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Sidney Nolan's Adventures in Paint - AICCM Bulletin V34-Dredge
Sidney Nolan's Adventures in Paint - AICCM Bulletin V34-Dredge
Sidney Nolan's Adventures in Paint - AICCM Bulletin V34-Dredge
Art Gallery of New South Wales and Centre for Cultural Materials Conservation, The University of Melbourne
Abstract
Micro-Fourier Transform Infrared Spectroscopy (μ-FTIR) and portable X-ray Fluorescence (pXRF) was undertaken on 11
paintings by Sidney Nolan (1917–1992) in order to identify paint type. Alkyd (oil-modified polyester resin) was identified
on two 1942 paintings and nitrocellulose paint was detected on several works from 1941. These early synthetic
paint types have not previously been noted on paintings by Nolan. The oil identified on paintings dated after January
1943 demonstrates good correspondence with the Ripolin brand of enamel paint when compared with the results
of a previous analytical study of cans from Nolan’s own studio. The analytical results provide new insight into Nolan’s
unusual use of commercial gloss paint in the Second World War period. This study also clarifies the brand names and
terminology used in the 1940s to 1950s to describe the different types of commercial paints and offers a model for
the cataloguing of Nolan’s paintings.
Terminology
The identification of the types of
paints favoured by Nolan as outlined
in his letters to Sunday Reed is
confusing due to his use of terms
that were deeply embedded in the
period (Nolan 1942–44). Much of the
specificity of the brands has changed
over the intervening decades, making it
now difficult to understand what type
of paint Nolan was referring to.
Table 1 describes the generic and
specific terms commonly used in
the 1940s for three common gloss
paint types with some examples of
the brands and products available
in Australia. In the 1940s the term
‘enamel’ was used specifically to
describe oil-based commercial paints
such as Ripolin. Dulux in Australia
was not the name of a paint maker as Figure 1. Advertisement for Taubmans Dynamel, Australian Women’s Weekly, 16
it is today, but a line of alkyd paint. October 1948, p. 35.
Dulux was manufactured by British
Australian Lead Manufacturers
(B.A.L.M.) under licence to DuPont in the United
States. As lead in paint became increasingly associated
with health issues, B.A.L.M. changed its name to
BALM Paints in the 1960s, and then Dulux Australia
in 1971 (Kolm 1988). In the 1930s and ’40s, alkyd
paints were often called ‘synthetic resin’. The distinction
between the terms ‘enamel’ and ‘synthetic’ during this
period is well illustrated by the label used on cans of
Dulux in the 1930s and ’40s that stated that it was ‘the
synthetic finish superseding enamels’ (Figure 2).
Another popular type of commercial ready-made
gloss paint available from the late 1920s was based on
nitrocellulose resin. Nitrocellulose paints were called
lacquers because they hardened by solvent evaporation
like varnishes, and not by oxidation and polymerisation presence of copper phthalocyanine, a pigment that was
like oil paint. The most popular brand of nitrocellulose not commercially available until 1935 (Gettens & Stout
paint was also manufactured in Australian by B.A.L.M. 1966), in one of the colours. They also could not have
under licence to DuPont and was called Duco. been manufactured before the English Ripolin factory
Observable features such as high gloss, a lack of was first opened in 1932 (Ripolin Ltd. 1931–32). It
stiff paint texture, and evidence of fluid paint, have is probable that the Wahroonga studio Ripolin cans
been previously used to identify Ripolin on paintings predate the war as ready-made paints were not imported
by Nolan. This methodology is problematic, however, into Australia after 1942, and it was some time after the
as it has been demonstrated that these paint features end of the war before supplies of non-essential paints
can also be replicated by the addition of solvents, oils were re-established (Dredge 2012). Other material from
and resins to standard artists’ oil paint (Carlyle 2011). the studio has associations with the period of Nolan’s
Neither can other types of gloss commercial paint, such service in the Australian Army from 1942 to 1944 and
as alkyds and nitrocellulose, be distinguished from each it seems probable therefore that the Ripolin may also
other or from Ripolin, by the appearance of the finished date from an earlier time than the building of the studio.
paintings alone. Instrumental analysis is necessary to An analytical study of the Wahroonga studio
identify these three different types of commercial paint Ripolin paint has previously been published (Dredge
binders. et al. 2013). The results confirm that the Ripolin was
oil-based and therefore traditional enamel paint. Two
The reference collection different types of tree resins were also identified in the
In 2006, Sidney Nolan’s daughter Jinx Nolan gave gloss Ripolin. The analysis of the Ripolin gloss colours
a collection of more than 100 items retained in indicated that the oil, copal and colophony had all
Nolan’s studio in Wahroonga, Sydney, to the Artists’ been heat treated. The addition to the Ripolin paints
Materials Archive at the Art Gallery of New South of these types of ‘cooked’ materials, heat-bodied oils,
Wales (AGNSW). This material includes 35 cans processed colophony and liquefied copal, is consistent
of Ripolin paint manufactured in England, most of with the historically documented types of processing
which had never been opened and retained the original used in the preparation of oil enamels in the first half
manufacturer’s seal. Other items include a can of black of the 20th century (Standeven 2011). The pigments
B.A.L.M. Dulux paint, solvents, receipts, paint charts present in the cans of gloss Ripolin paints retained
and a leather satchel with screw-capped cans modified in Nolan’s Wahroonga studio were also identified in
for transporting paint. this study. The base white pigments were found to be
Nolan moved permanently to the United Kingdom in zinc white or barium sulfate with the addition of high
1953 (Pearce, Klepac & Lindsay 2007) while his house tinting pigments: chrome yellow, chrome red, Prussian
and studio were retained by his family until 2006. The blue, carbon black, bone black, toluidine red (PR3) and
studio contents are therefore a unique time capsule of copper phthalocyanine.
the materials Nolan was using in his Australian, pre- The detailed analysis of the Ripolin paint from the
London period. Although the date of manufacture of studio was achieved using a number of techniques
the Wahroonga studio cans of Ripolin has not been including Meth Prep-GC/MS, Raman Spectroscopy
fully established, they must date after 1935 due to the and Energy Dispersive X-ray analysis (EDX), µ-FTIR
soap species appear in the FTIR absorbance spectra films on both of these works exhibited matte, pasty and
as a broad peak in the region 1570 to 1540 cm-1. As textured appearances generally associated with standard
the soaps mature within the paint, they may also form artists’ oil paint.
specific carboxylates species. Zinc stearate for example The paint media on two works from 1941: Luna
may be indicated by a sharp peak at 1542 cm-1 (Robinet Park and Bird were identified as nitrocellulose. All
& Corbeil 2003). of the samples from these two works gave the FTIR
absorption peaks associated with the nitrate group at
Results 1657, 1279 and 841 cm-1 that corresponds well with the
The analytical results from the examination of eleven published literature on FTIR of nitrocellulose paints
paintings by Nolan are given in Table 2. The two earliest (Learner 2005 p. 91) and matches with the FTIR
paintings of the test group: Head of Rimbaud (paint on spectra obtained from the can of Duco (Figure 3).
verso only tested) and Untitled (abstract), did not yield Both paintings exhibited an extensive network of sharp
µ-FTIR spectral results for the binder. This was due cracks suggesting that the paint films were brittle and
to the high pigment content compared to the binder. easily fractured. This is consistent with the presence
The pigments identified on these two paintings differed of nitrocellulose paints, which is known to become
from others in the study group and were lead chromate fragile with age (Standeven 2011). The white pigment
combined with calcium sulphate dihydrate (gypsum), identified was titanium dioxide. Titanium dioxide was
dinitroanaline red (PO5) and natural ochre. The paint preferred in nitrocellulose paints over lead and zinc
based white pigments due to its superior opacity and fine Lead carbonate was the dominant white used in several
particle size. colours on Water Wheel (Luna Park). No lead carbonate
Alkyd resins were detected on multiple colour areas was found in the samples from Dimboola, which was
of two paintings, The Water Wheel, (Luna Park) and principally titanium dioxide. This suggests that the two
Dimboola. These were identified by comparison with paintings, although both alkyd types, may have been
the dry residue on the outside of the can of black Dulux painted with different brands of paint.
from Nolan’s studio (Figure 4). Distinctive alkyd FTIR Oil was detected as the principal paint binder in all
absorption peaks in paint samples from both works were the remaining paintings of the study group. The principal
located at 1458, 1282, 1124, 1072 cm-1 with a doublet at white pigment was zinc oxide detected by the significant
742 & 705 cm-1. The white pigments used in the paints presence of carboxylates in the region 1500–1600 cm-1
of the two alkyd painting were different from each other. and the presence of zinc with pXRF. Red colours were
Figure 5. a. Transmission FTIR of sample of red gloss paint on First-class marksman and b. Nolan Studio Ripolin red 16 from
the can.