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CREED REVIEW CENTER

COMPREHENSIVE REVIEW THROUGH ENHANCED EDUCATIONAL DEVELOPMENT

CRIME DETECTION AND INVESTIGATION

FIRE TECHNOLOGY AND ARSON INVESTIGATION


certain gaseous products that are luminous at the
I. The Technology of Fire temperature of the burning material.

A. Glossary of Terms 11. Fire escape – A building structure arranged outside to


assist in safe evacuation of occupants during an
1. Accelerant – flammable fuel (often liquid) used by some emergency; may connect horizontally beyond a fire wall or
arsonists to increase size or intensity of fire. vertically to a roof or (preferably) to the ground, perhaps
with a counter-weighted span to deny access to intruders.
2. Backdraft – A fire phenomenon caused when heat and
heavy smoke (unburned fuel particles) accumulate inside a 12. Fire hazard – Materials, structures or processes that may
compartment, depleting the available air, and then result in creating a fire, permitting a fire to grow undetected,
oxygen/air is re-introduced, completing the fire triangle and or preventing people from escaping a fire.
causing rapid combustion.
13. Fire tetrahedron – The fire tetrahedron is based on the
3. Combustion – When materials smolder or burn.
components of igniting or extinguishing a fire. Each
component represents a property necessary to sustain fire:
4. Compartment Fire – An "Isolated" fire, or a fire which is
fuel, oxygen, heat, and chemical chain reaction.
"boxed in" or "closed off" from the rest of the structure. An
Extinguishment is based upon removing or hindering any
example of this is a fire in a room where all the windows
one of these properties.
and doors are closed preventing the fire from spreading to
other rooms.
14. Fire triangle – An outdated model for understanding the
5. Contained Fire – A fire restricted to boundaries major components necessary for fire: heat, fuel and
established by fire fighters. oxygen.

6. Conflagration – A large, typically urban, fire involving 15. Flame over – Also known as rollover. The ignition of
numerous structures; loosely defined as enveloping an heated fire gasses at the ceiling level only. While
area equivalent to one or more square blocks.
dangerous to firefighters, this is not as deadly as Flashover.

7. Deflagration – An explosion with a propagation front


16. Flash point – Lowest temperature at which a material will
traveling at subsonic speeds, as compared to supersonic
emit vapor combustible in air mixture.
detonation.

17. Flashover – simultaneous ignition of combustible materials


8. Exothermic reaction – Chemical reaction giving off heat in
in a closed space, as when materials simultaneously reach
the process, such as combustion.
their fire point; may also result in rollover.
9. Fire – is the manifestation of rapid chemical reaction
occurring between fuel and an oxidizer- typically the oxygen 18. HAZMAT – Hazardous materials, including solids, liquids,
in the air. Such rapid chemical reaction releases energy in or gases that may cause injury, death, or damage if
the form of heat and light.
released or triggered.
10. Fire – is heat and light resulting from the rapid combination
of oxygen, or in some cases gaseous chlorine, with other
materials. The light is in the form of a flame, which is
composed of glowing particles of the burning material and
19. High-rise building – Any building taller than three or four is enough oxygen present, the vapor will oxidize rapidly – it will
start to burn.
stories, depending upon local usage, requiring firefighters
to climb stairs or aerial ladders for access to upper floors. The start of burning is the start of a Chain Reaction (the
burning process). Vapor from heated fuel rises, mixes with air
and burns. It produces enough heat to release more vapor and
20. Overhauling – Late stage in fire-suppression process to draw in air to burn that vapor. As more vapor burns, flame
during which the burned area is carefully examined for production increases. More heat is produced, more vapor
remaining sources of heat that may re-kindle the fire. Often released, more air drawn into the flames and more vapor burns,
the chain reaction keeps increasing – the size of the fire
coincides with salvage operations to prevent further loss to increases until fuel is consumed.
structure or its contents, as well as fire-cause determination
and preservation of evidence. Combustion – combustion is one of the kinds of oxidation,
which is the same as actual burning. It is a rapid oxidation
accompanied by heat and light. When the heat generated by
21. Oxidizer – A hazardous material containing oxygen that combustion, becomes sufficient to cause the material being
can combine with adjacent fuel to start or feed a fire. oxidized to take fire, the material has reached its burning,
kindling temperature or ignition point.

22. Pyrolysis – Process of converting a solid substance to Types of Combustion


combustible fumes by raising its temperature.
1. Surface/Glowing Type of Combustion – A condensed –
phase combustion
23. Rollover – The ignition of ceiling-level fire gases. 2. Flaming Type of Combustion – Gas – phase combustion
24. Thermal balance – The degree of thermal balance existing 3. Explosion – The process is confined so that an
appreciable pressure occurs
in a closed room during a fire's development independent 4. Detonation – Combustion waves propagates at supersonic
upon fuel supply and air availability as well as other factors. speed, a shock develops ahead
The hot area over the fire (often termed the fire plume or
C. CHEMISTRY OF FIRE
thermal column) causes the circulation that feeds air to the
fire. However, when the ceiling and upper parts of the wall Obviously, three things are required for combustion or
linings become super-heated, circulation slows down until fire: FUEL (Combustible materials to vaporize and burn),
OXYGEN (Oxygen in air is the common oxidizing agent, to
the entire room develops a kind of thermal balance with combine with fuel vapor, air contains 28% O, 78 N, 1% inert
temperatures distributed uniformly horizontally throughout gas), and HEAT (to raise the temperature of the fuel vapor to its
the compartment. In vertical terms the temperatures ignition temperature). The combinations of these three elements
form the so-called Fire Triangle.
continuously increase from bottom to top with the greatest
concentration of heat at the highest level. The Fire Triangle

25. Thermal Imbalance – a product of combustion rise in the


building or flow out of an opening, an equal volume of air
replaces. This is a result of the extinguishments of fire by Oxygen Heat
water in which turbulent circulation of steam and smoke
may replace the normal flow of the products of combustion.
B. THE START OF FIRE
Fuel
All matters exist of one of the three states – solid, liquid
and gas (vapor). The atoms or molecules of a solid are packed
closely together, and that of a liquid is packed loosely, the Figure 1
molecules of a vapor are not packed together at all, they are free Figure 1 will show that if any side of the fire triangle is
to move about. In order for a substance to oxidize, its molecules missing, a fire can not start or if any side of the fire triangle is
must be pretty well surrounded by oxygen molecules. The removed, the fire will go off.
molecules of solids or liquids are too tightly packed to be
surrounded. Thus, only vapors can burn. With the presence of the elements of fire, combustion
may take place. Before a fuel will burn, it must be changed to its
However, when a solid or a liquid is heated, its vapor state. In a fire situation, this change usually results from
molecules move about rapidly. If enough heat is applied, some the initial application of heat. The process is known as
molecules break away from the surface to form a vapor PYROLYSIS. Pyrolysis (also known as thermal decomposition)
just above the substance. This vapor can now mixed is defined as the “chemical decomposition of matter through the
with oxygen. If there is enough heat to raise the vapor to its action of heat”. In this case, the decomposition causes a change
ignition temperature (temperature needed to burn), and if there from a solid state to vapor state. If the vapor mixes sufficiently
with air and heated to high temperature, combustion results.
6. Ignition/Kindling temperature – the minimum
The combustion process is better represented by the temperature to which the substance in the air must be
fire tetrahedron. heated in order to initiate or cause self – contained
combustion without the addition of heat from outside
sources.
The Fire Tetrahedron
7. Fire point – the lowest temperature of a liquid in an open
container at which vapors are evolved fast enough to
Oxygen Heat support combustion.

8. Flash point – the temperature at which a flammable liquid


forms a vapor-air mixture that ignites. The minimum and
maximum temperature are referred to as the lower and
upper flash point respectively.
Fuel
To burn a fuel (combustible material), its temperature
must be raised until ignition point is reached. Thus, before a
Chain Reaction fuel start to burn or before it can be ignited, it has to be exposed
to a certain degree of temperature. When the temperature of a
Figure 2 certain substance is very high, it releases highly combustible
vapors known as FREE RADICALS (combustible vapors such
The fire tetrahedron is useful in illustrating and as hydrogen gas, carbon monoxide, carbon dioxide, and
remembering the combustion process because it has room for nitrogen).
the chain reaction and because each face touches the other
three faces. During the process of pyrolysis, the following are
involved:
The basic difference between the fire triangle and the
fire tetrahedron is that: The tetrahedron illustrates how flaming • the fuel is heated until its temperature reaches its
combustion is supported and sustained through the chain fire point,
reaction. In this sense, the chain reaction face keeps the other • decomposition takes place – moisture in the fuel
three faces from falling apart. is converted to vapor,
• decomposition produces combustible vapors that
The fire tetrahedron also explains the flaming mode of rise to the surface of the fuel (free radicals)
combustion. The modes of combustion are either Flaming mode • free radicals undergo combustion.
or Surface mode (Glowing– represented by the fire triangle).
E. The Chemical Properties
A condensed phased combustion is called glowing
combustion 1. Endothermic Reactions – changes whereby energy
A gas-phased combustion is known as flame (heat) is absorbed or is added before the reaction takes
If the process is confined with pressure it is called place.
explosion
If combustion propagates at supersonic speed, it 2. Exothermic Reactions – those that release or give off
produced a detonation energy (heat) thus they produce substances with less
energy than the reactants.

D. Physical Properties of Matter Related to Fire 3. Oxidation – a chemical change that is exothermic, a
change in which combustible material (fuel) and an
1. Specific Gravity – the ratio of the weight of a solid or liquid oxidizing agent (air), react. Example of oxidation is
substance to the weight of an equal volume of water. combustion which is the same as actual burning (rapid
oxidation)
2. Vapor density – the weight of a volume of pure gas
composed to the volume of dry air at the same temperature 4. Flame - flames are incandescent (very bright/glowing
and pressure. with intense heat) gases. In order to be sustained, it
should maintained a high temperature and a
3. Vapor Pressure – the force exerted by the molecules on concentration of short – lived intermediate chemical
the surface of a liquid at equilibrium. reactants between fuel and oxidizer.

4. Temperature – the measure of the degree of thermal


agitation of molecules.
Types of Flames:
5. Boiling Point – the constant temperature at which the
vapor pressure of the liquid is equal to the atmospheric a. Based on Color and Completeness of Combustibility
pressure. of Fuel
1. Luminous Flame – is orange-red, deposit soot at
the bottom of a vessel being heated due to 2.1. Resistant Heating – it is produced when the rate of
incomplete combustion and has a low heat generation is proportional to the resistance and
temperature.
square of the current.
2. Non-Luminous Flame – is blue, there is complete
combustion of fuel and has relatively high 2.2. Heat Generated by Lighting – lighting passing the
temperature. cloud and the ground can develop very high
temperature in any material of high resistance in its
b. Based on Fuel and Air Mixture path, such as wood or masonry.
2.3. Inductive Heating – produced when the atoms are
1. Premixed Flame – is exemplified by a Bunsen-
subjected to electric potential gradients from external
type laboratory burner where hydrocarbon (any
substance containing primarily carbon and sources, the arrangement of an atom is distorted,
hydrogen) is thoroughly mixed with air before when a tendency for electrons to move in the direction
reaching the flame zone. of opposite direction. This is observed whether the
externally applied potential is due to a battery or
2. Diffusion Flame – is observed when gas (fuel) generator is a result of a magnetic field.
alone is forced through a nozzle into the
atmosphere which diffuse in the surrounding
2.4. Static Electricity of Frictional Electricity – an
atmosphere in order to form a flammable mixture.
The candle flame is an example of diffusion flame electrical discharge that accumulates on the surface
governed purely by molecular diffusion, and the of two materials that have been brought together and
flame of the oxyacetylene torch. (diffused – then separated. One surface becomes positively
dispersed, widely spread) charged and the other negatively. If the substances
are not bonded or grounded, they will accumulate
c. Based on Smoothness
sufficient electrical charge so that spark discharge
1. Laminar Flame – when a particle follows a may occur. In some instances, flammable gases and
smooth path through a gaseous flame. vapors as well clouds of combustible dust are capable
2. Turbulent Flame – are those having unsteady, of being ignited.
irregular flows. As physical size, gas density or
velocity is increased, all laminar gas flows tend to 2.5. Heat from Arcing – it is produced when electric
become turbulent. circuit, which is carrying currents, is interrupted, either
intentionally or accidentally. The temperature of arc is
F. Heat Energy Resources
very high, and the heat released may be sufficient to
ignite combustible or flammable material within the
1. Chemical Heat Energy – Oxidation reaction is
vicinity.
exothermic.

3. Mechanical Heat Energy – Mechanical heat energy is


1.1. Heat of Combustion – the heat of combustion is the
responsible for a significant number of fires each year.
amount of heat released during the complete
oxidation where the organic fuel is converted to water
3.1. Frictional Heat – it resulted when mechanical energy
and carbon dioxide.
is used in overcoming the resistance to motion when
two solids are rubbed together.
1.2. Spontaneous Heating – the process of increase in
temperature of a material as a result of slow oxidation,
3.2. Overheating of Machinery – resulted from the heat
that is, without drawing heat from its surrounding, until
accumulated from the rolling, sliding or friction in
the ignition temperature results into combustion.
machinery of between two hard surfaces, at least one
of which is usually a mental.
1.3. Heat of Decomposition – the heat released by the
decomposition of compounds requiring the addition of
3.3. Heat of Compression – heat released when gas is
heat for their formulation.
compressed. This is also known as the diesel effect.
The fact that the temperature of a gas increases, the
1.4. Heat of Solution – heat released when a substance
volume of the gas decreases, has found practical use
is dissolved in a liquid.
in diesel engines in which heat of compression
eliminates the use for spark ignition system.
2. Electrical Heat Energy – Produced when electric current
flows through a conductor or when a spark jumps on air
4. Nuclear Heat Energy – The nucleus of an atom are made
gap. In a current flow through a conductor, electrons are
up of particles bound together by tremendous forces which
passed along from one atom to another within the
can be released when the nucleus is bombarded by
conductor.
energized particles. Nuclear energy is released in the form
of heat, pressure and nuclear radiation. 4. Class D Fuels – they are combustible metallic substances
such as magnesium, titanium, zirconium, sodium and
potassium.
G. Heat Transfer
General Categories of Fuel
The physical methods by which energy in the form of
heat can be transferred between bodies are conduction and
1. Solid Combustible Materials – includes organic and
radiation. A third method, which also involves the motion of
inorganic, natural or synthetic, and metallic solid materials.
matter, is called convection.
2. Liquid Combustible Materials – includes all flammable
liquid fuels and chemicals.
Hence, there are three ways to transfer heat:
3. Gaseous Substances – includes those toxic/hazardous
Conduction, Convection, and Radiation.
gases that are capable of ignition.
Conduction – it is the transfer of heats by molecular
A. The Solid Fuels
activity with in a material or medium, usually a solid. Direct
contact is the underlying factor in conduction. Example, if you
The most obvious solid fuels are wood, paper and
touch a hot stove, the pain you feel is a first result of conducted
cloth. Its burning rate depends on its configuration. For example,
heat passing from the stove directly to your hand. In a structural
solid fuels in the form of dust will burn faster than bulky
fire, superheated pipes, steel girders, and other structural
materials.
members such as walls and floors may conduct enough heat to
initiate fires in other areas of the structure.
Types of Flammable solids
Convection – it is the transfer of heat through a
a. Pyrolyzable solid fuels – include many of the
circulating medium, usually air or liquid. Heat transfer by
ordinary accepted combustibles: wood, paper and so on. The
convection is chiefly responsible for the spread of fire in
vapors released by their chemical decomposition support
structures. The supper-heated gases evolved from a fire are
flaming combustion. This exemplifies a gas-to-gas reaction: the
lighter than air, and consequently rise, they can and do initiate
vapors released mixed with oxygen in the air to produce a flame.
additional damage. In large fires, the high fireball that
accompanies the incident is referred to as a firestorm and is an
b. Non-pyrolyzable solid fuels – solid fuels that are
example of convected heat.
difficult to ignite. A common example is charcoal. Chemical
decomposition does not occur because there are no pyrolyzable
elements present. No vapors are released. The glowing
Radiation – radiated heat moves in wave and rays
combustion that results is an example of a gas-to-solid reaction.
much like sunlight. Radiated heat travels the speed, as does
visible light: 186,000 miles per second. It is primarily responsible
for the exposure hazards that develop and exist during a fire.
The following are group of solid fuels:
Heat waves travel in a direct or straight line from their source
until they strike an object. The heat that collects on the surface
1. Biomass – it is the name given to such replaceable
of the object or building in the path of the heat waves is
organic matters like wood, garbage and animal manure that can
subsequently absorbed into its mass through conduction.
be use to produce energy. For example, heat produced by
burning nutshells, rice and oat hulls, and other by-products of
Conduction requires physical contact between bodies
food processing. They are often used to operate plant
or portions of bodies exchanging heat, but radiation does not
equipment.
require contact or the presence of any matter between the
bodies. Convection occurs when a liquid or gas is in contact with
a solid body at a different temperature and is always
accompanied by the motion of the liquid or gas. The science
Factors affecting the combustibility of wood and
dealing with the transfer of heat between bodies is called heat
wood-based products
transfer.
a. Physical form – the smaller the piece of wood, the easier
H. Classification of Combustible Materials it is to burn.
1. Class A Fuels – they are ordinary combustible materials b. Moisture content (water content) – the freshly cut wood
that are usually made of organic substances such as wood is more difficult to ignite and burn than dry wood.
and wood-based products. It includes some synthetic or
inorganic materials like rubber, leather, and plastic c. Heat conductivity - a poor conductor of heat takes a longer
products. time to ignite than those materials that are good conductors
of heat.
2. Class B Fuels – materials that are in the form of flammable
liquids such as alcohol, acidic solutions, oil, liquid d. Rate and period of heating – less flammable materials
petroleum products, etc. don’t easily ignite and needs direct contact with flame than
highly combustible materials.
3. Class C Fuels – they are normally fire resistant materials
such as materials used on electrical wiring and other
electrical appliances.
e. Rate of combustion – with an unlimited supply of oxygen, 4. Coal – a black, combustible, mineral solid resulting
the rate of burns increases, more heat is produced and fuel from the partial decomposition of matter under varying degrees
is consumed more completely. of temperature. They are used as fuels in the production of coal
gas, water gas, and many coal compounds. They are also used
f. Ignition temperature – the higher the temperature, the to heat buildings and to provide energy for industrial machinery.
faster it reaches ignition point and it varies depending on
the other factors above. The forms of coal are lignite or brown coal, sub-
bituminous coal, bituminous coal, anthracite. Bituminous coal is
2. Fabrics and Textiles – almost all fibers and textiles the most plentiful and important coal used by industry. It
are combustible. A fiber is a very fine thin strand or thread like contains more carbon and produces more heat than either
object. Fabrics are twisted or woven fibers. And textiles are lignite or sub-bituminous coal. It is also the coal best suited for
machine woven or knitted fabric. making coke. Antracite is the least plentiful and hardest coal.

Classification of Fibers It contains more carbon and produces more heat than
other coals. However, antracite is difficult to ignite and burns
a. Natural Fibers – they come from plants (Coir – coconut slowly.
fiber, Cotton – seed fiber, pulp – wood fiber) , from animals
(wool, silk, protein fibers – leather), from minerals 5. Peat – It is partially decayed plant matter found in
(asbestos) swamps called bags and used as a fuel chiefly in areas where
coal and oil are scarce. In Ireland and Scotland, for example,
b. Synthetic/Artificial Fibers – organic fibers, cellulose peat is cut formed in blocks, and dried; the dried bloks are then
fibers, cellulose acetate, non-cellulose, and inorganic fibers burned to heat homes.
like fiber glass, steel
B. The Liquid Fuels
Factors affecting the combustibility of fibers
Liquid fuels are mainly made from Petroleum, but
a. Chemical composition – natural and synthetic organic some synthetic liquids are also produced. Petroleum is also
fibers are generally highly combustible materials especially called crude oil. They may be refined to produce gasoline, diesel
if they are dry. Mineral fibers and synthetic inorganic fibers oil, and kerosene.
are normally fire resistant materials.
Other fuel oils obtained by refining petroleum to
b. Fiber finish or coating – fiber coating combined with distillate oil and residual oils. Distillate oils are light oils, which
organic fibers are supportive to continued burning of fabric. are used chiefly to heat homes and small buildings. Residual
oils are heavy, and used to provide energy to power utilities,
c. Fabric weight – the heavier the fabric, the greater its factories and large ships.
resistance to ignition, thus delaying its ignition.
Oil-based paint products are also highly flammable
d. Tightness of weave – the closer the fiber are woven, the liquids.
smaller the space it contains, thus it takes a longer period
to ignite it. In the process of vaporization, flammable liquids
release vapor in much the same way as solid fuels. The rate of
e. Flame retardant treatment – fabric treated with flame vapor is greater for liquids than solids, since liquids have less
retardant have higher resistance to ignition. closely packed molecules. In addition, liquids can release vapor
over a wide range, example, gasoline starts to give vapor at –
Fabric Ignition 40C (-45 F).
This makes gasoline a continuous fire hazard; it produces
Limiting Oxygen Index (LOI) is a numerical basis of flammable vapor at normal temperature.
measuring the tendency of a fabric to continuously burn once
source of ignition is removed. If the LOI of a fabric is high, the
probability that it will cease to burn once the flame is removed is General Characteristics of Liquids
also high. Fabrics with high LOI and high ignition temperature
are safer for clothing and furnishing because they do not ignite 1. They are matters with definite volume but no
easily. Also, they do not continue burning after the source of definite shape.
heat or flame is removed. 2. They assume the shape of their vessel because
there is free movement of molecules.
3. Plastics – plastics are included as ordinary fuels 3. They are slightly compressible. They are not
under class A except those materials of or containing cellulose capable of indefinite expansion, unlike gas.
nitrate. Cellulose Nitrate is a chemical powder used in bombs,
they are also called pyroxylin.
Two (2) General Groups of Liquid Fuels
Plastics comprise a group of materials consisting
mainly of organic substances or high molecular substances. 1. Flammable liquids – they are liquids having a flash point
They are solid in the finished state although at some stage of of 37.8 C (100F) and a vapor pressure not exceeding 40
manufacture plastics can be made to flow into a desired shape, psia (2068.6 um) at 37.8 C.
usually through the application of heat or pressure or both. 2. Combustible Liquids – these liquids have flash point at or
above 37.8 C (100F).
a. Natural Gas – the gas used to heat buildings, cook
Burning Characteristics of Liquids food, and provides energy for industries. It consists
chiefly of methane, a colorless and odorless gas.
Since it is the vapors from the flammable liquid which Natural gas is usually mixed with compounds of foul-
burn, the case of ignition as well as the rate of burning can be smelling elements like sulfur so gas leaks can be
related to the physical properties such as vapor pressure, flash detected.
point, boiling point, and evaporation rate.
Butane and propane, which make up a small proportion of
1. Liquids having vapors in the flammable range above the natural gas, become liquids when placed under large amount of
liquid surface at the stored temperature have rapid rate of pressure. When pressure is released, they change back to gas.
flame propagation. Such fuels, often called Liquefied Petroleum Gas (LPG) or
2. Liquids having flash points above stored temperature have liquefied Natural Gas (LNG), are easily stored and shipped as
slower rate of flame propagation. The chemical explanation liquid.
is, it is necessary for the fire to heat sufficiently the liquid
surface to form flammable vapor-air moisture before the b. Manufactured Gas – this gas like synthetic liquid fuels
flame will spread through the vapor. is used chiefly where certain fuels are abundant and
others are scarce. Coal, petroleum, and biomass can all
Factors affecting the Rate of Flame Propagation be converted to gas through heating and various
and Burning of Liquids chemical procedures.

wind velocity - temperature - heat of combustion - latent heat


of evaporation - atmospheric pressure 2. According to Physical Properties

Latent heat is the quantity of heat absorbed by a a. Compressed Gas – gas in which at all normal
substance from a solid to a liquid and from a liquid to gas. temperature inside its container; exist solely in the
Conversely, heat is released during conversion of a gas to liquid gaseous state under pressure. The pressure depends
or liquid to a solid. on the pressure to which the container is originally
charged and how much gas remains in the container.
C. The Gas Fuels However, temperature affects the volume and pressure
of the gas.
Gaseous fuels are those in which molecules are in
rapid movement and random motion. They have no definite b. Liquefied Gas – gas, which, at normal temperature
shape or volume, and assume the shape and volume of their inside its container, exist partly in the liquid state and
container. partly in gaseous state and under pressure as long as
any liquid remains in the container. The pressure
There are both natural and manufactured flammable basically depends on the temperature of the liquid
gases. Gas fuels flow easily through pipes and are used to although the amount of liquid also affects the pressure
provide energy for homes, businesses, and industries. under some condition. A liquefied gas exhibits a more
Examples of gas fuels are acetylene, propane, and butanes. complicated behavior as the result of heating.

Some properties of gas fuels are: c. Cryogenic Gas – a liquefied gas which exist in its
container at temperature far below normal atmospheric
compressibility – expandability - permeability (open to temperature, usually slightly above its boiling point and
passage or penetration) - diffusion (intermingling of molecules) correspondingly low to moderate pressure. Examples of
this gas are air, carbon monoxide, ethylene, fluorine,
Compressibility and expandability refer to the potential helium, hydrogen, methane, nitrogen, and oxygen.
in changes in volume. Diffusion is the uniform distribution of
molecules of one substance through those of another.
Permeability means that other substances may pass through or 3. According to Usage
permeate a gas.
a. Fuel Gases – flammable gases usually used for burning
Characteristics of Gas Fuels with air to produce heat, utilize as power, light, comfort, and
process. Most commonly used gases are natural gas and
1. They are matters that have no definite shape. the LPG (butane and propane).
2. They are composed of very tiny particles
(molecules) at constant random motion in a b. Industrial Gases - This group includes a large number of
straight line gases used for industrial processes as those in welding and
3. Gas molecules collide against one another and cutting (oxygen, acetylene); refrigeration (freon, ammonia,
against the wall of the container and are relatively sulfur dioxide); chemical processing (hydrogen, nitrogen,
far from one another. ammonia, chlorine); water treatment (chlorine, fluorine).

c. Medical Gases – those used for treatment such as


Classification of Gases: anesthesia (chloroform, nitrous oxide); respiratory therapy
(oxygen).
1. Based on Source
I. FIRE BEHAVIOR, CAUSES AND CLASSIFICATION 3. Smoldering Phase – this stage has the following
characteristics: oxygen content drops to 13% or below
The behavior of fire maybe understood by considering causing the flame to vanish and heat to develop in layers,
the principle of thermal balance and thermal imbalance. products of incomplete combustion increase in volume,
particularly carbon monoxide with an ignition temperature
Thermal Balance refers to the rising movement or the of about 1125 F, ceiling temperature is 1000-1300 F, heat
pattern of fire, the normal behavior when the pattern is and pressure in the room builds up, building/room contains
undisturbed. Thermal imbalance, on the other hand is the large quantities of superheated fuel under pressure but little
abnormal movement of fire due to the interference of foreign oxygen, when sufficient supply of oxygen is introduced,
matter. Thermal imbalance often confuses the fire investigator backdraft occurs.
in determining the exact point where the fire originated.
J. Classification of Fires
Dangerous Behavior of Fire
Based on Cause
Fire is so fatal when the following conditions occurred:
1. Natural causes – such as
1. Backdraft – it is the sudden and rapid (violent) burning of
heated gases in a confined area that occurs in the form of • Spontaneous heating – the automatic chemical reaction
explosion. This may occur because of improper ventilation. that results to spontaneous combustion due to auto-
If a room is not properly ventilated, highly flammable vapors ignition of organic materials, the gradual rising of heat in
maybe accumulated such that when a door or window is a confined space until ignition temperature is reached.
suddenly opened, the room violently sucks the oxygen from
the outside and simultaneously, a sudden combustion • Lightning – a form of static electricity; a natural current
occur, which may happen as an explosion (combustion with a great magnitude, producing tremendous
explosion). amperage and voltage. Lightning usually strikes objects
that are better electrical conductors than air. It can cause
2. Flashover – it is the sudden ignition of accumulated radical fire directly or indirectly. Indirectly when it strikes
gases produced when there is incomplete combustion of telephone and other transmission lines, causing an
fuels. It is the sudden burning of free radicals, which is induced line surge. It can also cause flash fire or dust
initiated by a spark or flash produced when temperature explosion. When lightning strikes steel or metal rod
rises until flash point is reached. covered with dust, the dust will suddenly burn thus
resulting to an explosion.
When accumulated volume of radical gases suddenly
burns, there will be a very intense fire that is capable of causing • Radiation of Sunlight – when sunlight hits a concave
flames to jump at a certain distance in the form of fireball. mirror, concentrating the light on a combustible material
Fireballs can travel to a hundred yards within a few seconds. thereby igniting it.
3. Biteback - a fatal condition that takes place when the fire 2. Accidental Causes – such as
resists extinguishment operations and become stronger
and bigger instead.
• Electrical accidents in the form of:
4. Flash Fire – better known as dust explosion. This may
Short Circuit – unusual or accidental connections between two
happen when the metal post that is completely covered with
points at different potentials (charge) in an electrical circuit of
dust is going to be hit by lightning. The dust particles
relatively low resistance.
covering the metal burn simultaneously thus creating a
violent chemical reaction that produces a very bright flash
Arcing – the production of sustained luminous electrical
followed by an explosion.
discharge between separated electrodes; an electric hazard that
results when electrical current crosses the gap between 2
The Three Stages of Fire
electrical conductors.
1. Incipient Phase (Initial Stage) – under this stage, the
Sparking – production of incandescent particles when two
following characteristics are observed: normal room
different potentials (charged conductors) come in contact;
temperature, the temperature at the base of the fire is 400-
occurs during short circuits or welding operations.
800 F, ceiling temperature is about 200 F, the pyrolysis
products are mostly water vapor and carbon dioxide, small Induced Current – induced line surge – increased electrical
quantities of carbon monoxide and sulfides maybe present. energy flow or power voltage; induced current; sudden increase
of electrical current resulting to the burning of insulating
2. Free Burning Phase – it has the following characteristics: materials, explosion of the fuse box, or burning of electrical
accelerated pyrolysis process take place, development of appliances.
convection current: formation of thermal columns as heat
rises, temperature is 800-1000 F at the base of fire, 1200- Over heating of electrical appliances – the increase or rising
1600 F at ceiling, pyrolytic decomposition moves upward of amperage while electric current is flowing in a transmission
on the walls(crawling of the flame) leaving burnt patterns line resulting to the damage or destruction of insulating
(fire fingerprints), occurrence of flashover. materials, maybe gradual or rapid, internal or external.
• Purely accidental causes 2.1. Carbon Monoxide – the gas is formed by the
• Negligence and other forms of human incomplete combustion of carbon.
error
2.2. Carbon Dioxide – this gas is usually produced in large
3. Intentional causes (Incendiary)
quantities from fires and high levels of this gas over
If in the burned property, there are preparations or stimulates the rate of breathing.
traces of accelerant, plants and trailers, then the cause of fire is
intentional. 2.3. Hydrogen Sulfide – when materials like rubber, skin,
hides, wool, hair, silk and meat are burned one of the
Accelerant – highly flammable chemicals that are used to products formed is hydrogen sulfide. This colorless
facilitate flame propagation. highly toxic gas smells like rotten eggs.
Plant – the preparation and or gathering of combustible
materials needed to start a fire. 2.4. Sulfur Dioxide – this colorless gas with irritating,
suffocating odor is formed when sulfur containing
Trailer – the preparation of flammable substances in order to organic substances like wood, rubber, wool and silk
spread the fire. are burned. Sulfur dioxide causes the eyes to be
watery and is irritating to the respiratory tract.
Based on Burning Fuel (the classes of fire)

1. Class A Fire – Ordinary fires; they are the types of fire 2.5. Ammonia – combustible materials containing nitrogen
resulting from the burning wood, paper, textiles, rubber and as silk, wool, feathers, skin, meat, acrylic plastic,
other carbonaceous materials. In short, this is the type of phenolio and melamine resins when burned produce
fire caused by ordinary combustible materials. ammonia. It is a colorless gas with strong pungent
odor.
2. Class B Fire – Liquid fires; they are caused by flammable
and or combustible liquids such as kerosene, gasoline,
2.6. Hydrogen Chloride – chlorine containing plastic
benzene, oil products, alcohol and other hydrocarbon
deviations. materials will produce hydrogen chloride when burned.
Polyvinylchloride is one plastic commonly used for
3. Class C Fire – Electrical fires; they are fires that starts in electrical conductor installation, conduit and piping.
live electrical wires, equipment, motors, electrical Hydrogen chloride is a colorless gas with pungent, very
appliances and telephone switchboards. irritating odor.

4. Class D Fire – Metallic fires; fires that result from the


2.7. Hydrogen Cyanide – relatively large quantities of
combustion of certain metals in finely divided forms. These
combustible metals include magnesium, potassium, hydrogen cyanide maybe produced by the incomplete
powdered calcium, zinc, sodium, and titanium. combustion of nitrogen containing materials such as
wool, silk, urethane, polymide and acrylics. Hydrogen
K. Combustion Products and Some of their Effects cyanide is a colorless gas which is highly toxic.
A. Products of Combustion
2.8. Nitrogen Dioxide – the reddish – brown nitrogen
1. Smoke – matter made up of very fine solid particles and dioxide is produced during the decomposition and
condensed vapor as a consequence of combustion. combustion of cellulose nitrate, ammonium nitrate and
Frequently, smoke provides warning of fire and contributes other inorganic nitrates. It is also formed when nitric
to panic because of its irritating effects. Combustion of acid comes in contact with materials or combustible
common combustibles (as wood) brings both fire gases that materials. This gas is extremely toxic.
contain water vapor, carbon dioxide, and carbon monoxide.
L. Color of Smoke and Fire
2. Fire Gases – gases that remain when the products of
combustion are cooled to normal temperature. Gases Color of Smoke Combustible Materials
formed by a fire depends on many variables among which Burned
are: 1. Black smoke with deep Petroleum products, tar,
red flames rubber, plastic
2. Heavy brown smoke with Nitrogen products
• The chemical composition of the burning
bright red flames
materials 3. White smoke with bright Magnesium
• The amount of oxygen available for white flames
combustion 4. Black smoke with red and Asphalt shingles
• The temperature blue green flames
5. Purple, violet or lavender Potassium
flames
6. Greenish – yellow flames Chlorine or manganese
7. Bright reddish yellow Calcium 2. EVALUATION – SIZE – UP (on-the-spot planning or
flame sizing-up the situation) - this is the process knowing the
8. Smoke of the usual color Usually indicative of a emergency situation. It involves mental evaluation by
found in most fires that back draft condition the operation officer-in-charge to determine the
changes to yellow or appropriate course of action that provides the highest
grayish yellow probability of success.

M. FIRE FIGTHING OPERATIONS AND 3. EVACUATION – This is the activity of transferring


EXTINGUISHMENT people, livestock, and property away from the burning
area to minimize damage or destruction that the fire
Fire fighting is an activity intended to save lives and might incur in case it propagates to other adjacent
buildings.
property. It is one of the most important emergency services
in a community. Fire fighters battle fires that break out in 4. ENTRY – This is the process of accessing the burning
homes, factories, office buildings, shops, and other places. structure. Entry maybe done in a forcible manner.
Fire fighters risk their lives to save people and protect
property from fires. The people who work as fire fighters 5. RESCUE – This is the operation of removing
also help others who are involved in many kinds of (extricating), thus saving, people and other livestock
from the burning building and other involved
emergencies besides fires. For example, fire fighters
properties, conveying them to a secure place
rescue people who may be trapped in cars or vehicles after
an accident. They aid victims of such disasters as 6. EXPOSURE – also called cover exposure, this is the
typhoons, floods, landslides, and earthquakes. activity of securing other buildings near the burning
structure in order to prevent the fire from the
Factor Affecting Fire Protection and Control extending to another building.

Fire protection and control is affected by the 7. CONFINEMENT – This is the activity of restricting the
accumulation of fire hazards in a building or area. Fire fire at the place (room) where it started : the process of
preventing fire from extending from another section or
Hazard is any condition or act that increases or may cause
form one section to another section of the involved
increase in the probability that fire will occur or which may building.
obstruct, delay, hinder or interfere with fire fighting
operations and the safeguarding of life and property 8. VENTILATION – This the operation purposely
conducted to displace toxic gases. It includes the
Conditions of Fire Hazards process of displacing the heated atmosphere within the
1. Existence of dangerous or unlawful amount of involved building with normal air from outside
combustible or explosives in the building not designed atmosphere.
to store such materials. 9. SALVAGE – The activity of protecting the properties
2. Defective or improperly installed facilities/ equipment. from preventable damage other than the fire. The steps
3. Lack of adequate exit facilities. are a) remove the material outside the burning area,
4. Obstruction at fire escapes or other designated and b) protecting or cover the materials by using
opening for fire fighters. tarpaulins (cotton canvass treated with water proofing).
5. Dangerous accumulation of rubbish waste and other
highly combustible materials. 10. EXTINGUISHMENT – This is the process of putting out
6. Accumulation of dust in ventilation system or of grease the main body of fire by using the 4 general methods
in the kitchen. of fire extinguishments.
7. Building under repair
8. Very old building or building is primarily made of 11. OVERHAUL – This is the complete and detailed check
combustible materials of the structure and all materials therein to eliminate
conditions that may cause re-flash; involves complete
extinguishments of sparks or smouldering (glowing)
substances (embers) to prevent possibilities of re-
Fire Fighting Operations ignition or rekindling.
12. FIRE SCENE INVESTIGATION - This is the final stage
Fire fighting operations refers to fire suppression of fire suppression activities. It is an inquiry conducted
activities. In general the following procedures should be to know or determine the origin and cause of fire.
observed:

1. PRE-FIRE PLANNING - this activity involves METHODS OF ENTINGUISHMENT


developing and defining systematic course of actions
that maybe performed in order to realize the objectives 1. Cooling – by reducing the heat to below the ignition
of fire protection: involves the process of establishing temperature
the SOP in case fire breaks out. 2. Blanketing – prevent the oxygen from combining with
the fuel
3. Smothering – by expelling oxygen
4. Removing or starving the fire by removing fuel.
A criminal investigator is a person who collects facts to
FIRE/ARSON INVESTIGATION accomplish a threefold aim – Phases of Investigation:

Fire Investigation – the process of determining the 1. Identify the criminal or guilty party – the identity of the
origin, cause, and development of a fire or explosion. criminal is discovered in one or more of the following ways:
confession; eyewitness testimony, or circumstantial
Nature of Fire Investigation – a fire or explosion evidence.
investigation is a complex endeavor involving skill, technology,
2. Locate the criminal or guilty party – commonly the
knowledge and science. The proper methodology of a fire answer to the question of the criminal’s whereabouts falls
investigation is to first determine the origin(s), then investigate easily out of the solution of the problem of his identity.
the cause; circumstances, conditions or agencies that brought
the ignition source, fuel, and oxidant together. 3. Provide evidence of his guilt for court presentation –
the most difficult phase of investigation, namely: gathering
CAUSES OF FIRE the facts necessary in the trial to prove the guilt of accused
beyond reasonable doubt.
1. Accidental fire cause – involve all those where the proven
cause does not involve a deliberate human act to ignite or Exigent or Emergency Circumstance:
spread into an area where the fire should not be.
2. Natural fire cause – it involve fires cause without direct A search conducted under exigent or emergency
human intervention, such as lighting etc. circumstance deals with a warrantless search based on the fact
3. Incendiary fire cause – is one deliberately set under that the time needed to obtain a warrant is not possible or
circumstances in which the person knows that the fire practicable.
should not be set.
4. Undetermined fire cause – whenever the cause cannot be
proven, the proper classification is undetermined. For fire investigators, exigent or emergency
circumstances involve a landmark decision in the US Supreme
N. CRIMINAL (ARSON) STAGE OF INVESTIGATION Court entitled Michigan v Tyler (436 US 499, 56 L Ed. 2nd 286)
in 1978. This decision supports a warrantless entry by fire
Criminal burning has always treated as a serious offense. The fighters for suppression activities and redefines the fire
old Roman Law of “incendium” though broader in scope than investigator’s activities in the subsequent investigation as to the
common law arson, included willful burning which endangered origin and cause of the fire.
another’s property, setting fire to
SC Conclusion:
cities, and causing conflagration by rioting. The penalty for this
crime at one time required that the offender be burned alive. We hold that an entry to fight a fire requires no warrant,
Today we find, depending on the jurisdiction, degrees of arson and that once in the building, officials may remain there for a
carrying penalties of up to 20 years in prison or even life reasonable time to investigate the cause of the blaze.
imprisonment. Under RA 7659 (Death Penalty Law) – If death Therefore, additional entries to investigate the cause of the fire
result as a consequence of arson the mandatory penalty of must be pursuant to a warrant procedure governing
death shall be imposed. The method of investigation of the administrative searches. Evidence discovered in the course of
arson fire is not basically different in any respect from that of the such investigation is admissible at trial, but if the investigating
fire that results accidentally. Lacking any real basis for decision officials find probable cause to believe that arson has occurred
the two, every fire should be investigated as though it could be and require further access to gather evidence for a possible
the result of arson. prosecution they may obtain a warrant only upon a traditional
showing of probable cause applicable to searches for evidence
The determination that a fire has been intentionally set is central of crime. (436 US 512,56 L ed 2nd 500)
to all fire investigation and is one of the more difficult phases of
that investigation. STAGES IN THE COMMISSION OF A FELONY
Arson – is the criminal burning of property. (Nolledo)
Consummated
Arson – The crime of maliciously and intentionally, or recklessly
starting a fire or causing an explosion. (NFPA 921) A felony is consummated when all the elements
necessary for its execution and accomplishment are present.
Arson – A crime committed by a person who burns or sets fire
to the property of another, or who sets fire to his own property Example: At a little past midnight Miguel noticed that the
under circumstances which expose to danger the life or property thatched roof of his house was on fire. When looking at the
of another. – Sec. 1 PD 1613. window, he saw the culprit beside the house carrying a stick
burning at its end. Miguel shouted for help and succeeded in
extinguishing the fire after a small part of the roof was burned.
The SC held: That the crime was consummated arson – “the more difficult because the physical evidence, normally providing
consummation of the crime does not depend upon the extent of material assistance in an investigation, is often destroyed by the
the damage caused. “ (People vs. Hernandez, 54 Phil. 122) criminal act itself. The same basic elements of all criminal
investigations, however, are required of arson inquiries, namely,
Frustrated the establishment of the corpus delicti and the identification of
the perpetrator.
It is frustrated when the offender performs all the acts Corpus delicti – Body or substance of the offense or in the
of execution which would produce the felony as a consequence accepted legal sense means merely the fact that a crime has
but which, nevertheless, do not produce it by reason of causes been committed. Since in law every fire is presumed to be
independent of the will of the perpetrator. accidental.

Example: Luke prepares a kerosene-soaked rag and places it Arson


in the combustible portion of Peter’s house with intent to burn
the latter. Luke lights the rag and while the latter is burning he Origin until proved otherwise, his presumption must be
runs away (Performs all acts of execution). Before the fire overcome an arson charge can be established. Evidence must
emitting from the rag consumes any part of the house, Peter, be adduced to show the corpus delicti of the offense, that is, the
the owner discovers the fire and puts it out (The felony is not existence of the essential facts demonstrating that the offense
produced due to the timely intervention of the owner had been committed. It must be emphasized that the
independent of the will of the culprit Luke). unsupported confession of a person with respect to the burning
is insufficient and inadmissible in the absence of a substantial
Attempted and independent showing of the corpus delicti.

There is an attempt when the offender commences the


commission of a felony, directly by overt acts, and does not
perform all the acts of execution which should produce the
felony by reason of some cause or accident other than his own To establish the corpus delicti the following two facts
spontaneous desistance (No voluntary desistance). must be established:

Example: Juan gets a rag and soaks it with kerosene with intent 1. Burning
to burn the house of Pedro. Juan puts the rag in a combustible 2. Criminal design
portion of Pedro’s house and while in the act of striking his
What constitutes burning?
match in order to burn the rag soaked with kerosene, Juan is
arrested by a policeman who happens to pass by. Preparatory
A structure is not burn within the meaning of an accusation of
acts, like buying a match does not constitute attempted arson.
arson by heat. Any appreciable burning is sufficient. It is not
There is only an attempted arson if the overt act is begun, that
necessary that there be a flame of that the structure be
is, a direct movement to do the act is executed.
consumed or materially injured. The ignition satisfies the
requirement of burning.
Malice.

Fire patterns – are the visible or measurable physical effects


There must be a malicious intent to burn otherwise no
that remain after a fire. These include thermal effects on
crime of arson exists. Malice is the intent to do injury to another.
materials, such as charring, oxidation, consumption of
Fires caused by negligence or accident do not constitute arson.
combustibles, smoke and soot deposits, distortions, melting,
The intent must be inferred from the facts. The condition
color changes, changes in the character of materials, structural
surrounding the act such as threats, quarrels, expressions of
collapse, and other effects.
dislike, application for fire insurance, and so forth, may supply a
basis for inferring intent. The prosecution must show that a
Other Evidence – once the corpus delicti is established, any
burning was accomplished with criminal design. The law
legal and sufficient evidence, direct or circumstantial, may be
presumes that a fire is accidental in origin; hence the criminal
introduced to show that the act was committed by the accused
design must be beyond reasonable doubt.
and that it was done with criminal intent. In arson cases direct
evidence is ordinarily lacking with respect to the connection of
Methods of Proof
the offender with the crime and the great reliance must be
placed on circumstantial evidence. The following general types
The investigation of arson often presents a complex
of evidence will usually be encountered in addition to those
problem because the methods employed by incendiaries and
already discussed.
the manner in which they operate are far greater in number and
more varied in aspect than those employed by most other types
Evidence Associating the Suspect with the Scene. Clue
of criminal. Proof of the commission of the offense is rendered
materials such as tools, matches and articles of clothing may be
found at the scene and sometimes traced to the suspect. 2.1. Any building used as offices of the government or any
Similarly, the suspect may have carried on his person or clothing of its agencies;
traces which link him to the crime scene. 2.2. Any inhabited house or dwelling;
2.3. Any industrial establishment, shipyard, oil well or
Evidence showing intent. The actions of the suspect can mineshaft, platform or tunnel;
frequently offer evidence of criminal intent. Example, 2.4. Any plantation, farm, pasture land, growing crop, grain
anticipating of a fire may be shown by such circumstances as field, orchard, bamboo grove or forest;
the removal of valuable articles or the substitution of inferior 2.5. Any rice mill, sugar mill, cane mill or mill central;
articles. Ill feeling or unfriendly relations between the accused 2.6. Any railway or bus station, airport, wharf or warehouse.
and the occupants of the burned building may be shown. The
absence of any effort to extinguish the fire or to turn in the alarm 3. Special Aggravating Circumstances of Arson
in the presence of opportunity is significant. The flight of the
suspect may be incriminating. 3.1. If committed with intent to gain;
3.2. If committed for the benefit of another;
O. Kinds of Arson 3.3. If the offender is motivated by spite or hatred toward
the owner or occupant of the property burned;
P.D. 1613 Classifies Arson Into: 3.4. If committed by a syndicate;

• Destructive Arson (Sec. 2) The offense is committed by a syndicate if it


• Other Cases of Arson (Sec. 3) planned or carried out by a group of three (3)
or more persons.
The classification is based on the kind, character and
location the property burned, regardless of the value of the 4. Prima Facie Evidence of Arson
damage caused.
Any of the following circumstances shall
1. Destructive Arson constitute prima facie evidence of arson:

Arson becomes destructive if the property burned 4.1. If the fire started simultaneously in more than one part
is any of the following: of the building or establishment;
4.2. If substantial amount of flammable substance or
1.1. Any ammunition factory and other establishment materials are stored within the building not necessary
where explosives, inflammable or combustible in the business of the offender nor for the household
materials are sorted; use;
1.2. Any archive, museum, whether public or private, or any 4.3. If gasoline, kerosene, petroleum or other flammable or
edifice devoted to culture, education or social service; combustible substances or materials soaked therewith
1.3. Any church or place of worship or other building where or containers, thereof or any mechanical, electrical, or
people usually assemble; foregoing are found in the ruins or premises of the
1.4. Any train, airplane or any aircraft, vessel or watercraft, burned building or property;
or conveyance for transportation of persons or 4.4. If the building or property is insured for substantially
property; more then its actual value at the time of the issuance
1.5. Any building where evidence is kept for use in any of the policy;
legitimate, judicial, administrative or other official 4.5. If during the lifetime of the corresponding fire insurance
proceedings; policy more than two fires have occurred in the same
1.6. Any hospital, hotel, dormitory, lodging house, housing or other premises owned or under the control of the
tenement, shopping center, public or private market, offender and/or insured;
housing or movie house or any similar place or 4.6. If shortly before the fire a substantial portion of the
building; effects insured and stored in building or property had
1.7. Any building, whether used as dwelling or not, situated been withdrawn from the premises except in the
in a populated or congested area. ordinary course of the business;
4.7. If a demand for money or other valuable consideration
2. Other Cases of Arson was made before the fire in exchange for the
desistance of the offender for the safety of the person
The property Burned is Any of the Following: or property of the victim.

NOTHING FOLLOWS

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