C hapter 7

Equilibrium

1. 
K p for the reaction, N 2 +3H 2  2NH 3 is 6. At a certain temperature Kc=1.8 litre2 mole–2 for
1.645×10–4 atm –2 at 400°C. What will be the K p 
N 2 +3H 2 
 2NH 3 . How many moles of NH 3
at 500°C? Heat of reaction in this temperature must be placed in one litre vessel in order to get
range is –25.14 kcal. 6 mole litre–1 H2 at equilibrium?
(1) Greater than 1.645×10–4 atm–2 (1) 27.88 mole (2) 40 mole
(2) Smaller than 1.645×10–4 atm-2 (3) 31.88 mole (4) 80 mole
(3) Equal to 1.645×10–4 atm–2 7. 
NH 4 HS(s)   NH 3 (g)+H 2 S(g). At a certain
(4) Greater than or equal to 1.645×10–4 atm–2 temperature K p=1.44 atm 2 . If the partial pressure
of NH3 at a certain extent is 1.08 atm. Then the
2. For the reaction PCl5 
 PCl3+Cl2 where P is reaction will proceed
the pressure at equilibrium,  is degree of
dissociation and K p is equilibrium constant, the (1) Towards forward direction
relation between  and Kp is-
(2) Towards backward direction
K p2 Kp (3) Will be at equilibrium
(1)   P  Kp (2)   P  Kp
(4) Data insufficient
Kp  P P
(3)   (4)   K 8. Which one is the conjugate base of HSO4– ?
Kp p
(1) H2SO4 (2) HSO3
3. 

For the following reaction, 2SO3 
 2SO2+O2 if (3) SO3 (4) SO4 2–
the observed vapour density of the mixture at
9. Which of the following can act as lewis base?
equilibrium is 30 then find the degree of
dissociation of SO3 . NH3(+)
(1) H3O(+) (2) O
(1) 0.66 (2) 0.33
(3) 0.44 (4) 0.5 (3) CH3CH2CH2OH (4) SF 6

4. In the dissociation of HI 20% is dissociated at 10. Which one has the highest basic strength?
equilibrium. (1) CH3– (2) NH2–
1 1 (3) HCO3– (4) NO3 –


Calculate Kp for HI(g) 
 H2(g)+ I2(g)
2 2 11. If we increase the temperature, then the pH value
(1) 0.25 (2) 0.3 of pure water
(3) 0.4 (4) 0.125 (1) Increases
5. A 2B+C K c =1.987×10 –8 mole 2 litre -2 then at (2) Decreases
equilibrium the reaction mixture contains greater (3) Remains same
number of moles of
(4) Increases and then decreases
(1) A
12. pH of 10–8M HCl is-
(2) B
(1) 8 (2) 4
(3) C
(3) 6.9 (4) 7.9
(4) Equal moles of A and B

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Medical Q-Bank-2020 Equilibrium
13. Which of the following statements is incorrect? Kp
22. log K + log RT=0 is a relationship for the
(1) Melting of ice increases due to increase in c

pressure reaction:-
(2) K2 SO4 doesn’t undergo hydrolysis (1) PCl5(g) PCl3 (g) +Cl2 (g)
(3) Human blood is a basic buffer (2) H2(g) +I2(g) 2HI(g)
(4) Solubility of NaCl in H 2 O decreases with (3) N2(g) +3H2(g) 2NH3(g)
increase in temperature
(4) 2SO2(g) + O2(g) 2SO3(g)
14. Calculate the pH of the solution containing equal
moles of (NH4 )2 SO4 & NH4 OH. Kb for NH4OH is 23. Find the value of G° for the reaction having Keq
2×10–5 value 4×105 at 300K temperature.
(1) 9.0 (2) 4.7 (1) 7.73 cal (2) 32.15 kcal
(3) 7 (4) 5 (3) 7.73 kJ (4) 32.15 kJ
15. The pH of the solution containing a salt of weak 24. Introduction of inert gas (at same temperature) will
acid and a weak base affect the equilibrium if-
(1) Is always greater than 7 (1) Volume is constant and ng = 0
(2) Is always equal to 7 (2) Volume is constant and ng  0
(3) Is always less than 7
(3) Pressure is constant and ng  0
(4) Can’t be predicted unless Ka and Kb values are
(4) Pressure is constant and ng = 0
known
25. Select from the following molecules/species that
16. Which one has the highest solubility in H2 O?
can’t act as amphiprotic
(1) Na2 S (2) Cu2 S
(1) SO4 2– (2) HSO4 –
(3) Ag2 S (4) CdS (3) NH3 (4) H2 PO4 –
17. Find Ksp for Hg2Cl2 (s) if its solubility is ‘s’ mol/L at
26. Find out the strongest conjugate base
25°C
(1) Cl– (2) NH2–
(1) s (2) s 2
(3) I– (4) SO4 2–
(3) 4s3 (4) 16s4 27. Find the correct order of acidity-
18. Find pH of a solution when 100 mL of 0.1 N HCl (1) HClO4>HCl>H2 CO3 >H2 O
is mixed with 100 mL of 0.1 M NH4OH solution
(2) H2CO3>HClO4>HCl>H2 O
[pKa(NH4+ )=9.3]
(3) HCl>HClO4 >H2 CO3 >H2 O
(1) 4.65 (2) 7
(4) HClO4>HCl>H2 O>H2CO3
(3) 8.7 (4) 5.3
28. If the [H+]=[OH–]=10–7 at 25°C then find pKa of 1L
19. Which of the following is the suitable indicator for
H2SO4 & NH4OH titration reaction? H2O. ( dH2O = 1g/ml)
(1) Phenolphthalein (2) Methyl orange (1) 14 (2) 15.74
(3) Methyl red (4) Both (2) & (3)
(3) 7 (4) 16
20. A+B C+D for this reaction Kc=9. If A and B are
29. Calculate the pH of mixture of 400ml 0.01M HCl
taken in equal amounts, ratio of mole of C and A
and 600ml H2O.
at equilibrium is
(1) 4 (2) 3.4
(1) 3 (2) 1
(3) 7 (4) 2.4
(3) 0.25 (4) 0.75
30. Calculate the pOH of the equimolar mixture of
21. For CaCO3 (s) CaO(s)+CO2(g) the pressure of NH4OH and NH4Cl.
CO2 at equilibrium is 8 atm. Then the value of Kp
is- (given Kb for NH4OH = 2×10–5)

(1) 64 atm2 (2) 8 atm (1) 9.3 (2) 12

1 (3) 4.7 (4) 67

(3) 8 atm-1 (4) atm-1
8
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Equilibrium Medical Q-Bank-2020
31. Calculate the value of hydrolysis constant of KCN 38. The variation of Kc with T was studied by plotting
(given Ka of HCN = 1×10-6) 1
logK with . H° of reaction is
T
(1) 10-8 (2) 10-12
(3) 10-20 (4) 10–2
45°
32. The pH value of the aqueous solution of 0.1 M
NaNO3 is- log K

(1) More than 7

1
(2) Less than 7 T
(3) Equal to 7 (1) +2 cal (2) –2 cal
(4) May be more or less than 7 (3) +4.606 cal (4) –4.606 cal
33. The solubility product of AgCl is 1.8×10 –10 . 39. The pH of 10–10 M NaOH solution is
Precipitation of AgCl will occur only when equal (1) 7
volumes of solutions of
(2) Slightly less than 7
(1) 10-7M Ag+ and 10-7 M Cl- are mixed
(3) Slightly greater than 7
(2) 10-5M Ag+ and 10-5M Cl- are mixed
(4) 10
(3) 10-4M Ag+ and 2×10-5M Cl- are mixed
40. A 0.05 N solution of CH 3 COOH is found to be
(4) 10-5M Ag+ and 2×10-5M Cl- are mixed
1.9% ionised. Calculate its Ka.

34. Solubility of Ag2CrO4(s) is maximum in (1) 2.9×10–5 (2) 5.4×10–5

(3) 1.8×10–5 (4) 2.4×10–4
(1) 0.1 M of AgNO3 Solution
41. Calculate the pH of a solution of 0.1M NH3 K b =
(2) 0.1 M of H2CrO4 Solution
1.8×10–5
(3) 0.1 M NaCN Solution
(1) 2.82 (2) 11.12
(4) Pure Water
(3) 8.64 (4) 9.58
35. The equilibrium constant for the reaction
42. A buffer solution with pH 9 is to be prepared by
A2(g) + B2(g)  2AB(g) is Kc = 10–2 at 27°C mixing NH4Cl and NH4OH. Calculate the number of
The standard Gibbs free energy change for the moles of NH4 Cl that should be added to 1 litre of
reaction will be 1M NH4OH, Kb = 1.8×10–5
(1) 5.744 kJ (2) 11.488 kJ (1) 3.6 (2) 1.8
(3) 22.976 kJ (4) Zero (3) 0.9 (4) 0.225

36. 1 mole of H2O and 1 mole of CO are taken in a 10 43. pH of a solution decreased from 4 to 2 then the
litre vessel and heated at 725K. At equilibrium concentration of hydrogen ion will be
40% of water (by mass) reacts with CO according (1) Increased by 2 times
to the equation. (2) Decreased by 2 times
H2O  g   CO  g  H2  g  CO2  g . Find the (3) Increased by 100 times
value of Kc (4) Decreased by 100 times
(1) 0.24 (2) 0.44 44. Solubility of lead iodide is 0.63g/lit. Calculate its
(3) 0.64 (4) 0.94 Ksp. (Pb=207, I=127)
37. An equilibrium mixture of NO2 and N2O4 has a VD (1) 1×10–6 (2) 2×10–6
of 38.3 at 300K. W hat is K p for the equilibrium (3) 1×10–8 (4) 2×10–8
N2 O4  g  2NO2 g if initially one mole of N O is 45. pKa of CH3COOH is 4.74. pH of a solution obtained
2 4

present and equilibrium pressure is 1 atm? by mixing 1L 1 M CH3COOH with 40g NaOH is

(1) 0.166 atm (2) 0.166 atm2 (1) 4.26 (2) 9.37
(3) 0.96 atm (4) 0.96 atm2 (3) 4.63 (4) 9.74

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Medical Q-Bank-2020 Equilibrium
46. pH of an aqueous solution obtained by mixing 4 g 52. At a temperature T K, the concentration of OH– is
NaOH in 500 mL water is: 10–5.5 , the value K w would be 10x in absence of
acid/base. The value of x is
(1) 13.3 (2) 12.3
(1) –10 (2) –11
(3) 11.3 (4) 10.3
(3) –12 (4) –14
47. The following reaction takes place in a 5L flask
53. 8g impure Na2CO3 is put into 1L water. 10 mL of


2SO2 g   O2 g 
 2SO3  g , K C  5 at a this solution required 9 mL 0.1 N HCl for complete
neutralisation. The percentage purity of Na2 CO 3
constant temperature. At equilibrium the moles of sample is :
SO 2 and SO 3 are equal. The mole of O 2 at
equilibrium would be (1) 49.6% (2) 59.6%

(1) 0.2 (2) 0.25 (3) 40.4% (4) 45%

(3) 0.5 (4) 1.0 54. Solubility of a metal (M) sulphide, MS in water is 10–
10 . The pH of the medium needed to prevent



48. If KC for the reaction 2SO2  O2  precipitation of this sulphide using 0.1 M H2S
 2SO3 , is
27, the KC1 (equilibrium constant) for K a1  K a 2 of H2 S  10 20  from 0.1 M solution of
1 M2+ is
SO2  

 SO3 would be nearly equal to
O2 
2 (1) 1 (2) 2

(1) 7.2 (2) 6.2 (3) 3 (4) 4

(3) 5.2 (4) 4.2 55. K1

HF  H2 O  H3 O  F ; K1
49. Vapour density of N 2 O 4 is 45.86 at a certain
temperature. The degree of dissociation of N2O4 at F  H2O 
K2
HF  OH ; K2
the same temperature would be approximately Which relation is correct?
(1) 0.003 (2) 0.03
(1) K2 = K w (2) K 2  1
(3) 0.3 (4) 0.0003 Kw
50. Phosphorylation of glucose is non-spontaneous at
300K. G° is found to be 14 kJ mol –1 . The K1
(3) Kw = K 1K 2 (4) K w 
thermodynamic equilibrium constant will be K2
(1) 3.65 × 10–2 (2) 3.65 × 10–3
M
(3) 3.65 × 10–4 (4) 3.65 × 10–5 56. Find the pH of HCOONH4.
10

A  B  C  D (Ka(HCOOH) = 10–4, Kb(NH4 OH) = 10–5)

51. At equilibrium 1M 1M 2M 1M
(1) 5 (2) 6.5
Volume of vessel is 1L. 1 mole of D is added from
out side. Equilibrium was re-established keeping (3) 2 (4) 4.5
temperature constant. The amount of ‘C’ reacts to 57. Which of the following is not correctly matched?
establish equilibrium is :
(1) F– Lewis base (2) Ag+ Lewis acid
(3) BH3 Lewis base (4) FeCl3 Lewis acid
2 2 2 1
(1) (2) 58. 4.0 gm of hydrogen and 128g of hydrogen iodide
2 1 2 2
are present in a 10 litre flask. The active mass of
hydrogen iodide is
2 2
(3) (4) (1) 0.15(M) (2) 0.1 mole L–1
2 1 2 1
(3) 0.01 mol L–1 (4) 0.2 mol L–1

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Equilibrium Medical Q-Bank-2020
64. The strongest Bronsted base among the following
59. The equilibrium constant for
anions is
5 
 (1) CN– (2) Cl–
2NH3(g) + O 
 2NO(g) + 3H2O(g) will be :
2 2(g) (3) – (4) Br–
65. Given : Enthalpy of ionization of two acids :
H2 + 1 O2 H2O ; K3
2 H° (HCN) = 4.52 kJmol–1
N2 + O2 2NO ; K2
H° (CH3COOH) = 2.1 kJmol–1
N2 + 3H2 2NH3 ; K1
Which relationship for the two acids is true ?
K1.K 2 (1) pKa(HCN) = pKa (CH3COOH)
(1) K1 .K 2 .K 3 (2)
K3 (2) pKa(HCN) > pKa (CH3COOH)
(3) pKa(HCN) < pKa (CH3COOH)
K 1.K 32 K 2 K 33
(3) (4) 2.1
K2 K1
(4) pKa(HCN) = pKa (CH3COOH)
45.2
60. NH 4 COONH 2(s) 


 2NH 3(g) + CO 2(g) . If
66. The correct formula to calculate the hydroxyl ion
equilibrium pressure is 3.0 atm for the above ([OH–]) of an aqueous solution of NH4NO3 is
reaction; ‘Kp’ will be
(1) 4 (2) 8 C Kw K w  Kb
(1) Kb (2)
(3) 16 (4) 27 C



61. M + N 
 P + Q. if initially the concentration
C Kw Ka  Kw
of M and N are both equal but at equilibrium, (3) (4)
Ka C
concentration of ‘Q’ will be twice of that of M, then
what will be the equilibrium constant of the
67. The solubility of Ba3(AsO4)2 (formula mass = 690)
reaction ?
is 6.9 × 10–2 g per 100 ml. Its Ksp is
4 9
(1) (2) (1) 1.08 × 10–11 (2) 1.08 × 10–13
9 4 (3) 1.0 × 10–15 (4) 6.0 × 10–13
1
(3) (4) 4 68. The given pH curve is valid for
9


62. C(s) + H2O(g) 
 CO(g) + H2(g) 12

The above equilibrium when subjected to increase pH

in pressure
7
(1) Remains unaffected
(2) Proceeds in the backward direction
(3) Proceeds in the forward direction V(ml)Base

(4) Reactions will stop

(1) Weak acid vs strong base
63. W hich of the following is a set of amphoteric
molecules and ions ? (2) Strong acid vs strong base
(3) Strong acid vs weak base
(1) H2O, HPO 24  , HCO3 –
(4) Weak acid vs weak base
2 
(2) H2O, HPO , H2PO3 2 69. Calculate pH for 0.01N Ca(OH)2.

(3) H2PO 4 , H2PO 2 , H2O (1) 2 (2) 12

(3) 6 (4) 4
(4) All of these

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Medical Q-Bank-2020 Equilibrium
70. The ionisation constant of acetic acid is 1.8×10–5 . 77. SO3(g) is heated in a closed vessel. An equilibrium
At what concentration will it be dissociated to 
: 2SO3(g)  
 2SO2(g) + O2(g) is established. The
2%?
vapour density of the mixture, in which SO3 is 50%
(1) 1 M (2) 0.018 M dissociated is
(3) 0.18 M (4) 0.045 M (1) 32 (2) 35
71. The solubility of AgCl at 20°C is 1.435 × 10–3 g/L. (3) 42 (4) 55
The solubility product is
78. Which of the following statements is/are correct
(1) 1.0 × 10–10 (2) 2 × 10–10 regarding standard Gibb’s free energy change and
(3) 1.035 × 10–5 (4) 1.08 × 10–3 thermodynamic equilibrium constant K :

72. pH of salt of a weak acid and strong base will be (1) When G° = –ve or K > 1
(2) G° = +ve ; or K < 1
1
(1) pH = 7 – pKa + pKb  (3) When G° = 0 or K = 1
2
1 (4) All are correct statements
(2) pH = 7  pKa + log C 79. For the reaction at 300K
2

1 

  V(g) + S(g)
A(g) 
(3) pH = 7  pKa – logC
2
rH° = –29.8 kJ/mol, rS° = –0.1 kJ k–1 mol–1
1 The value of equilibrium constant is :
(4) pH  7   pk a  pkb 
2 (1) 0 (2) 1
73. Which of the following is a lewis acid? (3) 10 (4) 100
(1) H2O (2) SnCl2 80. Solid ammonium carbamate dissociates as follows–
(3) C2H5OH (4) Cl– 

NH2COONH4(s) 
 2NH3(g) + CO2(g)
74. pH of solution formed by mixing 40 ml of 0.1 M
HCl with 10 ml of 0.45 M of NaOH is(given at Which of the following graphs correctly represents
25°C) the equilibrium
(1) 10 (2) 12 line (1) is for NH2COONH4(s) , (2) for NH3(g), (3) for
CO2(g)
(3) 8 (4) 6
75. For formation of NH3(g) from N2(g) and H2 (g) as (1)
conc.
N2(g) + 3H2(g) 2NH3(g) + 92 kJmol–1. Correct (2) and (3)
(1)
plot will be
time

ln Keq ln Keq (1)

(1) (2)
conc.
1/T 1/T (2)
(2)
(3)
time
ln Keq ln Keq
(3) (4)
1/T 1/T
conc.
76. The KP value for the equilibrium (1,2 & 3)
(3)


 2A 2 B (g) is 4×10 4 atm –1 at
2A 2(g) + B 2(g)  time
27°C. The KP value for the equilibrium

1 (3)


A2B(g) 
 A2(g) + B at 27°C is conc.
2 2(g) (2)
(4) (1)
(1) 1×10–5 (2) 2.5×10–5
time
(3) 5×10–3 (4) 5×10–5

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Equilibrium Medical Q-Bank-2020
81. Morphine (C17 H19NO3), which is used medically to 87. For
relieve pain is a base. It’s conjugate acid is
I:- A + B C ; Kc = K1
(1) C17H18NO3+ (2) C17H18NO3
II:- 2C D ; Kc = K2
(3) C17H20NO3– (4) C17H20NO3+
Then the value Kc for the reaction 2D + A + B
82. Which of the following is/are correct ?
5C, will be
(1) Strength of acid and base depends on role of
solvent K 22 K1
(1) (2)
(2) Acids like (HCl. H 2 SO 4 ) have equal acid K1 K 22
strength in water
(3) Acetic acid in ammonia is a strong acid K1 1
(3) (4)
(4) All are correct statements K2 K1K 22

83. Acids like (HCl, H2 SO4 ) dissociate completely in 88. For the reaction A(g) n B (g) ; if D = Vapour
water as water accepts all their protons. Thus density before dissociation
these acids in water have equal acid strength,
which is called d = Vapour density after dissociation and  =
degree of dissociation, then correct relationship is
(1) Levelling effect (2) Isotopic effect
(3) Polar effect (4) None of these Dd Dd
(1)   n  1 d (2)   n  1 D
84. 4g of NaOH was dissolved in one litre of a solution    
containing one mole of acetic acid and one mole
dD dD
of sodium acetate. The pH of resulting solution is (3)   n  1 d (4)   n  1 d
(given K a(CH3COOH) = 1.8×10–5 ) (log11 = 1.04,    
log3 = 0.4771, log2 = 0.301)
89. The reaction will move backward by which of the
(1) 4.83 (2) 5.83 following factors ?
(3) 2.83 (4) 6.93 N2 + 3H2  2NH3, H = – 46 kJ mol–1
85. Identify the correct statement/s ? (1) Rate will decrease in pressure
(1) The solubility of ‘AgCl’ decreases in presence (2) Rate will increase in temperature
of NaCl at given temperature
(3) addition of inert gas at constant pressure
(2) When two sparingly soluble salts are present
in water with at least a common ion, then the (4) All of these
solubility of both salt decreases 90. Haber's process reaction is expressed as
(3) Solubility increases due to complex formation
N2(g) + 3H2(g) 2NH3(g)
at given temperature
If a small amount of Argon gas is introduced in
(4) All are correct statements
the reaction vessel at constant pressure condition,
86. Following is the titration curve of two weak acids then the nature of the reaction will be
HA and HB (5 millimoles each) titrated against
strong base NaOH(0.1M) (1) Proceeds towards backward direction
12 (2) Proceeds towards forward direction
10
(3) Reaction remains unaltered
8
HA (4) At the beginning it proceeds towards forward
pH 6 direction, then proceeds towards backward
5 HB
4 direction
2 91. At a temperature under high pressure KW (H2O) =
10–12 M2
25ml 50ml 75ml
A solution having PH = 6.4, under these condition
volume of (NaOH)
is said to be
The pKa of HB acid is
(1) Acidic (2) Basic
(1) 3 (2) 4
(3) Neutral (4) Amphoteric
(3) 5 (4) 6

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Medical Q-Bank-2020 Equilibrium
92. 0.1 M CH3COOH is 0.1% Ionised, then pH of the 102. For a titration of 100 cm3
of 0.1M Sn+2
to Sn+4, 50
3
cm of 0.40M Ce +4 solution was required.
solution will be
The oxidation state of Cerium in the product is
(1) 2 (2) 3
(1) +5 (2) +2
(3) 4 (4) 1
(3) +4 (4) +3
93. pH of an acidic buffer is 5.04 and pKa (CH3COOH)
= 4.74. Then which of the following relationships 103. x ml of HCl is required for titration of a mixture of
is correct ? Na 2 CO 3 + NaHCO 3 with phenolphthalein as
indicator and y mI of HCl with Methyl orange as
(1) [Salt] = 2 × [Acid] indicator in same titration. Volume of HCl required
(2) [Salt] = [Acid] for complete reaction of Na2CO3 is
(3) [Acid] = 2 × [Salt] (1) 2y (2) 2x
(4) [Acid] = 4 × [Salt] xy xy
(3) (4)
94. pH of which of the following salts remains same 2 2
for 2 M and 6 M concentration of the solution ? 104. Equilibrium constant for a reaction 2A+B  2C is
(1) CH3COONa (2) C6H5NH3 +Cl–
10–4 which indicates that
(3) HCOONH4 (4) KCN (1) Concentration of product is 10 –4 times than
95. If Ksp of CaF2 = 1.8 × 10–10 M3
at 298K, then the reactant
solubility of CaF2 in 0.01 M NaF solution is (2) Concentration of product is 10 4 times than
(1) 1.8 × 10–8 (2) 1.8 × 10–11 reactant

(3) 1.8 × 10–6 (4) 1.8 × 10–9 (3) Rate constant for forward reaction is less than
that for backward
96. Unit of active mass of a substance is
(4) Rate constant for forward reaction is more than
(1) dimensionless quantity (2) mole/L that for backward
(3) g/L (4) mole - L
105. For the reaction A(g) + 3B(g)  2C(g) at 27°C, 2
97. For three acids (A, B and C) the pK a values are moles of A, 4 moles of B and 6 moles of C were
1.8, 2.2 and 4.1 respectively. Then correct order of present in 2L vessel. KC for the reaction is 1.2, the
acidity among the acids reaction will
(1) B > A > C (2) A < B < C (1) Move in forward direction
(3) C > A > B (4) C < B < A (2) Move in backward direction
98. Dissociation constant of 0.01 M CH3COOH is 1.8 (3) Be in equilibrium
× 10–5 , then calculate the dissociation constant of
CH3COO– (4) Be effected by catalyst

(1) 5.6 × 10–12 (2) 5.6 × 10–8 106. For the following 3A  2B + 2C
(3) 5.6 × 10–10 (4) 1.8 × 10–9 What is the relation between Kp, total pressure at
99. Calculate pH of 10 –1 M CH 3 COOH (K a of equilibrium (P) and degree of dissociation ()?
CH3COOH = 4 ×10–5)
P 4 4P 4
(1) 1 (2) 2 (1) K P  (2) K P 
1    9 1   
3 3

(3) 1.5 (4) 2.70

100. If 200ml 0.001M CH3COOH and 200 ml 0.001M 16P 4 4P 2
NaOH are mixed together, then pH of the solution (3) K P  (4) K P 
27 1     3    1   
3 3

will be (pKa of CH3COOH = 4.7)

(1) 9.35 (2) 7.72 107. For the reaction 2A + B  C
(3) 6.65 (4) 4.7 1 mole of A, 2 moles of B and 4 moles of C were
101. The solubility product of AgCl is 1.8 ×10–10. What taken initially in 1L vessel. At equilibrium moles of
will be the solubility of AgCl in 0.01M NaCl C was 0.5. What is the equilibrium constant?
aqueous solution ? (1) 1.4×10–3 (2) 1.1×10–2
(1) 1.8 × 10–10 (2) 1.8 × 10–12
(3) 3.5×10–4 (4) 2.8×10–2
(3) 1.8 × 10–8 (4) 1.8 × 10–6

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Equilibrium Medical Q-Bank-2020
108. What will happen when CaCO3 was decomposed 117. The dissociation constant of 0.01M HA (Acid) is
in open container against vaccum? –
2×10–5 then the dissociation constant of A will be
(1) reaction will reach equilibrium after certain time
(1) 5×10–5 (2) 2×10–5
(2) reaction will move forward always
(3) 5×10–10 (4) 5×10–9
(3) reaction will move backward always
118. A(g)  2B(g) + C(g)
(4) Data insufficient
For the above equilibrium, if initial pressure is 100
109. The dependence of vapour pressure and
temperature is explained by atm and pressure at equilibrium is 200 atm, Kp of
the reaction is -
(1) Arrhenious equation
(1) 10000 (2) 1000
(2) Clausious Clayperon equation
(3) 100 (4) 20000
(3) Vant Hoff equation
119. W hich of the following reactions will produce
(4) Tautons Rule increased amount of product on addition of He gas
at constant pressure ?
110. Which of the following ions will not have conjugate
base? (1) N2(g) + 3H2(g)  2NH3(g)
(1) H2PO4– (2) H2PO3–
(2) PCl5(g)  PCl3(g) + Cl2(g)
(3) H2PO2– (4) All of these
(3) N2(g) + O2(g)  2NO(g)
111. The strongest acid among the following is
(4) All of the above
(1) HOF (2) HOCl
120. W hich of the following is strongest acid in
(3) HOBr (4) HOI CH3COOH solvent ?
112. K a for CH3 COOH is 10–5 and pH of CH3 COOH (1) HF (2) HCl
solution is 3. W hat is the concentration of the
solution? (3) HBr (4) HI

(1) 0.1M (2) 0.01M 121. Final pH of the solution obtained on mixing 100 ml
0.01M HCl and 100 ml 0.01M CH 3 COOH (K a
(3) 0.2M (4) 0.02M  10–5) is- [log5 = 0.7]
113. pOH of 0.1M H2SO4 is (1) 2.3 (2) 3.7
(1) 1 (2) 0.7 (3) 4.3 (4) 4.5
(3) 12.7 (4) 13.3 122. If 100 ml 0.2M CH3COOH (pKa  4.74) is added
114. pH of 0.1M NH 4 Cl is 5. W hat is the degree of to 100 ml 0.1M NaOH solution, the final pH will be
hydrolysis of it? Given Kb of NH4OH = 10–5 (1) 13 (2) 6
(1) 10–2 (2) 10–3 (3) 4.74 (4) 4.1
(3) 10–4 (4) 10–5 123. If 100 ml 0.1M CH3 COOH (pKa = 4.74) is mixed
with 100 ml 0.1M NaOH solution, the final pH of
115. Solubility of Ba(OH)2 in pH = 11 is 10–8 . What is
the solution is -
the solubility product of Ba(OH)2 ?
(1) 7.72 (2) 6.72
(1) 10–11 (2) 10–14
(3) 4.72 (4) 8.72
(3) 10–9 (4) 10–12
124. K sp of Ag 2 CrO 4 is 1.1 × 10 –12 at 298K. The
116. The correct increasing order of the acid strength is solubility of Ag 2 CrO 4 (mol L –1 ) in 0.1M AgNO 3
(1) H2O < HF < NH3 < CH4 solution is -
(2) HF < NH3 < CH4 < H2O (1) 1.1 × 10–10 (2) 1.1 × 10–11
(3) NH3 < H2O < CH4 < HF (3) 1.1 × 10–12 (4) 1.1 × 10–9
(4) CH4 < NH3 < H2O < HF

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Medical Q-Bank-2020 Equilibrium
125. For dissociation of PCl5 (g) to PCl3 (g) and Cl2(g), 128. For which of the following reactions equilibrium
correct plot will be
27 4P2
constant can be expressed as, K P  ?
 
2
16 1   2
lnKp (1) N2O4(g)  2NO2(g)
(2) 2NH3(g)  N2(g)+3H2(g)
(1)
1 (3) 2C(s)+O2(g)  2CO(g)
T
(4) H2(g) + I2(g)  2HI(g)
129. The avarage molecular mass of N 2 O 4 in the
equilibrium is, 76.67. When N2O4 decomposes like
lnKp
N2O4  2NO2

(2) What is the degree of dissociation of N2O4 ?

1 (1) 10% (2) 20%
T
(3) 40% (4) 50%
130. For a reaction the value of K P increases with
increase in temperature. The H for the reaction
lnKp
would be
(1) Positive
(3)
1 (2) Negative
T
(3) Zero
(4) Either positive or negative

lnKp 131. Which of the following is an example of ampholyte

?
(1) HCO3– (2) H2PO2–
(4)
–
1 (3) HPO32 (4) H3PO4
T
132. Which of the following is most acidic ?

126. For an equilibrium 2A(g) + B(g)  3C(s) (1) HOCl (2) HClO2
(3) HClO3 (4) HClO4
at equilibrium [A] = 4[B]. When A was added in the
next equilibrium moles of A becomes 4 times the 133. W hat is the pH of 0.1M H 2 CO 3 (aq.) solution?
(Given Ka , Ka respectively are 4×10–3 and 9×10–
initial equilibrium. What will be the new concentration 6) 1 2

of B relative to its initial concentration ?

(1) 1.7 (2) 2.3
1 1
(1) (2) (3) 1.4 (4) 2.1
4 2
1 1 134. The pH of 0.1M NH4 OH (aq.) is 11. Which of the
(3) (4) following statements is true for the situation?
16 8
(1) Degree of dissociation of NH4OH = 10–2
K
127. For an equilibrium = 0.5. The relation states that (2) Kb for NH4OH = 10–5
Q
(3) pKa of NH4+ = 5
(1) ratio of reactant to product is 0.5
(4) Both (1) and (2)
(2) ratio of reactant to product is 2
135. The change in pH of a buffer solution is 10–2 when
(3) reaction will favour in forward direction
10 ml 0.1M HCl was added to 100 ml of buffer.
(4) reaction will favour in backward direction What is the buffer capacity of it ?
(1) 0.2 (2) 0.5
(3) 0.8 (4) 1

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Equilibrium Medical Q-Bank-2020
136. 100ml of 0.1 M NH4OH mixed with 100 ml of 0.05 143. W hich of the following equilibria can be shifted
M H2 SO4. What is the pH of resulting mixture at only in forward direction upon increase in pressure
25°C? (Given Kb of NH4OH = 10–5.) and temperature ?
(1) 5.85 (2) 5.15 (1) N2(g) + 3H2(g) 2NH3(g)
(3) 8.85 (4) 4.85
(2) PCl5(g) PCl3(g) + Cl2(g)
137. The degree of hydrolysis of AlCl3 will be maximum
in presence of (3) Ice(s) Water(l)

(1) NH4OH (2) NH4Cl (4) All of the above

(3) conc.NaOH (4) All of these 144. W hich of the following acids is strongest in
aqueous solution ?
138. At 300 K, the degree of dissociation of 0.066M
solution of an acid HA is 0.0145. The degree of (1) HCl
dissociation of 0.02 M solution of the acid at the (2) HNO3
same temperature will be
(3) H2SO4
(1) 0.258 (2) 2.78
(4) All are of same strength
(3) 0.0263 (4) Zero
145. If 0.02N HCl and 0.02N CH3COOH are mixed in
139. The pH value of a solution obtained by mixing 50 equal volume, final pH of the solution will be
mL of 0.2 N HCl (aq) solution with 50 mL of 0.1 N
NaOH (aq) solution is [log2 = 0.301, log5 = 0.699] (1) 1 (2) 2
(1) 1.301 (2) 2.669 (3) 1.7 (4) 3
(3) 3.71 (4) 0.699 146. In an aqueous solution 1 mol each of
CH 3 COOH(pK a = 4.75) and CH 3 COONa are
140. The pH of 10–10 M aqueous solution of NaOH at present. If 1L of 0.2M HCl is added to the
25°C is solution, final pH of the solution will be
(1) 7 (1) 8.55 (2) 3.55
(2) Slightly less than 7 (3) 4.57 (4) 10.55
(3) Slightly more than 7 147. pKa of CH3COOH and NH4OH are 4.76 and 4.75
(4) Zero respectively, pH of 0.1M CH3COONH4 solution is
141. Enthalpy of neutralization with respect to a given (1) 6.995 (2) 8.505
NaOH aqueous solution is maximum for (3) 4.755 (4) 7.005
(1) HF (2) HCl 148. Solubility product values of salts of types MX, MX2
(3) CH3COOH (4) HCN and M 3 X at same temperature are 4×10 –8 ,
4×10–12 and 2.7×10–15 . The salt having maximum
142. For the reaction CO(g) + Cl2 (g) COCl2 (g), solubility in water is
Kp/K c value is equal to
(1) M3X
1 (2) MX2
(1) RT (2)
RT (3) MX

(3) 1 (4) RT (4) All are of same solubility



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