Hunan Jianghai Environmental Protection Co.

, Ltd
World famous ammonium chloride manufacturer

SAFETY DAIA SHEET

Version I. 1
Revision Date 10.4.2021
Print Date II. 4.2021

1. PRODUCT AND COMPANY IDENTIFICATION

1.1 Product identifiers

Product name :Ammonium Chloride
Product Number
Brand
CAS-No. :12125-02-9

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses Mixing for formulations,Production of electroplating/Precision
Casting/Chemical Reagents

1.3 Details of the supplier of the safety data sheet

Company Hunan Jianghai Environmental Protection Co.,Ltd
Address No.9, Ziyuan Road,Ningxiang Economic Development Zone,Changsha City,
Hunan Province, China
Telephone + 86-0731-22397837
Fax + 86-0731-22397837

1.4 Emergency telephone number

Emergency Phone # + 86-0731-22397837

1.5 Reach Registration No : 01-2119489385-24-0052

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity - oral: Acute Tox. 4 (Hazard statement: H302: Harmful if swallowed.)
Serious damage/eye irritation:Skin corrosion (Category 1B), H314
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 GHS Label elements, including precautionary statements
Pictogram

Signal word Warning

Hazard statement(S)
H302 Harmful if swallowed
zH319 Causes serious eye irritation.
Precautionary statement(s)

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 Prevention Wash skin thoroughly after handling.
P264 Do not eat, drink or smoke when using this product.
P270 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P280

Response IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell：

P301 + P312 '
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P330 Rinse mouth.
P337+P313 Storage P403 IF eye irritation persists: Get medical advice/attention.
P233
P410 + P403 Store in a well-ventilated place.
Disposal Keep container tightly closed.
P501 Protect from sunlight. Store in a well-ventilated place.

Dispose of contents/container in accordance with local/national

regulation.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substance

Ingredient name CAS NO Content (%)

EINECS No
Ammonium Chloride 12125-02-9 >99.0
235-186-4

Note : The figures shown above are not the specifications of the product. Components contributing to the
hazard
Not contain PBT/vPvB, REACH SVHC listed ingredient
Not contain CMR, REACH SVHC listed ingredient
Not contain Health, REACH SVHC listed ingredient
Not contain Environ, REACH SVHC listed ingredient

4・ FIRST AID MEASURES

4.1 Description of first aid measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an
unconscious person.Get medical attention.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and
shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids
occasionally. Get medical attention.

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4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or
in section 11

4.3 Indication of any immediate medical attention and special treatment needed
No data available

5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media
Not considered to be a fire hazard.

5.2 Special hazards arising from the substance or mixture

At fire temperatures ammonium chloride begins to corrode metals and may dissociate into ammonia and
hydrogen chloride. Mixtures of about 16% to 25% (by volume) ammonia gas in air are flammable.
5.3 Advice for firefighters
Specific fire-fighting measures
Use any means suitable for extinguishing surrounding fire. Water spray may be used to keep fire exposed
containers cool.
Special protective equipment and precautions for fire-fighters
Wear fire/flame resistant/retardant clothing.
Wear protective gloves/protective clothing/eye protection/face protection.
Firefighters should wear self-contained breathing apparatus with full face peace operated

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment.
For personal protection see section 8.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid
dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in
excess of reportable quantities. The toll free number for the US Coast Guard National Response Center
is (800) 424-8802.

6.4 Reference to other sections

For disposal see section 13.

7. Handling and storage

7.1 Precautions for safe handling
Preventive measures
(Exposure Control for handling personnel)
Avoid contact with skin and eyes.
Avoid breathing^dust.
(Protective measures against fire and explosion) The substance does not burn and does not explode
(Exhaust/ventilator)

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 Exhaust/ventilator should be available.
Safety Measures
Wear protective gloves, protective clothing or face protection.
Avoid dust. Light unloading during handling to prevent packaging damage. Equipped with leakage emergency
handling equipment.
Any incompatibilities
Avoid contact with acids and bases.
Advice on general occupational hygiene
Wash contaminated parts thoroughly after handling.
Wash contaminated clothing before reuse.
Wash hands thoroughly after handling.
7.2 Storage
Conditions for safe storage
Store in a well-ventilated place. Keep container tightly closed.
Protect from sunlight. Store in a well-ventilated place.
Avoid contact with acids and bases. Special
Be careful not to mix with ammonium nitrate and potassium chlorate. Light unloading during handling to
prevent packaging damage. Equipped with leakage emergency handling equipment. Empty containers may residue
harmful substances

8. Exposure controls/personal protection

8.1 Control parameters

3
PC-TWA (mg/m ) : 10
3
PC-STEL (mg/m ) : 20 (ACGIH)
8.2 Exposure controls
Appropriate engineering controls
Washing facilities should be available.
Individual protection measures
Respiratory protection
When the concentration in the air exceeds the standard, wear a self-suction filter gas mask (half mask).
Wear an air respirator during emergency rescue or evacuation.
Hand protection
Wear protective gloves. Recommended material(s): impermeable or chemical resistant rubber
Eye protection
Wear safety glasses with side-shields or chemical safety goggle.
Skin and body protection
Wear protective clothing.
After work, shower and change. Pay attention to personal hygiene

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Physical state
Odor
Boiling point or initial boiling
point Melting point/Freezing point
Flammability (gases, liquids and solids): Non flammable
Auto-ignition temperature
Explosive properties
Density and/or relative density
Water solubility
:Colorless crystals, crystalline masses or white granular
powder. :odorlessness
:Date waiving. The substance decomposes before boiling
:No melting, sublimation at 338°C (decomposition).
:According to a study performed according to EC A. 16 guidelines,
ammoniumchloride is not autoflammable up to the highest tested
temperature, 400 degrees Celsius.
:Non explosive
3
:Density at 20°C is 1.5 q/cm
:Water solubility at 20°C >= 273 g/L water solubility at 25°C
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 >=283 g/L
Dissociation constant :pKa at 25 degrees C: 9.25

10, Stability and Reactivity

10..1 Chemical stability

Stable

10.2 Polymerization hazards:

non-polymerization

10.3 Incompatible materials

acid, base, lead, silver

10.4 Combustion (decomposition) products:

hydrogen chloride, nitrogen oxides

11. Toxicological Information

11.1 Information on toxicological effects
Acute toxicity data is not available.
Based on reliable data with ammonium chloride the acute oral toxicity in rats was determined to have an
LD50 of 1410 mg/kg bw. The acute dermal toxicity study showed no effects at 2000 mg/kg bw, LD50 >2000 mg/kg
bw.
11.2 Irritant properties
Skin irritation / corrosion: not irritating
Eye irritation: irritating
11.3 Allergenic and sensitizing effects
not sensitizing
11.4 Mutagenic effects data is not available.
11.5 Genetic toxicity: negative
Carcinogenic effects data is not available.
Teratogenic effects data is not available.
Reproductive toxicity data is not available.
STOT
STOT-single exposure data is not available.
STOT-repeated exposure data is not available.
Aspiration hazard data is not available.

12. Ecological Information

12.1 Ecotoxicity
Aquatic toxicity

12.1.1 Short-term toxicity to fish

LC50 for freshwater fish: 209 mg/L
LC50 for marine water fish: 174 mg/L

12.1.2 Long-term toxicity to fish

EC10/LC10 or NOEC for freshwater fish: 11.8 mg/L
EC10/LC10 or NOEC for marine water fish: 8 mg/L

12.1.3 Short-term toxicity to aquatic invertebrates

EC50/LC50 for freshwater invertebrates: 101 mg/L

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12.1.4 Long-term toxicity to aquatic invertebrates
EC10/LC10 or NOEC for freshwater invertebrates: 14.6 mg/L

12.1.5 Algae and aquatic plants

EC50/LC50 for freshwater algae: 1300 mg/L
EC50/LC50 for marine water algae: 90.4 mg/L
EC10/LC10 or NOEC for marine water algae: 26.8 mg/L

12.2 Persistence and degradability

12.2.1 Abiotic degradation

In aqueous solution, ammonium chloride is completely dissociated into the ammonium ion (NH4+) and the chloride
anion (CI-). Hydrolysis of ammonium chloride does not occur.
12.2.2 Biotic degradation
Studies do not need to be conducted since the substance is inorganic (Annex VII REACH)

12.3 Bioaccumulative potential

Simple inorganic salts with high aqueous solubility will exist in a dissociated form in an aqueous solution.
Such a substance has a low potential for bioaccumulation.
12.4 Mobility in soil
Nitrate is not bound to the soil and will follow water movements.

13. Disposal considerations

13.1 Waste treatment methods
Avoid release to the environment (- if this is not the intended use).
Dispose of contents/container in accordance with local/national regulation.
If possible, return the container to the supplier for recycling.
If possible, keep the warning label and SDS, comply with any notice of the product.

14. Transport Information

14.1 UN number
Not Applicable

14.2 IMDG
Hazards identification： None
Suggestion according to IMO IMDG： The substance is not subject to IMO IMDG code Packaging requirements：
None

14.3
IATA
Hazards identification： None
Suggestion according to IATA DGR： The substance is not subject to IMO IMDG code Packaging requirements：
None

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Other
information is not available.
Other regulatory information
We are not able to check up the regulatory information with regard to the substances in

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 your country or region, therefore, we request this matter would be filled by your responsibility.

16. Other information

GHS classification and labelling
Hazard statement(s)
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
Reference Book
Globally Harmonized System of classification and labelling of chemicals, (6th ed., 2015), UN Recommendations
on the TRANSPORT OF DANGEROUS GOODS 20th edit., 2017 UN IMO International Maritime Dangerous Goods Code
(2018 Edition) IATA Dangerous Goods Regulations(DGR) (62nd Edition) 2019 CH EMICAL SAFETY REPORT 2010-09-24
CSR-PI-5.2.6
General Disclaimer/Further information
Copyright 2021 Hunan Jianghai Environmental Protection Co.,Ltd.
License granted to make unlimited paper copies for
internal use only. The above information is believed to be correct but does not purport to be all inclusivea
nd shall be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product.ln the case of special handling, please make adequate
countermeasure to maintain your safety.

Version: 1.1 Revision Date: 10.4.2021 Print Date： 11.4.2021

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