Deodhar Classes

Chemical Kinetics JEE, KVPY

Time :- 30 Min. Total Marks :- 60

1. The velocity constant of a reaction at 290 K was found to be 3.2

x 10-3 . At 300 K it will be

a) 1.28 x 10-2
b) 6.4 x 10-3
c) 9.6 x 10-3
d) 3.2 x 10-4

2. For the reaction 2N2 O5 (g) 4NO2 (g) + O2 (g), if concentration

of NO2 in 100 seconds is increased by 5.2 x 10-3 m. Then rate of
reaction will be

a) 1.3 x 10-5 ms-1

b) 5 x 10-4 ms-1
c) 7.6 x 10-4 ms-1
d) 2 x 10-3 ms-1
e) 2.5 x 10-5 ms-2

3. Decay constant of a reaction is 1.1 x 10-9 / sec, then half life of the
reaction is

a) 1.2 x 108
b) 6.3 x 108
c) 3.3 x 108
d) 2.1 x 108

4. For reaction, A + B products, it is found that the rate of the

reaction is proportional to the concentration of A, but it is
independent of the concentration of B, then
 a) The order of the reaction 2 and molecularity 1
b) Molecularity of the reaction is 2 but order is 1
c) Order is 2 and molecularity is 2
d) Order of the reaction is 2 but molecularity is 0

5. In presence of HCl, sucrose gets hydrolysed into glucose and

fructose. The concentration of sucrose was found to reduce from
0.4 M to 0.2 M in 1 hour and 0.1 M in 2 hours. The order of the
reaction is

a) Zero
b) One
c) Two
d) None of these

6. Which one of the following does not represent Arrhenius

equation?

a) K = Ae-E/RT
𝐸
b) Loge K = loge A – 𝑅𝑡
𝐸
c) Log10 K = log10 A – 2.303𝑅𝑇
d) K = AE-RT

7. Energy of activation of a reactant is reduced by

a) Increased temperature
b) Reduced temperature
c) Reduced pressure
d) Increased pressure

8. Rate constant for a reaction H2 + I2 2 HI is 49, then rate

constant for reaction 2HI H2 + I2 is
 a) 7
1
b)
49
c) 49
d) 21
e) 63

9. The order of a reaction with rate equals is

a) 2
b) 1
1
c) −2
3
d)
2

10 .The time taken for 90% of a first order reaction to complete is

approximately

a) 1.1 times that of half-life

b) 2.2 times that of half-life
c) 3.3 times that of half-life
d) 4.4 times of half-life

11. Reaction 3CIO─ CIO3- + 2CI- occurs in following two step

Then the rate of given reaction = ….

a) K1[CIO-]2
b) K1[CIO-]
c) K2[CIO2-][CIO-]
 d) K2[CIO-]3

12. Which graph show zero activation energy for reaction?

a)

b)

c)

d)
13. The rate law for a reaction between the substances A and B is
given by, rate = K[A]n [B]m . On doubling the concentration of A
and halving the concentration of B, the ratio of the neq rate to
the earlier rate of the reaction will be as

1
a)
2(𝑚+𝑛)
b) (m + n)
c) (n ─ m)
d) 2(n-m)

14. A substance undergoes first order decomposition. The

decomposition follows two parallel first order reaction as

K1 = 1.26 x 10-4 s-1

K1 = 3.8 x 10-5 s-1
The percentage distribution of B and C are a)
75% B and 25% C
b) 80% B and 20% C
c) 60% B and 40% C
d) 76.83% B and 23.17%C

15. A reaction takes place in three steps. The rate constant are
𝐾1𝐾3
K1, K2 and K3. The overall rate constant K = . If E1, E2, and
𝐾2
E3 (energy of activation) are 60,30 and 10 KJ, respectively, the
overall energy of activation is:

a) 40
b) 400
c) 30
d) 60
Question Answer
1 B
2 A
3 B
4 B
5 B
6 D
7 A
8 B
9 B
10 C
11 A
12 C
13 D
14 D
15 A

Type equation here.