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The Magnetic Materials and Products 2021
The Magnetic Materials and Products 2021
The Magnetic Materials and Products 2021
Course Materials:
Etymology and Definition
The magnetism of solid is originated from the electrons of atoms. Electrons are making orbital
motions and spin rotations. Since an electron has a charge, magnetic moment appears just like
magnetic field is generated when current flows in solenoid coils. The magnetic moment appears
even from the spin orientation of electrons. The magnetic moment generated from the orbital or
spin motion of a single electron is called Bohr magnetron, which is the smallest unit of magnetic
moment of solids.
The word magnet came from Middle English magnete, via Old French magnete, Latin magnetum
(“lodestone”), from Ancient Greek μαγνῆτις [λίθος] (magnêtis [líthos], “Magnesian [stone]”), either
after the Lydian city Magnesia ad Sipylum (modern-day Manisa, Turkey), or after the Greek region
of Μαγνησία (Magnēsía) (whence came the colonist who founded the city in Lydia), which means
a piece of material that attracts some metals by magnetism.
Watch: Inductors and Inductance in YouTube, Inductors Explained - The basics how inductors
work working principle in YouTube, Transformers - Electric Power transmission in YouTube, How
does a Transformer work - Working Principle electrical engineering in YouTube,
Electromagnetism 101 | National Geographic shown in YouTube, How Inductors Work Within a
Circuit – Inductance shown in YouTube, Capacitor and Inductor Specification and Color Coding
Tagalog Version in YouTube, Solenoid Basics Explained - Working Principle in YouTube, How
Relays Work - Basic working principle electronics engineering electrician amp in YouTube
Important Terms
Ferrite - refers to a ceramic oxide materials composed of both divalent and trivalent cations (e.g.,
Fe2+ and Fe3+), some of which are ferrimagnetic.
Bohr magneton (μB) - is the most fundamental magnetic moment, of magnitude 9.27 x 10-24 A·m2.
Magnetic field strength (H) - refers to the intensity of an externally applied magnetic field.
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The Magnetic Materials and Products
Magnetic flux density (B) - refers to the magnetic field produced in a substance by an external
magnetic field, otherwise called magnetic induction (B).
Coercivity (or coercive field, Hc) - refers to the applied magnetic field necessary to reduce to
zero the magnetic flux density of a magnetized ferromagnetic or ferrimagnetic material.
Magnetic susceptibility (ꭓm) - refers to the proportionality constant between the magnetization
M and the magnetic field strength H.
Magnetization (M) - refers to the total magnetic moment per unit volume of material. Also, a
measure of the contribution to the magnetic flux by some material within an H field.
Saturation magnetization (Ms) - refers to the maximum magnetization (or flux density) for a
ferromagnetic or ferrimagnetic material, otherwise called flux density (Bs)
Permeability - refers to the proportionality constant between B and H fields. The value of the
permeability of a vacuum (μO) is 1.257 x 10-6 H/m.
Remanence (remanent induction, Br) - is the magnitude of residual flux density that remains
when a magnetic field is removed, for a ferromagnetic or ferrimagnetic material.
Diamagnetism - is a weak form of induced or nonpermanent magnetism for which the magnetic
susceptibility is negative.
Paramagnetism - is a relatively weak form of magnetism that results from the independent
alignment of atomic dipoles (magnetic) with an applied magnetic field.
Ferrimagnetism - is a permanent and large magnetizations found in some ceramic materials. It
results from antiparallel spin coupling and incomplete magnetic moment cancellation.
Ferromagnetism - is a permanent and large magnetizations found in some metals (e.g., Fe, Ni,
and Co) that result from the parallel alignment of neighboring magnetic moments.
Antiferromagnetism - is a phenomenon observed in some materials (e.g., MnO): complete
magnetic moment cancellation occurs as a result of antiparallel coupling of adjacent atoms or
ions. The macroscopic solid possesses no net magnetic moment.
Domain - refers to a volume region of a ferromagnetic or ferrimagnetic material in which all atomic
or ionic magnetic moments are aligned in the same direction.
Curie temperature (Tc) - refers to the temperature above which a ferromagnetic or ferrimagnetic
material becomes paramagnetic.
Soft magnetic material - refers to a ferromagnetic or ferrimagnetic material having a small B
versus H hysteresis loop, which may be magnetized and demagnetized with relative ease.
Hard magnetic material - refers to a ferrimagnetic or ferromagnetic material that has large
coercive field and remanence values, normally used in permanent magnet applications.
Hysteresis - is the irreversible magnetic flux density-versus-magnetic field strength (B-versus-H)
behavior found for ferromagnetic and ferrimagnetic materials; a closed B-H loop is formed upon
field reversal.
Superconductivity - is a phenomenon observed in some materials: the disappearance of the
electrical resistivity at temperatures approaching 0 K.
Magnetic field Strength (H) - is also called magnetic intensity or magnetic field intensity, the part
of the magnetic field in a material that arises from an external current and is not intrinsic to the
material itself. It is expressed as the vector H and is measured in units of amperes per meter.
If a magnetic field, H, is generated by a cylindrical coil (solenoid) of n turns and length l,
n·I where: I is the current in ampere (A)
H = ——— (A/m) l is the length of the wire measured in meter (m)
l H is the magnetic field strength measured in ampere per meter
Magnetic flux density (B) - is the magnitude of the field strength within a
substance subjected to a field H. It is the amount of magnetic flux in an
area taken perpendicular to the magnetic flux's direction.
quantity used to measure the tendency of an object to interact with an external magnetic field. It
is the magnetic strength and orientation of a magnet or other object that produces
a magnetic field.
Magnetic Sand
Black sand on the beaches of La Ventanilla, Mexico, is
magnetized. The iron oxide in the sand is attracted to the
strong magnetic field produced by the magnet the man is
holding.
Depending on the existence and alignment of magnetic moments with or without application of
magnetic field, three types of
magnetism can be defined.
Diamagnetism - is a weak form of magnetism which arises only when an external field is applied.
- It is a magnetism characteristic of materials that line up at right angles to a nonuniform
magnetic field and that partly expel from their interior the magnetic field in which they are
placed. First observed by S.J. Brugmans (1778) in bismuth and antimony, diamagnetism
was named and studied by Michael Faraday (beginning in 1845). He and subsequent
experimenters found that some elements and most compounds exhibit this “negative”
magnetism. Indeed, all substances are diamagnetic: the strong external magnetic field
speeds up or slows down the electrons orbiting in atoms in such a way as to oppose the
action of the external field in accordance with Lenz’s law.
- It arises due to change in the orbital motion of electrons on application of a magnetic field.
- There are no magnetic dipoles in the absence of a magnetic field and when a magnetic
field is applied the dipole moments are aligned opposite to field direction.
- The magnetic susceptibility, m = μr - 1 is negative i.e. B in a diamagnetic material is less
than that of vacuum.
Antiferromagnetism - is a magnetism that exist if the coupling of electron spins results in anti-
parallel alignment then spins will cancel each other and no net magnetic moment will arise. In
materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually
related to the spins of electrons, align in a regular pattern with neighboring spins (on different
sublattices) pointing in opposite directions.
- In substances known as antiferromagnets, the mutual forces between pairs
of adjacent atomic dipoles are caused by exchange interactions, but the forces between
adjacent atomic dipoles have signs opposite those in ferromagnets. As a result, adjacent
dipoles tend to line up antiparallel to each other instead of parallel. At high temperatures
the material is paramagnetic, but below a certain characteristic temperature the dipoles
are aligned in an ordered and antiparallel manner. The transition temperature Tn is known
as the Néel temperature, after the French physicist Louis-Eugène-Félix Néel, who
proposed this explanation of the magnetic behaviour of such materials in 1936.
A notable property of ferrites and associated materials is that the bulk spontaneous
magnetization, even at complete magnetic saturation, does not correspond to the value expected
if all the atomic dipoles are aligned parallel to each other. The explanation was put forward in
1948 by Néel, who suggested that the exchange forces responsible for the spontaneous
magnetization were basically antiferromagnetic in nature and that in the ordered state they
contained two (or more) sublattices spontaneously magnetized in opposite directions. In contrast
to the simple antiferromagnetic substances considered above, however, the sizes of
the magnetization on the two sublattices are unequal, giving a resultant net magnetization parallel
to that of the sublattice with the larger moment. For this phenomenon Néel coined the name
ferrimagnetism, and substances that exhibit it are called ferrimagnetic materials.
Superparamagnetism - is a form of magnetism which appears in small ferromagnetic or
ferrimagnetic nanoparticles. Magnetization can randomly flip direction under the influence of
temperature in sufficiently small nanoparticles. The typical time between two flips is called the
Néel relaxation time. When the time used to measure the magnetization of the nanoparticles is
much longer than the Néel relaxation time, their magnetization appears to be in average zero, in
the absence of an external magnetic field; thus, the material is in superparamagnetic state. A
state where an external magnetic field is able to magnetize the nanoparticles, similar to a
paramagnet. But its magnetic susceptibility is much larger than that of paramagnets.
Effect of Temperature
As demonstrated by the figure, the atomic vibration
increases with increasing temperature which leads
to misalignment of magnetic moments. Above Curie
temperature TC, all the moments are misaligned and
the magnetism is lost.
through the lattice phonon which causes a slight increase in the positive charge around an
electron and since thermal energy to scatter is low, this pair can move through the lattice.
Phonon is the quantum mechanical description of an elementary vibrational motion in
which a lattice of atoms or molecules uniformly oscillates at a single frequency. In classical
mechanics this designates a normal mode of vibration.
Superconductivity and Magnetism
Meissner effect - the expulsion of magnetic flux when
a material becomes superconducting in a magnetic field.
If the magnetic field is applied after the material has
become superconducting, the flux cannot penetrate it.
A material in its superconducting state will expel all of applied magnetic field.
A magnet placed over a superconductor will then float, a phenomenon known as
magnetic levitation.
Magnetic levitation (maglev) or magnetic suspension - is a method by which an object is
suspended with no support other than magnetic fields. Magnetic force is used to counteract the
effects of the gravitational acceleration and any other accelerations.
Types of Superconductors
Type I superconductors - characterized by a situation where
some superconducting materials come back to normal
conducting state above a critical magnetic field HC when the
field is increased.
superconductivity is abruptly destroyed via a first
order phase transition when the strength of the applied
field rises above a critical value HC, a
type of superconductivity exhibited by pure metals,
e.g. aluminium, lead, and mercury.
includes 13 types of compounds, namely: organic superconductors, A-15 compounds,
magnetic superconductors (Chevrel Phases), heavy fermions, oxides without copper,
pyrochlore oxides, rutheno-cuprates, high-temperature superconductors, rare-earth
borocarbides, silicon superconductors, chalcogens, carbon superconductors, MgB2
and Related Superconductors.
Type II superconductors - characterized by a
situation where the field gradually begins to intrude
above a critical value of the applied field (HC1) and at
a higher field (HC2) it turns into a normal conductor.
superconductor which exhibits an
intermediate phase of mixed ordinary
and superconducting properties at
intermediate temperature and fields above
the superconducting phases.
Nb3Sn and YBa2Cu3O7 are examples of such type
Applications of Superconductors
1. Magnetic Levitation (Maglev) Trains which can reach very high velocity
2. Nuclear Magnetic Resonance (MRI scan machines for Medical science, Brain imaging)
3. Transmission and Distribution Electrical Systems
4. Energy storage
5. Superconducting Quantum Interference Device (SQUID)
6. The Large Hadron Collider (LHC) for generating high velocity particles travelling at speed
of light
7. High efficiency electric generators, motors and transformers
Photo credit:
hyperphysics.phy-astr.gsu.edu
Self-Inductance - is the induction of a voltage in a current-carrying wire when the current in the
wire itself is changing. Due to self-inductance, the magnetic field created by a changing current
in the circuit itself induces a voltage in the same circuit, thus, self-induced voltage VL is produced.
Such voltage tends to oppose the change and will try to decrease the current if it is increasing or
increase the current if it is decreasing, such opposing flow of electric current is known as self-
induction.
di where: L is the inductance of the coil, (henry)
VL = L ------- di/dt is the change in current with respect to time, (ampere per second)
dt VL is the induced voltage, (volts)
Lenz’s law - is named after the physicist Emil Lenz who formulated it in 1834, which states that
the induced voltage VL must produce current with a magnetic field that opposes the change of
current that induces VL. The polarity of VL, therefore, depends on the direction of the current
variation di. When di increases, VL has polarity that opposes the increase in current; when di
decreases, VL has opposite polarity to oppose the decrease in current. In both cases, the change
in current is opposed by the induced voltage. Otherwise, VL could increase to an unlimited amount
without the need to add any work. Thus, Inductance is the characteristic that opposes any change
in current, that is why an induced voltage is often called a counter emf or back emf.
e.g.
A transformer consists of two electrically
isolated coils and operates on Faraday's
principal of “mutual induction”, in which an
EMF is induced in the transformers
secondary coil by the magnetic flux
generated by the voltages and currents
flowing in the primary coil winding.
Coefficient of coupling (k) - is the fraction of total flux from one coil linking another coil.
flux linkages between L1 and L2
k = ---------------------------------------------- thus LM = k √ L1 x L2
flux produced by L1
Types of Inductors
Fixed Inductors - an inductor whose coils are
wound in such a manner that the turns remain
fixed in position with respect to each other, and
which either has no magnetic core or has a core
whose air gap and position within the coil are
fixed. Belonging to this group are air core
inductor, radio frequency inductor,
ferromagnetic core inductor, laminated core
inductor, ferrite-core inductor, and toroidal core
inductor.
Variable inductor - are coil products that allow the inductance to be easily varied by changing
the position of the ferrite core in a threaded structure. The interior is covered by a metal case that
is magnetically shielded, while a resin molded structure protects the windings with a high degree
of reliability. Inductors of this type are widely used in radio applications to set a definite oscillating
frequency and to tune the resonant circuits. These may include many different types of slug tuned
inductors. Slug tuned inductors are widely used in RF and IF stages of super heterodyne radio
receivers. Tuned inductors are also used as the tank coil in the final RF power amplifiers.
construction of IF and RF tuning coils. e.g. is an rf coil for the radio broadcast band of 535 KHz to
1605 kHz may have an inductance L of 250 H, or 0.250 mH.
Iron-core inductors for the 60-Hz power line and for audio frequencies
have inductance values of about 1 to 25 H. Iron-core inductors are
commonly used for low frequency applications including Audio
equipment, Industrial power supplies, Power conditioning, Inverter
systems, and Rapid transit.
Incremental Current - is the DC current through the inductor that causes a drop in inductance
by 5% as compared to inductance at the initial zero DC bias, beyond it, inductance starts dropping
significantly at a rate depending upon the ferromagnetic material of the core and the shape of the
inductor core, but for powdered iron cores the drop remains linear and non-linear for ferrite cores.
Maximum DC Resistance - is the maximum resistance offered by the coil of the inductor with
DC current, considered as unwanted resistance of the inductor needed to be minimized for energy
efficiency of an inductor in a given circuit.
Quality Factor (Q Factor) - is the ratio of inductive reactance to the effective resistance that
depicts operating loss of the inductor, which is always indicated in datasheets for a given test
frequency. The higher the quality factor, the more energy-efficient is the inductor.
Self-Resonant Frequency (SFR) - is a certain frequency where the inductor does not show any
effect of inductance; instead, behaves like high impedance pure resistance, and some distributed
capacitance is created due to the number of coil’s turn in inductors, thus the capacitance and
inductance of an inductor become equal, and they cancel each other. At SFR, the quality factor
of the inductor drops to zero. The distributed capacitance is modeled as a parallel capacitance to
the pure inductance of the inductor.
Temperature Coefficient of Inductance - indicates the rate of change in the inductance of the
inductor per unit centigrade, expressed in “Parts Per Million” change per Centigrade (PPM/°C).
The rate is generally positive until the inductor gets hot enough at saturation current and turn
negative beyond it. The rate remains linear for powdered iron cores, while generally non-linear
with significant changes for ferrite cores. Inductance is shown in datasheets in reference to current
rather than temperature, therefore, the graphical curve of “typical inductance versus current
characteristics” should be examined in a datasheet for any effects of temperature on the
inductance.
Temperature Coefficient of Resistance - indicates the rate of change of DC resistance of the
inductor, expressed in PPM/°C, which is always positive. The DC resistance of the inductor also
changes with temperature but never exceed the maximum DC resistance specified for the
inductor until the inductor gets damaged.
Electromagnetic Interference - refers to the magnetic field radiated out from the inductor which
can produce additive or subtractive mutual inductance with other inductors in the vicinity or may
lead to unwanted interference to other magnetically sensitive components of the circuit like the
Integrated Circuits.
Impedance - Impedance is the effective resistance of inductor to alternating current which is the
combination of DC resistance and the reactance (inductive reactance and distributed capacitive
reactance) of the inductor.
Coupled magnetic fluxes between a stationary and a rotating inductor coil is used to produce
mechanical torque in induction motors.
Inductors are used as an energy storage device in switch-mode power supplies.
Variable inductors use an adjustable core, which is usually a ferrite core or powdered iron core,
that can change the inductance.
Inductance are found in transmission cables that determine the characteristic impedance in a
cable.
Inductance are also seen in microphone and computer network cables that use special cables
to reduce it.
Long power transmission lines also show inductance which limits the AC power that can be
sent through them.