Dra.

Nancy Castillo

FORMULARIO DE TERMODINAMICA

� �
= ∆ − ∆ � = � l� + l�
� �

l�
� �
Aplicable para cualquier ∆ = � − ∆ � = � l�
�
+ � l�
�
=
l�

� �
Proceso ∆� = � − ∆ � = � l� − l� Coeficiente
� �
Poli trópico
� =� − ∆ = ∫ ��

PROCESO Q W ECUACION
ISOTERMICO =− LEY DE BOYLE
= l�
= � ∆ = =
= ∆� = = l�
ISOMETRICO LEY DE GAY LUSSAC
= � =∆ =
=
=∞
ISOBARICO LEY DE CHARLES
= � = ∆� = − ∗
=
= = −
= ∆ − ∆�
−
−
=∆ ( )=( ) =[ ]
= −
= =
−
−
= ∗ �−
ADIABATICO − �

]=[ ]
=
[
=
= �
� �−
[ ] =

− −
−
= ∗
=∆ − − ( )=( ) =[ ]
POLITROPICO −
=
= −
=
�
�−
[ ] =

�−
�
[ ]=[ ]
TIPO DE GAS
�( ) ( ) � � � �
− −

MONOATOMICO .
= . = .
�, , , �,
DIATOMICO .
= . = .
, , ,
MAQUINA TERMICA MAQUINA FRIGORIFICA

∑
�=| | =| |
∑

|∑ +|
�=| | =
∑ +

� = [ −| |] ∗
=| �
|
| |−
�

� = [ −| |] ∗
=| � |
| |−
�
| |= | |
| |=| |

= . � , , , −

= �. , ,∆ ,∆ �∆ + −
+

LEY DE DALTON
+
��
= �
T,V son contantes +
Análisis
��
+ = + + �
= + + ……….
=∑ � un componente
�
Fracción masa
=
�
� = + + + = ∑ =
LEY DE AMAGAT

Volúmenes parciales T,V constantes Análisis molar

= + + ……… +
=
Fracción mol
+ + = + +
= + + − = ∑ =
=
Peso molecular promedio o
= = =
=