13-01-2023 - Jee SR ELITE (CIPL, IPL IC & ISB) - Jee-Main - GTM-6 - Key & Sols

SRI CHAITANYA IIT ACADEMY, INDIA 13-01-2023_ JEE Sr ELITE (CIPL, IPL IC & ISB)_Jee-Main_GTM-06_KEY & Sol’S
Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office – Madhapur – Hyderabad
Sec: Jee Sr ELITE (CIPL, IPL IC & ISB) Jee Main Date: 13-01-23
Time: 09.00Am to 12.00Noon GTM-06 Max. Marks: 300
KEY SHEET
PHYSICS
1 1 2 2 3 2 4 2 5 4
6 1 7 2 8 3 9 2 10 1
11 3 12 4 13 1 14 1 15 2
16 2 17 4 18 2 19 3 20 2
21 2 22 8 23 9 24 98 25 7
26 1350 27 3 28 2 29 957 30 3
CHEMISTRY
31 1 32 1 33 1 34 4 35 3
36 2 37 1 38 1 39 1 40 4
41 2 42 4 43 1 44 2 45 3
46 1 47 4 48 4 49 3 50 3
51 7 52 9 53 5 54 2 55 3
56 8 57 7 58 5 59 8 60 4
MATHEMATICS
61 3 62 3 63 1 64 4 65 2
66 4 67 1 68 4 69 3 70 1
71 2 72 2 73 4 74 2 75 3
76 2 77 3 78 3 79 3 80 2
81 4 82 2 83 0 84 3 85 10
86 34 87 1 88 7 89 3 90 2
Sec: Jee Sr.ELITE Page 1

SOLUTIONS
PHYSICS
1. Conceptual
2. Conceptual
3. Conceptual
4. Conceptual
5. Conceptual
6. Conceptual
7. F = m1g+m 2g=  m1 +m 2  g
8. Use concept of % error
9. Use the equation of motion
10. Conceptual
11. Modulation index
Em A
ma   1
Ec A
Equation of modulated signal Cm  t  
 EC   ma E C  sin m t
 A 1  sin mt  sin ct
(As E C   A sin C t )
12. Conceptual
13. Conceptual
14. Conceptual
15. Conceptual
16. Conceptual
17. Conceptual
18. Conceptual
19. Conceptual
20. Conceptual
21. Apply KVL for left roop

 1T
 e2  0.2V
5
e1  0.4V 1T
i i  i1 i1
5  i  i1   0.4  0
5i  5i1  0.4  0
5i  5i1  0.2  0
0.2  5  i  i1 
0.2  5i  5i1  0
22. Conceptual
23. Conceptual
24. f 1  98.01m
25. Conceptual
26. Conceptual
27. Conceptual
28. Conceptual
29. Conceptual
30. Conceptual
CHEMISTRY
31. PV 1 1
n   0.0408mole
RT 0.0821 298
Energy required for the given moles of H 2 to dissociate into atoms = 0.0408 x 436 = 17.89 kJ
Total energy required for first excitation
= Energy for dissociate + Energy for excitation
 2 1 1  23 3 
 17.89   Rhc 1  2  2   0.0408  6.023  10  10 
 1 2  
 17.89  80.35  98.24kJ

32. Sulphite gives SO2 with H 2 SO4 which turns acidified K 2Cr2O7 green according to following
reaction :
K 2Cr2O7  H 2 SO4  3SO2  K 2 SO4  Cr2  SO4 3  green   H 2O
H 2 S also gives green coloured solution with acidified K 2Cr2O7 solution but a slightly
coloured precipitate of sulphur is also obtained. The H 2 S gas has rotten egg smell.
33. Ca  R. A, H 2  O. A
34. B3 N3 H 6   polar  Non  polar bonds 
Planar molecule (sp2)

35. Bond order in [CO]=3
36. 8.27  4  128
6.023 10 23 a 3
 a  46.8 109 cm  4.68 A0  2  rO2  rCd 2 

 2 
 rCd 2  1.1A0
37. Loss of weight of solution  ps
Loss of weight of solvent  p 0  ps
p 0  ps Loss of weight of solvent

 
ps Loss of weight of solution
Loss of weight of solvent

or X B 
Loss of weight of solution
WB / M B 0.04 WB M A 0.04
   
WA / M A 2.5 M B WA 2.5
2.5  WB  M A 2.5  5  18
Or M B    70.31
0.04  WA 0.04  80
38. Lesser is the value of reduction potential, more is the reducing character.
39. For second order, t  1
1
2  A0 k
log t 1   log  A0  log 1/ k 
2

Hence reaction is second order.
1 1 1  4 1
k   ;   kt75%
t   At  A0  A0 A0
4 1 300
  kt25% ; t25%   33.33min
3  A0  A0 9
40. Total surface area available =   25  103  m2  2.5 108 cm2
Surface area covered by one molecule of NH 3   r 2

2
 22  0.3 7 
  22 
    10   cm 2    0.15  1014  0.15  cm 2
 7  2    7 
 0.0707  1014 cm 2  7.07  1016 cm 2
2.5 108
No. of ammonia molecules  16
 3.536 1023
7.07 10
3.536 1023
No. of moles of NH 3   0.587
6.023 10 23
Volume of NH 3 at NTP   0.587  22400   =13.282.4cm3

41.
42. Conceptual
43. Conceptual
44. Conceptual
45. Conceptual
46. Conceptual
47. Conceptual
48. Conceptual
49. Conceptual
50. Conceptual
51. Mass of nitrogen = 140gm.

Wt of Relative
Whole
number of Simplest ratio
Element number ratio
moles
C 300 25 2.5 5
H 70 70 7 14
N 140 10 1 2
E.F=C5H14N2
EFM=12x5+14+2x14=102
MM 102
n  1
EFM 102
Molecular formula= C5H14N2

52. M mix
d mix   M mix  39.2
22.4
 48x  32 1  x   39.2  x : moles of O3 

X=0.45
0.045
 PO3  X O3  PT   1  0.45atm
1
53. 209
E  q  w  100   100  50  50cal
4.18
E  nCv , m T , q  nCm T
q C
 m ; Cm  2Cv, m  5 R
E C v , m
54. For an organic acid (say RCOOH),
RCOOH  RCOO   H  ; pH  4.15
 log  H    4.15
So,  H    7.08 105 mol L1

Since  RCOO     H   So,  RCOO    7.08 105 mol 1
 RCOO    H   7.08 10 5  7.08 10 5

Then   5.01 107
 RCOOH  0.01
55.  Fe OH  2
Fe  OH 3 , MnSO4 
56. Conceptual
57. Conceptual
58. Conceptual
59. Conceptual
60. Conceptual
MATHEMATICS
61. We have
sin 4 x  cos 4 x  sin 2 x cos 2 x  

y 4 4 2 2
, x   0, 
sin x  cos x  sin x cos x  2
tan 4 x  tan 2 x  1
y
tan 4 x  tan 2 x  1
2
 y  1
tan x  tan 2 x  1
4
1  y  1
62. Put g ( x)  y  x 2  2  x  y  2  f ( y  2)  0
 y 5  20 y 4  40 y 3  79 y 2  74 y  23  0
Roots are g ( x1 ), g ( x2 ), g ( x3 ), g ( x4 ), g ( x5 )
g ( x1 ).g ( x2 ).g ( x3 ).g ( x4 ).g ( x5 )  23
And x1 x2 x3 x4 x5  1

g ( x1 x2 x3 x4 x5 )  g (1)  1
 g ( x1 ).g ( x2 ).g ( x3 ).g ( x4 ).g ( x5 )  30 g ( x1 x2 x3 x4 x5 )
 23  30  7
63. Let c   a,0  a  0 
a
Radius  r  
2
a
d=distance from  a, 0  to 3 y  x  0 is
2
Length of the chord = 2 r 2  d 2  2  a  2
Centre  2, 0  , radius = 2
64. dy1 1 dy1
i)  f  x  y1  0  f  x  
dx y1 dx
dy 1 dy1
ii)  .y  r  x
dx y1 dx
1 dy dy1
  y1 dx dx   y1 1
e e 
y1
d  y  r  x y r  x  dx  c
   
dx  y1  y1 y1 y1
r  x  dx
y  y1   cy1
y1
65. A  2 / a 2  x5/ 2
2a
0
 2a  x dx
Put x  2a sin 2   dx  4a sin  cos  d
1
2  /2 5/ 2
A 0  2a  sin 5   2a  2 cos   4a sin  cos   d
a2
8a.  8a 3   /2
 2  sin 6  cos2  d
a 0
 64a 2
 5.3.1 .1 . 
5
  a2
8.6.4.2 2 4
Also B = area of circle of radius a   a 2

A 5
 
B 4
66. Now according to condition a  1
b2 10b  25  a  1
 b 2  10b  24  0
 (b  4)(b  6)  0 i.e. b  4 & b  6
 b  [4, 6]
67. The inverse of p  q is  p  q the contra positive of  p  q is  q  p .
[Contra positive of p  q is  q  p ]
68. Taking  ,  ,  common from C1 , C2 , C3 respectively, we get
1 1 1
1 1  1 
   | 1 1 1 |
  
1 1 1 1 1
 
1 1  1 1  1
  1 0 1
    
[using C2  C2  C1 , and C3  C3  C1 ]
 (1)(    )(   ) 1   1  


(1   )(1   )(1   ) 1 1
 (   )(   )(   )


(1   )(1   )(1   )
As  ,  ,  are the roots of ax3  bx2  cx  d  0 .
ax3  bx 2  cx  d  a ( x   )( x   )( x   )
And   d / a

(d / a)(25 / 2) 25d
Thus,   
(a  b  c  d ) / a 2( a  b  c  d )
69.  5
2
2 225 17
We have ae =  10  2    24  20   4  6  2
 
Clearly other focus is at (-5, 16)
As hyperbola touches y – axis  y – axis is tangent
289 89
 p1 p2  b 2  b 2  50  a 2 e 2  a 2  50   a 2  a 2   2a  89
4 4
5
70. e x  x ln 5 x9
I   x ln 51 . 2
dx
e 1  x5 
 x 1
5
x9
 e . dx
5 2
1  x 
Let x5+1= t  5x 4 dx  dt
1 t  t  1
5
I  e . 2 dt
t
5
1 1 1  1 e x 1
  et   2  dt  C
5 t t  5  x5  1
71. Clearly R1,R2 are equivalence relations  R 1  R 2 is an equivalence relation.

R 1  R 2 need not be an equivalence relation
72. The 3 numbers whose product is not divisible by 4 can be chosen in
(i) all odd
(ii)two odd and one even
Which is not a multiple of 4 it can be done in 10  10  5  345 ways.

C C C
3 2 1
20C  345 53
So required probability = 3 
20 76
C
3

20 20
73.

Let 8  3 7  
 l  f , where f= fractional part and I = integral part.Also let 8  3 7  g
Then 0 < g<l

20 20
Here I  f  g  8  3 7   8  3 7 
2
 2 820  20C2 .818. 3 7   ......
 
 
 l  f  g = even integer
But 0 < f+g<2, So,I+1=even integer( f+g=1)
Therefore I is odd integer.

74. Required area of circle is shortest distance between two curves as diameter of
circle.Shortest distance is measured along the common normal of the curves.
y  x 2  1, y 2  x  1 are symmetric about the line y = x.
 common Tangent to parabola and circle is parallel to y = x and line perpendicular to

it is y   x  k
 y    x  1  k  1, it will be normal to y 2  x  1
1 1 3
if k  1  2am  am 2  2.  1   13 
4 4 4
7 7
k  ; thus ,the normal is y   x  , on solving with the given parabolas we get
4 4
1 5 5 1
P   ,  and Q   , 
2 4  4 2
3 2 3 2
PQ   minimum radiusof circle is
4 8

9
Minimum area of the circle is
32
75. A  adjA   A I ; A  29
76. i j k

A normal vector n to the plane OQR is OQ  OR  1 3 4  10i  10 j  5k
2 1 2
2i  2 j  k
And n 
3
 the perpendicular from P on OQR = Projection of OP on n
 2i  2 j  k 

 3i  2 j  k .  3
6  4  1 11
 
3 3
77. axa
x x
 1   0
a a 
78. x  1, y  1  f 1  2,3
2  2 x  1  1  8
y  1  f  x   f  
x  f 1  1  2 3
79. 1 1 1 1 1
A  1 2
 2  2  ...... , B  1  2  2  ......
2 3 4 3 5
1 4B  A 3A  B
 B A  3 A  4B  5
4 4 B
2 2
80. a  b  11  a  4   b  4  9  a  4, b  7
81. No.of solutions = 4

82. 37 + 66 a = 17 + 65 b
20 + 66 a = 65 b
20  66a 65a a  20
b  
65 65 65
For a = 45, we will get the first term common
37 + 66  45 = 3007,a=110 then second common term is 7297
Hence number of common terms will be 2

83. Applying Rotation formula at P and B we get
p  4 2i   2
2
  1  p  2i   2  2i  4    2  2i  4   4  2i   2 
p  2i  4
2i  8i  8 2 2  i  4i  4 
2
 p   i  2i
4i   2  4  4 2  i  4i 
p b 2
So, z   0 Z 0
2
84. 3  x  1 2  2  x  1

2
f '  x     x 1/ 3  1  x  1  0
3
2  x  1 1 x  2

f '  x  DNE at x  1, 0,1
Sign of f '  x 
85. There are n+2 lines through A including AB and AC. If BC is one side,then remaining two
sides can be selected in n  2 ways.there are two more lines parallel to BC.
C
2
Total number of triangles = n  2

C
2
 n  2 = 66
C
2

n2
C
= 66 = 12C
2 2
n+2 = 12  n =10
86. We have x  log 1 5.log125 343.log 49 729
3
log 5 log 343 log 729

= . .
1 log125 log 49
log
3
log 5 3log 7 6 log 3

= . .
 log 3 3log 5 2 log 7
 x  3
3log 11.log 17.log 784

Now, y  25 289 28 1331
3 log11 log17 2 log 28 1

. .
 25 2 log17 2 log 28 3 log11  y  25 2  5
 2
 v  3iˆ  5 ˆj  v  9  25  34
87. Putting x = 0 = y in the given relation we find f(0) =f(0)+f(0)+0-1  f(0)=1
f  x  h   f ( x)
f ' ( x )  lim
h 0 h
{ f  x   f ( h)  2 xh  1}  f ( x )
 lim
h 0 h
(Using the given relation)
f ( h)  1
 lim 2 x  lim
h 0 h 0 h
f (h)  f (0)
 lim 2 x  lim
h 0 h 0 h
 f ' ( x)  2 x  f ' (0)
 f ( x)   x 2  sin  .x  C ,
f (0)  0  0  c  c  1

 f ( x)   x 2  sin  .x  1
So, f { f ' (0)}  f   sin     sin 2   sin 2   1
 f { f ' (0)}  1
5 5 4
88. [ x] [1 x ]
 {x} dx    x  [ x] dx   1  x  1  x 
[ x]
dx
1 1 0
4
1 2 3 4
1[ x ]
 ( x  [ x])
0
dx   f ( x )dx   f ( x) dx   f ( x) dx   f ( x) dx
0 1 2 3
1[ x ]
Where f ( x)   x  [ x]
1 2 2 3 3 4 4 77
  xdx    x  1 dx    x  2  dx    x  3 dx 
0 1 2 3 60
89. 3  3  6 2  4   6   3  4
 
2 2 1
For last two   3  3    3  4
µ=1  point B  3,3,2 
Using µ=1 in
3 -2 +6=2 -4 +6
3 +4=2  2     2
Hence A(1,1,1)
AB  4  4  1  3
90. tan 2   tan 3
 2  3  2       

2 tan      p
  tan  
1  tan 2      q
2t p
= where t  tan(    )  Q
1-t 2 q
 pt 2  2tq  p  0  disc  4q 2  4 p 2
=4(p2+q2) must be perfect square p =3,q =4

13-01-2023 - Jee SR ELITE (CIPL, IPL IC & ISB) - Jee-Main - GTM-6 - Key & Sols

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

13-01-2023 - Jee SR ELITE (CIPL, IPL IC & ISB) - Jee-Main - GTM-6 - Key & Sols

Uploaded by

Copyright:

Available Formats

SRI CHAITANYA IIT ACADEMY, INDIA 13-01-2023_ JEE Sr ELITE (CIPL, IPL IC & ISB)_Jee-Main_GTM-06_KEY & Sol’S

Sri Chaitanya IIT Academy., India.

Sec: Jee Sr.ELITE Page 1

Equation of modulated signal Cm  t  

 A 1  sin mt  sin ct

Sec: Jee Sr.ELITE Page 2

5i  5i1  0.4  0

Total energy required for first excitation

= Energy for dissociate + Energy for excitation

 17.89  80.35  98.24kJ

Sec: Jee Sr.ELITE Page 3

K 2Cr2O7  H 2 SO4  3SO2  K 2 SO4  Cr2  SO4 3  green   H 2O

Planar molecule (sp2)

 a  46.8 109 cm  4.68 A0  2  rO2  rCd 2 

Loss of weight of solvent  p 0  ps

p 0  ps Loss of weight of solvent

Loss of weight of solvent

Sec: Jee Sr.ELITE Page 4

Hence reaction is second order.

Surface area covered by one molecule of NH 3   r 2

 0.0707  1014 cm 2  7.07  1016 cm 2

Volume of NH 3 at NTP   0.587  22400   =13.282.4cm3

Sec: Jee Sr.ELITE Page 5

Molecular formula= C5H14N2

 48x  32 1  x   39.2  x : moles of O3 

RCOOH  RCOO   H  ; pH  4.15

So,  H    7.08 105 mol L1

Sec: Jee Sr.ELITE Page 6

Since  RCOO     H   So,  RCOO    7.08 105 mol 1

 RCOO    H   7.08 10 5  7.08 10 5

sin 4 x  cos 4 x  sin 2 x cos 2 x  

g ( x1 ).g ( x2 ).g ( x3 ).g ( x4 ).g ( x5 )  23

Sec: Jee Sr.ELITE Page 7

 g ( x1 ).g ( x2 ).g ( x3 ).g ( x4 ).g ( x5 )  30 g ( x1 x2 x3 x4 x5 )

Length of the chord = 2 r 2  d 2  2  a  2

Sec: Jee Sr.ELITE Page 8

 (b  4)(b  6)  0 i.e. b  4 & b  6

 (1)(    )(   ) 1   1  

 (   )(   )(   )

As  ,  ,  are the roots of ax3  bx2  cx  d  0 .

Sec: Jee Sr.ELITE Page 9

Clearly other focus is at (-5, 16)

As hyperbola touches y – axis  y – axis is tangent

71. Clearly R1,R2 are equivalence relations  R 1  R 2 is an equivalence relation.

(i) all odd

(ii)two odd and one even

Which is not a multiple of 4 it can be done in 10  10  5  345 ways.

Sec: Jee Sr.ELITE Page 10

Then 0 < g<l

But 0 < f+g<2, So,I+1=even integer( f+g=1)

Therefore I is odd integer.

 common Tangent to parabola and circle is parallel to y = x and line perpendicular to

Sec: Jee Sr.ELITE Page 11

 the perpendicular from P on OQR = Projection of OP on n

Sec: Jee Sr.ELITE Page 12

For a = 45, we will get the first term common

37 + 66  45 = 3007,a=110 then second common term is 7297

Hence number of common terms will be 2

f '  x  DNE at x  1, 0,1

Total number of triangles = n  2

Sec: Jee Sr.ELITE Page 13

log 5 log 343 log 729