° SAGAR PUBLIC SCHOOL, BHOPAL ay) TERM - II EXAMINATION, 2022 - 23 CLASS - XII SET-A TIME: 3 Hours CHEMISTRY (043) M.M.: 70 General instructions: 4a) There are 33 questions in this question paper. All questions are compulsory. b) SECTION: A: Q. No. 1 t0 2 are case-based questions having four MCQs or Reason Assertion type based on given passage each carrying 1 mark and Q.No.3-16 is objective type carrying I mark each. d) SECTION: B: Q.No. 17-25 is short answers questions carrying 2 marks each. ¢) SECTION: C: Q.No.26-30 is short answers questions carrying 3 marks each. ¢) SECTION:D: Q.No. 31-33 is long answer questions carrying 5 marks each. SECTION-A Qu Read the passage given below and answer the following questions In these questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices: (a) Assertion and reason both are correct statements and reason is correct explanation for assertion (b) Assertion and reason both are correct statements and reason is not the correct explanation for assertion (c) Assertion is correct statement but reason is wrong statement. (@) Assertion is wrong statement but reason is correct statement (©) assertion and reason both are incorrect statements. Both alcohols and phenols are acidic in nature, but phenols are more acidic than alcohols. Acidic strength of alcohols mainly depends upon the inductive effect. Acidic strength of phenols depends upon a combination of both inductive effect and resonance effects of the substituent and its position on the benzene ring. Electron withdrawing ‘groups increases the acidic strength of phenols whereas electron donating groups decreases the acidic strength of phenols. Phenol is a weaker acid than carboxylic acid 1. Assertion: Boiling points of alcohols and ethers are high. i o Reason: They are involved in intermolecular hydrogen bonding. % 2. Assertion: The reaction of phenol with aqueous sodium hydroxide indicates that 1 1 phenols are strong acids than alcohols and water. Reason: The delocalization of negative charge makes phenoxide ion more stable and favors the ionization of phenol. , 3. Assertion: Primary alcohols are the easiest to dehydrate. ‘4, 1 Reason: Primary carbocations are less stable. 4, Assertion: Phenol is more reactive than benzene towards electrophilic substitution 1 reaction, a Reason: -OH group in phenol is 0, p directing.“Q2 Read the passage given below and answer the following questions: Standard electrode potentials are used for various Processes: . (i) Itis used to measure relative strengths of various oxidants and reductants, (ii) Its used to calculate standard cell potential. (ii) It is used to predict possible reactions, A set of half-reactions (in acidic medium) along with their standard reduction Potential, E° (in volt) values are given below: bier; v Ch#2e—2Cl 5 E=1.36 VMn*+ Mn” ; 50 V Fe™+ "Fe 77V O2t4H"+4e"2ER0 ; E*=1.23 V The following questions are multiple choice questions. Choose the most appropriate answer: () Which of the following statements is correct? 1 \@) Cl'is oxidised by Oz __(b) Fe** is oxidised by iodine (©) Tis oxidised by chlorine. (4) Mn** is oxidised by chlorine fi) Mn** is not stable in acidic medium, while Fe**is stable because (@) O2 oxidises Mn®* to Mn?* (b) Or oxidises both Mn’* to Mn** and Fe®* to Fe* \O Fe*oxidises 120 to O2 (@) Mn®* oxidises H20 to O2 (iii) The strongest reducing agent in the aqueous solution is ar (b) cr (c) Mn* (d) Fe* (iv) The emf for the following reaction is bh+KCl#2KI+Ch @)-082V byt0.82V (©)-0.73V @)40.73V The following questions, (3-14) are multiple choice questions carrying 1 mark each. Choose the most appropriate answer: Q3 Which of the following condition is not satisfied by an ideal solution? 1 a (a) AH mixing (©) AV mixing (©) Raoult’s Law is obeyed \0@) Formation of an azeotropic mixtureQs Q6 Qi Qs Quo -" Which has the highest boiling point at | atm pressure? 1 (@0.1MKCL fb) 0.1 M Celi. (c) 0.1 M Cele, (@) 0.1 MC2H20n A sugar syrup of weight 214.2 g contains 34.2 g of sugar, its molality would be SJ (a) 0.55 ws Few Be nat @55 Ny Wo, » (2) minimum boiling azeotropic mixture (b) maximum boiling azeotropic mixture (6) binary mixture (@) None of the above Which of the following solutions shows positive deviation from Raoult’s law? RA Which of the following is a secondary cell? M1 1 (@) Lectanche cell \Q®) Lead storage battery < () Concentration cell (@ All of these Equilibrium constant K is related to E°ea and not Beat because (a) E°ceu is easier to measure than Ext \) Eces becomes zero at equilibrium point but E°cell remains constant under all conditions (©) ata given temperature, Feat changes hence value of K can’t be measured (@) any of the terms Ecet or E¥e can be used ‘The compound obtained by the reaction of ethene with diborane followed by hydrolysis with alkaline H202 is vA (@) ethanol (©) propanol (e) butanol #8) riethyl bromide ‘Which of the following reactions follows Markovnikov’s rule? ti eh Coe + HBr (b) CsHs + Ch (©) Gals + HBr (@GHe+ BrQuy Qn, Qn Qu, Qus < veal rinated product Which of the following compounds can yield only one monochilo' Ubon 56 free radical chlorination? (a) 2, 2-Dimethylpropane \4b) 2-Methylpropane (©) 2-Methylbutane (d) n-Butane tion Which of the following alcohols does not give a stable compound on dehydrati a (a) 2-methyl-propan-2-ol ‘€6) 2-methyl -1-propanol (©) Butan-2-ol (@) methanol 4 0 By + 38 ——_» + SHB: Reagent is \(@) bromine in water (b) bromine in benzene (©) potassium bromide solution (d) bromine in CCl at 0° C Ammonia acts as a ve because (2) NH isa gas while NH«* is in liquid form. a (b) NHs undergoes sp? hybridisation while NHs* undergoes sp'd hybridisation \éc) NH¢” ion does not have any lone pair of electrons (d) NH«* ion has one unpaired electron while NHs has two “unpaired electrons. ry good ligand but ammonium ion does not form complexes i] ‘The oxidation state of nickel in [Ni(CO4)] is ae 1 @1 (b) 4 (2 We) 016 Among the 2 ng the following Which are ambidentate ligands? @ SCN Xai), NOs” ‘ aii) NOx @v) Cx? @) @) and Gi) q (b) @) and (iv) VO) (ii) and (ii) @ Gi) and (iv) SECTION-B : 17 e) What would be the value of Van't Hof’ factor fra dilute solution wisn sere ~Ci)_ Why is elycol and water mixture used in car adators in cold countries? se of vapour pressure and molar mass Q38 — Derive the relationship between relative lowering of solute, 2 Q19——Givereason: gy Thionyl chloride is preferred for converting aleohol to chloroalkane \ SG) Phenol cannot be converted to chlorobenzene by reacting with HC. Qa) ‘Draw the structure of major mono halogen product formed in the following react=~ 2 CH, oane Gi) Among the following pair of compounds, which will react faster by Sw1 mechanism and why? a 1 Q31y io A and W KQan i) ve does p-dichlorobenzene have a higher m.p. than its 0 and m-isomers? 2 e Ci) Why is (2)-Butan-2-0l optically inactive? QR —_Howwill youconvert: : 2 (@) Phenol to aspirin ® (@) Butanol to Butanoie acid ORWhich of the following is an appropriate set of reactants for the preparation of 1-methoxy-4-nitrobenzene and why? @ wy " CHhONe No; V6) ONa © ctor ——— Q.23* What happens when phenol is heated with: x ? \A)zine dust \@) chloroform in the presence of an alkali Q24 How would you account for the following? 4 2 4) CPt is reducing in nature while with the same d-orbital configuration (d*) Mn?" is an oxidizing agent, L¢#) Transition metals generally form coloured compounds, Q.25 i _ Indicate the types of isomerism shown by the complex: wa 2 [Co(NES)s(NO3)IQNOn).(At.No.Co=27)/**A9«. (ii) Name the following coordination compounds according to IUPAC system of nomenclature: Aa) [Co (NHs)s(H20)CI] Cl 8) [CrClaen)2]Cl SECTION-C Q.26 (i) The experimentally determined molar mass for what type of substances is always + 3 ower than the true value when water is used as solvent? Explain. Give one example of such a substance and one example of a substance which does not show a large variation from the true value. ‘U4ii) Calculate the osmotic pressure of 0.25 M solution of urea at 27°C. (R=0.0821 LatmimoVK) = 6/575 crn, Q.276 Given thatthe standard electrode potentials (E*) of metals are: 3 K*/K = -2.93 V, Ag'/Ag = 0.80 V, Cu**/Cu = 0.34 V, Mg*/Mg = -2.37 V, Cr°/Cr=-0.74 V, Fe*/Fe =-0.44 V. Arrange these metals in increasing order of their reducing power. Agtiag < Co¥cuc FeM/pe ty Yer < 2g CK|g The conductivity of 0.20 M solution of KCI at 298 K is 0,025 S em". CaleulatyAts molar conductivity 125 Semtnnt”! The sandard electrode potential (E*) for Daniel cell is +1.10 V. Calculate the 4G” a the reaction: Jae) # Cu*(aq) — Zni*(aq) + Culs) (LF =96500C mort) 13°39 KF 28 Illustrate the following reactions giving a chemical equation for each < c4a)Kolbe’s reaction 2CP (ayy + 3Feus , (Given E°eell = 0.30V) How many coulombs are required to reduce 1 mole CnO7* to CP*? What is meant by ‘disproportionation’? Give an example of a disproportionation 5 reaction in aqueous solution, A blackish brown solid ‘A’ when fused with alkali metal hydroxide in presence of ait, produces a dark green coloured compound ‘B’, which on electrolytic oxidation in alkaline medium gives a dark purple coloured compound ‘C’. Identify A, B, C and rite the reactions involved. What happens when an acid solution of green coloured ‘compound (B) is allowed to stand for some time, ‘The increase in size between the 3d and 4d metals is much greater than between the 4d and 5d metals Justify OR Ni?* compounds are thermodynamically more stable than Pt?", whereas Pt** compounds are more stable than Ni**. Why? Magnetic moment of Se™ion is zero? Justify. * Complete the following equations: 2MnOs+5SO;*+6H" —> Cr07?> + 14H* + 6Fe* —> Draw the structures of majgr mono halo products in each of the following reactions: 5 — on Le) Oo ree cr* CHC Vt) Br, heat or, ae OY owhS mis. fer Gi) UV iight Draw the structure of DDT and write its IUPAC name. OR How will you bring about the following conversions? (a) Toluene to benzyl alcohol (b) 1-Chlorobutane to n-octane (©) Benzene to biphenyl. tert-Butyl bromide reacts with ag. NaOH by Sx] mechanism while n-butyl bromide reacts by Sx2 mechanism. Why? (End of the question paper)