Heavy Metal Analyzer

HMA Series

Overseas Sales Division

Nov. 18th, 2019

What is Heavy Metal Pollution?

● Industry-caused environmental pollution

by wastewater and stack gas from factories
and mines.
● Actualized in case redevelopment of old
industrial area.
● Japanese Ministry of Environment specified
Cadmium, Lead, Chromium, Arsenic,
Mercury etc.
Disease caused
by Heavy Metal Pollution
● Acute intoxication (fever, stomach ache,
vomiting, diarrhea, anemia, neuralgia)
● Cirrhosis, brain damage, kidney damage
● Abnormal calcium metabolism
("Itai-itai" disease)
● Mucosal membrain damage, lung cancer
● Central nerve disease
("Minamata" disease)
 Targeted Market
of
Heavy Metal Analyzer

● Targets
- Monitoring wastewater from factories
- Monitoring environmental water quality
● Major heavy metals
- High priority : Pb, Hg, Cd, Cr/Cr6+
- Other parameters : Ni, Cu, Zn, Mn

4
 What type of analyzers are required?
● Surface water
Multi Single · Measure river and lake water
measurement measurement
· Simultaneous and multiple parameters
· Low concentration measurement
Factory Factory · High accuracy is required
· High price range
Centra HM HM
WWTP ● Industrial wastewater
lized
Factory in
WWT
factory
· Measure industrial wastewater
P
· Parameters depending on type of facility
Factory
· Single parameter
· Wide measurement range
· Low price range
 Targeted Factory and
Measurement Parameter
Cr6+
Cu Ni Mn
TCr
Electroplating ○ ○ ○
Mining and smelting ○ ○ ○
Iron and steel ○
Semiconductor ○
Battery ○
Tan and fur machining ○
 What is Measurement principle?
Colorimetric
－HMA Series－

1. Add coloring reagent Metal + Coloring

ion reagent
that selectively reacts to
target ion
2. Coloring reagent reacts
to metal ion and then Metal Coloring
ion reagent
produces paticular color
3. Measure absorbance
Measure absorbance
 How to Measure “Total Metal”?
－HMA Series－
M O M A-
+
H Digestion the sample water with
hydroxides M salts
+ acids, oxidizing agents so that
M O ion M
+
all metal compound to be
oxides complexes dissolved ions.
Digestion
process
M M Measurement data after
+ +
M M M digestion process shows good
+ + +

dissolved ion coloration to lab data

M
+
= Total
coloring reagent
 Features

● High Reliability

● Reduce Maintenance Frequency

● Eco-Friendly

● Stable Measurement
Available for Selling
in Your Country

● Expected big business opportunity

● DKK-TOA promotes the heavy metal

analyzers over the world
 Appendix

I. Main Specifications
II. Configuration
III. Is Measurement “Total”?
Appendix 1

Main Specifications
－HMA Series－
Industrial wastewater
Measurement (Final effluent water)
600 105
object
Cr6+, Total Cr, Cu, Ni, and Mn
Measurement (single-parameter )
parameter
Measurement Colorimetric method
principle Cr6+ 0.01 - 2 mg/L, 0.04-5mg/L
900

TCr 0.1 -10mg/L

Measurement
TCu 0.1 - 3mg/L , 0.5 - 10mg/L
range TNi 0.1 - 3mg/L , 0.4 – 10mg/L
TMn 0.1 - 3mg/L , 0.4-10mg/L
Measurement 30 min to 8 hours (Cr6+)
intervals 50 min to 8 hours (others)
D=255
Signal output DC 4-20mA, Modbus
Appendix 2

Configurations
－HMA Series－
Controller
(Touch panel, DC4-20mA, RS485, etc.)

Digestion unit

Colorimeter
Sample
water
Reaction
Sampling cell Drain tank
pump

Reagent tank (Max 6pcs)

Reagent tank
Appendix 3

Is Measurement “Total”?
－HMA Series－
M O M A-
+
H Competitors products measures
hydroxides salts
only dissolved metal ions
M
+

ion
Measured data without digestion
M O M
+ may have some difference to the
oxides complexes lab data

M
+
≠ Total
coloring reagent