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2019 JC2 Prelims H2 Chemistry Paper 1 Worked Solution
2019 JC2 Prelims H2 Chemistry Paper 1 Worked Solution
H2 Chemistry 9729 implies that it takes more energy to cause a spike in the concentration of
Paper 1 Worked Solution vaporise the ionic lattice into gasous all three gases.
ions. No bearing on the decomposition.
1 From Group 1318, the number of B : Decrease in temperature of a large
2,4: CO32– is more easily polarised as body of gas cannot be achieved
unpaired electrons es from 1 (Group 13) planar CO32– has a larger surface area instantaneously.
to 3 (Group 15), then es to 0 (Group 18). than the near spherical tetrahedral
Hence, W, X, Y and Z cannot be main SO42– ion. Hence the C–O bond is more amount
group elements, i.e. they are TM. readily weakened, causing CaCO3 to C : As conc , when volume of
volume
decomposing at a lower temperature.
W must have been 4d8 5s2 and not 4d2 5s2 container is decreased, the total
as the number of unpaired electrons es 3 : Due to smaller size of the CO32– ion pressure and conc of all three gases
with more electrons added. compared to SO42–, the charge density will increase suddenly. By LCP, eqm
is higher. However, higher anionic will shift to the side with fewer
B charge density has no bearing on the gaseous particles (right side), in
decomposition. attempt to bring down the pressure,
2 Angle of deflection,
z C leading to consumption of N2 and H2
m to form more NH3 at the new eqm.
z 1 7 Oxidation state of S in SF6 is +6, SCl2 is +2
1 D : Removal of NH3 will not result in a
For a proton, 11H , and S2Br2 is +1, which correlates with the
m 1 spike in concentration of all 3 gases.
ability of the halogen to oxidise S.
z 5 1
For particle X, 1 D
C
m 15 3
A: 3
A ; B : 52 B ; C : 36 C ; D : 94 D3 0.13 14
pOH pK w pH lg 2.4 1014 7.4
1 8 Number of 13C atoms L 0.01L
13 6.22
A OH 106.22 6.03 107 mol dm3
Each 13
6 C atom has 13 – 6 = 7 neutrons
3 A : trans-isomer is non-polar (C–Cl bond Number of neutrons 0.01L 7 0.07L B
dipole cancels), while cis-isomer is
polar. Hence cis-isomer is more B
soluble in polar H2O. 15
9
B : C=O is more polar than C–Cl as O is
more electronegative. Also, oxygen of
C=O can form H-bond with water via
its lone pair. CH3COCH3 is more
soluble. Since there are two chiral centers and one
cis-trans double bond,
C : CH3CH2CH2CH2CH(OH)CO2H can
form intermolecular H-bond with H2O, Number of stereoisomers = 23 = 8
while CH3CH2CH2CH2CH(NH3+)CO2–
is zwitterionic and forms stronger ion- D
dipole interaction with H2O, hence
more soluble. 16 There are 8 different types of H on the
molecule:
D : 2-nitrophenol can form intramolecular B
H-bond, while 4-nitrophenol forms
intermolecular H-bond with H2O, 10 I2(s) + Cl2(g) 2ICl(s) H1 --------- (1)
hence more soluble. ICl(s) + Cl2(g) ICl3(s) H2 --------- (2)
B
1 1 3
(1) (2) : I2 (s) Cl 2 (g) ICl 3 s
4 A : Like graphite, each C is sp2 hybridised 2 2 2
with one unpaired e– in the remaining
p-orbital, which is delocalised, 1 1
Hf ICl3 (s) H1 H2 14 88
allowing CNT to conduct electricity. 2 2
B : Like graphite, the C–C bonds within 81 kJ mol1
C
each molecule is stronger than that in
C
diamond as they result from sp2-sp2
17
overlap. However, between two
11 Combustion of fuel (hydrocarbon) is an
molecules, there is only weak
intermolecular id-id attraction, hence exothermic process, so H is –ve.
softer than diamond. Combustion leads to the production of more
C : Like graphite, the high melting point is gaseous CO2 and H2O molecules than O2(g)
due to energy required to break the consumed. Hence, entropy increases, i.e.
strong intramolecular C–C bond and S is +ve.
not to overcome the weak G = H – TS is –ve for all T. C
intermolecular id-id attraction.
D
D : Like graphite, the C–C bonds within
each molecule is stronger than that in 18 A :
12 A : Since HI, a strong acid is produced,
diamond as they result from sp2-sp2
although H+ is a catalyst, the [H+] es.
overlap.
Ea
A B : The rate constant, k Ae RT , is
independent of concentration.
5 I: H2SO4 oxidises Br– to Br2, itself B :
reduced to SO2 C : Given rate k H CH3COCH3 . So
II : H2SO4 catalyses the condensation rate es by 4 when concentrations
reaction between an acid and an of all reactants are doubled. C :
alcohol to give an ester (and water), but D : pH 1 [H+] = 10–1 = 0.1 mol dm–3
making the C=O more electrophilic.
pH 2 [H+] = 10–2 = 0.01 mol dm–3
III : Acid-base reaction where H2SO4 is D :
the acid and NaOH the base, to give [H+] es by 10 , rate es by 10
salt (Na2SO4) and water. A
D C
28 The left-hand-side cell is a electrochemical
19 1 : 23 A : cell, i.e. battery source of +1.52 V:
[O]: Mn Mn2+ + 2e– E 1.18 V
[R]: Cu + 2e Cu
2+ –
E 0.34 V
2 :
Ecell 0.34 1.18 1.52 V
B :
Electrolysis occurs on the right-hand-side:
3 : There is no intermediate in SN2
Cathode (Reduction) :
E Ag Ag 0.80 V
Ag is
deposited
4 :
C : E Na Na 2.71 V
for A,
while H+
A E H H 0.00 V
2 or H2O is
reduced
20 From the rate of formation of ppt (solvolysis), E Zn Zn 0.76 V
2
to H2(g)
P is C6H5CH2Br, Q is X–C6H4CH3, for the
R is C6H5CH2I, S is C6H5CH2Cl
D : E H O H 0.83 V
2 2 rest
A : R should have the longest C–X bond Anode (Oxidation) :
since it is the weakest and most D NO3– cannot be oxidised
reactive. H2O or
B : Free radical substitution does not work
24 The ester, amide and halogenoalkane E O 2 OH 0.40 V OH– is
moieties will be hydrolysed by NaOH(aq),
with I2. giving 2 -amino acids and 1 -amino acid: E S O2
2
8
SO24 2.01 V
oxidised
to O2(g)
C : Q can be BrC6H4CH3 formed from E O H O 1.23 V
2 2
for all
cases
C6H5CH3 + Br2 in the presence of AlBr3.
D : Only P, R and S gives benzoic acid
E Cl Cl 1.36 V
2
E Au I Au 0.40 V 9 B 19 A 29 D
A A 10 C 20 C 30 A