 ´ 2 ´ 52.9 ´ 10-12
. ´ 91
solution.
= 548 ´ 103 m/s
However, it gives violet colour with neutral FeCl3 solution.
= 548 k m s-1
OH
24. (54) HNO3 + NaOH ¾® NaNO3 + H2O;
DH neut = 57 kJ mol -1
6 + FeCl3 [(Ph O)6 Fe]3– Volume = 600 mL 400 mL
Violet colour Conc. = 0.2 M 0.1 M
Moles = 600 ´ 0.2
Hence, compound ‘ X ’ is phenol. = 120.0 m mol = 40.0 m mol
l After reacting 80 m mol 40 m mol
21. (1000) In case of solution 1, cell constant = 129 m-1
A DH neutralisation = 57 ´ 40 ´ 10-3 = 2.28 kJ
Resistance, R = 100 W Specific heat of water, C = 4.2 JK -1g -1
1 l 1 DH = mCDT
Specific conductivity, k = × = . W-1 m -1
´ 129 = 129
R A 100 2.28 ´ 103 J = 1000 ´ 4.2 ´ DT
Concentration, C = 74.5 ppm DT = 0.54°C = 54 ´ 10-2 °C .
74.5
Molarity, M1 = 25. (1) Given, Henry’s constant, K H = 46.82 K bar
molar mass ´ 1000
74.5 = 46.82 ´ 103 bar
= = 10-3 M
74.5 ´ 1000 Partial pressure of O2 , pO2 = 0.92 bar
k Using the Henry’s equation,
Molar conductivity L1 =
M pO2 = K H × c O2 [c = mole fraction]
.
129 129 ´ 103 pO
L1 = = 1290W-1 m-1 M-1 or So, c O2 = 2
10-3 100 KH
In case of solution 2, 0.92 ´ 10-3
Resistance, R = 50W c O2 = = 0.02 ´ 10-3
46.82
1 129 -1 -1
k= ´ 129 = W m Mole fraction of water, c H2 O = 1 - c O2 = 1 - 0.02 ´ 10-3 = 0.99
50 50
149 1 L water = 1000g (r H 2O - 1 gmL-1 )
M= = 2 ´ 10-3 M
74.5 ´ 1000 1000
Moles of water = = 55.55 mol
k 129 ´ 103 -1 -1 -1 18
L2 = = W m M
M 50 ´ 2
5 Online JEE Main Chemistry Solved Papers July Attempt 2022

55.55 ´ 0.02 ´ 10-3 14 ´ 10-3 0.4

So, moles of O2 , nO 2 = =
0.99 2 ´ 10-3 .
01
= 1.13 ´ 10-3 mol M = 4´2 = 8
= 1.13 m mol 8 80
So, M : L = = = 40.
» 1m mol 0.2 2
26. (282) Given, Ksp (PbS) = 8 ´ 10-28 28. (1) A tetrapeptide means there are three peptide bonds. So,
2+ 2- the number of amino acids should be four.
PbS( s) r Pb ( aq) + S ( aq)
S S So, (number of amino acids) - (number of peptide bonds)
Ksp = S 2 = 4 - 3 = 1.
-28 Br Br
8 ´ 10 =S 2
½ ½
Þ S= 8 ´ 10-28 = 2.82 ´ 10-14 29. (3) CH3 ¾ C ºº CH + 2Br2 ¾® CH3 ¾ C ¾ C ¾ H
½ ½
So, solubility, S = 282 ´ 10-16 mol L -1 . Br Br
x = 282 yield = 27 %
27. (40) Mass of bromine = 1g
1
Experiment [X ] mol L-1 [Y ] mol L-1 initial rate Moles of bromine = mol
160
mol L-1 min -1
From given reaction,
I 0.1 0.1 2 ´ 10-3 2 moles bromine gives 0.27 mole 1, 1, 2, 2 -
-3 tetrabromopropane
II 1 0.2 4 ´ 10
1 1 1
mole bromine gives ´ 0.27 ´ mole
III 0.4 0.4 M ´ 10-3 160 2 160
Molar mass of product = 360 g mol -1
IV 0.1 0.2 2 ´ 10-3
360 ´ 0.27
Mass of product = = 0.303 g » 3 ´ 10-1 g.
Rate = k[X ][Y ]0 = k[X ] 160 ´ 2
Using data of experiment I and II, 30. (3) In [Fe(CN)6 ]3 -
RateI k [X I ] Oxidation state of Fe is +3.
=
RateII k [X II ] As complex is inner sphere, so electrons are paired.
2 ´ 10-3 .
01
=
4 ´ 10-3 L
Þ L = 01
. ´ 2 = 0.2
Using experiment III and IV, CFSE = - 0.4 ´ 5D o = - 2D o
RateIII K [X III ] So, answer is 2.
=
RateIV K [X IV ]