DPP CHEMISTRY

DATE: 17/07/2021 [PERIODIC TABLE]

1. General electronic configuration of d-block elements is (2) a decrease from O2– to F– & then increase from
(1) nd1–10 (n+1) s0–1–2 ; n = 3, 4, 5, 6 Na+ to Al3+
(2) (n–2)d1–10 (n–1) f14 ns2; n = 4, 5, 6, 7 (3) a significant increase from O2– to Al3+
(3) ns2nd1–10; n = 4, 5, 6, 7 (4) a significant decrease from O2– to Al3+
(4) None 12. In which of the following pairs, the size of the first
2. Which statement is correct for long periodic table- species is not more than the second?
(1) This shows arrangement of electrons in sub (1) Li, F (2) Fe2+, Fe3+
energy level s, p, d, f (3) Na+, F– (4) S, O
(2) This help in forcast of stable valency of elements 13. Which one of the following is smallest in size
(3) This tells about direction of change in physical (1) N3– (2) O2–
and chemical properties
(3) F– (4) Na+
(4) All are correct
14. Increasing order of metallic character of C, Si, As, Sb,
3. Elements of Zinc group (Zn, Cd and Hg) is called-
Bi is-
(1) Noble metals (2) Coinage metals
(1) C > Si > As > Sb > Bi
(3) Volatile metals (4) Precisious metals
(2) C <Si < As < Sb < Bi
4. Wrong statement about Mendelief's periodic table-
(3) Si < C < As < Sb < Bi
(1) It provides systematic way of study of elements
(4) Bi < Sb < As < Si < C
(2) It remove doubtful atomic weights
15. Ionic radius of Al3+ is less than Mg2+, because-
(3) It provide suitable way of discovery of new
(1) Mg atom has less neutron than Al
elements
(2) Al3+ has more effective nuclear charge than Mg2+
(4) None of these
(3) Its electronegativity is partial
5. Atomic number of an element is 43. Then electronic
(4) Ionisation potential of Al is less than Mg atom
configuration of the element present upwards on it in
periodic table- 16. Atomic radius of inert gas is high, because-
(1) 1s2, 2s2,2p6, 2s23p6, 3d5, 4s2 (1) Its Vanderwall radius is very large
(2) 1s2, 2s22p6, 3s23p6, 3d10, 4s24p5 (2) It contains metalic bond
(3) 1s2, 2s22p6, 3s23p6, 3d6, 4s1 (3) It contains covalent bond
6. Which are correct match- (4) It contains molecular bond
(a) Eka silicon-Be (b) Eka aluminium-Ga 17. Size of N–3 is more than O2– because-
(c) Eka manganese-Tc (d) Eka scandium-B (1) Z/e ratio is less
(1) b, c (2) a, b, d (2) increases Z/e ratio
(3) a, d (4) all (3) Z/e ratio is same for both
7. Element with the electronic configuration given below, (4) Don't depend upon Z/e
belong to which group in the periodic table 1s2, 2s2, 18. Atomic radius of fluorine and Neon is respectively-
2p6, 3s23p6 3d10, 4s2 4p6 4d10, 5s2 5p3 (1) 0.72, 1.60 (2) 1.60, 1.60
(1) 3rd (2) 5th (3) 0.72, 0.72 (4) None of these
(3) 15th (4) 17th 19. The ionic radii of O2–, F– Na+ and Mg2+ are 1.35, 1.34,
8. X is placed in group number 7 and 5th period. It 0.95 and 0.66 Å respectively. The radius of the Ne
outermost electronic configuration is- atom is-
(1) 5s2, 5p5 (2) 3d5, 4s2 (1) 1.39 Å (2) 1.12 Å
5 2
(3) 4d , 5s (4) 4d5, 4s1 (3) 0.85 Å (4) 0.50 Å
9. Which of the following is not a Doeberiner traid 20. Four elements P, Q, R and S have ground state
(1) Li, Na, K (2) Mg, Ca, Sr electronic configuration as-
(3) Cl, Br, I (4) S, Se, Te P  1s2 2s2 2p6 3s2 3p3
10. There are 10 neutrons in the nucleus of the element Q  1s2 2s2 2p6 3s2 3p1
19
ZM . It belongs to
R  1s2 2s2 2p6 3s2 3p6 3d10 4s4 4p3
(1) f-block (2) s-block S  1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p1
(3) d-block (4) None Comment which of the following option represent the
11. The ions O , F Na , Mg2+ and Al3+ are isoelectric.
2– – + correct order of true (T) and false (F) statement-
Their ionic radii show- (I) size of P < size of Q (II) size of R < size of S
(1) an increase from O2– to F– & then decrease from (III) size of P < size of R (IV) size of Q < size of S
Na+ to Al3+ (1) TTTT (2) TTTF
(3) FFTT (4) TTFF

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 DPP CHEMISTRY
DATE: 17/07/2021 [PERIODIC TABLE]

21. Match list-I with list-II and select the correct answer 22. Which of the following sequences is correct for
using the codes given below decreasing order of ionic radius
List-I List-II (1) Se–2 > I– > Br– > O–2 > F–
(Ion) Radius (in pm) (2) I– > Se–2 > O–2 > Br– > F–
(i) Li+ (a) 216 (3) Se–2 > I– > Br– > F– > O–2
(ii) Na+ (b) 195 (4) I– > Se–2 > Br– > O–2 > F
(iii) Br– (c) 60
(iv) I– (d) 95
(1) i = a, ii = b, iii = d, iv = c
(2) i = b, ii = c, iii = a, iv = d
(3) i = c, ii = d, iii = b, iv = a
(4) i = d, ii = c, iii = b, iv = a

ANSWER KEY
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
A. 1 4 3 4 1 1 3 3 2 4 4 3 4 2 2
Q. 16 17 18 19 20 21 22
A. 1 1 1 2 1 3 4

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