SS ee BB Unoogunio Norn 4p iT = OMeMberiex | kevones eee Additional Conjugadion s0nm Nomoannwjast diene ee Ring yesidue fae Subtle on = bond miles © 307-007 B= 5, membered Ketones, Z ZO020M i. A= no addi oyvea| conjugn 0 bee Exocyclic double hung = 59m 1 R= po io B-51INg ntesidue- See S = NO subshtute o 256nm a= pase value = ee - ning Recto PO Z cxocycne E Snm Z2ANBV= Ememberec| Ring = 215nm A= 2B extension = 6Onm pe 2 Exocyclic Bond = 5x2 = 10 = LB- = lanm R ne AS z L¥Ynm 257k = oo S= no subshtuent=Onm __ asinm EN _OH 7 B= (ememberted ketone) = 2159m A= No DB addifon = Onm So = no = Onm R= p- ting otesidue = |2nm. S = AlKyl substituent = cLanm OH ploup = 35mm 2 nm® % ELC, : | B= Base Volue = 6 inembened =0 =2165qm | a A= Additionay Conjugation = 30 nnn a Homoonnutosy = = 35mm | ND Exocyclic double bond = Onn R= X Position = Loam. P,PoSthon = 12mm | VY Position = ¢ S = no Substivent = 6 2 t = 324m | B=6 member ketone = 25mm A= DB. extension = 20 nm Homo annua = 23 nm E = exo fclic op oni, RS ie : 1tonm PRR LE nm “31am Be Omemberted ketone = 215mm. CH A= No E = No Re B-RR = Lanm PoAIKY! droup= Lamm, = OH ot of positign = 35mm 244 nm aCH OCOCHa \ le 4 B® PRAGAyONhory Seton Bs $= AMEMMAT Kelas (Save As PadN onal Compagation, AO ya t Homoonaday Wene XG R= Rog ave e Ne OF Meer dire \ S = Sahudete av © hand Qn AVS y\any Do VW R= 5 B= Smentored Kehoness = agawan : = We adtthonal Gangre e eer ( t NOCHE douse bot = Hyer Re ss an SAAN B-9tt0g vealdye Bran S = NO sds Nok O Se ake Be ace value tb yay » = Ring Reaidue RAMA * r : Ny Sane f = Exec y \G vyKetone TES €rnernt Bot B ya ic Unsatuted Gonbonysl siems 2 ___Unsadwiote ated Conbonyls | Value, Acyclic &, B- Unsofustated Ketons. 244nm_ 6 memeved Cyclic %, B- Unsofuriated 215nm ketones. = 5 membered CYCliC X, B- nsatwiated 202mm ketones. & B- Unsoduioted Aldeyhdes . 240nm : boxycl} | | re unsatuyjased Cormboxiclic Caids fp 435m SteNS - Homoannwas diene. 39m. Values tO Bo 6 8 posinons Substiuenhons & _Auxochstome Jena, L Beto. __| sone, ieee OH 35 30 oo | 0R (0-CHs) ey | ee 14 31 | 3 By 25 30 - = | ch | ae | “Hs O71 AK) Gnioup is q Riga nesidue A i me OCORexocycle dovble bond, Hylogen : Pheny| ning. NOTES & Dosting the Co One 4 She dowble bond Ouy a Jhe >in. —X (cl, Bot) —OR —SR —NR2 —OC(0)CHy — Ph the whDle se ected omg. ft onm +onr Fon, | | | | +30nm | | h60nm | | +onm Pheny| Bin 4 | Pheny| Ring (445nm) } unting Exocyclic double bond ‘ Endocyclic double bond.Absonplion Xr maxima = B+ 8 $1 Et+ R+S 5 Here, B= Basic Value A = Additonal Conjagochory E = Exo or Endocyclic double bond - R= Ring sqesidue S = Substhution on double bonded cabo) only. Diene ~C=C-C=C Zien | Homoannulat 253nm ( Tn 1945, Robert Bums W0odWorid gave certaiy sujes fox Conmeloding. Amax with molecujo Structuye- 1959, Lous Fredenick Fiese modified these mwes with mone experi - pera! dota ,on this modified ules is Known as wood ae Fiesey Rujes. T+ is used to calculading the position ind max £031 all the Compounds like Diene ,chxomphosie L %, Br unsaturated Compounds etc. In on wltstayjoleh Specttum Ff the given compounds. This may be differs £10m observed Values by. 5- 65mm his Fiese s1uje myst be applied fo certajy ! eas Plants pi + such qs coniotenajds with even mote th ida jon 4 jouble bond: CONUgated Acconding 4o Woodwooid Feisen aule. Fre max FH molecue con be Cafcjated by using A foimulg + Amox = Base Value + S Substtuent Contsiibudions + = other contotibuhons . oo. jerie the base Value depends upon whe other the ssl iS -hefenoannwjedt ot homoonnufast diene 01 cyclic on icyclic - 50, yore iS the Simplified Posimula fom sfememberance ,