Diagrama de composicion

P1=X1*Pº1
P2=X2*Pº2 Pº1= 344
PT=P1+P2 Pº2= 512
Y1=P1/PT r1= 1
Y2=P2/PT r2= 1
a1=x1r1
a2=x2r2
IDEAL
X1 X2 P1 P2 PT Y1 Y2 a1
1 0 344 0 344 1 0 1
0.8 0.2 275.2 102.4 377.6 0.72881356 0.27118644 0.8
0.55 0.45 189.2 230.4 419.6 0.45090562 0.54909438 0.55
0.33 0.67 113.52 343.04 456.56 0.24864202 0.75135798 0.33
0.17 0.83 58.48 424.96 483.44 0.12096641 0.87903359 0.17
0 1 0 512 512 0 1 0

Ideal Real IDEAL

P1 P2 P1 P2 600
344 0 344 0 500
275.2 102.4 291 272
400
189.2 230.4 250 390
300
113.52 343.04 217 438
200
58.48 424.96 18 465
100
0 512 0 512
0
1 2 3 4 5 6

1 0.8 0.55 0.33 0.17 0 0 0.2 0.45 0.67 0.83 1

1 0.8 0.55 0.33 0.17 0

ΔG=n1*RT*InX1+n2*RT*InX2
Δs=-(n1*R*InX1+n2*R*InX2)
ΔH=0
 REAL
IDEAL-REAL
a2 r1 r2 p1 p2 pt 700
600
0 1 0 344 0 344 500
0.2 1.05741279 2.65625 291 272 563 400
300
0.45 1.32135307 1.69270833 250 390 640 200
0.67 1.91155743 1.27681903 217 438 655 100
0.83 0.30779754 1.09422063 18 465 483 0
1 2 3 4
1 0 1 0 512 512
1 0.8 0.55 0.33 0.17 0 0 0.2
1 0.8 0.55 0.33 0.17 0 1 0.8
EAL REAL 0 0.2 0.45 0.67 0.83 1 1 0.8

700
600
500
400
300
200
100
0
4 5 6 1 2 3 4 5 6

0 0.2 0.45 0.67 0.83 1 1 0.8 0.55 0.33 0.17 0 0 0.2 0.45 0.67 0.83 1
1 0.8 0.55 0.33 0.17 0
 IDEAL-REAL

2 3 4 5 6

1 0.8 0.55 0.33 0.17 0 0 0.2 0.45 0.67 0.83 1

1 0.8 0.55 0.33 0.17 0 1 0.8 0.55 0.33 0.17 0
0 0.2 0.45 0.67 0.83 1 1 0.8 0.55 0.33 0.17 0
Diagrama de composicion
P1=X1*Pº1
P2=X2*Pº2 Pº1= 1177.7
PT=P1+P2 Pº2= 233.33
Y1=P1/PT
Y2=P2/PT

1400

1200
X1 X2 P1 P2 PT Y1 Y2
0 1 0 233.33 233.33 0 1 1000

0.2 0.8 235.54 186.664 422.204 0.55788197 0.44211803 800

0.4 0.6 471.08 139.998 611.078 0.77089995 0.22910005
600
0.6 0.4 706.62 93.332 799.952 0.883328 0.116672
0.8 0.2 942.16 46.666 988.826 0.95280666 0.04719334 400
1 0 1177.7 0 1177.7 1 0
200

0
1 2
 Chart Title
1400

1200

1000

800

600

400

200

0
1 2 3 4 5 6

P1 P2
Diagrama de composicion
P1=X1*Pº1
P2=X2*Pº2 Pº1= 495.8
PT=P1+P2 Pº2= 934.4
Y1=P1/PT
Y2=P2/PT

X1 X2 P1 P2 PT Y1 Y2
0 1 0 934.4 934.4 0 1
0.2 0.8 99.16 747.52 846.68 0.11711627 0.88288373
0.4 0.6 198.32 560.64 758.96 0.26130494 0.73869506
0.6 0.4 297.48 373.76 671.24 0.44317979 0.55682021
0.8 0.2 396.64 186.88 583.52 0.67973677 0.32026323
1 0 495.8 0 495.8 1 0
Diagrama de composicion
P1=X1*Pº1*r1
P2=X2*Pº2*r2 Pº1= 1177.7 log⁡〖𝑟 1=𝐴_1,2/ 〖 (1+𝑋1/𝑋2∗𝐴_1
PT=P1+P2 Pº2= 233.33
Y1=P1/PT A1,2= 0.89
Y2=P2/PT A2,1= 0.65

X1 X2 r1 r2 P1 P2 PT Y1
0 1 7.76247117 #DIV/0! 0 233.33 233.33 0
0.2 0.8 3.11855388 1.10222688 734.54418 205.746079 940.290259 0.78118876
0.4 0.6 1.75082879 1.40612916 824.780428 196.85527 1021.6357 0.80731363
0.6 0.4 1.24575422 1.9679094 880.274848 183.668921 1063.94377 0.82736971
0.8 0.2 1.05006326 2.91596194 989.327601 136.07628 1125.40388 0.87908672
1 0 #DIV/0! 4.46683592 1177.7 0 1177.7 1
〖𝑟 1=𝐴_1,2/ 〖 (1+𝑋1/𝑋2∗𝐴_1,2/𝐴_2,1 ) 〗 〖^2
log⁡〖𝑟 2=𝐴_2,1/ 〗
(1+𝑋2/𝑋1∗𝐴_2,1/𝐴_1,2 ) 〗 ^2 〗

Y2
1
0.21881124
0.19268637
0.17263029
0.12091328
0