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Metals Class Notes
Metals Class Notes
DEFINITIONS
(i) Tenacity
Tenacity is strength in tension, usually expressed as tensile stress at failure
i.e.
Maximum load
Original cross-sectional area
(ii) Stress
Stress is the force carried by unit area, expressed as N/mm2
(iii) Strain
Stain is the deformation caused by a force. Tensile and compressive strains
are expressed as ratios:
Increase (or decrease) in length
Original length
(iv) Modules of Elasticity (E) or young’s modulus
Within the elastic limit is the point at which deformation of a stressed
material cease to be elastic and becomes plastic
(v) Yield
Yield is an increase in strain without any increase of stress. The upper yield
stress is where yield begins and the lower yield stress is the lowest stress at
which it proceeds
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(xii) Hardness
This is resistance to abrasion and penetration.
(xiii) Work hardening
This is an increase in length and hardness of metals when rolled, forged or
otherwise manipulated at normal temperature.
Unlike hot working in which the grain structure during manipulation is
constantly refined, cold working distorts the grain structure thus increasing
strength and hardness.
(xiv) Fatigue
This is a term used to describe loss of strength resulting from repeated
application of a force which is less than would cause failure with a single
application
(xv) Creep
This is slow plastic deformation under a constant stress which becomes
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OCCURRENCE OF IRON
Iron is never available pure in nature. It has to be extracted in the form of
pig iron from the various iron ores.
The ores from which iron is extracted are:-
(i) Magnetite: (Fe304). It contains 70 to 75% iron
(ii) Haematite: (Fe203) . It has about 70% iron
(iii) Iron Pyrites: (FeS3. It contains 47% iron but not preferred because
of higher sulphur content which makes it brittle.
(iv) Siderite: (FeC03): It contains 40% iron.
PIG IRON
To remove impurities from the iron ore carbon and flux are added while
melting it in a blast furnace at 11000C.
The refined product so obtained is the crudest form of iron and is called
pig iron. It is cast unto rough bars called pigs.
67Properties.
(i) It is hard and brittle as such it is neither ductile nor malleable.
(ii) It is difficult to bend.
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i. Cast iron, wrought iron and mild steel are obtained by refining the pig iron.
ii. Because of its high compressive strength it is used in columns, base plates,
door brackets, wheels and pipe work.
CAST IRON
Pig iron is melted with Limestone and coke and poured into moulds of
deserved shapes and sizes to get purer product known as cast iron.
Carbon contents in cast irons vary from 2.0% to 4.5%
Properties
i. It is used for casting, rain water pipes, gutters, gratings, railings, cisterns,
manhole covers and balustrades
ii. Because of high compressive strength it is used in making columns,
supports for heavy machinery, carriage wheels and bed plates etc.
iii. It is the basic material for the manufacture of wrought iron and mild steel.
WROUGHT IRON
Nearly all the carbon and other elements in pig iron are oxidized and may
be left with 0.25 per cent of carbon to attain wrought iron.
It is by far the purest form of iron in which the total impurities do not
exceed 0.5 per cent.
Properties
USES
i. It is used for making roofing sheets, rods ,corrugated sheets, gas and water
pipes, boiler tubes, plain and ornamented iron work such as grills, gates
and railings, window guards, grating and electromagnets.
STEEL
The essential difference between cast iron and steel is the amount of their
carbon contents.
Steel goes on becoming harder and tougher with the increase in its carbon
contents
Up to a content of about 1.5 per cent all the carbon gets into chemical
combination with iron and none of it exists in its free state.
If carbon contents increases beyond 1.5 per cent then it does not combine
with iron and is present as free graphite.
It is at this stage that the metal falls in the category of cast iron. The carbon
contents may be increased to 4.5 per cent for cast iron.
For a material to be classified as steel there should be no free graphite in its
composition.
Has carbon content upto 0.15 per cent. They are soft and suitable for iron
wire and thin sheet for tin plate.
MILD STEELS
Propjerties
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Uses
The carbon content is 0.20 to 0.50 per cent and are suitable for forgings
and for general engineering purposes.
These are steels wherein the carbon contents are between 0.55 to 1.5 per
cent. Higher percentage of carbon is it renders it harder and tougher.
Properties
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TYPES OF FURNACES
In making steel the carbon, silicon, phosphorous and other elements in pig
iron are reduced in quantity by oxidation.
Gas and preheated air, together with oxygen and oil, later heated a charge
of pig iron with up to 50% per cent of steel scrap.
Some carbon and most of silicon were oxidized by the flame, and the
remaining impurities were removed by the addition of iron ore, mill scale
and lime.
3. ELECTRIC FURNACES
Electric arc and high frequency induction furnaces are used to produce alloy
steels from molten steel and selected scrap.
Shorter refining periods are possible by injecting oxygen. The high
temperatures attainable allow both the melting of alloy additions and the
removal of impurities.
With steel the heavy and costly plant used in the ingot making and
heavy rolling process conveniently used to form semi-finished products,
is eliminated.
Very accurate mouldings are made in some metal by using their resin-
bonded sand shells supported in sand.
Accurate and permanent moulds of steel are used for mass producing small
castings of low melting point metals e.g. aluminium, copper and Zinc alloys.
The practice of gravity die casting is similar to ordinary foundry practice but
in pressure die casting, the molten metal is injected under high pressure to
make complex shapes.
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(5) Centrifugal casting
When the metal has solidified rotation stops and the pipe or tube is
withdrawn.
The product is stronger and is less likely to contain defects than its san-
cast equivalent. Centrifugal cast products are often termed spun
products but these should not be confused with spun sheet products.
ROLLINGS
1. Hot rolling
Hot rolling is used to produce long lengths of sections e.g. strips, sheets and
sections such as angles, channels and I- sections.
Heavy rollers are used to reduce the section size and thus extend the
length.
With steel a billet or slab is heated to above 7000oC prior to rolling so that
rolling forces are reduced and the grain structure refined to improve the
durability of the finished product.
Steel I-Sections are produced up to 920mm deep and strips up to 1830mm
wide.
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2. Cold rolling
Forging is a process of squeezing hot metal into shapes, the products being
tougher than casting. Hammering by hand is more today, most products
being drop forged using mechanical hammers and suitable dies.
4. Extension
5. Drawing
Wire and tubes are pulled through tapered dies or a series of dies to reduce
the thickness of the metal.
Normally the metal is cold and the process improves its strength.
Suitable soft and ductile sheets can be shaped by cold forming. Prefinished
products such as plastics coated steel sheets can be cold formed since most
coatings withstand more deformation than the base metal.
7. Roll forming
Corrugated and other profled sheets, simple sections (beams and purlins)
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and complex sections are formed in any length by passing flat strip through
a series of rollers.
With steel the maximum strip thickness is normally 5mm and the minimum
economic run is about 3000m, although for simple sections smaller
quantities may complete with press- baked sections.
8. Pressing
The rubber can produce lightly dished or patterned products are building
panels.
The sheet is pressed over a wooden former by rubber pads which are
placed on the sheet and pressurized by an oil filled rubber bag contained in
the upper part of an hydraulic press.
Tool press brake employs a V shaped die and punch which is able to form a
bend with each stroke of the punch. It can be used to make limited
quantities of troughed sheets and other open sections.
Low tool costs and great versatility facilitate small quantity production.
Length unlike in roll forming, is commonly limited to 4m although some
presses produce sections above 9m long.
9. Deep pressing
Deep pressing are made in hydraulic presses using highly accurate matched
steel dies which prevent the metal from buckling during the extensive
deformation which takes place.
It is important to realize that large dies are very costly and require mass
production runs such as those provides by baths and can body panels.
Sheet is held at the edges and stretched over a male former of simple
shape.
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11. Spinning
Hemispheres, cones and similar regular shapes for lighting, fittings and
containers up to about a rotating sheet against a rotating former.
Copper, bronze, aluminum alloys and stainless steel are the metals most
commonly spun while cold boomed ends for pressure vessels are spun from
heated steel plate up to 4.3m diameter.
12. Panel beating
Irregular shapes are beaten from flat sheets and damaged car bodies re
repaired by this highly skilled hand work.
13. Bossing
Steel lead, soft temper copper, aluminium and stainless steel can be
formed to complex shapes by bossing by hand using box-wood shapes and
a mallet.
(a) Hardening
This treatment of steel consist of heating the steel to red heat and then
suddenly cooking it by dipping it in a bath of cold water or oil.
This way of cooking hot steel is known as quenching or hardening. The steel
after quenching is known as quenched steel which become hard and brittle.
The hardness of quenched steel depend upon the medium used for
quenching and the rate of cooling.
(b) Tempering
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Tempering gives hardened steel increased ductility with only a slight loss of
strength, by reheating to a temperature below the hardening temperature
followed by cooling at any rate.
The higher the reheating temperature the greater the ductility and also the
loss in strength.
(c) Annealing
Annealing softens the steel and removes internal stresses caused, for
example, by welding or cold working.
(d) Normalizing
This treatment is done to refine the structure and to remove strains that
might have been caused by cold working. When steel is cold worked its
crystallized structure may get brittle and even crack.
Also when the metal is heated to very high temperatures as for forging
then it may loose its toughness.
To remedy these defects steel is slowly heated to about 10000c and
allowed to cool in air.
To increase the carbon content steel is encased in cast iron or steel boxes
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together with a substance rich in carbon like charcoal granules, bone dust
etc and the boxes are heated in furnace to a temperature of 9000c to 9500c
At this temperature carbon infuses into the surfaces of steel and converts it
to high carbon steel. The depth to which this effect takes place depend
upon the time of heating, usually 3-4 hours are sufficient.
The steel when taken out of boxes that have been allowed to cool has a
soft core and a casting of high carbon steel.
DETERIORATION OF METALS AND PROTECTION METHODS
1. Tarring
Iron is dipped in hot coal so that a film of it sticks to the surface which
protects the surface from rusting and corrosion. Pipes or ends of poles to
be embedded in earth are usually given this protective treatment.
2. Painting
Paints, usually the lead paints, are applied on the surface to be protected,
exposed metal surfaces as in case of roof, trusses and bridge structures are
given this treatment which has to be invariably repeated after regular
intervals of time.
3. Enameling
4. Plastic coating
Steel sheet or strip up to 1320mm wide and any length available surfaced
on one both sides with pvc, acrylic, expoxide or phenolic coatings applied as
liquids or laminates.
These products like those having paint coatings, can be pressed and
otherwise fabricated without damage to the coating. For external and
corrosive exposures a zinc pretreatment is necessary and lives up to thiry
years can be expected.
Polyester powder coatings on steel window sections are likely to last atleast
fifteen years, after which they can be painted In the normal way.
5. Metal coatings
(a) Galvanizing
The surface is then dried and dipped in molten zinc. The fine film of zinc
that get deposited protects the surface from contact with atmosphere and
consequent oxidation.
(b) Electroplating
(d) Sheradizing
(e) Cladding
(f) Spraying
(g) Hot-dipping
Hot-dipping is most commonly used process on steel products such as
cisterns, corrugated and flat sheets, light structural sections and windows.
Essentially, after pickling in acid, drying and pre-heating, the object is
dipped in molten zinc which form an alloy longer with it.
Distortion resulting from the hot process can usually be avoided by correct
design and galvanizing techniques, and it can be corrected mechanically.
Whenever practicable thick-walled components should be galvanized “after
manufacture” to avoid unprotected cut and drilled edges.
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L3 NON-FERROUS METALS
1. ALUMINIUM
Properties
i. It is silvery white color and shows bright lustre on a freshly broken surface.
ii. It is highly ductile and malleable.
iii. It is very light in weight.
iv. It withstands atmospheric corrosion exceedingly well.
v. It is a very good conductor of electricity.
vi. It is very soft.
vii. It can be welded and riveted but cannot be soldered.
viii. It is very easy to work upon.
Uses
It is one of the most widely used metals. High cost is prohibitive factor in its
extensive usage in engineering.
Properties
Uses
i. Copper wires are used for winding electric motors and generations and for
transmission of electricity. It is used for electro-plating.
ii. It has wide usage in making alloys like brass, bronze and gun metal.
iii. In form of sheets it is used in damp proofing buildings.
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3. LEAD
Properties
Uses
i. It is used as a base in paints, lead pipes and lead joints in sanitary fittings
are widely used
ii. It is used in lead batteries, cable coverings, making bullet shots, as lining in
chemical and metallurgical industries.
4. TIN
Properties
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Uses
5. ZINC
Properties
Uses
i. It is used for galvanizing iron sheets and pipes, for batteries and printing
blocks, for preparing paints and for making important alloys like brass and
German silver.
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6. NICKEL
Nickel is a white metal which is resistant to many acids, is hard and takes a
high polish.
It is used for electroplating food vessels, equipment for the chemical
industry and on steel as a base for chromium plating.
7. CADMIUM
i. Anodizing
Anodizing which is an electro-chemical process which applies only to
aluminium, form a coating which is integral with, but harder than the
parent metal.
ii. Electroplating
The metal to be protected should be made the cathode in a bath and metal
is deposited on it either from a reactive anode or from the electrolyte.
These alloys have high resistance to corrosion, and high electrical and
thermal conductivities.
(a) Brasses
(b) Brass-based alloys
(c) Bronze
(d) Bronze-based alloys
(e) Copper – nickel alloys
(f) Copper-silicon alloys and
(g) Copper- aluminium alloys
It contains 0.1 to 2.0 percent vanadium and is very strong and ductile. It is
capable of resisting shocks. Its elastic limit is high.
It is used for making drilling machines and high speed cutting tools.
Addition of 12-15 percent manganese to steel makes the steel very hard,
tough and non – magnetic.
It is used for making paints and crossings in rail track and machine parts
etc.