SECTION-A

fallowing questions are multiple-choice questions with one correct answer. Fach
1 mark. There is no internal choice in this section. question carries
1.The boiling points of alcohols are higher than those of
due to: hydrocarbons of comparable masses
(a) Hydrogen bonding (b) lon - dipole interaction
(c) Dipole- dipole interaction (d) Van der Waal's forces.
2. Which of the following isomer has the highest melting point?
(a) 1,2-dichlorobenzene
(b) 1,3-dichlorobenzene
(c) 1,4-dichlorobenzene
(d) All isomers have same melting points.
3. Which one of the following does not correctly
represent the correct order of the property
indicated against it?
(a) Ti < V <Cr
Mn, increasing number of oxidation states
<

(b) Ti < V < Mn < Cr, increasing second ionisation enthalpy

(c) Ti<V < Cr< Mn, increasing melting point
d Ti <VS* <CF* < Mn*"*, increasing magnetic moment
4. The rate constant ofreaction is 2.0 x 10 molL'sl. The order ofthe reaction is
(a) 0 b) 2
(c) 1 (d) 3
5. Which of the statements about solutions of electrolytes is not correct?
(a) Conductivity of solution depends upon size of ions.
(b) Conductivity depends upon viscosity of solution.
(c) Conductivity does not depend upon solvation of ions present in solution.
(d Conductivity of solution increases with temperature.
13. The absorption maxima of several octahedral complex ions are as follows
S.No Compound a(nm)
ICo(NH,1 475
310
2 ICo(CN),
3 490
Co(H,0),*
The erystal field splitting is maximum for:
(a) [Co(H,O),*
(b) [Co(CN),1*
(c) [Co(NH1*
(d) All the complex ions have the same splitting, A,
14. What is the correct IUPAC name of the given compound?
CH3

CH-CCH-CH
COOH
(a) 2, 2-Dimethylbutanoic acid (b) 2-Carboxyl-2-methylbutane
(c) 2-Ethyl-2-methylpropanoic acid (d) 3-Methylbutane carboxylic acid
 7. The most reactive amine towards dilute hydrochloric acid is

(a) CH-NH2 (b) HC

HCNH

NH2
(c) HCN-CH (d)
HC
8. The formula of the coordination compound "Tetraammineaquachloridocobaltctts
is ) chlr.
() [Co(NH,),(H,O)CIJC (b) [Co(NH),(H,O)CIjCl,
(c) [Co(NH,),(H,O)CijCl, (d) ICo(NH,)4(H,O)CIjCI
9. Reaction of phenol with CCl, and NaOH followed by hydrolysis is likely to give
OH CI
CI 0-H
(a) (b)
C-H

OH OH
CHO -OH
(e) O
10. Benzylamine may be alkylated as shown in the following equation:
CH,CHNH, +R-X cH,CH,NHR
Which of the following alkylhalides is best suited for this reaction through Syl mechanism?
(a) CHBr (b) CH,Br
(c) CH,CH,Br (d) CH Br
11. A carbonyl compound react with HCN to form a cyanohydrin which on hydrolysis formsa
racemic mixture of a-hydroxy acids. The carbonyl compound is
(a) acetone (b) diethyl ketone
(c) acetaldehyde (d) formaldehyde
12. In a
reaction, 2A- Products, the concentration of A decreases from 0.5 mol LD
0.4 mol L in 10 minutes. The rate during this interval will be
(a) 0.005 mol L min (b) 0.007 mol L- min
(c) 0.015 mol L' min (d) 0.105 mol L- min
13. The number of ions produced per formula unit in an aqueous solution of [Colen),1Cl, s
(a) 4 b) 3
(c) 6 (d) 2
The following questions are multiple-choice questions with one correct answer. Each question carries
I mark. There is no internal choice in this section.
1. Lower molecular mas of alcohols are:
(a) miscible in limited amount of water.
(b) miscible in excess of water.
(c) miscible in water in all proportions
(d) immiscible in water.
2. Major product obtained on reaction of 3-Phenyl propene with HBr in presence of organic
peroxide will be

(a) 3-Phenyl-1-bromopropane (b) 1-Phenyl-3-bromopropane

(c) 1-Phenyl-2-bromopropane (d) 3-Phenyl-2-bromopropane
3. Transition elements show magnetic moment due to spin and orbital motion of electrons.
Which of the following metallic ions have almost same spin only magnetic moment?
() Co* (i) Cr*
(ii) Mn2+ (iv) Cr
(a) (i) and (i) b) (i) and (ii)
(c) ) and (iv) (d) (iii) and (iv)
4. In the reaction, A B, the rate of reaction increases two times on increasing the
concentration of A four times, the order of reaction is
(a) 2 (b) 0

)3
5. Which of the
following relationship is correct for A, and A for strong electrolytes?
(a) A-A+ AC (b) A, =A,xC
(c) A= A - VC (d) A, - A - AC

6. Identify the order of reaction, if k = 3 x 10s

(a) First order (b) Pseudo first order
(c) Second order (d) Third order
 SECTION-A
The following questions are multiple-choice questions with one correct answer. Each question carries
1 mark. There is no internal choice in this section.

1. Phenol does not undergo nucleophilie substitution reaction easily due to:

AL (a) acidic nature of phenol.

Alco

(b) partial double bond character of C-OH bond.

(c) partial double bond character of CC bond.
(d) instability of phenoxide ion.
2. Which of the following is a correct statement for C,H Br?
Mo (a) It reacts with metallic Na to give ethane.
H a l o

(b) It gives nitroethane on heating with aqueous solution of AgNO,.

(c) It gives C,H,OH on boiling with alcoholic potash.

(d) It forms diethylthioether on heating with alcoholic KSH.

than binary compound with
3. Among K, Ca, Fe and Zn, the element which can form more one

2D chlorineis
(a) K (b) Ca
(c) Fe (d) Zn

4. In the reaction,
K'wuho

BrOg(aq) +
5Br (ag) +6H 3Br,()+ 3H,0)
of bromide ion as
The rate of appearance of bromine is related to rate of disappearance
d[Br>] 5 d[Br1
d[Bral5 d[Br] (b) 3 dt
(a) dt 3 dt dt

d[Br]3d[Br] (d)
d[Br-3d[Br
(c)
dt dt
=1.33 V EChCr1.36 V
dt 5 dt

5. ECr,oIG
1.51 V
ECC-0.74 V
EMnOz/Mn2+ order of reducing power is
Based on using above data, the correct
< C < Mn* <Cr
(b) Mn< Cl < Cr* < Cr
(a) Cr
MnO, (d) Mn< Cr* < CI< Cr
(c) C<Cr<Cr,0, <

119
 does not show inst.
Which ofthe following options
6.
i n i h y

yi
Consider the
rate
graph given below.
ofreaction at 40th second?
stantanesus
V
Va
V

O 203 40 50

- V-
(a) 50 30 (b) 50- 30

-V V-
(c)
40 30 (d)40-20
7. Which of the following is the weakest Brönsted base?
7.
NH
(a) (b) -H

NH2
(c) (d) CH NH,
d e Which
P Whie ofthe following has highest molar conductivity?
(a) potassium hexacyanoferrate (II) (b) hexaaqua chromium (llI) chloride
()tetraamminedichloridocobalt (III) chloride (d) diamminedichlorido platinum (I)
9. How many alcohols with molecular formula C^H1,O are chiral in nature?
(a) 1 (b) 2
(c) 3 (d) 4
10. Amine that cannot be prepared by Gabriel phthalimide synthesis is
(a) ethylamine (b) aniline
(c) benzylamine (d) isobutylamine
11. Aldol condensation between which
of the following two compounds gives 1,3-diphenyl prop-
2-en-1-one?
(a) Acetaldehyde and benzophenone (6) Acetophenone and benzophenone
C) Acetaldehyde and acetophenone (d) Benzaldehyde and acetophenone
12. The overall order of the two reactions having the rate expression, Rate =k [A]"* [B" and

viRate =k [AJ"*[BJ respectively are

(a) 2, 1/2 (b) 3, 1
(c) 2, -1/2 (d) 4, 2
13. One mole of CrCla. 6H,O compound reacts with excess AgNO,solution to yield two moles
of AgCl (s). The structural formula of the compound is
(a) ICr(H,0),CIjCl2. H,O
b) ICr(H,0),Cl,) 3H,0
(Cr(H,O),Cl,IC1.2HO
d ICr(H,O),jCi,
14. Addition of water to alkynes occurs in acidic medium and in the
presence of Hg ions as a
catalyst. Which of the following products will be formed on addition of water to but-1-yne
under these conditions?
O

(a) CH3-CH2-CH2-C-H (b) CH-CHC-CH

O O O
(c) CH3-CH2-C-OH +
CO02 (d) CH3-C-OH + H-C-H