KIRLOSKAR INDEPENDENT PU Preparatory Exam

COLLEGE, HARIHAR. Class : PUC I

Sub : CHEMISTRY (34) Date: 21.01.2023
Marks: 70 Time: 3hr.15min
Instruction: 1. The question paperhas four parts. All the four partsare compulsory.
 PART-A Carries 20 marks, each question carriesone marks.
 PART-B Carries 8 marks, each question carries two marks.
 PART-C Carries 12 marks, each question carriesthree marks.
 PART-D Carries 30 marks, each question carries five marks.
PART-A
I. Select the correct option from the given choices: 15x1=15
1. The number of oxygen atoms in 4.4g of CO₂ is
a) 1.2 x 1023 b) 6.02x1023 c) 3.01x1023 d) 12x1023
2. The mathematical is statement of Boyle's law is.
1
a) V 𝛼 P b) V 𝛼 𝑃 c) V α n d) V𝛼 𝑇
3. For reaction, N₂ + 3H₂ ⇌ 2NH3, ∆H = ?
a) ∆U+2 RT b) ∆U-2RT c) ∆U = RT d) ∆U=RT
− −
4 Write the conjugate base of 𝐻𝑆𝑂4 . (a) 𝐻2 𝑆𝑂4 (b) 𝐻2 𝑆𝑂4 c) 𝑆𝑂4−2 d) 𝐻 +
5. If the atomic number an element is 33, it will be placed in the periodic table in the
a) First group (b) third group (c) fifth group (d) seventh group
6. Among BMO and ABMO, the one which has least energy level is a) BMO b) ABMO c) Both d) None
7. The oxidation state of Cr in Cr 2𝑂7−2 is a) -6. b) +12 c) +6 d) +4.
8. The radioactive isotopes of hydrogen is. a) Protium. b) Deutarium c) Tritium d) Hydronium ion
9. Which compound will show the highest lattice energy? =) a) RbF (b) CsF c) NaF d) KF
10 Which one of the following does not show electrical Conduction?
a) Diamond b) Graphite C) Potassium d) sodium.
11. Baron compounds behave as Lewis acids, because of their
a) Ionization property (b) electron deficient nature c) acidic nature (d) Covalent nature
12. What is the hybridization state of carbon in benzene ring a) sp3 b) sp² c) dsp² d) sp 3 d 2
13. Paper chromatography is an example of a) adsorption chromatography b) Partition chromatography
c) Thin layer chromatography d) column chromatography
14 Which of following the alkane cannot be made in good yield by Wurtz reaction?
a) n-Hexane b) 2,3-Dimethyl butane
c) n-Heptane d) n- Butane
15. Among the following the one that is not a greenhouse gas is a) SO2 b)N2O c) CH4 d) O3
II Fill in the blanks by choosing appropriate word from those given in the brackets. 1X5=5
[ Group seventeen, Bronsted acids, 𝐵3 𝑁3 𝐻6 , CH, Maleic anhydride]
16 ______________ is an empirical formula of Benzene
17 Proton donors are __________________
18._________________element are called Halogens
19 _________________ is called an inorganic Benzene
20. The oxidation of benzene by V₂O5 in the presence air produces________________
PART-B
III. Answer any four of the following questions - 2x 4 = 8
21 State law Of conservation of mass with an example
22. Calculate the volume Occupied by 25g of CO2 at 303K and 0.974 atm. pressure.
[R= 0.0821𝐿𝐾 −1 𝑎𝑡𝑚𝑚𝑜𝑙−1 ]
23. Write the electronic configuration and Bond order for hydrogen molecule.
24. Write any two uses of POP.
25. Write balanced equations for a) BF3+ LiH→ b) NaH + B2 H6 →
26 Explain Wurtz reaction.
27. State Markovnikoffs rule with an example
28. Write any 2 Common chemicals of photochemical smog.
PART-C
IV. Answer any four of the following questions- 3X4=12
29 a ) State Modern periodic law.
b) How does atomic radius vary along the period and down the group?
30. Write any three postulates of MOT.
31 Explain the formation Methane molecule on the basis of hybridization.
32 Define dipole moment of polar bond. Show that BeF 2 molecule has zero dipole moment.
33.Balance the following equation by oxidation number method 𝐶𝑟2 𝑂7−2 + 𝑆𝑂3−2 → 𝐶𝑟 3+ + 𝑆𝑂4−2 [ in acidic medium]
34 Write any 3 differences between soft water and Hard water.
35 Write any 3 anomalous behavior of Lithium.
36. Waite any 3 structural differences between Diamond and Graphite
PART-D
V. Answer any four of the following questions 5x4=20
37. a) An organic compound contain 4.07% of hydrogen, 24.27% of carbon and 71.65% of Chlorine What is its empirical
formula? [Atomic masses of H=1, C=12, Cl=35.5] (3+2)
b)Calculate the molality of NaCl if 2g of it is dissolved in 18g of water.
38. a) State three postulates of Bohr’s atomic Model for hydrogen atom.
b) The atomic number and mass number of Bromine are 35 and 80 respectively. Find the number of protons and
neutrons in its atom.
39. a) Write the significance of each of any three of the quantum numbers.
b) What will be the wavelength of a ball with a mass of 0.1kg moving with a velocity of
10𝑚𝑠 −1 ? (ℎ = 6.626𝑋10−34 𝐽𝑆)
40. a) Write any three postulates of kinetic theory of gases.
b) What is viscosity ? How does it vary with the temperature? (3+2)
41. a) Define standard enthalpy of formation.
b) Calculate the standard enthalpy of formation of benzene from the following data.
1
i) 𝐶(𝑠) + 𝑂2(𝑔) → 𝐶𝑂2 ; ∆𝐻𝑓0 = −393.5 𝑘𝑗. 𝑖𝑖) 𝐻2(𝑔) + 2 𝑂2 (𝑔) → 𝐻2 𝑂(𝑙) ; ∆𝐻𝑓0 = −285.83𝑘𝐽
1
iii) 𝐶6 𝐻6 (𝑙) + 7 2 𝑂2 → 6𝐶𝑂2(𝑔) + 3𝐻2 𝑂(𝑙) ; ∆𝐻𝑓0 = −3267𝑘𝐽 (1+4)
42. a) Define i) Entropy. Write its S I unit ii) Extensive property.
b) State I law of thermodynamics. Write its mathematical statement. (3+2)
43. a) Show that 𝑝𝐻 + 𝑝𝑜𝐻 = 14.
b) The concentration of 𝐻𝑁𝑂3 𝑖𝑠 0.5 𝑀. 𝐶𝑎𝑙𝑐𝑢𝑙𝑎𝑡𝑒 𝑖𝑡𝑠 𝑝𝐻 𝑣𝑎𝑙𝑢𝑒. (3+2)
44. a) State Le-Chatelier’s principle. What is the effect of pressure and temperature on the following equilibrium.
𝑁2 + 3𝐻2(𝑔) ⇌ 2𝑁𝐻3(𝑔) ; ∆𝐻 = 92.38𝑘𝐽𝑚𝑜𝑙 −1 .
b) The equilibrium constant Kc for the reaction is 2𝑋1013 𝑎𝑡 300𝐾 𝐶𝑎𝑙𝑐𝑢𝑙𝑎𝑡 ∆𝐺 0 𝑎 𝑡ℎ𝑒 𝑠𝑎𝑚𝑒 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑒
[𝑅 = 8.314 𝐽𝑘 −1 𝑚𝑜𝑙−1 ]
VI. Answer any two of the following questions 5x2=10
45. a) Write the principle and calculation involved in the estimation. Carbon present in organic Compound by Liebig's
method.
b) Give any two differences between Inductive and Electromeric effect. (3+2)
46. a) 𝐶𝐻3 − 𝐶𝐻2 − 𝐶𝐻 ≡ 𝐶𝐻 − 𝐶𝐻3 i) Write the IUPAC name ii) Bod line formula. iii) Number of 𝜎 𝑏𝑜𝑛𝑑𝑠.
b) What if functional isomerism? Give an example (3+2)
47. a) Explain the mechanism of chlorination of methane.
∆
𝐴𝑛ℎ𝑦𝑑
b) Identify X and Yin the following. i) +Zn→ 𝑋 ii) +𝐶𝐻3 𝐶𝑙 → 𝑦. (3+2)
𝐴𝑙𝐶𝑙3
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