Chemistry assign - 1 Name:..................................

Date : 28-12-2022 Date of completion:..............

Batch...................................

CHEMICAL BONDING
Ionic Bond, Co-valent Bond, Co-ordinate Bond, Fajan's rule

1. Which type of bond is formed in following cases.

(i) Metal-metal (ii) Metal-non metal (iii) Non metal-non metal
(iv) Electronegativity difference between non-metals is very less or zero
(v) Electronegativity difference between elements is large.
2. Select the true-false statements
(i) For ionic bond formation, ionisation energy of metal should be high.
(ii) For ionic bond formation, a non metal must have high electron affinity.
(iii) Ionic character of the compound will be maximum if electronegativity difference is minimum.
(iv) Ionic bond is formed between a metal and non metal.
(v) Ionic bond is never formed between two non-metals.
(vi) Ionic bond always results a neutral molecule.
(vii) Co-valent bonds are always non polar.
(viii) In co-ordinate bond, electrons donated by one atom, so it must have two positive charge.
(ix) Co-valent compounds have low m.pt and b.pt than ionic compounds.
(x) Co-ordinate bond is basically combination of ionic and co-valent bond.
3. Find the number of ionic, co-valent and co-ordinate bonds in each molecule (Lewis concept)
(i) Na 2S (ii) K 2SO 4 (iii)BaSO4 (iv) CuSO4 (v) K 2 CO 3 (vi) KClO4
(vii) K 2S2 O 3 (viii) K 3 PO 4 (ix) Ca 3 ( PO 4 ) 2 (x) Al 2 (SO 4 ) 3 (xi) K 2 Cr2 O 7
(xii) K 2S2 O8 (xiii) KNC (xiv) K 4 [ Fe (CN ) 6 ] (xv) K 2 [ Ni (CN ) 4 ] (xvi) Na 2S4 O 6
4. Select T/F statements in the following
(i) Ionic compounds are good conductor of electricity even in solid state.
(ii) Aqueous solution of ionic compounds are good conductor of electricity.
(iii) HCl is soluble water, although it is a co-valent compound.
(iv) HCl bond strength is more than H2.
(v) Decreasing bond energy for halogens is Cl2  Br2  F2  I 2
(vi) The graphite is good conductor of electricity.
(vii) In co-valent compounds intermolecular force is Vander Waals' force.
(viii) Melting point of diamond is high even it is a co-valent compound.
5. Arrange the following in decreasing order as instructed.
(i) Li  , Cs  , K  , Rb  (Polarising power) (ii) Sr 2 , Mg   , Ca   , Be   (Polarising power)
(iii) Al3 , Mg   , Na  (Polarising power) (iv) C 4 , O 2 , F , N 3 (Polarisibility)
(v) Mn 2 , Mn 4 , Mn 6 , Mn 7  (Polarising power) (vi) I  , Br  , Cl  , F (Polarisibility)
6. Arrange the following in decreasing order
(i) NaF, NaBr , NaCl , NaI (Co-valent character) (ii) NaCl, AlCl3 , MgCl 2 (Co-valent character)
(iii) CaF2 , CaCl2 , CaI2 , CaBr2 (Ionic-character) (iv) Li 2 CO 3 , K 2 CO 3 , Rb 2 CO 3 , Na 2 CO 3 (Ionic- character)
(v) Be(OH) 2 , Mg(OH) 2 , Ca (OH) 2 , Sr (OH) 2 (Ionic- character)
(vi) GeCl2 , GeCl4 (Ionic- character) (vii) SnCl 2 , SnCl4 (Ionic- character)
(viii) PCl3 , PCl5 (Ionic- character) (ix) HF, H 2 O, NH 3 (Ionic- character)
(x) NaI, AgI (Ionic- character)

Building No. 12B/58, 2nd Floor, Rd Number 203, Sector 12B, Dwarka New Delhi-110075, Tel No. 7042232561, Email: xiitacademy@gmail.com 1
Hydrogen Bond
7. Hydrogen Bond : Identify the case where hydrogen bonding is possible
(i) H 2 O( g ) (ii) NH 3 () (iii) CH 3  O  CH 3 (iv) C6 H 5  OH (v) NH2  OH
(vi) CCl3  COOH (vii) C 6 H 5  O  CH 3 (viii) C6 H 5  CH 2  OH

OH OH OH CH 2  OH
NO 2 CH 3 OH
(ix) (x) (xi) (xii)
OH
8. Select the molecule separatly showing inter/intra or both hydrogen bonding OH
CH 3
(i) CH 2  OH (ii) CH 2  OH (iii) HO  CH 2  CH 2  OD (iv) D C  OH (v)
  CH 3
CH 2  OH (CH 2 ) 2
OH

CH 2  OH
OH
OH OH
(vi) (vii) (viii) (ix) CH 3 (x)
CH 3
NH 2 OH H OH H OH
COOH H OH HO H

CH 3 CH 3
9. Arrange the following in decreasing order :

(i) (a) OH (b) CH 2  OH

CH 3
(c) OH (d) CH 2  CH 2  OH (Boiling point)

(ii) (a) CH 3  CH 2  CH 2  CH 2  OH, (b) CH 3  CH 2  CH  CH 3 ,


OH
CH 3

(c) CH  C  CH (Decreasing solubility)
3 3

OH
CH 3
(iii) (a) , (b) , (c) , (d) (Decreasing order of boiling point)
N N N N
 CH 3   
H H CH 3 H

OH OH OH CH 3
OH
(iv) (a) , (b) , (c) , (d) (Decreasing order of boiling point)

OH CH 3

Building No. 12B/58, 2nd Floor, Rd Number 203, Sector 12B, Dwarka New Delhi-110075, Tel No. 7042232561, Email: xiitacademy@gmail.com 2
10. Answer the following : by using the concept of hydrogen bonding.
(i) C 2 H 5  OH is soluble in water while CH 3  O  CH 3 is not.
(ii) H2 O2 is liquid while NH3 is gas at 25oC and 1 atm.
(iii) In KHF2, hydrogen bond is formed as F  .....H  F .

(iv) C 2 H 5OH is soluble in water, and not soluble in C6H6.

(v) HCHO is soluble in water while CH 3  C  CH 2  CH 3 is not.


O
OH OH
NO 2
(vi) is less acidic than

NO 2
(vii) Sugar is soluble in water and toluene.
(viii) Order of viscocity is Glycerol >Glycol > water.
(ix) NH3 can be liquified easily by applying pressure while PH3 not.

CH 3
O  CH 3 CH 2  OH OH
(x) is less soluble in water than OR

Hybridisation

11. Select the correct and incorrect statements regarding the hybridisation.
(i) Hybridisation is a real phenomenon.
(ii) In hybridisation, hybrid orbitals are always equivalent.
(iii) In hybridisation same no. of hybrid orbitals are obtained as mixed initially.
(iv) Any type of orbital (Half filled, full filled or blank) can participate in hybridisation.
(v) Promotion of electron(s) to other sub-orbit of high energy and mixing of orbitals requires energy.
(vi) Only half filled hybridised orbital can participate in bonding.
(vii) Fully filled and fully vacant orbital can also participate in bonding.
(viii) Hybridised orbitals overlap more efficiently to form stronger bonds.
(ix) In hybridisation orbitals of two same or different elements are mixed.
(x) Different facts like bond angle, bond length variation can be explained on the basis of hybridisation.
12. Find the hybridisation of central atom
(i) PCl 3 (iii) PCl 5 (iii) NH 4 BrF5
(iv) (v) XeF2 (vi) CO2
(vii) NO 
2
(viii) N 2O (ix) NO 
2
(x) NO 3 (xi) CO3  (xii) BO 3 
(xiii) H 3 O (xiv) ClO 3 (xv) SO 
3 (xvi) ClO 4 (xvii) PO 4   (xviii) HCN
(xix) H 2 O 2 (xx) N 2 O 3 (xxi) HNO3 (xxii) SO 2 (xxiii) SO3 (xxiv)H 2SO 3
(xxv) H 2SO 4 (xxvi) H 3 PO 4 (xxvii) SO 2 Cl 2 (xxviii) HIO 3 (xxix) BF3 (xxx) ClF3
(xxxi) XeF4 (xxxii) BrCl5 (xxxiii) SF6 (xxxiv) XeF6 (xxxv) I F7

13. Find the shape of following species according to VSEPR theory.

 
(i) H2 O

(ii) N H (iii)XeF2 (iv) XeOF2 (v) XeF4 (vi) ClF3
3
(vii) XeO3 (viii) I F5 (ix) ICl 2 (x) ICl4 (xi) XeOF4 (xii) XeO2 F2
(xiii) XeOF6 (xiv) XeO4 (xv) XeO3 F2 (xvi) XeO2 F4 (xvii) KrF4
Dipole Moment
14. Arrange the following compounds in decreasing order of dipole moment.

(i) NH , N F
3 3
(ii) CH 4 , CCl 4 , BF3 (iii) CH 3Cl, CH 2 Cl 2 , CHCl3  CCl 4

(iv) CH 3 F, CH 3I, CH 3Br, CH 3Cl (v) HI, HBr , HCl, HF

Building No. 12B/58, 2nd Floor, Rd Number 203, Sector 12B, Dwarka New Delhi-110075, Tel No. 7042232561, Email: xiitacademy@gmail.com 3
 Br Br Br Br F
Br OH
(vi) , , , (vii) (Showing different dipole moment than expected)
Br
Br
F C C C
CH 3 C C
(viii) (Showing different dipole moment than expected) (ix) , ,
C C C C
C C
Molecular Orbital Theory
15. Select the T/F statements regarding the MOT.
(i) Orbital used in MOT is common to all the atoms involved in bond formaton.
(ii) In MOT orbitals of different atoms are mixed to give same number of molecular orbitals.
(iii) In MOT orbitals of same atom are mixed to give same number of molecular orbital.
(iv) The energy of B.O is less as compared to orbitals mixed initally.
(v) The energy of A.B.O is more as compared to orbitals mixed initially.
(vi) B.O present nearest to the nucleus of atom involved in molecule formation.
(vii) A.B.O present nearest to the nucleus of atoms involved in molecule formation.
(viii) Bond strength increases as bond order increases.
(ix) Bond length increases as bond order decreases.
(x) Species containing unpaired electron(s) are diamagnetic in nature.
16. Find the bond order of following species.
(i) H2 (ii) H 2 (iii) H 2 (iv) He2 (v) He 2 (vi) N 2
(vii) N 2 (viii) O 2 (ix) O 2 (x) O 2  (xi) NO (xii) NO  (xiii) C2
(xiv) C 2 (xv) C 2  (xvi) CO (xvii) CO  (xviii) C 2 (xix) NO  


(xx) C N (xxi) Ne2 (xxii) F2
17. Arrange the following as instructed
(a) H 2 , He 2 , N 2 , N 2 (Decreasing bond strength) (b) O 2 , O 2  , O 2 , O 2 (Decreasing bond length)
(c) N 2 , N 2 , N 2  , N 2 (Decreasing stability order) (d) NO, NO  , CO, CO  (Decreasing bond order)
18. Select the paramagnetic /Diamagnetic species.
(i) H2 (ii) N 2 (iii) C2 (iv) H 2 (v) O 2 (vi) C 2
(vii) H 2 (viii) O 2 (ix) C 2  (x) He2 (xi) O 2  (xii) CO

(xiii) He 2 (xiv) NO (xv) CO  (xvi) N 2 (xvii) NO  (xviii) C 2

Building No. 12B/58, 2nd Floor, Rd Number 203, Sector 12B, Dwarka New Delhi-110075, Tel No. 7042232561, Email: xiitacademy@gmail.com 4
 -----------------------------------ANSWER KEY----------------------------------------
1. (i) Metallic bond, (ii) Ionic bond, (iii) Co-valent /Co-ordinate (iv) Co-valent/Co-ordinate (v) Ionic bond
2. (i) F (ii) T (iii) F (iv) T (v) T (vi) F (vii) F (viii) F (ix) T (x) T

O O
  
3. (i) Na  S  Na  (ii) K  O   S  O  K  (iii) Ba   [O  S  O]
 
O O
O O O
  
(iv) Cu   [O  S  O]  (v) 2K  [O  C  O]  (vi) K  [O  Cl  O]
 
O O

S O O
  
   
 
(viii) K O  P  O K (ix) 3 Ca 2 [O  P  O ]

(vii) K  O   S  O  K 
  
O OK  O
O O O O O
     
(x) 2 Al 3 [O  S  O]
3  
(xi) K O  Cr O  Cr  O  K  (xii) K  O   S  O  O  S  O  K 
    
O O O O O

 CN  

CN CN NC CN

(xiii) K  N  C
 (xiv) 4K  Fe2 (xv) 2K  Ni  
  

CN  CN NC CN
CN
O O
   
(xvi) Na  O   S  S  S  S  O Na
 
O O
4. (i) F (ii) T (iii) T (iv) T (v) T (vi) T (vii) T (viii) T

5. (i) Li   K   Rb   Cs  (ii) Be    Mg    Ca    Sr   (iii) Al3  Mg    Na 

(iv) C 4   N 3  O    F  (v) Mn 7   Mn 6  Mn 4   Mn 2 (vi) I   Br   Cl   F 

6. (i) NaI  NaBr  NaCl  NaF (ii) AlCl3  MgCl 2  NaCl

(iii) CaF2  CaCl2  CaBr2  CaI2 (iv) Rb 2CO 3  K 2 CO 3  Na 2CO 3  Li 2CO 3
(v) Sr (OH) 2  Ca (OH) 2  Mg(OH) 2  Be2 (OH) 2 (vi) GeCl2  GeCl4 (vii) SnCl2  SnCl4
(viii) PCl3  PCl5 (ix) HF  H 2O  NH 3 (x) NaI  AgI

7. (ii), (iv), (v), (vi), (viii), (ix), (x), (xii), (xi)

8. Inter - (i), (ii), (iii), (iv), (v), (vi), (vii), (viii), (ix), (x)
Intra - (i), (iii), (vi), (viii), (ix) Both - (ii), (iii), (vi), (viii), (ix)
9. (i) dba c (ii) cba (iii) bda c (iv) ba cd

10. (i)T (ii) T (iii) T (iv) T (v) T (vi) T (vii) F (viii) T (ix) T (x) T

11. (i) F (ii) F (iii) T (iv) T (v) T (vi) F (vii) T (viii) T (ix) F (x) T

Building No. 12B/58, 2nd Floor, Rd Number 203, Sector 12B, Dwarka New Delhi-110075, Tel No. 7042232561, Email: xiitacademy@gmail.com 5
12. (i) (sp3) (ii) (sp3d) (iii) (sp3) (iv) (sp3d2) (v) (sp3d1) (vi) (sp)
(vii) (sp 2 ) (viii) (sp) (ix) (sp) (x) (sp 2 ) (xi) (sp 2 ) (xii) (sp 2 )

(xiii) (sp 3 ) (xiv) (sp 3 ) (xv) (sp 3 ) (xvi) (sp 3 ) (xvii) (sp 3 ) (xviii) (sp)

(xix) (sp 3 ) (xx) (sp 2 ) (xxi) (sp 2 ) (xxii) (sp 2 ) (xxiii) (sp 2 ) (xxiv) (sp 3 )
(xxv) (sp 3 ) (xxvi) (sp 3 ) (xxvii) (sp 3 ) (xxviii) (sp 3 ) (xxix) (sp 2 ) (xxx) (sp3d1)
(xxxi) (sp3d2) (xxxii) (sp3d2) (xxxiii) (sp3d2) (xxxiv) (sp3d3) (xxxv) (sp3d3)

13. (i) (V -shape) (ii) (Pyramidal) (iii) (Linear) (iv) (T-shape) (v) (Squar planer)
(vi) (T-shape) (vii) (Pyramidal) (viii) (Sqare pyramidal) (ix) (Linear)
(x) (Square planer) (xi) Square pyramidal (xii) (Sea-saw)
(xiii) (Pentagonal bipyramidal) (xiv) (Tetrahedral) (xv) Trigonal bipyramidal
(xvi) Octahedral (xvii) Square planer

14. (i) a > b (ii) a = b = c (iii) a > b > c >d (iv) da cb
(v) cdba (vi) abdc (vii) Due to hydrogen bonding
(viii) Steric repulsion (ix) a  b  c' ( Zero)

15. (i) T (ii) T (iii) F (iv) T (v) T (vi) T (vii) F (viii) T (ix) T (x) F

1 1 1
16. (i) 1 (ii) (iii) (iv) 0 (v) (vi) 2.5 (vii) 2.5 (viii) 1.5 (ix) 2.5 (x) 1 (xi) 2.5
2 2 2
(xii) 3 (xiii) 2 (xiv) 2.5 (xv) 3 (xvi) 3 (xvii) 2.5 (xviii) 2.5 (xix) 2.5 (xx) 2.5 (xxi) 0 (xxii) 1.5
    
17. (a) N 2  N  H 2  He
2 2
(b) O  O2  O  O
2 2 2

(c) N 2  N 2  N 2  N 2  (d) CO  NO   NO  CO 

18. Paramagnetic - ii, iv, v, vi, vii, viii, x, xiii, xiv, xv, xvi, xviii , Diamagnetic - i, iii, ix, xi, xii, xvii

Building No. 12B/58, 2nd Floor, Rd Number 203, Sector 12B, Dwarka New Delhi-110075, Tel No. 7042232561, Email: xiitacademy@gmail.com 6