St.

Bridget’s Convent – Colombo 7

2nd Term Examination – November 2019
Chemistry I
Grade 13 Time – 2hrs
Index number……………………………………

✓ Periodic table is
provided for you. ✓ Universal gas
✓This paper contains 5 constant,
pages.
R= 8.314JK-1mol-1
✓ Answer all questions.

✓Use of calculator is not

allowed. ✓ Avogardro constant
✓Write your index NA= 6.022x 1023mol-1
number in the space
provided in the answer
sheet.
✓Plank’s constant
✓In each of the question
from 1-25, pick one of the h= 6.626 x 10-34Js
alternative form (1), (2),
(3), (4), (5) which is
correct or most
appropriate and mark ✓ velocity of light
your response on the
c= 3 x 108ms-1
answer sheet with a cross
(x).
 St.Bridget’s Convent – Colombo 07
2nd Term Examination – November 2019
Grade 13 Chemistry II Time – 3hrs

1st Te Index number ………………………………………..

✓ Periodic table is provided in the

last page.
For Examiner’s use
✓ Use of calculator is not allowed.

✓Universal gas constant R= 8.314JK-

Part Question Marks
1mol-1 number
✓ Avogardo constant NA= A 1
6.022x1023mol-1 2
Part A – Structured Essay 3
✓ Write the answers in the space 4
provided for you. B 5
✓ Write short answers space 6
provided for you is sufficient to write
your answer.
C 7
Part B- Essay
8
Total
✓Answer all the questions.
%
✓After completing your answer
always attach part B after Part A and
give to the examiner.
1. The mass of 1 mole of Mg is 24g. What is the mass of one Mg atom in grams?
1) 6.022 x 1023 2) 6.022 x 10-23 3) 3.99 x 10-23 4) 3.99 x 1023 5) 1.32 x 1023

2. The following half equation should be used to answer this question.

Cr2O72-(aq) + 14H+(aq) + 6e→ 2Cr3+(aq) + 7H2O(l)

Fe2+(aq) →Fe3+(aq) + e

C2O42-(aq) → 2CO2(g) + 2e

Which of the following represents the correct stoichiometric ratio for the complete reaction
of Iron Oxalate and dichromate(vi) ions?
1) 1 Cr2O72- : 2 FeC2O4 2) 2 Cr2O72- : 1 FeC2O4 3) 3Cr2O72- : 2 FeC2O4
4) 6 Cr2O7 : 1 FeC2O4
2- 5) 1 Cr2O7 : 3 FeC2O4
2-

3. What is the electronic configuration of the atom of the element which is isoelectronic
with H2S?
1) 1s2 2s2 2p6 2) 1s2 2s2 2p6 3s2 3) 1s2 2s2 2p6 3s2 3p2 4) 1s2 2s2 2p6 3s2 3p4
5) 1s2 2s2 2p6 3s2 3p6

4. If the quantum numbers of the outermost electron of an element is (4,0,0,+1/2) the

element is?
1) Na 2) K 3) Li 4) Ca 5) Mg

5. For the complete combustion of 1mol of an organic compound A, 2 mol of O 2 was

required and 2mol CO2 and 2 mol H2O were the only products. The molecular formula of A
is,
1) C2H4O2 2) C2H4O 3) C2H4 4) C2H6 5) CH4O

6. In the Lewis structure of S2O32- ion the oxidation states of S1 and S2 are
O

O S1 O

S2
1) +4, 0 2) +6, +2 3) +2,+3 4) +3,0 5) +6,0

7.The chemical formula of ammonium aquabromidotricyanidohydridoferrate (III)

according to IUPAC rules is?
1) NH4[Fe(H2O)Br(CN)3H] 2) (NH4)2 [Fe Br(CN)3H(H2O)]
3) (NH4)2 [FeBr(CN)3(H2O)] 4) [ NH4Fe (H2O)Br(CN)3H]
5) [(NH4)2FeBr(CN)3H(H2O)]

1
8. Which of the following statement is not true regarding the 3d block elements in the
periodic table.
1) The highest oxidation state of each of th elements Sc, Ti, V, Cr, Mn are equal to the group
number of those elements.
2) V has the highest melting point among 3d elements.
3) In all the cations of the elements 4s orbitals are completely vacant and at the same time
all valence electrons occupy 3d orbitals.
4) Some metallic oxides are amphoteric.
5) The oxo ions of Cr and Mn, support oxidation.

9. Which of the following reactions shows one correct step in the free radical chlorination
of methane.

1) Cl - Cl uv Cl . + Cl. 2) H -CH3 + Cl. → CH3Cl + H. 3) . CH3+ .Cl →CH3Cl

4) H -CCl3 + .Cl → .CCl3 + HCl 5) . Cl + .Cl→Cl2

10. Which of the following properties of the elements of group IV of the periodic table
shows a decrease with increasing relative atomic mass?
1) The first ionization energy 2) The atomic radius 3) Electropositivity
4) The ionic chrarcter of the compounds 5) None of the above.

11. Which one is not isoelectronic?

1) CO 2) O2 3) N2 4) CN- 5)NO+

12. Which ion has the same shape as that of NO3- ion?
1) SO32- 2) ClO3- 3) PO33- 4) BrO3- 5) CO32-

13. Which ion contains a paired electron?

1) Ca2+ 2) Cu2+ 3) K+ 4) Zn2+ 5) Mg2+

14. Which of the following has a negative enthalpy value?

1) Na(s)→Na(g) 2) Na(g) →Na+(g) + e 3) Na+Cl-(s)→Na+(g) +Cl-(g)
4) Cl2(g)→2Cl(g) 5) Cl(g) + e →Cl-(g)

15. The atomic number of Titanium is 22. Which of the following cannot exist as a
compound of Titanium?
1) K3TiF6 2) TiCl3 3) TiO 4) KTiO4 5)TiO2

16. Which of the following pairs of Sulphur compounds have Sulphur in the same oxidation
state?
1) H2S and SCl2 2) H2SO4 and SO3 3) Na2S2O8 and Na2S4O6
4) Na2SO3 and Na2S2O6 5) Na2S2O4 and Na2S4O6

2
17.Y is a liquid which burns with a yellow flame. When it is warmed with dilute acidified
Potassium Permanganate the latter is decolourised. Which of the following could Y be?
1) Ethene 2) propane 3) Hexene 4) Ethane 5) Ethyne

18. X(s) + O2(g)→ XO2(g) ΔH® = -akJ , 2XO(g) + O2(g)→2XO2(g) ΔH®= -bkJ

The standard enthalpy of formation of XO (g) is ?

1) b-2a 2) 2a-b 3) b-2a 4) 2a-b 5) b+2a
2 2

19. The oxidation number of Pt in the following compound isbb[Pt(NH3)2Cl2]

1) +3 2) +1 3) +2 4) +5 5) +4

20. The molecule having the same shape as that of ICl 4- is?
1) SF2 2) CHCl3 3) XeF2 4) XeF4 5) SiCl4

21. IO4- react with I- in acidic medium to give I2 and water. Number of moles of H+ required
for 1 mole of IO4- to react is?
1) 2 2) 3 3) 6 4) 7 5) 8

22. X(s) + conc.HNO3→ NO2(g) + 4H2O(l) + acid

X does not react with water but reacts readily with air. X and acid are?
1) Sulphur and Sulphuric acid 2) Carbon and Carbonic acid
3) Phosphorous and Phosphorous acid 4) Iodine and HIO3 acid
5) Nitrogen and HNO2 acid

23. In the ideal gas equation Pv=nRt, the value of universal gas constant would depend only
on,
1) The mass of the gas 2) The nature of the gas
3) The pressure of the gas 4) The units of measurement
5) The temperature

24. The partial pressure of hydrogen in a flask containing 2.016g of Hydroegen and 16.0g of
Oxygen is,
1) 1/8 of the total pressure 2) ¼ of the total pressure
3) 2/3 of the total pressure 4) 1/6 of the total pressure
5) ½ of the total pressure

25. Which of the following which does not decolourise a solution of OH-/ KMnO4?
1) C3Br6 2) C2H2 3) C2H2Br2 4) C5H10Cl2 5) CH3CHO

26. A compound of a certain S block element on heating evolved brown gas. A small amount
of the solid compound dissolved in water and when concentrated NaOH was added to the
solution white precipitate was observed. The carbonate of the element on heating evolved
a gas, which turned lime water milky. Which of the following is the original compound?
1) Ba(NO3)2 2) LiNO3 3) KNO3 4) LiBr 5) Zn(NO3)2
27. Which of the following pairs of the compounds will have the same boliling point?
1) CH3CH2CH2CH2OH and (CH3)2CHCH2OH 2) CH3(CH2)4CH3 and (CH3)2CHCH(CH3)2

3) CH3 H CH3 CH3 4) CH3 CH3

C=C and C=C CH3 and
H CH3 H H

5) CH3 CH3 CH3

C and C

H Cl CH2Br BrH2C Cl H

28. Which of the following compounds will exhibit both geometrical and optical
isomerism?
1) CHF=CHCH(CH3)2 2) CF2=CHCH(CH3)CH2CH3 3) CHF=CHCH(F)CH3
4) CHF=CHC(F)2CH3 5.)None

29. Which of the ions in the table below would have the largest hydration enthalpy?

Ion Ionic radius/nm Ionic charge

A 0.06 +1
B 0.08 +2
C 0.12 -1
D 0.16 -2
E 0.18 +1

1) A 2) B 3) C 4) D 5) E

29. Which of the following transition metal ion has the maximum number of unpaired d
electrons?
1) Ni2+ 2) Co2+ 3) Mn2+ 4) V2+ 5) Zn2+

30. Which of the following reactions do propanol and butanone have in common.The
formation of
A) A dark red precipitate when boiled with Fehling’s solution
B) Addition compound with HCN
C) Formation of a silver mirror when heated with ammonical silver nitrate
D) Crstalline derivatives on reaction with excess 2,4- DNP solution.

1) A,B 2) C,D 3) A,C 4) B,D 5) A,D

4
Instructions for question 31 to 40 is given below.

(1) (2) (3) (4) (5)

Only (a) and Only (b) and Only © and (d) Only (a) and Only one
(b) are correct (C) are correct are correct (d) are correct response or
any other
number of
responses
31. Which of the following reactions will not occur?
(a) 2Cl-(aq)+ I2(aq)→Cl2(aq)+2I-(aq) (b) 2I-(aq)+ Br2(aq)→I2(aq)+Br2(aq)
( c) Mg2+(aq)+ Cu(s)→Cu2+(aq)+Mg(s) (d) 2Cl-(aq)+Br2(g)→Cl2(aq)+2Br-(aq)

32. Which of the following aqueous solutions of salts will be basic?

(a) KCN (b) BaCO3 (c) RbClO4 (d) Mg(NO3)2

33. Which of the following will give N2 on heating?

(a) NH4NO3 (b) NH4NO2 (c) (NH4)2Cr2O7 (d) (NH4)2C2O4

34. Which of the following systems contain delocalized electrons?

(a) Copper (b) Cyclohexane (c) Graphite (d) Benzene

35. Which of the following is /are required to calculate lattice enthalpy of the hypothetical
compound MgH?
(a) Standard electron affinity of hydrogen (b) First ionization enthalpy of Hydrogen
(c ) Bond energy of Mg-H (d) Standard enthalpy of formation of MgH2

36.Which of the following react/reacts with SO2?

(a) HI(aq) (b) K2CO3(aq) (C) I2(aq) (d) dil HNO3

37. Which of the following reactions are exothermic?

(a) Ca(g)+ e→Ca2+(g)+ 2e (b) O(g) + e→O-(g)
(c )O-(g)+ e→O2-(g) (d) Ca2+(g)+ O2-(g)→CaO(s)

38. Which of the following pairs cn be distinguished using NaOH solution?

(a) ZnCl2 and MgCl2 (b) CuSO4 and FeSO4 (c) AlCl3 and ZnCl2 (d) MgSO4 and CaCl2

39. Which of the following could be used to distinguish C2H5OH and C6H5OH?
(a) Na (b) KOH (c) CH3COOH (d) Anhydrous ZnCl2

40. Which of the following statement/ statements pertaining to the composition of a

solution prepared by dissolving 18g of glucose in 180g of water at 277K is/are true?( molar
masses of glucose and water are 180g/mol and 18g/mol respectively, density of water at
277K is 1.0g/cm3)

(a) The concentration of glucose in the solution is 0.55mol/dm3.

(b) The mole fraction of glucose in the solution is 1/101.
(c ) the mass fraction of glucose in the solution is 0.10 (d) None of the above. 5
Instructions for questions 41-50 are given below.
Response 1st statement
(1) True
(2) True
(3) True
(4) False
(5) False
41. HNO3 cannot act as a base.
42. The hardness of diamond is very much
higher than the hardness of solid CO2.
43. The melting points of alkali metals
decrease down the group.
44. Ionization energy of elements in the
third period of the periodic table shows a
gradual increase.
45. Chlorobenzene on nitration forms ortho
and para nitro compounds.
46. Phenol decolorizes a bromine solution.
47. NH4+ ions have a tetrahedral shape.
48. S cannot act as an oxidizing agent.
49.When NaOH is added to CuSO4 a light
blue precipitate is formed, which is
insoluble in excess NaOH.
50.Aceytelene gives a red precipitate with
ammonical Cuprous Chloride.
6
2nd statement
True and explains the first statement
True does not explain the first statement
False
True
False
HNO3 is an acid.
The C-C bond strength is very much higher
than the C=O bond strength.
The atomic radius of alkali metals increase
down the group.
Ionization energy is that energy required to
remove the last electron from a gaseous
element.
Chlorine and Chlorobenzene activates the
benzene ring.
Phenol is an unsaturated compound.
N does not have lone pair of elelctrons.
Electronegativity of S is relatively low.
Copper Hydroxide is soluble in water.
Aceytelene has an acidic Hydrogen.
 Structured Essay

1.) A)The following parts (i) to (v) are based on the ion [C2H4SNO4]-. It has the following
skeleton.
O

H–O–N–C–C–S-O

H H H O

(i) Draw the most acceptable Lewis structure for this ion.

(ii) Draw four resonance structures for this molecule.(Including the structure drawn in part
(i))

(iii) Based on the Lewis structure drawn in (i) above, state the following regarding the C, N
and S atoms given in the table below.
O
H-O-N-C -C -S-O
1 2

H H H O

N C1 S
i) VESPR Pairs
ii) Electron pair
geometry
iii) Shape around the
atom
iv) Hybridization
1
(iv) Identify the atomic orbitals involved in the formation of the following σ bonds in the
Lewis structure drawn in part (i) above.

i) N-H= N………………………… H……………………………

ii) N-C1= N……………………….. C1………………………….

iii) C1-H= C1………………………. H…………………………..

iv) C2-S= C2………………………. S……………………………

B) Answer the following questions in the space provided.

i) The highest valency shown by element 7, and to get the inert gas electronic arrangement
that element can accept only one electron at room temperature. A2 is non-radioactive solid.
Identify A……………………….

ii) Of the three isoelectronic anions, P3-,S2-, Cl- which ion has the largest
radius………………………………………

iii) The most thermally stable Carbonate among K2CO3, BeCO3, MgCO3
…………………………………………………..

iv) Write the increasing order of the electronegativity of Oxygen atom for the following
NO3-, NO2-, NO2

………………………………………………………………………………………………………………….

v) Out of As, Zn, Bi and Be two elements which shows amphoteric properties
…………………………………..

vi) Write the increasing order of bond angle of NO2+, SO32-, and CO32-
………………………………………………………

C) Select the most appropriate answer and write in the box given below.

i) Species in which the bond angle Cl-Al-Cl is greater than (NH3, CH4, POCl3, XeF2)

ii) Compound that does not have the 3D lattice structure.( Diamond, Graphite, NaCl, Silica)

iii) Species has both ionic bond and covalent bond ( K2SO4, SO3, H3PO4)

iv) The element which has the highest boiling point ( Mn, Cr, Zn ,V) 2
2. a) Chlorine is added to swimming pools as a disinfectant. Then Na 2S2O3 is added to
remove excess of Chlorine which reacts to form SO 42-, Cl- and H+.

i) Write the changes in the oxidation states of S and Cl.

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

ii) Write the balanced equation for the reaction between Cl2 and Na2S2O3.

………………………………………………………………………………………………………………………………………

iii) NaNO3, Al and NaOH when heated liberates a gas which turns moist red litmus blue.
Write the oxidation and reduction half reactions for the above reaction.

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

b) Unlabled four colourless solutions contain H2SO4, Ba(NO3)2, MgSO4 and Na2SO3. These
slutions were named as A, B, C and D and then one of the solutions was mixed with the rest
of the three solutions. The following observations were given as in the chart below.

A B C D
A - White White White
precipitate precipitate precipitate
B White - White
precipitate precipitate
C White White - X
precipitate precipitate
D White Colourless gas x -
precipitate
Identify A,B, C and D.

A…………………………………….. B………………………………………… C…………………………….

D……………………………….

c) In the periodic table a group 2 hydroxide exist as a hydrate M(OH) 2.nH2OOn heating 1.0g
of this hydrate lost 0.542g in the form of steam and it was converted to anhydrous M(OH) 2.
This was further heated and a product with a constant mass was observed.

3
i) This resulted in the anhydrous hydroxide M(OH)2 losing a mass of 0.0689g. Calculate the
value of n.

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………….……………

…………………………………………………………………………………………………………………….…………………

……………………………………………………………………………………………………………….………………………

ii) Calculate the atomic mass of M.

………………………………………………………………………………………………………………………………………

…………………………………………………………………………………………………………..……………………………

…………………………………………………………………………………………………..……………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

3. a)A compound X contains 72.96% Carbon, 5.45% Hydrogen and Oxygen only. The
relative molecular formula mass of X is about 140. Determine the molecular formula of
X.(C=12, H=1,O=16)

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

b) The equation for the complete combustion of sucrose C12H22O11 is

C12H22O11(s) + 12O2(g) → 12CO2(g) + 11H2O(l)

i) Calculate the standard entropy of the system for this combustion using the following
data. 4
ΔSØ C12H22O11(s) = +392.4 Jmol-1K-1

ΔHcØ C12H22O11(s)= -5639.7kJ/mol

ΔSØ 1/2O2(g)= +102.5j=Jmol-1K-1

ΔSØ CO2(g)= +213.6Jmol-1K-1

ΔSØ H2O(l)=+69.9Jmol-1K-1

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

ii) Calculate the standard entropy change of the surrounding for this combustion at 298K.

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

iii) Calculate total standard entropy for the combustion at 298K.

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

iv) State the significance of your answer.

……………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

5
v) State and explain the effort if any if increasing the temperature on ΔSØ surrounding and
total entropy and the extent of the reaction.

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

c) The compound X [Co(NH3)5Br]SO4 is isomeric with the compound Y [Co(NH3)5SO4]Br.

i) What ions will these two isomers yield in solution.

………………………………………………………………………………………………………………………………………

ii) How would you confirm which isomer was which? ( You are required to describe a
simple test for each isomer.

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

………………………………………………………………………………………………………………………………………

iii) What is the (I) Oxidation state, (II) Coordination number of Cobalt in each complex ion.

Complex compound Oxidation number Coordination number

X
Y
iv) Write the names of the ligands in each complex ion.

……………………………………………………………………………………………………………………………………….

4.a) X is an organic compound containing C, H and O only. X is not a cyclic compound and
shows the following properties.

The hybridization of the carbon atoms are sp, sp2 and sp3. It gives a white precipitate with
ammonical Silver Nitrate.It reduces both Tollen’s and Fehling’s reagent. It contains a chiral
centre.

i) Write the molecular formula of X taking into account the minimum number of atoms.

………………………………………………………………………………………………………………………………………

6
ii) X undergoes the following reaction procedure.

X Na / Δ A CH I
3 B excess CH MgBr
3 C H+/H O
2 D

Write the structures A, B, C, D in the releant boxes below.

A B

C D

b) A part of the mechanism of the reaction of A with CH3MgBr is given below. Writing the
structures corresponding to B, C and D in the boxes below, Complete the mechanis using
curved arrows where appropriate.

CH3-CH2

C=O CH3-MgBr

CH3 O

CH3-MgBr

7
C) Consider the following reaction schemes.

i) Write down in the appropriate boxes the structures of the compounds and also the
reagents.

H + / KMnO4

OH
NaOH
(CH3)2-CH-CH2-C-CH-(CH3)2
CH3

…………………

CH3-CH-CH3

MgBr

H3O+

8
 ii) NH2

Br

C=N-CH2

CH3
9
 Part B

Essay

5. a) i)State the expressions for ideal gas equation and identify its terms.

ii) Derive Boyle’s law from ideal gas equation.

iii) Derive the equation for Aerage kinetic energy of ideal gases using your knowledge in
Chemistry. ( )

iv) State five assumptions in kinetic molecular theory of gases.

√
v) Root mean square velocity of an ideal gas is gien by √ . Assuming ideal
behaviour of Oxygen and Nitrogen at 27◦C. Find the ratio of √ ( ) √ (g)

b) In a 5dm3 vessel at 27°C A2B4(g) is present. The pressure was measured to be 2.995 x
105Nm-2. Vessel was heated up to 100°C, At 127°C A2B4(g) involves to following
decomposition and attain equlibrium as follows.

A2B4(g)↔ A2(s) + B2(g)

Pressure at equilibrium 8x 105Pa. Volume of A2(S)formed is 0.843dm3.

i) Find the number of moles of A2B4(g) at 27°C.

ii) Amount of gas mixture at 127°C.

iii) Sketch a graph representing the number of moles of A2B4(g) and B2(g) with time from
initiation of reaction to equilibrium state.(27°C→127°C)

c) An experimet have been arranged at 25°C regarding the reaction between 1M NaOH and
1M HCl. The experiment setup was arrnaged with the following.

° 500ml of NaOH and 500ml of HCl.

◦ Calorimeter of mass 530g and specific heat capacity of 0.4Jg -1K-1.

◦ Test tube

◦Volumetric flasks

10
◦ Neutralization enthalpy =- 57.356kJ/mol

The experiment is carried out and final maximum temperature was measured.

◦ Specific heat capacity of water is 4.2Jg-1K-1

i) Briefly state how you would say that the maximum temperature has been attained?

ii) Calculate the maximum temperature change expected at the end of th experiment.

iii) But the maximum temperature attained was 30°C point out some reasons regarding the
above observation.

iv) In another day an experiment was carried out using weak base and weak acid, the
neutralization enthalpy obtained under standard condition with least degree of errors was
– 50.4kJ/mol. Briefly explain the deviation of standard neutralization enthalpy in above
two situations.

6. a) i) Define the term average rate for a given chemical reaction.

ii) List out the factors that affet the rate of a reaction and explain 2 of them using collision
theory.

iii) The reactant P, Q and R react with each other in an aqueous medium to yield products S
and T. Shown below.

P + Q+ R→ S + T

I) Write the rate of the reaction in term of reactants and products.

II) Using the following diagram find the rate of the reaction of the above reaction.

concentration/moldm-3
4.0
[T]
2.0

1.0

[P]

t Time

III) Find the rate of the reaction at time t.If t=20seconds.

iii) The table given below is the result of the four experiments performed at 32°C to
inestigate the kinetics of a reaction. 11
Experiment Initial Initial Initial Initial
concentration of concentration of concentration of concentration of
A moldm-3 B moldm-3 C moldm-3 D moldm-3
1 0.1 0.1 0.1 8.0x10-4
2 0.2 0.2 0.1 3.2x10-3
3 0.1 0.1 0.2 1.6x10-3
4 0.2 0.1 0.1 1.6x10-3

I)Write the mathematical expression to relate the rate of the above reaction to
concentration of A, B and C.

II) Calculate the order of the reaction with respect to A, B and C.

III) Write the total order of the reaction.

IV) Write the rate equation and find the rate constant.

b) Enthalpies of formation of some substances are given below.

Substance H2O(l) CO2(g) C4H10(g)

ΔH®f/kJ/mol -286 -394 -126

i) Draw the hees’s law cycle to calculate the enthalpy of combustion of C 4H10.

ii) Draw the Born Haber cycle of MgBr2.

iii) Using the following enthalpy changes find the Latice entalpy of MgBr 2.

ΔHØF MgBr2(s) -520kJ/mol

ΔHØs Mg(s) +90kJ/mol
ΔHØD Br2(g) +250kJ/mol
ΔHØI1Mg(g) +420kJ/mol
ΔHØI2Mg(g) + 800kJ/mol
ΔHØEA1Br(g) -400kJ/mol

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c) i) 1.6g of a sample containing only SrCO 3 and BaCO3 was dissolved in excess of 50cm3
0.8M HCl. To neutralize the excess acid if 40cm 3 of 0.5M NaOH solution was required.
Calculate the mass percentage of SrCO3 and BaCO3.(Sr-88, Ba-137, C-12, O-16)

ii) Mn+ ion of a 3d block element can be oxidized to MO2+ ion by Cr2O72- in the presence of
dilute Sulfuric acid. In an experiment 20cm3 of 0.1M K2Cr2O7 was required to oxidize 4x10-
3mol of Mn+ to MO2+. Using these data calculate the value of n.

7. a) The following procedure was used to find the percentage of Cu in an alloy. 11g of the
alloy was dissolved in concentrated H2SO4 and the solution was made up to 500ml. H2S was
passed through 25ml of this solution. 80ml of 0.1M KMnO 4 solution was added in excess to
this solution to convert the CuS precipitated into Cu 2+, Mn2+ and SO2. The SO2 produced into
SO42-. The excess KMnO4 was titrated against 0.5M Fe2+ solution. At the end point the
reading on the burette was 10ml. Calculate the percentage of Cu. (Cu=63.5)

b) The colour aqueous solution Q contains three metal ions as their chlorides. The test
performed with solution Q together with their onservation are given below.

Test
1. Equal volume of NH4OH aqueous and
NH4Cl aqueous were added to the solution
Q.
2. To the above filtrate from (i) NH4Cl and
NH4OH were added then H2S gas passed to
it.
3. To the above filtrate from (ii) NH4Cl and
NH4OH were added and then (NH4)2CO3 was
added to it. To the above precipitate flame
test was done.
Observation
A green colour precipitate was formed. This
precipitate dissolve in excess KOH solution
formed dark green solution.
Pink precipitate was formed.
White precipitate was fromed
Crimson red colour was observed

i) Identify the metal in Q.

ii) Identify the precipitate obtained in the test (i), (ii) and (iii).

iii) Give the balanced chemical equation for the reaction of the dark green colour solution
formed in test (i).

c) An aqueous solution ‘A’ contains three anions. The following tests were carried out to
identify three anions.

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 Test Observation
1 a) Pb(NO3)2 solution was Yellowish white precipitate
added to solution A. was observed.
b) The solution containing Portion of the precipitate
yellowish white precipitate was dissolved.
was boiled.
c) The solution obtained Golden spangle cristal was
from (b) was filtered in a hot formed.
condition. After that it was
allowed to cool to room
temperature.
2 Dilute HCl solution was A pea yellow colour
added to the solution A. precipitate was formed at
the same time pungent smell
was felt.
3 Aluminium powder and
dilute NaOH was added to
the solution and it was
heated. The filter paper turns to
The evolved gas was tested brown colour.
with the filter paper which
was dipped in Nessler’s
reagent.

Using the above data identify the three ions present in A.

8. a) Show how you would carry out the following conversion in not more than six steps.

CHO OH
CH2CH2 –C-CH3
CH3

b) Identify P1- P5 and Q1 to Q6 in order to complete the reaction scheme.

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 O

- C-NH-CH2-

Q1 Q2

P2 P3
Q4
Q3

P4 P5
Q5 Q6

CONH2 dry AlCl3

CH2-

Write down the use of dry AlCl3 in the above reaction scheme.

c) i) Using your knowledge of the mechanism of the reaction between acetaldehyde and
dilute NaOH, Propose a mechanism for the above reaction.

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ii) The following reactions give two products.

CH3CH2Br C H O-
2 5

I) Write the stuctures of the two products.

II) Write the mechanism for the formation of these two products.

iii) The following reaction gives two products too.

A
C CH3CH2Br D B

I) If A is an alkene and B is an alcohol write the reagents C and D.

II) Write the products A and B.

III) Write the reaction type of A and B.

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