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GMM Pfaudler 腐蚀检测
GMM Pfaudler 腐蚀检测
GMM Pfaudler 腐蚀检测
Instrumentation
for Highest
Standards
For over 130 years, Pfaudler is the
leader in developing new technologies PRODUCTS & EQUIPMENT
to meet the highly specific chemical
processing needs of its clients. One
reason why our glass-lined equipment
is trusted by over 90% of the world’s Glass Lined Reactors
top chemical companies is the sheer
reliability of our reaction technologies
and comprehensiveness of our glass- Glass Lined Mixing
lined accessories. These technologies
are critical to the safe containment of Systems
corrosive contents, maintaining the
vessel pressure and ensuring the final
batch quality. Baffling Technoliges
In short, our glass-lined technologies
are absolutely integral to an effective Storage Tanks &
process. Receivers
Accessories
Glass Lined
Instrumentation
Sectors Applications
In the chemical and pharmaceutical Did you know that many daily consumer
industries, Pfaudler has been synonymous products are made using Pfaudler technology?
with glass-lined vessels and components Here are just a few examples.
for decades. But glass-lined measurement
technology offers decisive benefits in other · Beer · Yoghurt · Cheese · Rice · Sugar
sectors as well. · Mayonnaise · Cheese spread · Herb butter
· Ketchup · Mustard · Crème fraîche · Jam
· Syrup · Paper · Glue · Cream · Shampoo
· Shower gel · Hair perming products
· Plant protection products
Sectors
Chemicals Beverages
Pharma Paper
Energy Cosmetics
4
5
Technology and Benefits
Advantages of the glass-lined measurement technology
Benefits
ANALYTICAL
DATA
ION SENSITIVE
pH Value 2.0
6
TOP LAYER
GROUND
LAYER
STEEL
7
Liquid Analysis
Because glass has its limits
pH measurement
• High mechanical strength and
PH
Whenever robustness and chemical
resistance are key, Pfaudler’s low- suitable for use in high temperatures
MEASUREMENT maintenance and durable pH • Proof against glass breakage
measurement systems are your • Can be used without a retractable
first choice. We supply probes in system or bypass installation
various designs for virtually all • CIP and SIP compliant
process engineering applications. • Self-cleaning and low-maintenance
For hygienic processes, we offer
specially developed probes with
EHEDG certification.
Conductivity measurement
LF The conductivity of a medium • Wide measurement range 0.01 mS
can be determined with a durable to 2000 mS
CONDUCTIVITY glass-lined probe in a 4-conductor • Suitable for high temperatures
MEASUREMENT
circuit. To achieve this, four rhodium • Standard use at up to 40 bar
electrodes are arranged behind positive pressure
each other on a measuring probe • Dirt-resistant
and fused into the probe carrier’s • Suitable as ring probe for phase
glass lining. separation and ‘empty’ signal
8
Glass-lined pH Probes
Long-lasting and low-maintenance
The pH value is one of the most important Probes can therefore be installed in piping
and commonly measured values in many fields and vessels where they are directly exposed
of process engineering. The stability of the to the flow, enabling direct continuous online
entire production process can be increased measurement in the main product stream.
by regulating the pH value in a targeted way. Moreover, the smooth surface the glass
Thanks to their maintenance-free operation lining gives the probe protects it against
and long service lives, robust glass lined pH corrosion and product build-up. Combined
probes are a cost-effective option for with a pressurised electrolyte system, these
constant use. properties allow the probe to be installed in
any position and direction, so the pH sensor
Steel probe body can be installed directly at the point of use.
The glass lined pH probe comprises a steel
probe body with a highly-resistant, anti- No aging
adhesive technical glass lining to protect Unlike in glass electrodes, there is no internal
the surface in contact with the product. This buffer (discharge electrode). In contrast to
makes the probe resistant to mechanical strain conventional glass electrodes, the ion-sensitive
by flows, pressure, abrasion and vibrations. glass area is only in contact with the process
medium on one side. This prevents ageing and
drift of the pH sensor. The operating life of a
Pfaudler pH probe is depending of chemical
PH
MEASUREMENT
corrosion and abrasion (diagram corrosion
resistance).
140
Permantent exposition over one year
- Increase expotentially to temperature
120
Temperature °C
100
Abtrag
80 0,4 mm
resistance 0,2 mm
60 0,1 mm
40
Hydrochlorid acid sodium hydroxide
20
0
-2 0 2 4 6 8 10 12 14
pH value
10
Structure of ph-Glass-lining
Structure of ph-Glass-lining
11
Glass-lined pH Probes
For highest heavy-duty process standards
HEAVY
DUTY
PH
MEASUREMENT
12
Relative pH-measurement principal The other sensor surface – the reference glass
Differential pH probes provide values or reference electrode– responds to the salts
measured against a product-dependent dissolved in the liquid, especially the Na+ ions
reference parameter. The measured value is resent, and thus provides a product-specific
therefore a product-specific value (relative pH reference potential. Once the transmitter
measurement) that allows a statement as to has been configured with data from the
whether a process is performed according to measurement and test report provided, the
defined specifications. This measured value is pH differential probe is calibrated in its
therefore ideal for controlling and monitoring installed position using a product sample.
recurring batch processes (e. g. formulations The probe then works like a “normal
without changes) or continuous measurement. absolute” pH measurement device in
Differential pH probes are simple in structure: the specified range. The special relative
two ion-sensitive enamels are fused onto a measurement principle means that the probe
steel probe carrier and form the measuring functions without an electrolytic liquid. This
part of the sensor. One sensor surface eliminates the risk of the product being
responds to H+ ions and provides a potential contaminated by the electrolyte and ensures
that depends only on the pH value; this is practically maintenance- free operation.
called the pH glass.
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Glass-lined pH Probes
For highest hygenic process standards
Easy to clean
∆ pH 0,1
135 °C steam
0 95 °C water
80 °C water
–0,1
25 °C water
–0,2
–0,3
–0,4
–0,5
0 10 20 30 40 50 60 70 80 min
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ELECTROLYTE
VESSEL
STAINLESS STEEL
PH-PROBE
TYPE PH-REINER
15
Glass-lined Probes
For highest process standards
ORP REDOX
POTENTIAL
MEASUREMENT
16
Conductivity measurement
In the LF measuring probe, four metal (rhodium)
electrodes are aligned longitudinally and fused
into the enamel coating of the probe carrier.
Thermometer tubes, baffles or spacer rings may
be used as probe carriers. The cell constant
is dependent on the geometry and location
of the probe and cannot be predetermined.
For this reason, a fourwire circuit is used. A
constant alternating current flows across the
two outer electrodes and through the product.
The resultant voltage drop is sensed by the two
inner electrodes and transmitted to a high-
impedance measuring transmitter.
LF
CONDUCTIVITY
MEASUREMENT
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Technical Data
Product overview
Temperature
Pt 100 Pt 100 Pt 1000
compensation
L = 300 – 3200
D = 38 – 180
L = 300 – 3200
DN = 50 – 200
Dimensions (mm) D = 38 – 180 L = 120 / D = 12.5
DN = 50 – 200
Ring-probe***:
DN 50 / DN 80
6-pin gold-plated,
Electrical connection 5-pin, Lemo 5-pin, Lemo
interconnex Variopin
* depends on temperature
** depends on alkali error
*** other dimensions on request
**** higher pressure on reguest
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ANALYTICAL
DATA
ION SENSITIVE
pH Value 2.0
Absolute pH and
Relative pH Relative pH Redox potential Conductivity
Redox potential
Diaphragm +
Reference enamel Reference enamel Reference enamel –
reference electrode
-1200 to +1500 mV
3 to 12 pH 3 to 12 pH -1200 to +1500 mV 0.01 to 2000 mS/cm
0 to 10 pH
Pt 100 (optional)
Pt 100 Pt 100 Pt 100 (optional) Pt 100
Pt 1000
II 1/2 G EEx ia IIB T6 II 1/2 G EEx ia IIB T6 II 1/2 G EEx ia IIB T6 II 1/2 G EEx ia IIB T6
or – or or or
II 2G EEx ia IIC T6 II 2G EEx ia IIC T6 II 2G EEx ia IIC T6 II 2G EEx ia IIC T6
6-pin gold-plated,
5-pin, Lemo 5-pin, Lemo 5-pin, Lemo 5-pin, Lemo
interconnex Variopin
No KCL solution is No KCL solution is Special Pfaudler No KCL solution is No KCL solution is
needed needed KCL solution needed needed
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Features and Benefits
Product overview
pH 03,
pH 40, pH rH, LF,
Features pH 03 Dual,
pH 18 Reiner pH /ORP LF Ring
pH Ring
Self-cleaning • • • • •
CIP- / SIP-compliant • • • • •
Slope is maintained
throughout service life • • •
EHEDG cerification •
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pH 03,
pH 40, pH rH, LF,
Benefits pH 03 Dual,
pH 18 Reiner pH /ORP LF Ring
pH Ring
No retractable holder /
bypass installation required • • • •
No electrolyte contamination
of the product • •
Combined pH / ORP
measurement possible •
No catalytic or biological
effects • • • • •
21
Temperature
Measurement
Sometimes speed is key
Early recognition of process temperatures Quick measurement results are essential for
enables you to regulate it precisely and optimal temperature control.
minimise fluctuations. Lower energy input and Pfaudler’s fused-in glass lining solutions
lower energy losses result in well-balanced closely offer a clear advantage – they are in
energy management and therefore lower contact with the medium. Sometimes speed
costs. Various technologies are available, is key!
depending on the application.
Fused-in resistance
TWFUSED-IN
thermometer
The functionality of Pfaudler’s type
• Fastest glass-lined temperature
probe
RESISTANCE TW temperature probe relies on the • No sealing elements
THERMOMETER
temperature dependence of the • Long service life, excellent long-term
electric resistance of platinum. The stability and maintenance free
platinum measuring unit, a PT 100 • No drifting
resistance thermometer, is fused
into the glass lining of baffles or
thermometer wells, providing an
optimal heat transfer. Compared
to conventional glass lined
temperature measurements the
heat transfer coefficient of fused-in
sensors is lower, ensuring extremely
low half-value times.
Fused-in thermocouple
T In the Pfaudler type T temperature • Up to six measurement points on
probe, the temperature is measured one probe carrier
FUSED-IN exactly where it is needed. A • No sealing elements
THERMOCOUPLE • Long service life, excellent long-term
Pallaplat thermocouple is fused into
the glass lining of C-baffles or valve stability and maintenance free
cones, providing an optimal heat • No drifting
transfer.
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Time response
100%
Half time value
90%
E T or TW
0 [s] 10 20 30 40 50
+200oC
TMI T
TW
23
Features and Benefits
Early detection. Precise control
Features TW T TMI
Benefits TW T TMI
Technical Data
Type TW T TMI
24
TOP LAYER
PT 100
RESISTANCE
THERMOMETER
TW
FUSED-IN
RESISTANCE
THERMOMETER
GROUND
LAYER
STEEL
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Corrosion Monitoring
With analysis of the decomposition voltage
always the right decision
The Pfaudler technology not only enables Solutions are available for continuous
to monitor glass-lined surfaces but also other corrosion monitoring and systems for
corrosion-resistant surfaces (e.g. PTFE- periodical mobile corrosion testing.
coated) of reactors including fittings. It is thus possible to storage vessels regularly
for corrosion damage at low costs and effort.
Thanks to the implemented algorithm false
alarms are ruled out. Reliable information Corrosion monitoring must be above
about the condition of the reactor are all – reliable!
obteined and the systems connected
components.
Continuous corrosion
CDS
CORROSION
monitoring
Continuous corrosion
• Principle of decomposition voltage
analysis
DETECTOR monitoring can be carried • Measurement not influenced by
STATIONARY
out with measuring electrically conductive fittings
electrodes fused into the • Monitors all corrosion-resistant surfaces
glass lining – the CDS-probe • Control measurements rule out false
– in conjunction with the alarms
associated electronics – the • Displays operating conditions based on
Corrosion Detector. defined current thresholds
The measuring electronics • Certified for explosion zone 0
are connected to the parts
being monitored by means
of the point-type electrodes
and the product. These can
be embedded in glass-lined
baffles, thermo-wells or glass-
lined valve stems.
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CDP
CORROSION
DETECTOR
PORTABLE
GLASTEEL
_
ANTI CORROSION
ANTI STICK
ANTI STATIC CORROSION DETECTOR
PORTABLE
CORROSION
DETECTOR
CDS
CORROSION
DETECTOR
STATIONARY
ON
VALVE STEM
ON ROD-PROBE
OR BAFFLE
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COP electrodes
Set new standards in terms of reliability and longevity
In highly corrosive and abrasive processes in The new CryCo-Lock® technology additionally
glass-lined vessels, corrosion monitoring is an enables the monitoring of shrink-fitted
indispensable safeguard for the protection of turbines, thus providing perfect all-round
plant and employees. protection for your vessel.
With the new development of the sintered
corrosion monitoring electrodes (COP probe),
Pfaudler is further improving its unrivaled
corrosion monitoring system and setting new
standards in terms of operational safety and
durability - even in most aggressive processes.
NEW
COP CORROSION
PROOF
ELECTRODES
Optimized electrodes
- for maximum service life Benefits
The technology of corrosion protection • Extremely high resistance to acids
monitoring is based on a detailed measuring and alkalis
electrode, the COP probe, in conjunction with • Electrode surface approx. 36x larger
the associated measuring electronics, the • Product conductivity >1mS/cm
Corrosion Detector. • No surface tensions between
The electronics are connected to the parts to electrodes and glass-lining
be monitored by means of the electrodes via • Maximum service life and long-
the product. term stability, maintenance-free
• For baffles and quatro-pipes
Due to the significantly increased electrode • ATEX Zone 0
surface, use with product conductivities
of > 1mS / cm is now also possible.
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NEW
COP
CORROSION
PROOF
ELECTRODES
PROBE
CARRIER
BAFFLES /
QUATRO PIPE®
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Mobile Corrosion Testing
Corrosion Detector Portable (CDP)
The Corrosion Detector Portable offers The operating principle of the decomposition
corrosion testing according to a maintenance voltage analysis is the same as in the
plan or when required, and tolerates stationary measurement system.
electrically conductive fittings. The hand-held
device is supplied with a PTFE dip probe, a
reference electrode and an earthing clamp.
Measurements can be transmitted to a PC
using the USB adapter cable provided. The
associated software is provided on a USB stick.
•
Principle of decomposition voltage
analysis
Measurement not influenced by
DETECTOR a reference electrode and an
PORTABLE earthing clamp. Measurements electrically conductive fittings
can be transmitted to a PC • Monitors all corrosion-resistant surfaces
using the USB adapter cable • Control measurements rule out false
provided. The associated alarms
software helps to administrate • Earthing clamp with electronic contact
the measuring results and monitoring
to create a test certificate if • Can store up to 10,000 measurements
required. • Certified for explosion zone 1
Regular and preventive control play a key role in terms of avoiding long downt-
imes and detect potential damages in an early stage.
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GLASTEEL
_
ANTI CORROSION
ANTI STICK
ANTI STATIC
CDP CORROSION
DETECTOR
PORTABLE
31
CryCo-Lock
Corrosion monitoring on turbines
Continuous monitoring of the glass lining inside The use of the Corrosion Detector in conjunction
a vessel during operation is indispensable in with Pfaulder’s new Conductive Cryo-Lock
highly corrosive processes, in order to rule out (CryCo-Lock) technology has now made this
large and costly tantalum repairs or even possible.
rupture of vessels. A corrosion detection system
is the solution. Where multi-piece glass-lined
agitators are used, it has never before been
possible to monitor the entire agitator assembly.
GLASS
DAMAGE
CD
CORROSION
DETECTOR
NONE
CONDUCTIVE CRYCO-
LOCK
TURBINE
GLASS MONITORING
DAMAGE
CONDUCTIVE
GLASS
SPOT
CRYCO-LOCK
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CRYO-
LOCK
SHAFT
CRYCO-
LOCK
TURBINE
MONITORING
CRYO-
LOCK
TURBINE
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Functional Principle
Features and benefits
The analysis of the decomposition voltage
happens in a recurring cycle as changing Corrosion monitoring must be above
conditions like the temperature or the pH value all – reliable!
have to be considered. With Pfaudler technolgy, false alarms are
a thing of the past. Whether you monitor
A voltage is applied at regular intervals your equipment continuously or check it
between the two rhodium electrodes of the priodically, you can depend on the result
P probe, and a base curve is created. Starting every time.
from this reference line, the Corrosion Detector
calculates a so-called Corrosion Alarm Window.
If the current/voltage values are within the
Corrosion Alarm Window in two successive
control cycles, an alarm message is provided.
34
Features and benefits
Features COP/CD CDP
Benefits
Type COP probe (P)/Corrosion Detector (CDS) Corrosion Detector Portable (CDP)
COP:
II 1/2 G Ex ia IIB T6 Ga/Gb
or II 2 G Ex ia IIC T6 Gb
Explosion protection II 2G Ex ib 11B T3 Gb -10°C ≤ Ta ≤ +50°C
CDS:
II 2(1) G
or II 2G Ex ia IIC T6 Gb
or Ex ib IIC T6 Gb
* depending on component or nozzle size
35
Level Measurement
Fast, precise, durable
Radar
Levelpulse radar sensors emit • Low transmission frequency –
LEVELPULSE microwave signals, and are used insensitive to product deposits
RADAR for continuous level monitoring of • Accurate measurement even in the
corrosive fluids in reactors. presence of temperature fluctuations
• Adjustment without filling or
emptying the reactor
Vibration
Safety Swings rely on the tuning fork • High mechanical strength and
SAFETY
principle to achieve a limit level chemical resistance through the use
SWINGS
measurement that is accurate to of glassed steel
VIBRATION
the millimetre – regardless of the • Works perfectly even in foam,
medium’s density and viscosity. The bubbles and suspended particles
probe can be used as a maximum • Certified as an overfill safety device
limit switch, as an additional overfill under WHG (German Water
safety device, as a minimum limit Management Act)
switch or as protection against
running dry.
36
MAX
LEVEL
MEASUREMENT
MI N
SAFETY SWING
LEVELPULSE
FT
CAPACITIVE
FS
CAPACITIVE
37
Sampling Systems
Reliable, maintenance free, variable
Generally, sampling systems are used as an The fleXampler loop used in combination
alternative for the online liquid analysis. It is with the Pfaudler Quatro-Pipe, for example,
crucial here that the production process is not provides a complete measuring system with
interrupted, that no contamination occurs and which samples are taken and temperature,
that surfaces which come into contact with pH value and corrosion monitoring are
the product are protected against aggressive measured or monitored at the same time.
media. Yet another area in which the glass And all of this with just one vessel nozzle.
lining from Pfaudler comes into its own.
fleXampler
The fleXampler standard sampling • Modular design
FLEXAMPLER system is the ideal solution for the • Large outlet for sampling
STANDARD
reliable and closed sampling of fluid • Parts with PFA internal coating
media from reactors and vessels. (FDA-certified)
A Dip-Pipe or a Quatro-Pipe baffle • TA Luft (Clean Air Act) compliant
is mounted on an available vessel • Options
nozzle. The sample can be taken by • Design with recirculating pump
inserting the PTFE suction hose into • Automatic control with motorised
the Quatro-Pipe or Dip-Pipe. The valves
connection on the lower flange of the • Sampling flask cage
fleXampler sampling system enables
the use of the Dip-Pipe or Quatro-
Pipe to inject fluid media.
fleXampler loop
The fleXampler loop continuous • Maintenance-free and self-cleaning
FLEXAMPLER sampling system really comes into for representative results
LOOP
its own when used with a Quatro- • Suitable for viscous substances
Pipe baffle, as this configuration only • Piston syringe with glass cylinder for
requires one vessel nozzle for two or quick visual inspection
more functionalities. The sample is • No escape of gas or product
taken near the agitator by means • Compressed air diaphragm pump
of an internal PTFE tube. All parts with diaphragm monitoring designed
that come into contact with the for zone 0
product are metal-free. Thanks to • Surfaces in contact with product
the constant circulation (loop), there have highly corrosion-resistant
is no need to clean the sampling coating (glass lining, PFA, PTFE)
device. The loop circulation system
also offers the option of integrating
a pH-ring probe without any effort
or expense.
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SAMPLING
SYSTEMS
FLEXAMPLER LOOP
FLEXAMPLER STANDARD
QUATRO-
PIPE
BAFFLE
PROBE
DIP-PIPE
PFAUDLER
QUATRO-PIPE
39
Global Services
Capability
40
Pfaudler Safety First
Delivering excellent safety performance is
necessary for any company operating in the
process industries. Over the years, and all over
the world, Pfaudler has provided security in its
products and highly-qualified service teams.
Pfaudler guarantees:
• skilled professionals properly prepared
and qualified on security and risk
management
• observance of international standards
• use of professional personal protective
equipment
• reduced operating risks
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Worldwide
Presence
NETHERLANDS
UK
GERMANY
FRANCE SWITZERLAND
USA SOUTH KOREA
ITALY
CHINA
MEXICO
INDIA
SINGAPORE
BRAZIL
100
pharmaceutical, food and energy industry.
1500 +
offering system we are able to meet complex industry demands
worldwide.
04
GMM Pfaudler’s continued legacy.
Continents
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