Aits 2223 Ot Jeem TD Sol

FIITJEE
ALL INDIA TEST SERIES

OPEN TEST
JEE (Main)-2023
TEST DATE: 15-01-2023
ANSWERS, HINTS & SOLUTIONS

Physics PART – A
SECTION – A
1. B
Sol. Applying conservation of angular momentum of system about centre of
mass of disc
2mR2
mvR  mv R  
2
v   R
mvR  mv R  mv R
v 2g g
v   
2 2 2 M
2. D
Sol. I = neA (e + h) E
2
 1.0  106  1.6  1019  4  104 1.0   = 6.4 × 10–14 A
3
2  10
3. C
Sol. Basic concepts
4. C
dW
Sol. C  CV 
ndT
3T0 3T0
5R
 dW   TdT  
T0 T0
2
dT for one mole
W  (4T0  5R)T0
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AITS-OT-PCM(Sol.)-JEE(Main)/2023 2
5. C
dN
Sol.  R  N
dt
N t
dN N
So  R  N   dt  ln R  N 0  t
0 0
R  N
So ln  t
R
N R
So 1 
R
 e t  N 

1  et 
6. C
Sol. Zener current will be maximum, when V = 15V
15  (i  2.5k) = 5
i = 4 mA
iz = 3 mA
7. B
1/3
RGe  X 
Sol.  
RBe  9 
X = 72
Number of neutron = 72  32 = 40
8. B
Sol. frequency received by submarine
 1400  100   15 
n1     40  103     40  103
 1400   14 
Frequency reflected by submarine
 1400   15  3 600
n2  
1400  100  n1   13   40  10 Hz = 13 kHz
   
9. C
2(1  cos C )
Sol. f
4
2  1  1 1 
f 1  1  2   1  1  2 
4    2   
10. D
Sol. For (r  R)
r
E  4r 2   cx4x 2 dx / 0
0
So E  r2
and For (r  R)
1
E
r2
3 AITS-OT-PCM(Sol.)-JEE(Main)/2023
11. D
2 2 4
Sol. 1 H 1 H  2 He
BEH  1.1 MeV
BEHe  7 MeV
Qvalue = Binding energy of product  Binding energy of reactants
= ( 4  7  4  1.1) MeV = 23.6 MeV
= 23.6  1.6  1019  106 = 37.76  1023
12. C
0 dI 0Id0  Id
Sol. B   0 0
2R (2R)(2R) 42R2
13. D
Sol. After long time,
2V
IA   20 mA …(i)
7R
Immediately after the key is closed,
V 70
I  mA
3R 3
14. C
ax
Sol. For 1st secondary minima  1
D x
a
ax 3 2
For 1st secondary maxima 
D 2 D
3
1   2
2
 = 440 Å
15. D
Sol. Basic Concepts
16. A
Sol. When S is open When S is closed
48C 48C 96C 36C
A A
B B
72C 72C 48C 108C
30V 30V
So charge flown = 60 C
From A to B
17. B
Sol. Basic concept
18. C
d
Sol. E2r  (Br 2 )
dt
r dB
E
2 dt
Qr 2 dB
  QEr 
2 dt
19. B
0i i
Sol. B
2R
0ir 2
  Br 2 
2R
2
 0 r R
Mutual inductance, M  
i 2R
20. D
Sol. Rate of cooling
4 4
dT A(T  Ts )
  r
dt mC
rsphere m a3
 cube 
rcube msphere 4
 r 3
3
given, 4r 2  6a2
3/2
 4 
3 r3
rsphere  6  
 
rcube 4r 3 6
SECTION – B
21. 6
D
Sol. Separation between two maxima  
d
22. 40
Sol. v 02  4v 02   2  g  d   2gd  3v 02
v 02  v 2   2  5g  d   v 2  v 20  15V02
So v  4v0
23. 1
2v 3v
Sol. 
2   0  1.2d 4   c  e 
So 4  23  e   3  30  2e 
So e = 1 cm
24. 9
Sol. E0 = CB0
= 3  108  3  10 8 = 9 V/m
25. 30
1 1 1
Sol.  2  ,
fe f fm
1  4  1  1
Where    1  
f  3   40  120
1 1 1 1
So  2    cm
fe 120 20 15
So R = 30 cm
26. 2000
Sol. 100  v 10   200  v  20   50  v  40  0
So v = 100 volt
Q = 40  50 = 2000 C
27. 24
dV pr 4
Sol. 
dt 8
P0r 4
Q
8
3P0 (2r)4 3P0r 4
Now, Q    24Q
8 2 
28. 4
 x R  1
Sol. y  x tan   1    H  tan  1  
 R 2  2
R tan 
 H
4
3R  3R  H
y tan   1  
4  4R 
3R 3R 4H 3H
 tan   
16 16 R 4
29. 16
Sol. a = R
F  f S = ma …(i)
mR2   a
fSR  F
2
ma
fS  ..(ii)
2 fs
3ma
F
2
2F ma F
 a  fS  
3m 2 3
30. 2
Sol. In steady state, v = constant F
9 mg = 3F
 F = 3 mg … (i) m r v
T + mg = F T
T = F – mg = 3mg – mg = 2mg
T = 2mg T
8m 2r v
2F
Chemistry PART – B
SECTION – A
31. B
Sol. P1 V1  P2 V2
10m   4   A  10  h  m  h  A
h  3.06 m
32. C
Sol. Dithionous acid  H2 S2 O4 S  3
Dithionic acid  H2 S2 O6 S  5
33. C
X
Sol.
X
X
Y
Y Z
Z
Z Y
Y X
34. D
Sol.
Br

HC
H

H2O HC
HC OH
Br
35. B
Sol. Me
Cl Si Cl Chain formation
Me
Me Me
HO Si O Si O Chain
Me Me
36. C
Sol. LiClO4 is more soluble than LiF.
37. D
Sol. Factual
38. B
Sol. BF3 is electron deficient and is used to generate electrophile in F.C. reactions. Therefore, acts as
catalyst in industrial processes.
39. B
Sol. Uridine is glycosylated pyrimidine-containing uracil attached to ribose ring.
Ribose  sugar   Uracil base   Nucleoside
40. A
Sol. Degenerate orbitals  n2
2
  5   25
41. D
Sol. S  State function S  S1  S 2
q
S  since q = same; smaller temperature, higher entropy.
T
42. D
Sol. Ti3  3d1  t12g
Cr 3  3d3  t 32g
Mn3  3d4  t 32g eg1
Co 3  3d6  t 42g eg2
43. A
Sol. Factual
44. B
Sol. MnO2 oxidises unhindered primary allylic and benzylic alcohols to aldehyde.
45. C
1 1
Sol.   k2 t
xo  a xo
Rearranging
a
 xo k 2 t
xo  a
a
 vs. t gives x o k 2 as slope.
xo  a
46. C
Sol. Cl
O
N Cl S Cl
N NH C OH
(ii) (i)
O
H2N COOH
N
H
N NH C N
N NH C Cl
(iii)
O (- HCl) O
47. A
Sol. H Cl Cl
Me  Li
C 
 CH
 C
4
Cl LiCl H
H
Cl
Cl C H
C
H Cl
NH 
HCl

NH
N N
H
48. D
Sol.
2 NH OH

H O

2
O
N OH
O
H3C C Cl
(- HCl)
CN
 AcO CN  AcO
 
 AcOH O
Product
H N O C CH3
49. B
H O
O
Sol. Me O Hydrogen bonding and as 1-3 dihedral interaction between methyl and
H
hydrogen.
50. B
0.744  0.359Zeff
Sol. xA   Alfred  Rochow scale
rA2
SECTION – B
51. 13
Sol. O
COOH O C O
HOOC COOH C O
C


3H2O
 O DOU  13
C
HOOC COOH C O
COOH O C O
O
52. 2
Sol. H   104
 
104
 Ca2   M
2
Weight of Ca 2  20  104 g in 1 L
20  104  106
 Weight of Ca 2 ion in 106 mL H2 O  =2
103
 Hardness = 2 ppm.
53. 1
Go
Sol. Theoretical efficiency 
Ho
Go
0.84 
285
Go  0.84  285 kJ  nFEocell
Eocell  1.24 V
54. 2
Sol. Cd2  H2 S  Cd  s   2H
Initial 0.1  10 3 moles 0.08  10  103 moles
final  0.8  103  0.2  103
 10 3 moles
10 3
 H    1000  0.01 M  102 M
final 100
pH = 2.0
55. 8
Sol. For KCN: Tf  i.K f .m  0.8  K f .0.2  2
Kf  2 … (i)
Hg CN  mCN  Hg CN
m
 2  m  2
Initial 0.1 0.2 
Final  0.2  0.1 m  0.1
Final effective molality = (0.2 – 0.1 m) + 0.1 + 0.2
= 0.5 – 0.1 m
New: Tf  K f .m
0.6  2   0.5  0.1 m 
m=2
4m = 8
56. 3
Sol. XeO2 F2  sp3 d x3
3
B 2 H6  sp x6
2
NiCl4   sp3 x3
2
PtCl4   dsp2 x2
N  SiH3 3  sp2 x2
H3 BO3  sp2 x2
 x  3  6  3  2  2  2  18

x  3
6
57. 2
Sol. CH3 CH3
H OH HO H
H OH HO H
HO H H OH
CH3 CH3
58. 0
Sol. CO CO
CO
CO
CO Mn Mn
OC CO
CO CO CO
59. 6
Sol. Black coloured : PbS, CuS, HgS, Ag2S, NiS and CoS.
60. 6
Sol. 1 and 5 have correct products.
2. CH2 CH2 CH3  H2 /Ni
H3C (CH2)4 CH3  CH2 CH2 CH3
3. COOH
  COOH
 CO2
COOH
4. O

2CH3  CH2  COOH   H3C CH2 O C CH2 CH3
O
Mathematics PART – C
SECTION – A
61. B
Sol. A = {1, 2, 3, …… , 141}
A  (B  C) = {5, 11, 14, 17, 23, 26, 29, …… 134, 137}
Sum of elements = (5 + 11 + 17 + ……. 137) + (14 + 26 + 38 + ….. 134)
62. C
2
Sol. x  ax + 4 = 0 must have atleast one positive root
  > 0
 both roots must be positive
 a4
63. B
60
Sol. 30(1 + x + x2)30 (1 + 2x) =  rar xr 1 (1 + x + x2)
r 0
Equating coefficient of x20 on both sides we have,
30(a20 + 2a19) = 21a21 + 20a20 + 19a19
 21a21 = 10a20 + 41a19
64. C
Sol. Use   xg  x   g  x   dx  xg  x   C1
65. C
Sol. k = 2500 = 22.54
 number of factor = 5
66. B
Sol. b = 4, c = 9
2sin2 = 3cos
 2cos2 + 3cos  2 = 0
1 3
cos =  sin2 =
2 4
3
 4x2  4y2 + xy + 12x + y + 9 = 0
2
67. A
r1r2
Sol. r=
r1  r2  2 r1r2
68. B
1 2 2 3
Sol. A= (4  8t)8t = 16(t  2t )
2
dA 2 1
= 16(2t  6t ) = 0  t = 0,
dt 3
d2 A 1
= 16(2  12t) < 0 at t =  A is maximum Q 2
dt 2 3 16t,8t
 16 8  2
 Q  ,  lies on the line  m =
 3 9 3 R P(4,0)
69. A
Sol. M is (1, 10)
 N is (4, 16)
L is (–2, 4)
Equation of tangent to (x + a)y =  is

y  2x   2  a  t ;   2t 2
t
 2a – 4t = +8  a – 2t = 4
2
and (a – 2)4 =  = – 2t
2
 (t + 2) = 0
 t=2
 =–8&a=0
70. B
Sol. 4a2 – b2 = 25
Equation of auxiliary circle is x2 + y2 = 8
 a2 = 8, b2 = 7
Also a2 + b2 = A2 – 2
 2 = 25 – 15 = 10
10 3
 eccentricity of ellipse e  1   .
25 5
71. D
Sol. IF = e x/2 sin x  cos x

 solution is yex/2 sin x  cos x   e x/2 tan x  2 sec 2 x dx 
x/2 x/2
ye sin x  cos x  2e tan x  c
 
 y    23/4  c = 0
4
2 tan x
y
sin x  cos x
72. D
 z4  z 
Sol. Arg  2 0
z z
 z(z  1)(z2  z  1) 
 Arg    0 ; z  0, 1
 z(z  1) 
 z2 + z + 1 is positive real number (x + iy)2 + x + iy + 1 > 0
 x2  y2 + x + 1 > 0 and y(1 + 2x) = 0
(i) y = 0, x2 + x + 1 > 0  x  R
1 2 3  3 3
(ii) x =  , y <  y   ,  .
2 4 
 2 2 
73. C
a b c
Sol.   2
a 3 b 5 c 7
b c
If a  2 3 , then  0
b 5 c 7
2 5
Possible value of b  ,c= 2 7.
3
74. D
1  4 A
sin  tan1  BD sin 
2  3
Sol. 2 tan17
1  
2
1
4

sin tan 7 BD sin    
 D
4
sin  4
5 11  tan1
  2  cot = 3
7  cos   sin   7
  B C
5 2 2 
75. C
2 3
Sol. P(A) = , P(B) =
5 5
3
P(D) =
20
2 3 3 1
6 x   x  x
5 5 20 20
3 19
 B  P B D
P C  
C
 
 5 20 
57
C 85
D  P(D ) 85
100
76. A
n
 xi fi 15a  25b  980 277
i 1
Sol. n
  …(1)
26  a  b 9
 fi
i 1
26  a  b
 a  b  3
2 335
Also 30   10 
11 11
 a + b = 19 …(2)
From (1) and (2) a = 7, b = 12.
77. B
78. A
h C
Sol. tan( + ) =
50
8 h 4h/5

h 21 250  2000  21h
 
50 8 h 5250  8h D
1 
21 250
h = 25 h/5


A 50 B
79. B
Sol. 3 5 …… = 9  5 = 45
__ 3 5 ____ = 8  5 = 40
……………. = 8  9  9  5 = 3240
N = 3325
80. A
Sol. PB = 324  64  388 P(20i)
B(18,12)
PA = 36  400  436
OP = 20
O A(6,0)
SECTION – B
81. 5
    
15
sin    m      m  1  
18  18 
Sol.       
m 1
cos    m  cos    m  1 
 18   18 
15
     
  tan    m   tan    m  1 
m 1  18   18 
 5 
 tan      tan   4  2 3
 6 
 5 
 cos  2   1
 6 
5
   n  ; n  I.
12
82. 59
Sol. Squaring and adding
1 + sin6A + cos6A + 2(cos4A – sin4A) = 1/4
 2 + 1 – 3sin2A cos2A + 2cos2A = 1/4
2 – 3/4 sin22A + 2 cos2A = 1/4
 3 cos2 2A + 8 cos2A + 4 = 0
cos 2A = – 2/3
5
sin A 
6
 5 5 5 5
 cosB  2    .
 6 6 6  54
 
83. 13
5 
Sol. a ,b
12 3
5  /12
 tan x 
  dx
 /3  3 
tan1 2 3 5  /12
=  1  2dx  cot 1 2 3  co sec 1 13 .
 /3 1
tan 2 3
84. 546
 0 0 0  0 0 0
  2   3
Sol. Let A = I + B where B =  a 0 0 , B =  0 0 0  , B = 0 (Null)
   ab 0 0 
a a b 0  
n n n 2
 A = I + C1B + C2B
 
 1 0 0
n  
A =  n a 1 0
 n(n  1) 
na a  ab n b 1
 2 
 n a  n b  72  a = b and 72a + 36 72  a  3600  
 a = 4  a = 16 and n = 18.
85. 20
Sol. Let P(t, t2), Q(t4, t2)
t t2
  y2=x
 x 
2
 f  x  dx  2  y  y 2 dy
0 0
 t2  f(t) = 2(t  t4)2t
 f(t) = 4t5  3t2 y=x2
 1 4 3 20 Q
f     . P(t,t2)
 2  32 4 32
O
R
86. 20
x
Sol. f(x) = 1 + 4
sin(4  4)  2  2x
x
lim 3  ln8
x 1 x  7x 2  ax  b
0
For   form a + b = 6
0
Also lim
 cos(4 x

 4) 4 x ln 4  2x ln2
 ln8
2
x 1 3x  14x  a
6ln2
  3ln 2
a  11
 a  11 = 2  a = 13, b = 7
87. 81
Sol. For continuity at x = 0
cx
2 3  1 c ln 4
lim   c=2
x 0 cx 3 3
3
For differentiability at x = 0
cx
2 3  1 ln 4
6a  ln2 
2 
1 x 3
lim 2
  lim
x 0
 b  x  3 x 0 x
1  
 3 
cx
2
6a  ln 2  3(2 3  1)  x ln 4
  lim
 b 2  x 0 3x 2
3 1  
 9 
 cx c
2
3  2 3 ln2    ln 4
ln 2   3  2(ln2)2
= 2  lim  
9 x 0 6x 9
2 2
6a  ln 2   9 2 ln2  b2  9
=  =  81
3 b2  9 9 a
88. 1386
Sol. h(g(g(x))) = x
h'(g(g(x)).g'(g(x).g'(x) = 1 ; g(x) = f1(x)
h'(0)  g(g(x)) = 0  g(x) = f(0) = 3  x = f(3) = 309
1
Also g'(f(x)) =
f(x)
1 1
g'(3) = 
f 0 3
1 1
g'(309) = 
f   3  462
1
 h'(0) =
g  3  g  309 

89. 10648
Sol. L1 is parallel to vector 2iˆ  ˆj  kˆ and it passes through point (13, 7, 0).
Equation of plane P is x + 5y  3z + 22 = 0
22 0 0
1 22 (22)3
V= 0  0  .
6 5 90
22
0 0
3
90. 225
Sol. Let xˆ  yˆ  a , yˆ  zˆ  b , xˆ  zˆ  c

xˆ  yˆ  zˆ  p  a  b  c = 2 …(1)
Also cyˆ  azˆ  q …(2)
and cyˆ  bxˆ  r …(3)

 q  yˆ  5  c  ab = 5 …(4)
and c  a = 1 …(5)
Hence a = 1, b = 3, c = 2

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