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    IR Assignment

    Uploaded by

    Prakash Dolai
    The document describes the infrared absorption peaks of various organic compounds, including p-aminobenzoic acid, cinnamic acid, p-nitrobenzaldehyde, o-hydroxyacetophenone, salicyaldehyde, salicylamide, p-bromoacetanilide, vanillin, p-nitroaniline, p-methyl-α-bromoacetophenone, diethyl maleiate, and diethyl fumerate. For each compound, the document lists the absorption frequency in wavenumbers and assigns each peak to a particular bond or functional group, such as aromatic C=C stretches, C-H bends, C=O stretches, and

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    IR Assignment

    Uploaded by

    Prakash Dolai
    72 views4 pages
    The document describes the infrared absorption peaks of various organic compounds, including p-aminobenzoic acid, cinnamic acid, p-nitrobenzaldehyde, o-hydroxyacetophenone, salicyaldehyde, salicylamide, p-bromoacetanilide, vanillin, p-nitroaniline, p-methyl-α-bromoacetophenone, diethyl maleiate, and diethyl fumerate. For each compound, the document lists the absorption frequency in wavenumbers and assigns each peak to a particular bond or functional group, such as aromatic C=C stretches, C-H bends, C=O stretches, and

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    The document describes the infrared absorption peaks of various organic compounds, including p-aminobenzoic acid, cinnamic acid, p-nitrobenzaldehyde, o-hydroxyacetophenone, salicyaldehyde, salicylamide, p-bromoacetanilide, vanillin, p-nitroaniline, p-methyl-α-bromoacetophenone, diethyl maleiate, and diethyl fumerate. For each compound, the document lists the absorption frequency in wavenumbers and assigns each peak to a particular bond or functional group, such as aromatic C=C stretches, C-H bends, C=O stretches, and

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    72 views4 pages

    IR Assignment

    Uploaded by

    Prakash Dolai
    The document describes the infrared absorption peaks of various organic compounds, including p-aminobenzoic acid, cinnamic acid, p-nitrobenzaldehyde, o-hydroxyacetophenone, salicyaldehyde, salicylamide, p-bromoacetanilide, vanillin, p-nitroaniline, p-methyl-α-bromoacetophenone, diethyl maleiate, and diethyl fumerate. For each compound, the document lists the absorption frequency in wavenumbers and assigns each peak to a particular bond or functional group, such as aromatic C=C stretches, C-H bends, C=O stretches, and

    Copyright:

    © All Rights Reserved
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    of 4

    p-Aminobenzoic Acid

    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3461 & 3364 -N-H stretching of Primary amine
    (symmetric & antisymmetric)
    2954 Aromatic =C-H stretching
    1652 C=O stretching of Carboxylic Acid
    1637 Aromatic C=C stretching
    1575 N-H bending
    1310 C-N stretching
    843 C-H bending, indicating p-disubstitution

    Cinnamic Acid
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3027 Alkene =C-H stretching
    2977 Aromatic =C-H stretching
    2596 broad, O-H stretching of Carboxylic Acid
    1686 C=O stretching of Carboxylic Acid
    1631 Conjugated C=C stretching
    1288 C-O stretching
    982 C-H bending for conjugated trans alkene
    769 & 712 C-H bending, indicating mono substitution

    p-Nitrobenzaldehyde
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3107 Aromatic =C-H stretching
    2862 CSp2-H stretching of aldehyde
    1710 C=O stretching of aldehyde
    1608 Aromatic C=C stretching
    1543 & 1347 Symmetric & antisymmetric stretching of –
    NO2 group
    819 C-H bending, indicating p-disubstitution
    o-Hydroxyacetophenone
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3060 broad, H-bonded O-H stretching
    1643 Conjugated & H-bonded C=O stretching of
    ketone
    1631 Conjugated C=C stretching
    1617 Aromatic C=C stretching
    1582 Benzene ring
    1245 Phenolic C-O stretching
    755 C-H bending, indicating o-di substitution

    Salicyaldehyde
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3189 broad, H-bonded O-H stretching
    3064 Aromatic =C-H stretching
    2847 & 2747 CSp2-H stretching of aldehyde
    1665 Conjugated & H-bonded C=O stretching of
    aldehyde
    1645 & 1621 Aromatic C=C stretching
    1581 Benzene ring
    1228 Phenolic C-O stretching
    757 C-H bending, indicating o-di substitution

    Salicylamide
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3396 & 3190 -N-H stretching of Primary amide
    (symmetric & antisymmetric)
    3060 Aromatic =C-H stretching
    1675 Conjugated C=O stretching of amide
    1630 Aromatic C=C stretching
    1590 Benzene ring
    1253 C-O stretching of amide
    761 C-H bending, indicating o-di substitution
    p-Bromoacetanilide
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3304 & 3265 -N-H stretching of secondary amide
    (symmetric & antisymmetric)
    3064 Aromatic =C-H stretching
    2966 & 2926 Csp3-H stretching of keto-methyl group
    1671 C=O stretching of amide
    1604 Aromatic C=C stretching
    1588 & 1536 Benzene ring
    836 C-H bending, indicating p-di substitution
    ~ 505 C-Br Stretching

    Vanillin
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3539 Non H-bonded O-H stretching
    3075, 3015 Aromatic =C-H stretching
    2943 CSp3-H stretching of -OMe
    2819 & 2724 CSp2-H stretching of aldehyde
    1698 C=O stretching of aldehyde
    1600 Aromatic C=C stretching
    1509 Benzene ring
    1258, 1149 & 1034 C-O stretching

    p-Nitroaniline
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3484, 3365 & 3244 -N-H stretching of Primary amine
    (symmetric & antisymmetric)
    1633 Aromatic C=C stretching
    1603 Benzene ring
    1589 & 1313 Symmetric & antisymmetric stretching of –
    NO2 group
    843 C-H bending, indicating p-di substitution
    p-Methyl-α-bromoacetophenone
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3031 Aromatic =C-H stretching
    3002 & 2953 CSp3-H stretching of -Me
    1693 C=O stretching of aldehyde
    1612 & 1606 Aromatic C=C stretching
    1392 Alkane C-H deformation
    836 C-H bending, indicating p-di substitution
    552 C-Br stretching

    Diethyl maleiate
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    3058 & 2986 Aromatic =C-H stretching
    2942 & 2908 CSp3-H stretching of ethyl group
    1730 C=O stretching of Carboxylic ester
    1641 Aromatic C=C stretching
    1368 Alkane C-H deformation
    1299 & 1164 C-O stretching of Carboxylic ester
    970 Csp2-H bending, indicating trans alkene

    Diethyl fumerate
    Assignment of IR absorption peaks:

    Absorption frequency (cm-1) Assignment


    2986 Aromatic =C-H stretching
    2941 & 2907 CSp3-H stretching of ethyl group
    1726 C=O stretching of Carboxylic ester
    1645 Aromatic C=C stretching
    1368 Alkane C-H deformation
    1297 & 1164 C-O stretching of Carboxylic ester

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