56 Ion-selective electrodes, ISE’s

With glass membrane With solid-state membrane

Built similarly to a pH electrode, but using glass which is
sensitive to a certain ion.
In practice, only electrodes for sodium ions are
manufactured.
It is an indicator electrode which must always be used
with a reference electrode. See page 43.
The sensitive membrane is a mixture of salts or a crystal
in the case of the F- ISE.
The membrane and the internal electrolyte can be
replaced.
They are indicator electrodes, and should always be
used with a reference electrode. See page 43.

96 50, Sodium Na+. 96 51, Bromide Br-.

Measuring range: 0.02 ppm... 20 g/l
Linear measuring range: From 1 ppm
Working conditions: pH 8 ... 11, 0 ... 80°C
Interferences: Ag+, NH4+, K+, Li+, H+
Electrolyte for the reference electrode: NH4Cl 0.1M
Applications: Foodstuffs, biological solutions, the
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Measuring range: 0.4 ppm ... 80 g/l
Linear measuring range: From 5 ppm
Working conditions: pH 2 ... 12, 0 ... 80°C
Interferences: S2-, CN-, OH-, I-, Cl-, S2O32-.
Electrolyte for the reference electrode: KNO3 1M
Applications: photographic emulsions
96 52, Chloride Cl-.
Measuring range: 0.4 ppm ... 35 g/l
Linear measuring range: From 5 ppm
Working conditions: pH 2 ... 11, 0 ... 80°C
Interferences: S2-, Br-, I-, CN-.
Electrolyte for the reference electrode: KNO3 1M
Applications: foodstuffs, waters, etc.

96 53, Cyanide CN-.

Measuring range: 0.03 ppm ... 2.6 g/l
Linear measuring range: From 0.5 ppm
Working conditions: pH 11 ... 13, 0 ... 50ºC
Interferences: Cl-,I-, Br-, S2O32-, CO32-, CrO42-.
Electrolyte for the reference electrode: KNO3 1M
Applications: waters, galvanizing baths.

96 54, Ag Sulphide//Ag2S.
� �� Measuring range:
0.01 ppm ... 108 g/l as silver, 0.3...32 g/l as sulphide
Linear measuring range: From 0.1 ppm Ag+, 0.5 ppm S2-
Working conditions: Ag+, pH 1...9, S2-, pH 2...14, 0...50ºC.
Interferences: There should be no Hg2+ and proteins.
Electrolyte for the reference electrode: KNO3 1M
Applications: waters

96 55, Fluoride F-.

Measuring range: 0.02 ppm ... 20 g/l
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Linear measuring range: From 0.1 ppm

Working conditions: pH 5 ... 8, 0 ... 80ºC
Interferences: OH-, high concentrations of Lanthanum complexers
Electrolyte for the reference electrode: KCl 3M
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Applications: potable waters, toothpastes, milk, etc.
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96 56, Iodide I-.
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Measuring range: 0.01 ppm ... 127 g/l
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Linear measuring range: From 0.5 ppm
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Working conditions: pH 0 ... 12, 0 ... 50ºC
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Interferences: There should be no Hg2+, Cl-, Br-, S2-,
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S2O32-, CN-, CO32-, CrO42-.
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Electrolyte for the reference electrode: KNO3 1M
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Applications: Plants, milk, waters.
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Laboratory Catalogue 2004

1st Edition
Ion-selective electrodes, ISE’s 57

96 57, Copper Cu2+-.

Measuring range: 0.1 ppm ... 6 g/l
Ordering information
Linear measuring range: From 1 ppm
Code Description
Working conditions: pH 1 ... 6.5, 0 ... 50°C
Interferences: Pb2+ and Cd2+. Electrodes
Electrolyte for the reference electrode: KNO3 1M Specify code and name of the ion to be measured
Applications: galvanising baths. IMPORTANT: Solid-state and polymer-membrane selective electrodes are
supplied with an electrolyte solution.
With polymer membrane
The polymer membrane is made up of several ion-selective
Spare membranes
substances, depending on the ion to be measured.
The membrane and the internal electrolyte can be replaced. 96 70 Bromide (Br-), 1 membrane
Used together with a reference electrode. 96 71 Chloride (Cl-), 1 membrane
96 72 Cyanide (CN-). 1 membrane
96 60, Calcium Ca2+.
96 73 Ag Sulphide (Ag2S), 1 membrane
Measuring range: 0.04 ppm ... 40 g/l
Linear measuring range: From 10 ppm 96 74 Fluoride (F-), 1 membrane ������
Working conditions: pH 3 ... 12, 0 ... 50°C 96 75 Iodide (I-), 1 membrane
Interferences: Cation detergents, Sr2+, Ba2+, Zn2+, Mg2+, 96 76 Copper (Cu2+), 1 membrane
Li+, Cs+, Na+, K+, Rb+ and NH4+.
96 80 Calcium (Ca2+), 1 membrane
Electrolyte for the reference electrode: KCl 3M
Applications: milks, serums, soils, waters. 96 81 Potassium (K+), 1 membrane
96 82 Nitrate (NO3-), 1 membrane
96 61, Potassium K+. 96 83 Ammonium (NH4+), 1 membrane
Measuring range: 0.04 ppm ... 39 g/l
Linear measuring range: From 5 ppm
Working conditions: pH 2 ... 12, 0 ... 50°C

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Interferences: Cation detergents, Rb+, Na+, H+, NH4+, Cs+,
Mg2+, Ca2+, Ba2+, Sr2+. Spare electrolytic solutions
Electrolyte for the reference electrode: Al2(SO4)3 0.9M 96 87 Bromide (Br-), 10 ml flask, 2 units
Applications: potable waters, toothpaste, milk, etc. 96 88 Chloride (Cl-), 10 ml flask, 2 units
96 62, Nitrate NO3-. 96 89 Cyanide (CN-), 10 ml flask, 2 units
Measuring range: 0.6 ppm ... 60 g/l 96 90 Ag Sulphide (Ag2S), 10 ml flask, 2 units
Linear measuring range: From 10 ppm 96 91 Fluoride (F-), 10 ml flask, 2 units
Working conditions: pH 3 ... 12, 0 ... 50°C 96 92 Iodide (I-), 10 ml flask, 2 units
Interferences: Anion detergents, I-, Br-, F-, Cl-, SCN-,
96 93 Copper (Cu2+), 10 ml flask, 2 units
MnO4-, HCO3-, NO2-, ClO4-, SO42-.
Electrolyte for the reference electrode: : Al2(SO4)3 0.9M 96 94 Calcium (Ca2+), 10 ml flask, 2 units
Applications: fertilizers, waters, meats, vegetables. 96 95 Potassium (K+), 10 ml flask, 2 units
96 96 Nitrate (NO3-), 10 ml flask, 2 units
96 63, Ammonium NH4+.
Measuring range: 0.02 ... 18 g/l 96 97 Ammonium (NH4+), 10 ml flask, 2 units
Linear measuring range: From 5 ppm
Working conditions: pH 4 ... 7, 0 ... 50°C
Interferences: Cation detergents, K+, Na+, Li+, H+, Rb+,
Cs+, Mg2+, Ca2+, Ba2+, Sr2+.
Electrolyte for the reference electrode: Al2(SO4)3 0.9M
Applications: foodstuffs, fertilizers, boiler waters.
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Ionic Strength Adjusters (ISA’s)

Aluminium Sulphate Al2(SO4)3 0.9M.
This is the ionic strength adjuster and the reference
electrolyte for potassium-, nitrate- and ammonium-
selective electrodes
TISAB III Ionic strength adjusters, ISA
This is the ionic strength adjuster for the fluoride 99 00 TISAB III, for F- electrode, 250 ml flask
selective electrode.
99 02 Aluminium sulphate, for K+,NO3-,NH4+, 250 ml flask

Laboratory Catalogue 2004

1st Edition
 58 Ion-selective electrodes, ISE’s
(continued)

With membrane for gases 96 65, Ammonia NH3

These are combined electrodes integrating a pH
electrode. This pH electrode is immersed in an electrolyte
and separated from the solution to be measured by a
gas-permeable membrane.
The membrane and the internal electrolyte can be
replaced. That is why they are supplied in boxes of 20
membranes and a flask of 50 ml of electrolyte.
The membrane for these electrodes is PTFE and is
common for both NH3 and CO2.
No reference electrode is required.
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Measuring range: 0.1 ppm... 17 g/l
Linear measuring range: From 1 ppm
Working conditions: pH 4...13, 0... 50ºC
Interferences: volatile amines. At pH < 11, CO2, SO2,
Cl2, H2S.
Applications: waste waters, Kjeldahl.
96 66, Carbon dioxide CO2
Measuring range: 2.6 ppm ... 0.9 g/l
Linear measuring range: From 5 ppm
Working conditions: pH 1...5, 0 ... 50ºC
Interferences: volatile acids
Applications: mineral waters, wines, bacteriological
cultures.

Etc, … Spare parts

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DIN USA ���������

Note: These electrodes are

manufactured with fixed
cable and BNC connector. �Membranes
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���u.)
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Electrolyte (50 ���
ml)
They can also be supplied,
under demand, with
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another connector.
See page 60.
Price does not vary.

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Ordering information
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Code Description
Electrodes
96 65 Combined electrode (NH3), BNC connector
96 66 Combined electrode (CO2), BNC connector
IMPORTANT: Selective electrodes with membranes for gas are supplied
with 20 membranes and 1 electrolyte solution.
Spare membranes (common for both electrodes)
96 85 Set of 20 membranes for NH3 or CO2 electrodes
Spare electrolytic solutions
96 98 Ammonia (NH3), 50 ml flask
96 65 NH3
96 99 Carbon dioxide (CO2), 50 ml flask
96 66 CO2

Laboratory Catalogue 2004

1st Edition