© SRI CHAITANYA EDUCATIONAL INSTITUTIONS, INDIA A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI,RANCHI SEC: SR NPL& NEON(IC) JEE MAIN DATE: 18-01-2023 JEE MAIN GRAND TEST- KEY MARKS-300 IMPORTANT INSTRUCTIONS: 1. The test is of 3 hours duration. 2 The Test Booklet consists of 90 questions. The maximum marks are 300. 3. ‘There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and Mathematics having 30 questions .Each Subject will have two sections. Section A will be of Multiple-Choice Questions (MCQs) and Section B will contain Questions whose answers are to be filled in as a numerical value. In Section B, candidates have to attempt any 05 (five) questions out of 10. There will be negative marking for both Section A and Section B. For each question in Section B, a candidate has to enter the correct integer value of the answer using the mouse and the on-screen virtual numeric keypad in the place designated to enter the answer. For Section B, the answer should be rounded off to the nearest integer. Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases. PHYSICS 1j/_2 |2] 3 |3j/ 1 ]4] 3 [5s] 3 6| 2 |7/ 4 /s) 1 jo] 4 fio] 4 uj 8 iz) 3 |13/ 4 [raf 1 isi 3 16| 2 /|i7)/ 1 (iis) 3 [io 4 20] 2 21/ 32 |22|/ 30 |23/ 5 24] 3 j25| 6 26/ 5 27; 5 |2s{/ 3 29] 30 [so] 1s CHEMISTRY [3if_ 1 _Ja2]|_ 3 a3, 2 (34) 3 _ias]_ 4 36/3 [37] 1 |3s|__3 39/3 |4oj_ 1 [ai] 4 [42/3 |a3i|_ 4 jaa) 2 |45|_ 2 46/3 |47/ 4 (asi 4 49) 2 [sol 4 si| 4 /52/ 512 |53| 6 (54) 6 |5s/ 3 56/5 |57|/ 3 ssi 4 (59) 4 J|eol 4 Sri Chaitanya Page |MATHEMATICS 61/2 j|o2/ 1 jes; 1 j|e4) 1 Jes|_ 3 66| 2 |o7| 2 Jes) 1 j|69) 2 |7o/ 4 m1 3 |72[| 2 ~|73|_ 1 |74)_ 2 7s| a 76| 1 |77/_3 |78|_ 2 |79/ 2 Jsoj 4 81/8 |s2/ 31 |s3| 4 |s4) 1 |ss| 3 86/ 3 |s7/ 1 |ssi| 3 |s9) 9 J90/ 2 SOLUTIONES Velocity of body striking water = Terminal speed of body in water Vay, 2 Tano =" Pgh = 2 OPE jar g 7 4. Applying kirchofits voltage law 2 : y,-in+is-L ay, dt = D=LT" V,-5x1+15~5x109(-10°)=7, 3. If projectile returns to point of V,-S4+15+5=V, projection, displacement. along x= V,-V, =157 direction should be zero. A F00s0 - 7 7 1, - [ReBeh _ [Pa2eP _ [6 % = 3 3 3 4 =V2=14144 Fysind . 6. i=—28__ 4 A ig2y V1, 200+200 400 Mtb aast? 2 Power loss in each zener diode = x10 =40me O=v,sindiT +h 7. Following method of integration dx T= time of flight = —x Sri Chaitanya Page 2_3l(2a+b 4\3atb 8. Under balance condition R x < (§ —> <— (100-1) —> Incase (1) R= 329 Bb x 100-1 75.3 pk A nd? 4 p(Li2) x(d/2)° Incase (2) Rot x 100-1" I 2R I =it x 100-/' 3R 100-1" = 1'=40cm 9. Find velocity at t= 2s And use work energy theorem Sri Chaitanya 10. lL. V mis) 50 (0.0) 10 as vou _ 0-50 : a= aS m/s? t 10 yemete v=-5r+50 att=0,v=50m/s att=2s;v=40m/s 1 = 5 xlo(4 Using snells law at first face Isini, = usin, sin d= sin Page 3x say 22 ea 4° wa ms 12. V,, =5(1+0.6c0s6280r)sin (211x10%r) “Beeserecien) ‘ox = 543 =8V;V, =5-3=2 3) KE=K(Ei)= 4) kxE=kx(Hi)= E(kx?)=-Bi 14, From law of conservation of mechanical energy. Energy of system at the instance of release = Energy of system at the instance of collision. {om Sr) 2] d 2R 2 nl 5-7) Rd Sri Chaitanya We know when source crossing a stationary observer An 2y, M1100 =x 100 = 220 n v 320 =12.5% DeBroglie wavelength for electron V2mE- Wavelength associated with a photon = he E Ratio = mE he TE =PE+KE=0.4+0.5=0.9J We know TE = fimo a? 2: 09-1 x02% 2ax=| xa? 2 1 A=0.06m =6cem Using Bernoulles equation. V, Given initially 6, =0,= 4G 42 =4 4n(2R) ae y When connected charge flows until their potentials are equal =P, By conservation of charge Page 420. 21. F=32i 22. For ball A BUA 25 ¢ ey t 100m 80=0(+2)+5(10)(142)° =1=2s Sri Chaitanya 23. 25. 26. For ball B i; 80 =ut+ x10xt 80 =u(2)+5(2)° 60 =2u u=30m/s oi B Magnetizing force = H =— Hy Hani 40, 2x10! = 107 xi reons 7, an" a3 Red shift = AA ="=2 c = 286%10"X630%10" _ syg6 igi 3x10° = 6x10" Remaining = 1-2 =4 & 8 Page 528. 29. 30. LLY oo ne3 8 (2 Time lapsed aay 15=3xT,5 Typ =Sminutes Energy of gas due to its thermal motion ‘onst oar T? =Const > vaT* . mv F = tension in string = mg-+ "73 When body is at bottom of circle. Efficiency of heat engine Sri Chaitanya 31. 32. 33. 34. r Case (1) : 0.4=1-— ase) 500 = 7, =300K h Angular momentum = /(/+1) Qn On 2(2+1) Spherical nodes:- n-/-1=0 Angular nodes / = 2 oh, _ Voh+4n 2 on %IC =16(X,-X,)+3.5(X,-X,)° =16(3-2.1)+3.5(3-2.1) =16x0.9+3.5(0.9)° =17.2 %XxP, _ 42x760 100 100 42.7.6 =319.2mm Na,C,O, + H,C,0, _ KMnO, 2M+2M _V,x0.1x5 O+2M ~ V,x0.1x1 Page 635. aX k, k 36. p" =10 pil +p =14 p™ =14—p" = p™ = 14-10 pp" =43 (OH Ba(OH), = 2(OH)+ Ba* ky, = (Ba*\(oHr) 5x10" =(Ba*?)(10“) sx1o¥ 10° 5x10 [Ba ]=5x10* =5x10 x10° (Ba 37. C,-C,=R C.-C, =R Sri Chaitanya 38. 39. 40. 41. G- ""M(y-1) End to end Identical even no of chiral carbons no of Meso compounds 2 a2 a2 Stability order Aromatic > Non Aromatic >Anti Aromatic om, “ON S ° ne tr a ook 434 5an-c-ap c HO LNA “ Gy On a, ! cH, PC=a0 I OL,-O1,-C-A4,-Gi, => FC H=0 | a, | OF, Page 742. Conceptual , . 43. Don =”, 10 GMW * wiof HO . 610" _, 6000 59m Sy 120° 10°” 120 44. 4k* +[Fe(CN), |‘ no of Ions 50 a= = 100 0.5 m=iCRT C=0.1= decimolar = 3X 0.1% 0.0821 300 T =27+273=300 m=0.3X 24.63 n=738 45, Interms of P, and P Ae) > Fe) * Ce) 0 a... aP, a-x 2x x total a—x+2x+x=a+2x a p, aaP, at2xaP a=P, Pj+2x=P Sri Chaitanya 46. 47. 48, los 2h, “aR =F At anode Ni Ni? +2e"? Ni? +2€0— Ni Cone. Decreases = 10 time a" 0.1 2. Neal 10 0.06 E=E-——1 2 oe E +S jog(Ni2) E +0.03log(10"') E-0.03 volt E" -0.03x1000mvolt Decresed by 30m. volts 1 =kp" Page 849. Sl. 53. Cees Allylic3° carbocation more reactive CFSE = [-0.4Xx,2, 40.6%, Jy [mn (H, o]" =3x(-0.4)+2x0.6=(0) [cr(1,0), J 3x(H [2m(#,0), ]” =3x(-0.4) +1x0.6= 0.64, [cr(H,0), } =3%(-0. 0.4)+1x0.6=0.6A, 4) +0x0.6=1.2A, TiCl, - Al(C,H,), Transition element = Ti" = +4 Cyl xO, > 9 chiral carbons Total Isomers are 2” P2512 Aldehyde which do not contain alpha hydrogen atoms. ” Op saean me, Nitro bervene Sri Chaitanya 55. (HPO,), Total 3=> P=0 bonds 56. Ag,SO, AgCl Ag.C0, AGC.O, AgNO, CH,COOAg AgPO, pee AGO) red 57. CH, White ppt Each carbon undergoes = sp* 1018, PO 6 Ratio of HO Page 958. 60. 61. Hemalite > FeO, Magnetite + Fe,0, Siderite > FeCO, Limonite = FeO(OH)nH,O XeO, + XeO, + XeOF, + XeF, Lp +1Lp+lLp + Lp = 4Lone Pairs I 8 No of y atoms = 1x1=1/ unit cell a) No of x atoms comer = 8x No of — “0" atoms =3/unit cell Formula is XYO, => X,¥,0, b) No of ‘o” atoms missing from two edge centre/ unit cell 1 . =2x—=+/unit cell 4 No of ‘0’ aroms left a3-ls 2.5/ unit cell Formula = XYO,, => X,Y,0, = X,¥,0. Total value of [(x+y+2z)-(a+b+c)] = [(2+2+5)-(1+1+3)] =(9-5)=4 A+B=21 A'+BT=31 Multiplying by matrix A in equation (2) AAT + ABT = 3A >1 + AB! = 3A Now multiplying by matrix B IB+AB'B=3AB > B+A=3AB 21=3AB Sri Chaitanya 63. Let height of tower MN is h In AQMN, tan 30° man] QM ae V3 QM = QM=V3h In AMNP.MN=PM Page 1065. 66. Sn) In APMQ, MP=,|(200) = h=¥40000-3h? = h? +3h? = 40000 (a,b) and (b, a) lie on circle Ram does not get a first class, then he does not work hard Max. arg(z |Max.arg(z) -Min arg(z)| = (2-0-0) +) Sri Chaitanya 67. AoNBN2 NE *6*7x13=91 68. 69. 70. £(0)={c0s0-+H)-{cxs0-1}-{cx80-2)-cos0-3)=7-2ae0 FO) = Faia 71. Given line AB meets x — axis at A(2, 0), B(0,4) slope of ABEquation of line L is y = (1) and (2) weget C = (-5, -1) dD Perpendicular distance from G to AB (2) solve <. centriod G= 2 +1-4] W5 = V5 Ix-1 y-2 243 72. Equation of plane is] 3 1-2 |=0 205 4 = IIx + y +172 +38=0 (20 se -1) ® Soe =, Ce eMens) x30 x(x+2)e"" 74. again diff wrt x = yot xy =-4y 7. £(x)=xe™ f!(x)=xe"" (12x) +e (1) If f(x) 20 = x-2x? +120 = 2x?-x-1S 0 Sri Chaitanya 16. 71. 8. (2x+1)(xI)s 0 “Eh Equation line is y 2x —2y-3=0 From ellipse = ¢, From hyperbola, . Given e; .e)=1 =e esl a=2a¢, B=2ae,=10 (B, @)=(10, 8) Put x=t? => dx=6t' dt (e+e! +1) 60° (+e) dt Page 12=x) + 6tan*} x® fre 2 79. x’ cosy Wa? siny=e* dx > x! cosy y's y ix = d(x" siny) =xe* on integrating weget x‘ siny=(x- e+e () Putx=1,y=0 > ¢=0 x‘ sin y=(x—1)e* = siny=(x—1e*x™ 80. Let ‘d’ be the common difference then the sequence a, b, ¢ can be written as bed. b, b 82. 83, 84. = (2°) + Multiple of 9. =(9—1)"7 + Multiple of 9. =- (1-9)? + Multiple of 9. =-1+ Multiple of 9 =8 + Multiple of 9, Using fundamental principle of counting number of one — one functions = 31 Apply Baye’s theorem MM” IM? N=M? 4M! +......+M! (I-M?)N=M?-M™ =-21 = asl AA+3=0 > 2=1,3 A+6=0 => K=2,3 V9=0 = =-3,3 => b'=a?c? = ac =+ b* “(ake k++ sd=0¢4 4 a Hence a1 (acb atbte=0 (3) Solve (1), (2), (3) weget a yea, c= 2 2a-b-2e=-1-4+7=2 Page 14