Carbonyl. Add Preparation — Methods Tl Ester byetrolysi> @ Base medium ou ° R-2—op' + Nagd Ne? e he ee e Re+G Na ket or i Nau: Mechanism . : : Ore ih ee e 5 Ip Roe {ph a> R- colt + RO OH Scanned with CamScannerKey points : S ydelys of eer in alkaline — medulim © kenwwn as Saponixitatiim reaction FS bueversible reaction tay’ a ler to tee ren reversible seachen . > In both’ medium hydilyo atyl tarbon 4 oxygen bond = eavage- > EWE on R 4 RR! increases the nal 4 hydrolysis - Fobtems > White the produds for the -Feoltowing + 4 of oon and iy 8 $n + tts ° if 6 H > e-o-ors tle _, (Oy Ton + enon od. 5 be I oO oO x oe " A cyan UF ang Olea sy ener —b 3 ondH Scanned with CamScanneroO 0 M i q at~E-0-{0) Bide sy noe) Wk the readtivily order for ester huyprolysts =9 3 By. s- 6-0 ett, 2-0 {8} wor x xr w ms: Mere rew i i GQ ay -b 0 ary tty - 2 -0- Gs x= zr Ans Eex Scanned with CamScannerAL From RMyd gO 2h (or) Rug + Ws tee” _, rewoH + MMi Mechanism + ° ron — +) tho” pao Oo t R- RMgd + vzeSo ———» p-e -0 Math +. SS : Hg et low)” Wsigh —7e 5 enugo Os Uta gh 235 etree. 20) Gly bE eae Mg, $0 > eg tty OOH 2] Fem alkyl wanides R-c=N —taot_, aot wh _Hib" > alton + MH atky _ Amide carbo xyle apnide ‘abd, te 5 ° ety -c2N —HB2 > en, Yn > CgtooH + Nt e 7 i tty cya KEM emp -cnzeny US cry 04, E — NM 1 Jot Oy-uh -WOH + NH, t oN A Me Scanned with CamScanner(oy lla (oy an-u KON» (oy-anen (urnde), A Ate chaln Alkyl benzene with atleast one benzyli hydra en ot oi cr -Og | 0 —) >: cH a mo > CL on Ch ts & 5) Hoch xn ra » om YD Aikene + co's tao SPH tartonpt avid Gteam) T]he en tnvolues coo adden by mevtkonikovs ule Scanned with CamScannerC3 — wor > R- Mn, - wor Hy ct, looH (Ott, -wons Scanned with CamScanneror cron > > ND », prem» SF tom sant 1 fin a Coot eM chy wor > eget > HIN % war. won > lage Ng Se attend th eo” oP inereases atladd nature are . Nm * oilhy effeer / NH 7 a toot tow too | Con ° ow v v sts uy. Mito 477% GOH + 627.0 =) Ferralin > Fr Bese. = Scdiwn bozok & ood LP 8 or 09 esto Vinegar > fare aati auld tweveds te te Vee “olid blow JOBE called as“ gilactal acta” obrained by Lystelivzing Separating and mreliing acetfe auld Tntemrediate ty manufactvlig of Nylonch => wWichevanone Scanned with CamScanner ay aFlyjsieat properties 2 Goponyi? auld . Corborytii auiels — aye Mighen — ppt than hudrotanbens, halo alkanes, aluchols, ethers, aldehydes kelones | esters, and amines. Because ids tan Ferm — yd mer by inker molecular He bonaiing . wees Abmer Carkonyli atids ate oluble. fo water due 42 tydegen bonding with — water Note : 4 Hote 2 Mept gwen re 4 taton atoms gf higher, .tran the next tbwer' y po Ghemieat Hes, M&A member payiy ald carton etter Al o-n Wavage reactions [audit nalirre q aids] Jl &n with adie metals HOH. + NQ —____y HtooNa + eta, Cigwook 2 Nal > eryuoNa tr Me ctgtoon + a, Mteddge t Me Je with base. HwoH + NaOH ——— > HlooNa + Hed tooo + th ty t00H + NAOH | ————3 2a toon + ale), > Ewa + 2H Scanned with CamScannerBl Ren wth Naa tog ts Nalls ' ° w 4 engeoona + 0 Chz~C-OH + NOH iQ, ————> Wa. td w u wona + i R tty 2-0 Naztog 3 “ton + 7 Key potnis . : 4 than Garbouytca aids ae TONY as 1 aud can canton: avid Cott) > Hence. oTbRagt 2, it tattonalis 3 ewive to, gre by» reasdthg . with % s bilartorates Uke NOHto,, Na2l0; 0, 9% tb ewlved rom Nats Ndzto3 but nor fuom carborsyel aude Like aud , aulphon aud put aude and alkyl buydengen sulphate 2 ao lve “ gas by pan wtltn Natiies ctl BD readlion with efqnand reagent RM + plo ——> RH ft May (100) ergy + ame —— a GltieMgd + eis eon ——9 Ne isa + erator —— Ms" Scanned with CamScanneri on $ roo REED tte te ether CH, Woon 4 City Loo Oy as On, 1, C00" 3 Og Uh WD He woot" _s O)-wory C-0 , leavage staclian | Ecterifitatien Ren [Fcher esteapledtion] ° ° 8 ae usu eos red con miley ety pb Bae + 0 Mech + , os a i i # ot Roe 1 gt tra r- 2-04 fbcon SP RE om a oH 2 wt bau | nebo! ek ig Py , | + + | a no Scanned with CamScannerE need To get gwd yield for forward pe ile: & ake extess — altoho) The rag estentpiealin <& —-aenelve m lui hindenance- oO eubsthition in both = alkohol eAlows down the tab oqo &e: orden qo ak estentpreabien i a HWOH > = oy-woH > Neon > Deeoon > eig-on > Oy-tHoH > yon > -fe froblins : Wits the prwauds fer tne. petlowing nNs24 on, — cp sO Fo or o~ Hy oH o. Au + Oyu -0H 2 \ASo- aon i ") Wy ie ow oNo oH on 5 Meats! oye beh + pre E-oH iD oy Scanned with CamScannerReadion — utth Pd; ,Pds and ds o. 0 ret _on +) sod. —— Reaction uth = NK ° @ i og ance es petion + NH, —> R-E-—o NH ——> Roe — Nie ammonium alt 4- amide autora atid " a ay -b—on, + Ay cry -€ NM eramide m 9 2 dpe boo qromd!g—> th oe -E hie propanamide ° . (By Pon «my ———s GF) Benzamile Scanned with CamScannerNote» jer yan Amides with Pads FOF BR a ead num, os /- R- (0) ens nits \| 1 | we lhe see oye Ot meget, = cere mC 1 Scanned with CamScanner- : ( 2 Reactions tmwoling ov hyplrtagen or otk Tp tarboxyi? auld. @oWve reaction’ (Hatt volliard Zelinsky x9) i = «oer or oe Red P/xz * Reette econ EO pady -e00H Fivtonyut aud) Pts © hauling alteast xe dy Br ‘ one oc hyd] 1 ’ , » Rodis -won Re P/ Bs dn lO ~ Mechanism : Potsere 9 P BY e ¢ g 3R-Giz—%-0n 4 PRrg ———>_ 3 Rt EmBr + MgO ° n Ray - 6 - gr ee Pat tee at ° ~ ; Br Root eR + Roam - FO ———> een 5 -OH RG oe bo ° Wile the products for the following. a a | eddelel. crnioon etre Soon eats ere eta dy “ah » ey —on-woon AMO ny ty 008 mua P/F one Scanned with CamScannerOe = MO toon ROPLES oo oy halo Huz ran X~ subsHluled — tarboxylii atids Nawh x to! R-CH — Loon. R-cn-woon — : x halo aula o i$ Naen i, R- EH = wor. Lng: R- at —won. Note. fw-d > Redo > Piwre! - Pete reer gine &) Test ob forme aud @ Formi avd — will give tollen’s tet Eo Fomi auid wil) give — Fenuing Fest 4 Had, tes we Hook + Hale —— > "yi, + Gunite ppt) Higa, tH ———3 gb toe Gorey rp) Ned cs CoN, + C1t3t00H PHN. etguontteatte + etsto0 Ald, benzene, tgs volts + utp coonl. Stes Recor peed tty coo + entsoH Naottya a Cty Woe 4) 4u00NA +esHsoH PM setts cont. + caltroH éMtylo0cHs + ditsoH GNsoH (en), con tg Lo NIL-NG ,— th6cy Ihe 5 CH oot + (NH) S0y Ch CONK, NAOH guooNa + Hy | p Ble sagen +ty0 Nan, + HA Clo + Ne & Hep br, tKOH 5 CNH + Kato + KBr +H30. All these 4 detivalves undeigu Nu subs rxn Readtvity p ’ order r-led > (Rtd),0 > Recor > ROE NAL rewards Puy! ankytcs esters amides Nu Subs" raude Scanned with CamScanner