WAT 32 19-12-21 Model B Solutions QP

SEC: JR_*CO-SC Date: 19-12-21
Time: 3 Hrs Max. Marks: 186

19-12-21_JR.IIT_STAR CO-SC (MODEL-B)_JEE ADV_WAT-32_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Heat Transfer: Heat conduction in one
dimension; Elementary concepts of convection and radiation;
Newton’s law of cooling, Blackbody radiation: absorptive and
emissive powers; Kirchhoff’s law; Wien’s displacement law, Stefan’s
law.
PREVIOUS WEEK (20%): First law of Thermodynamics : Isothermal
and adiabatic processes, bulk modulus of gases; Equivalence of heat
and work; First law of thermodynamics and its applications (only for
ideal gases)
CHEMISTRY: PRESENT WEEK (80%): Hyper conjugation, Reactive intermediates,

Strengthof acids
PREVIOUS WEEK (20%): GOC: Electronic effects: Inductive

effect, Resonance, Aromaticity
MATHEMATICS: PRESENT WEEK (80%): VECTORS: Introduction to Vectors,

Addition of Vectors, Linear combination of Vectors, Linearly
independent Vectors, Position Vectors, Collinearity, Coplanarity,
Geometrical problems, Scalar product of two vectors and its
applications
PREVIOUS WEEK (20%): AOD
Narayana IIT Academy 19-12-21_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-32_Q’P
Time: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 5) Questions with Single Correct Choice 3 -1 5 15
Questions with Multiple Correct Choice
Sec – II(Q.N : 6 – 13) 4 -2 8 32
(Partial Marking +1)
Sec – III(Q.N : 14 – 18) Questions with Integer Answer Type 3 0 5 15
Total 18 62
CHEMISTRY:
Sec – II(Q.N : 24 – 31) 4 -2 8 32
Total 18 62
MATHEMATICS:
Sec – II(Q.N : 42 – 49) 4 -2 8 32
Total 18 62
Jr.IIT_*CO SC Page No: 2

PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. A body with an initial temperature 1 is allowed to cool in a surrounding which is at a
constant temperature of  0 ( 0  i ) . Assume that Newton’s law of cooling is obeyed.
Let k=constant. The temperature of the body after time t is best expressed by
A) ( i   0 ) e  kt B) (i   0 ) ln(kt ) C)  0  ( i   0 ) e  kt D) i e  kt   0
2. The three rods of same material and cross-sectional area from the sides of a triangle
3T
ABC. The points A, B and C are maintained at temperature T, T 2 and
( 2  1)
respectively. Assuming that only heat conducting takes place and the system is in
steady state, the angle at B is (The temperature difference per unit length along CB
and CA is equal)
A) 300 B) 450 C) 600 D) 900
3. A rod of uniform cross section is heated at temperature t0 at a point which is at n1

times of its length (n1  1) from its one end in steady state. The temperature at this end
is t1 , and at other end is t2 . Rate of vaporisation of water at either end of the rod is
same. The end at which is temperature is t2 is how much more far away than the other
end from the point at which the rod is heated.
n1 (t0  t2 ) n1 (t0  t1 ) 2n1t0 n1 (t1  t2 )

A) B) C) D)
t0  t1 t0  t 2 t0  t 2 t0  t1

4. Consider 0.01 moles of an ideal diatomic gas is enclosed in an adiabatic cylinder of
cross–sectional area A  10 4 m 2 . In the arrangement shown, a block of mass M = 0.8kg
is placed on a horizontal support, and another block of mass m = 1kg is suspended
from a spring of stiffness constant k = 16 N/m. Initially, the spring is relaxed, and the
volume of the gas is V  1.4  104 m3 . Then the angular frequency (in rad s 1 ) of the
suspended system is
A) 4 B) 6 C) 8 D) 12
5. 0.5 mole of an ideal gas at constant temperature 27 0 C kept inside a cylinder of length
L and cross-sectional area A closed by massless piston. The cylinder is attached with a
conducting rod of length L cross-section area   m 2 and thermal conductivity k whose

1
9  
other end is maintained at 00 C . If piston is moved such that rate of heat flow through
L
the conducting rod is constant, then the velocity of piston when it is a height from
2
the bottom of cylinder is (Neglect any kind of heat loss from system)
k k k k
A) B) C) D)
50 R 100 R 110 R 90 R

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
6. The figure shows the P-V plot of an ideal gas taken through a cycle ABCDA. The part
ABC is a semi-circle and CDA is half of an ellipse. Then,
P
A
3
2
D B
1
C
0
1 2 3 V
A) the process during the path A  B is isothermal

B) heat flows out of the gas during the path B  C  D
C) work done during the path A  B  C is zero
D) positive work is done by the gas in the cycle ABCDA
7. A process is shown in the diagram. Which of the following curves may represent the
same process? (B→C is isothermal)
A) B)
C) D)

8. One mole of an ideal monatomic gas has initial temperature T0, is made to go
through the cycle abca shown in Figure. If U denotes the internal energy, then
choose the correct alternative
A) Uc  Ub  Ua B) U c  U b  3RT0
9RT0
C) Uc  Ua 
3RT0
D) U b  U a 
2 2
9. When we consider convection with radiation in Newton’s law of cooling while
temperature of the object in consideration is slightly higher than the environment
temperature. Correct statements about rate of heat loss are
A)Directly proportional to emissivity
B)Directly proportional to Stefan’s constant
C)Directly proportional to surface area
D)Directly proportional to temperature difference of body and room.
10. A100cmlongcylindricalflaskwith inner and outerdiameter2cmand

4cmrespectivelyis completely filled with ice as shown in the figure. The constant
temperature outside the flask is 40oC. Then (Thermal conductivity of the flask is
0.693W / m 0C , Lice  80 cal / g & ln2  0.693 )

A)Rate of heat flow from outside to the flask is 80 J / s

B)The rate at which ice melts is kg / s
4200
C) The rate at which ice melts is 100 kg / s
D)Rate of heat flow from outside to flask is 40 J / s
11. A hot body emits radiation which is maximum intensity at frequency m . If the
temperature of the body is doubled
A) The maximum intensity radiation will be at frequency 2 m
m
B) The maximum intensity radiation will be at frequency
2
C) The total emitted energy per second will increase by a factor of 16
D) The total emitted energy per second will increase by a factor of 4 and maximum
2
intensity radiation will be at frequency m 2 .
12. Two bodies A and B have thermal emissivities of 0.01 and 0.81 respectively. The
outer surface areas of the two bodies are the same. The two bodies emit total radiant
power at the same rate. The wavelength B corresponding to maximum spectral
radiancy in the radiation from B is shifted from the wavelength corresponding to
maximum spectral radiancy in the radiation from A , by 1.00  m . If the temperature of
A is 5802 K
A)The temperature of B is 1934 K
B) B  1.5 m
C) The temperature of B is 11604 K
D) The temperature of B is 2901 K

13. Two ends of a conducting rod of varying cross section are maintained at 2000 C and
00 C respectively. In steady state
200 100
A B C D
x
x
A) Temperature difference across AB and CD are equal if the rod is homogeneous.
B) Temperature difference across AB is greater than that of across CD if the rod is

homogeneous.
C) Temperature difference across AB is less than that of across CD if the rod is

homogeneous .
D) Temperature difference may be equal or different depending on the thermal

conductivity of the rod
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
14. Two spherical stars A and B emit blackbody radiation. The radius of A is 400 times
 
that of B and A emits 104 times the power emitted from B. the ratio  A  of their
 B 
wavelengths  A and  B at which the peaks occur in their respective radiation curves is
15. A metal is heated in furnace where a sensor is kept above the metal surface to read the
P
power radiated (P) by the metal. The sensor has a scale that displays log 2   , where
 P0 
P0 is constant. When the metal surface is at a temperature of 487 0 C , the sensor shows a
value 1. Assume that the emissivity of the metallic surface remains constant. Then the
value displayed by the sensor when the temperature of the metal surface is raised to
2767 0 C is

16. The ends Q and R of two thin wires, PQ and RS, are soldered (joined) together.
Initially, each of the wire has a length of 1m at 100 C . Now, the end P is maintained at
100 C , while the end S is heated and maintained at 400 0 C . The system is thermally
insulated from its surroundings. If the thermal conductivity of wire PQ is twice that of
the wire RS and the coefficient of linear thermal expansion of PQ is 1.2  105 K 1 , the
change in length of the wire PQ is(in mm)
17. Two conducting cylinders of equal length but different radii are connected in series
between two heat baths kept at temperatures T1  300 K and T2  100 K , as shown in the
figure. The radius of the bigger cylinder is twice that of the smaller one and the
thermal conductivities of the materials of the smaller and the larger cylinders are K1
and K 2 , respectively. If the temperature at the junction of the cylinders in the steady
K1
state is 200K, then 
K2
18. Water of mass ‘m’ and specific heat capacity 'S' is kept inside a thick spherical shell of
inner and outer radii ‘a’ and ‘2a’ as shown. Thermal conductivity of the shell varies as
C
k where 'C' is a constant and ‘r’ is the distance from the centre. The surrounding
r3
temperature is  0  300 C . If the time required to decrease the temperature of water from
 mSa 2 l n3 
60 C to 40 C is t  n 
0 0
 . The value of n is
 8 C 

CHEMISTRY Max Marks: 62
SECTION – I
19. The strongest acid is
A) HC  CH B) C6 H 6 C) C2 H 6 D) CH 3OH
20. The hyper conjugative of tert-butyl cation and 2-butene, respectively, are due to
A)   p and    * electron delocalization
B)    * and    electron delocalization
C)   p (filled)  * and    * electron delocalization
D) p(filled)  * and    * electron delocalization
21. Arrange the carbanions,
 CH3 3 C, CCl3 ,  CH3 2 C H , C6 H5CH 2

, in order of their decreasing stability
C6 H5CH 2  CCl3   CH3 2 C   CH3 2 CH

A)
 CH3 2 CH  CCl3  C6 H5CH 2   CH3 3 C

B)
CCl3  C6 H5CH 2   CH3 2 CH   CH3 3 C

C)
 CH3 3 C   CH3 2 CH  C6 H5  CH 2  CCl3

D)
22. The correct order of the following is
OH
OH COOH COOH
Cl
CH 3
(I) (II) (III) (IV)
A) IV>III>I>II B) III>IV>II>I C) II>III>IV>I D) II>II>I>IV

23. In which of the following pairs, former is more stable than later?
A) B)
C) D) Ph3C  ,  CH 3 3 C 
SECTION – II
cases
24. Which of the following carbocation (s) undergo favourable rearrangement into more
stable one?
+
O O
A) + B)
+
C) O D)
25. Predict the major product in the following reaction
HO OH
1 mole NaOH
O2 N OH
OH
HO OH
OH HO
O2 N OH O2 N OH
A) OH OH B) O

HO O HO OH
O2 N OH O2 N O
C) OH D) OH
26. Among the following statements which one is/are correct
A) Cyanic acid  H  O  C  N  and isocyanic acid  H  N  C  O  are not separable in

H 2O
B) Ka of formic acid is higher than IInd K a  K a  of oxalic acid

2
C) Acids which are weaker than H 2CO3 will liberate CO2 on treatment with NaHCO3
D) In case of dicarboxylic acid K a (Ist dissociation), is always greater than K a (IInd

1 2
dissociation)
27. Which of the following pairs has Ist having more resonance energy than IInd?
A)
NH
B) NH
C)
D) O O

28. Among the following orbital interactions which represents hyper-conjugation
interactions>
PZ

H

H
C
C H H
H
H H
H
Free radical
CH 3  CH 2  CH3  CH 2 
A) B)
H 
+ H
C CH C
H H
 

 2  CH  CH 2 
H C
 
C) D)
29. Which one of the following pairs of structures represent the phenomenon of
resonance?
O O

H 2C  CH  C  H ; C H 2  CH  C  H
A)
 
B) CH 2CH  C H Cl; C H 2  CH  CH  Cl
O O
 CH3 2 CH  C  O ;  CH3 2 CH  C  O
C)
O
O
CH 3  CH 2  C  CH 3 ; CH 3  CH  C  CH 3
D)

30. Correct order of stability of intermediate is/are
>
>
A) B)
0 0
CH 2 CH 2
<
CH 3
CCl3  CF3 CH 3
C) D)
31. Which of the given statement is/are not correct?
A) H H is less acidic than CH 2  CH  CH 2  CH  CH 2
 
B) CH 3  N Me3 is more acidic than CH 3  P Me3
NC CN
H H H H
C) is more acidic than
O O O
OH OH
D) HO is less acidic than HO

SECTION – III
32. How many of the following are more acidic than bezoicacid?
COOH
COOH
COOH
OH
HO OH
COOH COOH OH
CH 3
CH 3
NO2
OH COOH
COOH
COOH
COOH
OCH 3
OCH 3
SO3 H
33. The total number of contributing structures showing hyperconjugation for the
following carbocation is
CH 3

34. How many among the given will undergo carbocations rearrangement?
CH 3
, H 3C  CH  C  0 , H 3C  N  CH  CH  CH 2  CH 3
,
CH 3 CH 3
CH 3
CH 3
, H 3C  C  CH  O  CH 3
CH 3
35. Indicate the number of species which are destabilised by delocalisation
(I) (II) (III)
(IV) (V) (VI)
36. The number of following compounds more acidic than phenol

OH
OH OH OH OH
CH 3 OH
Cl
NO2
OH OH OH OH
OH
OCH 3
OH
OCH 3
Cl
CH  CH  OCH 3 OCH 3

MATHEMATICS Max Marks: 62
SECTION – I
37. a  2i  j  2k, b  6i  2 j  3k and unit vector in the direction of angle bisector of
a & b is xi  yi  zk then 21 2z  x  y  
A) 0 B) 1 C) -1 D) 2
38. If a  5i  4 j  3k
b  2 i  j  2k
the orthogonal projection of a on b is
A)
6
25

5i  4 j  3k  B)
2
25

2i  j  2k 
C)
4
3

2i  j  2k  
D) 2 5i  4 j  3k 
39. Let us define the length of a vector aiˆ  bjˆ  ckˆ as a  b  c . The definition coincides
with the the usual definition of length of a vector aiˆ  bjˆ  ckˆ if and only if
A)a=b=c=0 B)any two of a,b and c are zero
C)any one of a,b and c is zero D) a+b+c=0
40. If the points i  j, 2i  3j  k, j  k , i  j  xk are coplanar, then the value of x is
A) -1 B) 2 C) 1 D) -2
41. If pth , qth , r th term of a G.P are the positive numbers a,b,c then the angle between the
vectors log a 2i  log b 2 j  log c 2 k & (q  r )i  (r  p ) j  ( p  q )k is
  1
A) B) C) sin 1 D) none of these
3 2 a 2  b2  c2

SECTION – II
cases
42. The vectors xiˆ   x  1 ˆj   x  2  kˆ,  x  3 iˆ   x  4  ˆj   x  5  kˆ and
 x  6  iˆ   x  7  ˆj   x  8 kˆ are coplanar if x is equal to
A)1 B) -3 C) 4 D) 0
43. The sides of parallelogram are 2iˆ  4 ˆj  5kˆ and iˆ  2 ˆj  3kˆ. The unit vector parallel to
one of the diagonal is
1)
7

1 ˆ
3i  6 ˆj  2kˆ  B)
7

1 ˆ
3i  6 ˆj  2kˆ 
C)
1 ˆ
69

i  2 ˆj  8kˆ  D)
1
69

iˆ  2 ˆj  8kˆ 
44. The vector iˆ  xjˆ  3kˆ is rotated through an angle  and is doubled in magnitude. It
now becomes 4iˆ   4 x  2  ˆj  2kˆ. The values of x are
A)1 B)-2/3 C)2 D) 4/3

   
45. If non-zero vectors a and b are equally inclined to coplanar vector c , then c can be
  
 a  b  ba 
A)   a   b B)   a    b
a 2 b ab ab ab
   
 a  b  a b
C)   a  b D)   a    b
a 2 b a 2 b 2a b 2a b
   
46. If unit vectors a and b are inclined at an angle 2 such that a  b  1 and 0     , then
 lies in the interval
A)  0,  / 6  B)  5 / 6,   C)  / 6,  / 2  D)  / 2,5 / 6

     
47. If a and b are non-zero vectors such that a  b  a  2b , then
 2  2
A) 2a.b  b B) a.b  b
 1  1
C)least value of a.b   2 is 2 D) least value of a.b   is 2  1
b 2 b 2
48. Which of the following is/are FALSE?
A) Three coplanar vectors are always linearly dependent
B) Two non collinear vectors are linearly dependent
C) Any four vectors are always linearly dependent in 3-Dimensional space.
D) If three vectors are coplanar then they are collinear
49. If points iˆ  ˆj , iˆ  ˆj and piˆ  qjˆ  rkˆ are collinear, then
A)p=1 B)r=0 C) q  R D) q  1
SECTION – III
 
50. If a and b are any two unit vectors, then find the greatest positive integer in range if
 
3 ab  
 2 a b
2
51. If f  x   x 3  x  1 then the minimum value of f  x  in 1, 4 is
1
52. If the function f  x   x is decreasing in the internal  a,   then the least possible
x
integral value of a is_____
53. If the angle between the curves x 2 y  4 and y  x 2  4   8 is '  ' then 6 tan  
54. Let f ( x) be a thrice differentiable function  a, b and a  1   2   3   4   5  b and
f ( a )  f (b)  2, f (1 )  f ( 3 )  3, f ( 2 )  f ( 4 )  3, f ( 5 )  1, then what is the
minimum number of roots of the equation f ( x ) f "'( x )  f '( x ) f "( x )  0 for x   a, b ?

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SEC: JR_*CO-SC Date: 19-12-21

Time: 3 Hrs Max. Marks: 186

CHEMISTRY: PRESENT WEEK (80%): Hyper conjugation, Reactive intermediates,

PREVIOUS WEEK (20%): GOC: Electronic effects: Inductive

MATHEMATICS: PRESENT WEEK (80%): VECTORS: Introduction to Vectors,

Jr.IIT_*CO SC Page No: 2

A) 300 B) 450 C) 600 D) 900

3. A rod of uniform cross section is heated at temperature t0 at a point which is at n1

n1 (t0  t2 ) n1 (t0  t1 ) 2n1t0 n1 (t1  t2 )

Jr.IIT_*CO SC Page No: 3

conducting rod of length L cross-section area   m 2 and thermal conductivity k whose

Jr.IIT_*CO SC Page No: 4

A) the process during the path A  B is isothermal

Jr.IIT_*CO SC Page No: 5

A)Directly proportional to emissivity

B)Directly proportional to Stefan’s constant

C)Directly proportional to surface area

D)Directly proportional to temperature difference of body and room.

10. A100cmlongcylindricalflaskwith inner and outerdiameter2cmand

Jr.IIT_*CO SC Page No: 6

C) The rate at which ice melts is 100 kg / s

D)Rate of heat flow from outside to flask is 40 J / s

A) The maximum intensity radiation will be at frequency 2 m

C) The total emitted energy per second will increase by a factor of 16

power at the same rate. The wavelength B corresponding to maximum spectral

radiancy in the radiation from B is shifted from the wavelength corresponding to

maximum spectral radiancy in the radiation from A , by 1.00  m . If the temperature of

A)The temperature of B is 1934 K

C) The temperature of B is 11604 K

D) The temperature of B is 2901 K

Jr.IIT_*CO SC Page No: 7

A) Temperature difference across AB and CD are equal if the rod is homogeneous.

B) Temperature difference across AB is greater than that of across CD if the rod is

C) Temperature difference across AB is less than that of across CD if the rod is

D) Temperature difference may be equal or different depending on the thermal

Jr.IIT_*CO SC Page No: 8

Jr.IIT_*CO SC Page No: 9

 CH3 3 C, CCl3 ,  CH3 2 C H , C6 H5CH 2

C6 H5CH 2  CCl3   CH3 2 C   CH3 2 CH

 CH3 2 CH  CCl3  C6 H5CH 2   CH3 3 C

CCl3  C6 H5CH 2   CH3 2 CH   CH3 3 C

 CH3 3 C   CH3 2 CH  C6 H5  CH 2  CCl3

A) IV>III>I>II B) III>IV>II>I C) II>III>IV>I D) II>II>I>IV

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26. Among the following statements which one is/are correct

A) Cyanic acid  H  O  C  N  and isocyanic acid  H  N  C  O  are not separable in

B) Ka of formic acid is higher than IInd K a  K a  of oxalic acid

D) In case of dicarboxylic acid K a (Ist dissociation), is always greater than K a (IInd

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31. Which of the given statement is/are not correct?

A) H H is less acidic than CH 2  CH  CH 2  CH  CH 2

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(I) (II) (III)

(IV) (V) (VI)

36. The number of following compounds more acidic than phenol

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a & b is xi  yi  zk then 21 2z  x  y  

the orthogonal projection of a on b is

A)a=b=c=0 B)any two of a,b and c are zero

C)any one of a,b and c is zero D) a+b+c=0