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1610jeemaleaderiip1 CBT Off 39022 Test Sol Tteteghjcl
1610jeemaleaderiip1 CBT Off 39022 Test Sol Tteteghjcl
PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6
SECTION-I (i)
A. A,B,C,D A,D B,D B,D A,B,D B,D
Q. 7 8 9 10
SECTION-I (ii)
A. C A A C
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 1.00 4.00 7.00 5.00 4.00 75.00 15.70 90.00
PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6
SECTION-I (i)
A. A,B,C,D B,C,D A,C A,B,C,D C,D B,C
Q. 7 8 9 10
SECTION-I (ii)
A. A A B C
Q. 1 2 3 4 5 6 7 8
SECTION-II
A. 12.00 9.00 0.00 1.00 2.00 6.00 8.00 0.00
HINT – SHEET
PART-1 : PHYSICS 3. Ans ( A,B,C,D )
SECTION-I (i) dP
(F ext )net = m + 10) a ⃗
= (
dt
1. Ans ( C )
w.r.t. plank
So 10gsin37° = 10acos37°
3
a = 10 × = 7.5 m/s2
4
1
KE b = × 10 × (7.5t) 2
2
dKE b
= 562.5t
dt
1001CJA103222005 HS-1/7
Target : JEE (Main + Advanced) 2023/16-10-2022/Paper-1
PART-1 : PHYSICS
4. Ans ( A,D )
SECTION-II
1. Ans ( 8.00 )
11
(50 + 100)2 = 50 (v–3/5) + 100 v ⇒ v =
5
11 3
∵ vM
⃗
g = vP⃗ g + vM p = − ;
/ / /
5 5
8
vM
⃗
g = ;
/
5
−−−−−−
Vc = √22 + 42 = √−−
20 m/s S = vM /g × 5 = 8 m
2. Ans ( 2.00 )
5. Ans ( A,B,C,D ) 1
Sy = Uy t + a y t2
2
m g 2
0 = √−−−
2gh − μg (1 + t
− 10 sin 53o = 10 cos 53o t − t
M
)
2
−−−
t = 2 sec
√ 2gh M
t =
μg (m + M )
−−−
m × √2gh + M × 0
4. Ans ( 4.00 )
vcm =
m+M
−−−
√ 2gh
Impulse = Mvf – M × 0 = Mm
m+M
PART-1 : PHYSICS
SECTION-I (ii)
L
8. Ans ( B ) t=
v
μL
F= g sin θ + μv
v
μgh
mv2 F= + μv
µ + mg =
v
r
−μgh
1 × 12 For Fmin ⇒ μ = 0
22 + 1 × 10 =
v2
+
R
3 v = √−−
gh
R =
8
μgh −− −−
9. Ans ( A ) F min =
−−
+ μ√gh = 2μ√gh
√ gh
−−
τ min = 2μ√gh R
5. Ans ( 200.00 )
Relative velcoity VA/B must be along line of
joining A and B
100 20
tan θ = =
D 40
⇒ D = 200 M
HS-2/7 1001CJA103222005
Leader Course/Phase-II/16-10-2022/Paper-1
6. Ans ( 3.00 ) 5. Ans ( A,B,D )
For expansion and compression both, with
proper sign convention
Wirr > Wrev
⇒ ΔUirr > ΔUrev
⇒ T2 irr > T2 rev.
6. Ans ( B,D )
10/180 50
T – 10N = 1a
(A) Molality = = m
90/1000 81
30N – T = 3a 50
(B) ΔTb = 0.52 × = 0.32°C
7. Ans ( 2.00 ) 81
50
(C) ΔTf = 1.86 × = 1.148°C
81
10
180 1
(D) Xg glucose = =
10
+
90 91
180 18
PART-2 : CHEMISTRY
SECTION-I (ii)
3g – T2 = 3a ..........(i)
10. Ans ( C )
T2 – T1 = 6a...........(ii)
T1–1g = 1a ............(iii)
Step i : fast
2g – (T2–T1) = 4a .............(iv)
_____________________________________
2g – 6a = 4a
Overall : 2O3(g) —→ 3O2(g)
10a = 2g
d[O 3 ]
1 − = k3[O3] [O] ........... (1)
a = g dt
5 k1 [O 2 ] [O] k [O ]
= ⇒ [O] = 1 3 ........... (2)
8. Ans ( 4.00 ) k2 [O 3 ] k2 [O 2 ]
10 2 From (1) & (2),
a = = 1m/s
2+4+4
4 d[O 3 ] k3 k1 [O 3 ] 2
T = (2 + .2) 1 = 4N −
dt
=
4 k2 [O 2 ]
PART-2 : CHEMISTRY PART-2 : CHEMISTRY
SECTION-I (i) SECTION-II
and Na+ ions occupy all the octahedral voids Electrophiles : (i), (iii), (vi), (viii), (ix), (xi), (xii)
with 6 : 6 co-ordination.
1001CJA103222005 HS-3/7
Target : JEE (Main + Advanced) 2023/16-10-2022/Paper-1
7. Ans ( 15.70 ) 4. Ans ( A,B,C,D )
w = – 1 atm (4 – 1) = – 3 L-atm = –300 Joule
a b 2c
q = CΔT
lim x ( + )−
x→0
P 2 V2
T2 = . T1 = 2T = 600 K
1
P 1 V1 Now ckeck the options.
q = 50 × 300 = + 15000 J
ΔH = (q + w) + (P2V2 – P1V1)
5. Ans ( C,D )
= + 15000 – 300 + (20 – 10) × 100
3 2
600 = P Ao × + P Bo × .......... (1)
5 5
4.5 2
630 = P Ao × + P Bo × .......... (2)
7 7
Graph of f(x)
ƒ(3) = 1 = d ...(1)
ƒ ′ (3) = –1 = c ...(2)
50 61
< d<
ƒ ″′ (3) = 12 = 6a ⇒ a = 2 ...(4)
13 13
2
ƒ ′ (x) = 6(x – 3) – 1 aa3 = a 11 = 3 + 10d = 43
2. Ans ( B,C,D ) 15
15
∑ ai = (2 (3) + 14 (4))
−5 1 2
M = ,N = i=1
15 15
= 15(3 + 28)
3. Ans ( A,C )
sin 3x + A sin 2x + B sin x = 15(31) = 465
lim( ) = f (0)
x→0 x5
= ƒ(0)
7. (I) cot–1 tan(–37°) or π + tan–1 (tan37°)
Ans ( A ) 2
3α = nπ + kα
–1
⇒ cos (–cos53°) ⇒ 180° – 53° = 127°
α(3 – k) = nπ
⇒ k = 3
(III) sin( 1 cos 1
−
(
1
))
2 9
(II) ∴ (x – 1)(3 – x) > 0 & x ≠ 2
let 1 cos − 1 (
1
) = θ
2 9
1 < x < 3 & x ≠ 2
1
1
∴ cos ) = 2θ
−
(
2 2
(III) (2cos y – 1)(2cos x – 1) = 3a – 2
9
3a − 2 1
cos2y – cos2x = .....(1)
or cos2θ =
2 9
a2 1
cos2x + sin2y = .....(2)
or 1 −
9
= 2sin 2 θ
2
equation (1) + (2)
2
or sinθ =
a2 3a − 2 3
⇒ a2 + 3a – 4 = 0
+
1 =
2 1 1 1 2
∴ sin( cos −
( )) =
a = 1 & a = –4 (impossible)
2 9 3
(IV) 36 = 18a
(IV) cos( 1 cos − 1 (
1
))
2 8
22 × 32 = 32a × 2a
1 1 1
let cos −
( ) = θ
2 8
22–a = 32a–2 ........(1)
1
72 = 24b
or cos2θ =
8
23 × 32 = (3 × 23)b
1
or 2cos2θ – 1 =
8
23–3b = 3b–2 ........(2)
3
from (1) & (2)
cosθ =
4
2a − 2 b−2
=
2−a 3 − 3b
6a – 6 – 6ab + 6b = 2b – 4 – ab + 2a
4a + 4b – 5ab = 2
1001CJA103222005 HS-5/7
Target : JEE (Main + Advanced) 2023/16-10-2022/Paper-1
9. Ans ( B ) 3. Ans ( 0.00 )
ƒ(x) = 3
1
lim f (x) =
1 1 1 1/3 1 x→0 3
(I) + + +. . . ∞ = =
xα + β tan x 1
3 9 27 1 2
1− lim
x→0
=
3
3 x2 tan x
(II) tan–13 + tan–12
αx + β (x +
x3
+. . .)
3 1
3+2 ⇒ lim =
= π + tan 1 ( −
)
x→0 x3 ( tan x
) 3
1 − 3.2 x
β
π 3π ( α + β) x + ( 3 ) x 3 +. . .
= π − =
1
4 4 ⇒ lim =
x→0 x3 3
(III) |x – 3| ≤ 4
β 1
⇒ –4 ≤ x – 3 ≤ 4
so α + β = 0, =
3 3
⇒ –1 ≤ x ≤ 7
⇒ β = 1, α = −1
1
2x + 1 x − 1 4. Ans ( 1.00 )
(IV) lim ( e2 3
/
x→1 3
) =
As sin–1(x2) = cos–1x ⇒ x > 0
sin–1(x2) = sin–1√1 − x 2
−−−− −
⇒p+q=5
4 2
10. Ans ( C ) ⇒ x + x = 1
2x − 1
1 –1
4
x
5
x x ⇒ ƒ(x) = ƒ (x)
b = lim 3 (2 + 3(
3
) + 4(
x
) ) = 3
x→(−∞) ⇒ ƒ(ƒ(x)) = x
–1
(III) At x = n, n ∈ I
⇒ ƒ(x) + 2ƒ (x) + 2 = ƒ(ƒ(x)) reduces to
3(x − 2)
LHL = n sin(π(2n – (n – 1)))
= x − 2
2x − 1
= n sin((n + 1)π) = 0
(x − 2)
⇒ (3 − 2x + 1) = 0
⇒ 2(x – 2)(2 – x) = 0
⇒ x = 2
x/3 x
⎛
e − − 1 ⎞
3 3 1 1 6. Ans ( 6.00 )
(IV) lim 3 ⎜
⎜
⎟
⎟ = . =
x→0
⎜
x2 ⎟ 9 2 6 y = ax2 + bx + c
⎝ .9 ⎠
9
y is max at x = –2
PART-3 : MATHEMATICS b
⇒ − = − 2 ⇒ b = 4a
SECTION-II 2a
D −
4a
2
(b − 4ac) 1
sin–1 (sin 9) + tan–1 (tan 9) + sec2 (tan–1 1) + =
4a 2
cosec2 (cot–1 3)
4ac – b2 = 2a
2. Ans ( 9.00 ) 2c – 8a = 1
x 2 + 2x + 7
ex→∞(
lim
− 1) (3x + 5) = e9 ⇒ 2c – 8a + 5 = 6
x2 − x + 1
HS-6/7 1001CJA103222005
Leader Course/Phase-II/16-10-2022/Paper-1
7. Ans ( 8.00 ) 8. Ans ( 0.00 )
6cos5θ – 6cos4θ – 5cos3θ + 5cos2θ + cosθ – 1 = 0
π 3 π
2 tan( )+
π
− 4 cos( )
4 2 10 cos( 10 ) 10
⇒ 6cos θ(cosθ – 1) – 5cos θ(cosθ – 1) + (cosθ – 1) = 0
π
π 3 − 4cos2 (
10
)
4 2
⇒ (cosθ – 1){6cos θ – 5cos θ +1} = 0
= 2 tan( )+
π
10 cos( 10 )
π π
2 2
⇒ (cosθ – 1)(3cos θ – 1)(2cos θ – 1) = 0
π ( 4cos3 (
10
)− 3 cos( 10 ))
= 2 tan( )−
π
10 cos2 ( )
10
π ) cos( π ) − cos( 3π )
2 sin( 10 10 10
=
π
cos2 (
10
)
cos2 (
10
)
2π 3π
= 0 (sin = cos )
10 10
1001CJA103222005 HS-7/7
(1001CJA103222006) Test Pattern
PART-2 : CHEMISTRY
Q. 1 2 3 4
SECTION-I (i)
A. A C A C
Q. 5 6 7 8 9 10
SECTION-I (ii)
A. A,B,C A,C,D A,C,D B,C B,D B,D
Q. 1 2 3 4 5 6 7 8
SECTION-III
A. 7 5 4 5 4 5 9 2
PART-3 : MATHEMATICS
Q. 1 2 3 4
SECTION-I (i)
A. D A D A
Q. 5 6 7 8 9 10
SECTION-I (ii)
A. C,D A,B,C A,B,C D B,D A,B
Q. 1 2 3 4 5 6 7 8
SECTION-III
A. 9 2 0 5 4 1 6 5
HINT – SHEET
PART-1 : PHYSICS PART-1 : PHYSICS
SECTION-I (i) SECTION-I (ii)
Δt = 3s
V B⃗ / A = V B⃗ − VA
⃗
= − ^ + 4i 4^j
150m
ux = = 50 m/s
3s
Range = 50 × 9 = 450 m
1001CJA103222006 HS-1/6
Target : JEE (Main + Advanced) 2023/16-10-2022/Paper-2
6. Ans ( B,C ) PART-1 : PHYSICS
SECTION-III
1. Ans ( 4 )
N = F = 20 N
incorrect option)
20 – μk N = 2a
a = 4 m/s2
(C) By constraint there can be acceleration of A
towards right such that M will have an 2. Ans ( 8 )
acceleration upwards with no acceleration of f = 2N
2
(By constraint of string) W = –8J
7. Ans ( A,B,D ) 3. Ans ( 4 )
For the (man + cart) system
< F > = m < a >
= =
πR/v0 πR
3
x is the displacement of cart until man reaches at 4. Ans ( 3 )
point B is left side. And also from Dvcm = 0
u
m(u – v) = 2mv ⇒ v = (left)
3
v = velocity of cart when man jumps from the cart mv0 v0
u 2u
vCM = =
3m 3
∴ velocity of man = u − =
3 3 2v0
vB = 2vC⃗ − u ⃗ 2 = − 0 = 2 ⇒ v0 = 3m/s
Total horizontal distance travelled by man
3
−
−−−
2L 2u 2H 5. Ans ( 4 )
+ √ (Range = vH × t)
3 3 g ∫ x ⋅ dm ∫ xπy2 dxρ
x cm = =
∫ dm ∫ xy2 dxρ
8. Ans ( A,B,C )
6
Iω = τ Δt
∫ x ⋅ πρ ⋅ xk dx
2 0 2 63
1 τΔt)
( = = × = 4m
hence I ω2 = 6 3 62
2 2I ∫ xρ xk dx
0
HS-2/6 1001CJA103222006
Leader Course/Phase-II/16-10-2022/Paper-2
6. Ans ( 8 ) 4. Ans ( C )
τ = Iα
ΔTf = i Kfm
2
0.12 = × 1.5 × (0.2)2 α
⇒ 0.0054 = i × 1.8 × 0.001
3
α = 3 rad/s2
⇒ i = 3
0 = 24 – 3t
⇒ Complex is [MA6]A2
t = 8 sec
PART-2 : CHEMISTRY
7. Ans ( 5 )
F ⃗ = mg sin θ
SECTION-I (ii)
d ⃗ = 1m
5. Ans ( A,B,C )
0.5 1 (A) N(SiH3)3
sin θ = =
1 2
W = 5 × 1 = 5J
8. Ans ( 2 )
Due to back bonding sp3 hybridisation becomes
sp2 hybridised.
d
10 = ω0 − v1
2
d d 2md 2
m × 10 × = mv1 + × ω (A.M.C.) (B)
2 2 k
PART-2 : CHEMISTRY
SECTION-I (i)
1. Ans ( A ) Nodal plane of dπ lies in xy plane.
1
XeF 6 + H 2 O −−→ XeOF 4
1 : 3
back bonding.
3. Ans ( A )
–
PCl5 +4H2O → H3PO4 + 5HCl
√ 3a
= 2r C
XeF2 + H2O → Xe + 2HF + O2
4
–
⇒ rC =
√ 3
× 356 = 77.07 pm. B2H6 + 2NH3 → [BH2(NH3)2]⊕ [BH4–]
8
1001CJA103222006 HS-3/6
Target : JEE (Main + Advanced) 2023/16-10-2022/Paper-2
10. Ans ( B,D ) 8. Ans ( 2 )
1 (V − V0 ) (60 − 20)
k= ln ∞ = 1 ln
Required ΔH = –20 – 1200 + 3(40) + 3(–300)
= ln = ln 2
120 5 40 ∴ |ΔH| = 2
ln 2 ln 2 × 40
t1 2 = = = 40 sec.
PART-3 : MATHEMATICS
k ln 2
/
+
V0 ∝ [H ] ......... (1)
SECTION-I (i)
V∞ ∝ [H+] + a ......... (2)
(2)/(1)
1. Ans ( D )
[H +
]+ a V∞ 60 Applying the method of multiplication and
⇒ = = = 3
[H +
] V0 20
a division by conjugate, we get
⇒ 1 + = 3
[H
−−−− −−−−
√a + x + √a − x
+
]
−2ax
a Lim
⇒ = 2
x→0 2x −−−−
√ 2 −
a
−−−−
ax
−− −−−−
2 +√ 2 +
x
−−−−−−
2 a ax x
[H
+ + +
]
6 − a ⋅ 2√−
a
⇒ = 2
= = − √−
a
[H
+
] 2a
+
⇒ [H ]=3 2. Ans ( A )
PART-2 : CHEMISTRY
Limit
SECTION-III
2. Ans ( 5 )
c 2a a+c
+ =
2 4 2
f(0) = b
a + c)
(
function is continuous then f(0) = b =
Tetracycline has five chirality centres 2
6. Ans ( 5 ) 3. Ans ( D )
y = f(|x|)
2
For H2O(g) CPm = 4R
7 7
ΔCP = 2 × 4R – (2 × R + 1 × R)
2 2
= 8R – 10.5 R = – 2.5R
o
ΔH 400 =
0
ΔH 300 + ΔC P (400 − 300)
K K
− 2.5 (100) × 2
y = –f(|x|)
or o
ΔH 400 − ΔH
0 = kcal
K 300 K 1000
o
or ΔH 300 0
K − ΔH 400 K = 0.1 x = 0.5
or x = 5.
7. Ans ( 9 )
ΔH = ΔU + (P2V2 – P1V1)
= 2 + (16 – 9) = 9 L atm.
HS-4/6 1001CJA103222006
Leader Course/Phase-II/16-10-2022/Paper-2
4. Ans ( A ) 8. Ans ( D )
2
x 2 + 2x − n = 0 ⇒ (x + 1) 2 = n+1
cos6x = 1 − tan 2 x
1 + tan x
−−−−
⇒ x = −1 ± √ n + 1
cos6x = cos2x
nπ
Thus, n + 1 should be a perfect square. Now,
⇒x=
4
n ∈ [5, 100] ⇒ n + 1 ∈ [6, 101]
and x ≠ (2n + 1) π
2
Perfect square values of n + 1 are 9, 16, 25 , 36, x = 0, ,
3ππ
, π,
5π 7π
, , 2π
49 , 64, 81 , 100.
4 4 4 4
PART-3 : MATHEMATICS
that of sec–1 x and cosec–1 x, each is
SECTION-I (ii)
(–∞, –1] ∪ [1, ∞)
5. Ans ( C,D )
∴ Domain of f(x) must be {–1, 1}
−π − π 3π −π
1/4 ( π
) . ( ). ( )( ) . (π). ( )
GM = ( αβγδ) = 2
2 4 4 2
3π 6
HM =
4 4αβγδ 4.(16)
2 =− and f(1) = 0 {as cos–1 1 = 0}
1 1 1 1
=
∑ αβγ
=
32
=
64
+ + +
α β γ δ
GM = HM ⇒ α = β = γ = δ = 2
∴ a = –4
b = 24
6. Ans ( A,B,C ) (i) Domain is {–1, 1}\ Number of non-negative
N = log23 > 1
integers in the domain of f(x) is one
N
⇒3=2 ,
∴ (A) is incorrect statement
N can't be an integer.
(ii) f(x)max= 0 and f(x)min = -3π6/64
max min
64
7. Ans ( A,B,C )
∴ (B) is correct statement
sin(x n ) n
n .x
sin x xn
If m,n ∈ N, x→0 lim
m = lim sin x m
,
(iii) f(x) is one-one hence injective
sin x) x→0 m
x ) .x
(
(
∴ (C) is incorrect statement
= lim xn − m
then by observation
x→0
(A) 1, if m = n
(iv) Thus, the graph of f(x) is a two point graph
(B) 0, if n > m
which doesn’t lie above x - axis
1001CJA103222006 HS-5/6
Target : JEE (Main + Advanced) 2023/16-10-2022/Paper-2
10. Ans ( A,B ) 5. Ans ( 4 )
−−−−
√ sin x
= tan x ........(i)
We have,
sin ⩾ 0 & tan ⩾ 0
st
⇒ x must in I quadrant except where both
f(x) =
sinx = tanx = 0
we check differentiability at x = –2
squaring (i)
sinx = tan2x
s2
∴ f(x) is not differentiable not continuous at x = 0
⇒ s = ⇒ s – s3 = s2
1 − s2
2
∴ Also, f(x) is not differentiable at x = 0. ⇒ s + s2 – s = 0 ⇒ s(s2 + s – 1) = 0
–
1 ± √5 −
⇒ s = 0 or s =
PART-3 : MATHEMATICS 2
–
√5 − 1
SECTION-III ⇒ sinx = 0 or sinx =
2
–
√5 − 1
1. Ans ( 9 ) ⇒ x = nπ or x = sin 1 ( )
2
Put x = y = 0
–
√5 − 1
⇒ x = 0, π, 2π or sin 1 ( )
2
use get ƒ(0) = 1
Number of values = 4
put y = 0
6. Ans ( 1 )
∴ ƒ(x) = x + 1
On simplication, ƒ(x) = cos2x
∴ ƒ(8) = 9 7. Ans ( 6 )
Given a(1 + r + r2) = 21 ...(1)
Eq. (1) 2 r2 + r + 1 7
⇒ n = 2
2 2
⇒ 7r – 7r + 7 = 3r + 3r + 3
3. 2
Ans ( 0 ) ⇒ 4r – 10r + 4 = 0
2
π ⇒ 2r – 5r + 2 = 0
sin2x = sin4x = 0 at x =
2
⇒ 2r – 4r – r + 2 = 0
2
π ⇒ 2r(r – 2) – 1(r – 2) = 0
∴ f ′ ( ) = 0
2 1
⇒ r = (∵ r ∉ I)
2
4. Ans ( 5 ) 1 1
∴ (1) ⇒ a (1 + + ) = 21 ⇒ a = 12
2 4
2
ƒ(x) = (x + 4) + 4 ∀ x ∈ [–4, 0)
a 12 S
∴S= = = 24 ⇒ = 6
1−r 1− 1 4
ƒ(x) ∈ [4, 20), a = 4, b = 20 2
8. Ans ( 5 )
P(x) = (x3 + 2x2 – x + 1) = (x –α) (x –β) (x –γ)
P(2) = (15) = (2 – α) (2 – β) (2 – γ)
–3 = (2 + α) (2 + β) (2 + γ)
HS-6/6 1001CJA103222006