Scribd Logo
Upload

Welcome to Scribd!

  • Born-Oppenheimer Approximation

    Uploaded by

    Sup Fans
    46 views9 pages
    Born-oppenheimer approximation pdf Proof of Born-oppenheimer approximations

    Original Title

    Born-oppenheimer approximation

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    Born-oppenheimer approximation pdf Proof of Born-oppenheimer approximations

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    Download as pdf
    46 views9 pages

    Born-Oppenheimer Approximation

    Uploaded by

    Sup Fans
    Born-oppenheimer approximation pdf Proof of Born-oppenheimer approximations

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    Download as pdf
    of 9
    2. BORN- OPPENHEIMER APPROXIMATION The. oldeot farmultion of 2m adbebclic. spprmmidn in DM s1ce cchrly gies only « caple + yer cfor QM wer dicated, by Beinn Oppenhemer a 1927. is usekl ever nov to recd! Heim argumest, which es pve ins use foachon fitnulchen , ead, to thes pephrcse “Ker cayomint “in < move melon fram s The moder» fermuletiny vnskees et clone hyw/ He stpercion of entsyy sever s mabey sual dt leds duck tr « systemche adisbdic. expersion 2(a) ORIGINAL FORMULATION : 1. quethn coleud ee eet te by Bowne pesheu v4 engmely col in deme pgs yee 5 he ln yn te cnet he mmdleur ddymn ing mulecdle, in Yer presene of roidh Imai dhe) stall ak die sine tnd oh fal te! cleckate Anand cortiguccton of = CO maleenle aps ace 2 slosdy rmevhe nude , of mas ~ Q4,000 "dbo iver (for He O nucleus), od OR, 000 elector m-ner =) fe te C nucleus). Tous ite cleerl clettrina move se Fotbih_ Latptente dete bet thd we cary to frat ayprmimcion, teed Yer nudes a stchenvy » The Born = Opperbemmer cpprerimcin 1s Ge neet cpproumcien eyead “us. Dh heyn by canstlouy < mare gerre! poten. Suppese_ve her « slow system, wth Dedade QD ae cenenical Weleda, P, ad tis caupledd ty 5 act of Fot-mouing verdes X= C4 y). Toes Mele ti His 5 etaderd snsooneire = compe eh (32) section (1) of Hs discussion o£ slow DM, We nov write He selehen to the Full Herubhnren, 2. HlEO.n> + €/bOxD in the. form (ignerin “he alepedce.) # IFO? = ZZ@O)|~,0x7 se thd Yo Bl) st oo He cocfhsedls in tre expenin & E. Il we pat Be tne depedece im expat, , we have : ~ fae Ege Z(Qwxm) > £ F9w;*) Po Ow, xo) & hid shold be compocd with opt, (33) in sechenr (1). Husever wie receynoe from loshin + (4) List not enly can ve view the cocfheieds BD) < the egpeann cocfiaeds fr the fot yendle- wie -Fuctiot Om (PX) Cin sasligy wrt eG (git) Im sechon (1); we cen she Ginle of dlem ox the adidebe vere furchert of he slor/ vendbles. Let's prisue Lue, by substtining (G) ito (3). Lie ther hive 2AM +VO0 Kw] E@Ipex> = © EQ Ipl0x> wd in He usd vy ve ney mull an the Ie by + En F,0) = ES,() Ths 15 td en epuctan for the sly were -tachen BO). To prceed 13 taschl gut an explett form For He shy vende Heathen Hy (QD). ble wil satune Yok 4m -Grue + (ZB. uo] (2) @) 4) (3) (¢) fe) wy Tt 1s now 5 mcber of single menpulston to stm Hrd the eh. CO cw be the, 20 HE@ BQ) = EG(e) who He eferke Henthuen H*CD) er metre elements HO) = Not the fine! Bam~ Opperiner iby Pale |Par Noha Ud te get ACD) mm Ye fon (1), an bene espe end se mdene elemeds im (4) + SlVe (Be lte>) = £ (Ba %p-iPig OVP) B The simlernty of brut clevelrynet to tit m the chseussin of the adrabclic regime in QM, gtr n Ye leot sector, x obra. Dr the sine wy belorg pe con ao viele Ago) = + Caley + 0) - &(9) wy (” (10) m (ia) (is) (w) o) (1) S cad al of the proviene clyscassien 5% of the physice & such ids In -pleken [Dy tent becdlnd Ipoe!_ le. be red 4 ge r BQ) = x Alor = Im lt * ab p> = A> Etat Uy z “ot et i 2eR 4 REE ele shee Ry oe te swdeer poate, 9, hee, 0, He elediore parrbar, “od” Vi cords in the thd for is syrten ix swithen e 3 Oe Jia be Ra) He sucler een numbor, € te. ckctuaie 2 Vr, . The srye d the Fig is he resuk ak complee eletiete screening elects (4) One sho her the ellche pobdrel sche eo Us (R) el ale label, = (8) + Uy (8) ww (22) (23) (24) (28) (2t) cS thee Voy (R) is simly te stomuclee- unteyscher + QP, e* 222 Wule= 98 i) cod 31 Yor renumdecal sderschun eg (B) _loeke fis" 5 hd bey bg, ba the adisbche etsy levels leely corteined nxbhin these coy selaces = one con nse. them on cclakd [oft otegph Bch pO, [aphth fo | Bite taht Ld but te gege Sdd A, (R)® Tt is cle fin Ye clove Yiek this ence = eomeded A _rotchom af He nuclei crowd exch clher . Fhe, in the exrape of CO, we coe magne ming the O mad He Com < Greut, Ter ye sue smmedtely thd x Bory jphec YO + fd. of a” "fat * pet af de Hemitlerin, ae on (2). be ceardisly winter Ber Ligregica in Her form Lx) = L@+Li@x)+ ho) Lo + Lx) ed ceadlaly we wile the papgele fe the combed fat + stony yorstler (29) mw Ka Goer it) = {dq [Dee a far deep Gs, (30) ‘ a ba \ fo thet) = fDpe eit See Lol9) Fone he an Leo) % on eh Jer Golg) = SDan GOam 6 490057) 3) Hoe sie hte defined < ners ebyert, the Greer frelon Gy (2,1 £9), wid Grn fuck te te fod Vewhler, endboal ate pat gtr) of te slay versbles « Consider 2 diheret wieys ve mubt eychste tas Loot Greer Foucher » depeding on which stden We ux 40 berg Poacher : (a) Suppo ve ty +e culenlele Ge by psd tm He eyeutder Tee hedepllt ‘catmoelt [inl cox LUMA Sook def A Gren faction Bo = wr &8F* ey) (sa) whe Ge ster [p> bdr of fe a de [p> ve eyes & hw se be EA i Te advatye of this yuo it thd hecme Hele) 11 tre-ndlpedeat, se Cin tite: ~ ereplg im tyme of the tre-rdepaded dhoxer ef, , of fe fot Legroer hep l9), wh 9 eben co 4 q procter, Now, in dereleymecte Fenilr trom the discussie of DM in He adjebehic negine , We wate the He ttre evelator «f hoe shder <+ ous + bo) = Ingo (34) shee Ge time olution opercler ie oled Ue = Pie ih fae alge. 49) ) Now Fon the theory af sdisbstia precenes, ve recall hd in the adicbche rose ve co ure, for a mite! side ING OID, ad He subset ste will be: qo) = B lingn> eh Ste Te, (90 Soun + Ge Sl By neg J » (7) whee, = & 9) Ingp ead ve note thes (97) sito Lillenas ftom the single leatdy + z > wd tnqor> « hl & Inga + 7% Ingo] | - 7 = ZT EGO) Sn + 49 CGI ngi>] Imager The farm of ‘he foot Gren Ah, Giller samediolely fem (37) « Steger = im GE kgensa) = bmx ete foyer Ke Jnip IL? 8922 8G nl r7, ) * =o ery ree nr ft sdicbche opastden Ingen7. Ty cllet ve hwe GORng HA) = 2 Arle Shag 7 1 #2

    You might also like