Section 3.

5 NRTL Activity Coefficient Models

Summary of Applicability....................................................................................... 3 •79
Polymer NRTL Model Overview ............................................................................ 3•80
Polymer NRTL Model ............................................................................................. 3 •81
Random Copolymer NRTL Model .......................................................................... 3•83
Parameters for the NRTL Models ....................................................................... 3•85
Comparisons of the Polymer NRTL Models .......................................................... 3•86
Similarities ........................................................................................................... 3•86
Differences ............................................................................................................ 3 •86
Specifying the Polymer NRTL Models................................................................... 3•86
References ............................................................................................................... 3 •87

Section 3.6 UNIFAC Activity Coefficient Model

Summary of Applicability....................................................................................... 3 •89
Polymer UNIFAC Model ........................................................................................ 3•90
Polymer UNIFAC Model Parameters ................................................................. 3•92
Specifying the UNIFAC Model............................................................................... 3•92
References ............................................................................................................... 3 •93

Section 3.7 Polymer UNIFAC Free Volume Model

Summary of Applicability....................................................................................... 3 •95
Polymer UNIFAC Free Volume Model .................................................................. 3•96
Polymer UNIFAC Free Volume Model Parameters........................................... 3•97
Specifying the Polymer UNIFAC Free Volume Model ......................................... 3•97
References ............................................................................................................... 3 •98

Section 3.8 Polymer Ideal Gas Property Model

Summary of Applicability....................................................................................... 3 •99
Polymer Ideal Gas Property Model...................................................................... 3•100
Polymer Ideal Gas Model Parameters .............................................................. 3•102
Specifying the Ideal Gas Model............................................................................ 3•102
References ............................................................................................................. 3 •103

Section 3.9 Sanchez-Lacombe EOS Model

Summary of Applicability..................................................................................... 3 •105
Sanchez-Lacombe Model ...................................................................................... 3•108
Pure Fluids ......................................................................................................... 3•108
Fluid Mixtures .................................................................................................... 3•110
Polymer Systems ................................................................................................ 3 •111
Sanchez-Lacombe Model Parameters ............................................................... 3•112
Specifying the Sanchez-Lacombe EOS Model ..................................................... 3•112
References ............................................................................................................. 3 •113

Polymers Plus User Guide xi