Aiits HCT-3 Jee Adv Paper 1 Solution

ALL INDIA INTEGRATED TEST SERIES
HALF COURSE TEST – III

JEE (Advanced)-2022
PAPER –1
TEST DATE: 30-05-2021
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
SECTION – A
1. B
b
Sol. m 
T
b
 500 
TA
b
And 1500 =
TB
TA
 3
TB
UA (4rA2 )TA4
 =9
UB (4rB2 )TB4
2. A
Sol. In equilibrium vertical line passes through the centre of mass of A
2l/3
the system of three rods. 
Let O be the centre of mass. P
l/2 3 B l/2 D
In triangle AOP, tan  =  O
2l / 3 4
3 C
 Sin  =
5
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
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2
AIITS-HCT-III (Paper-1)-PCM(Sol.)-JEE(Advanced)/2022
3. A
Sol. y = 3cost + 4sint
3 4 
= 5  cos t  sin t 
5 5 
= 5 sin(t + 37°)
2
 Amplitude = 5, Period = = 3.14 s

4. B
  3m 3m
Sol. For a varying force, we must integrate: W   F  dr =  Fy dy = (2N/m3)  y dy
3
0 0
3m
1  81
 (2N / m3 )  y 4   N  m  40.5J
4 0 2
5. D
d4G R
Sol. ‘E’ at cavity due to solid =
3 2
3
d 4 R  Gd2
2
F  mE       E 
2 3 2 8
6. C
dq  dT 
Sol.  kA   = constant throughout rod.
dt  dx 
7. AD
3
Sol. 1  (2R)
4
1
2  (2R)
4
  path difference   1   2
For maxima   n

For minima   (2n  1)
2
8. CD
Sol. If 1 = 0, 2  0
t1 = 0, balancing torques about A
cos 
N1 sin  = mg
2
mg
N1 tan  =
2
3
If 1  0, 2  0
T2 = 0, equilibrium cannot be attained.
If 1  0, 2  0
N1 = t2 = 2N2 ; N2 + t1 = mg
N2 + 1N1 = mg ; N2 + 1(2N2) = mg
mg
N2 
1  1 2
9. AB
dv v2
Sol. at   2  constant ; ar 
dt R
As v increasing therefore ar is increasing
a
tan   r
at
10. BC
Sol. F.B.D. of ball in frame of container 4Vg
4Vg  Vg Y
ay   3g
V Va 4Va
L 1 L X
 3gt 2  t
2 2 3g Vg
4Va  Va
ax =  3a
V
1 2L
L 3at 2  t
2 3a
2L L
Ball to collide at point Q, t    a = 2g
3a 3g
11. BC
  
Sol. For coplanar vectors A. B  C = 0 
12. BD
1
Sol. mV 2  t  V2  t
2
dV 1
V t  
dt t
1 1
 F  F
t V
4
SECTION – C
13. 00000.57
Work done in cycle
Sol. Efficiency =
Heat added
Consider only those q of processes which come out as +ve to find heat added.
14. 00003.75
3
Sol. T = M 2L2
8
F 3 M2L2 cos2 
Stress = 
(A / cos ) 8 A
15. 00136.00
Sol. Let the bus be at O when it sends a signal that is B D C
detected by the detector as of frequency = 1500 Hz O 
 v 
 f=   1000  1500 l
 v  v B cos  
3
 cos =   = 30°
2 S
By the time signal reaches at S the bus reaches at D.
Let this time be t0
OS lcosec 
 t0 =  … (1)
v v
Now man fires and the bullet reaches C in time t1 (say). In the same time bus moves
from
D to C
l
 t1 = ; where u = speed of bullet
u
Also, OD + DC = lcot
vB t0 + vBt1 = lcot
 lcosec  
vB 
v  + vB (l/u) = lcot 
 
2 2 v
2  3
3 3 3 3u
v 5
 
u 2
2 2
 u = v   340 = 00136.00 m/s
5 5
16. 00001.80
Sol. (T + T cos 60) vw – T vb = 0
5
17. 00003.46

V v
Sol.  = 
r 
V
18. 00001.85
Sol. For equilibrium of block rod
Mg sin  = (N)
m
= (Mg cos  + mg cos )  = 0.5
30o
6
Chemistry PART – II
SECTION – A
19. D
Sol. Because Nlone pair is delocalized by reasonance.
20. C
Sol. 0.1 mole of the carbohydrate contains 1g hydrogen. 1 mole of the carbohydrate will
contain 10g hydrogen.
 The molecule should contain 10 hydrogen atoms
21. B
Sol. 2s  2p transition increases the number of unpaired electrons of carbon.
22. B
Sol.
( I ) H2C CH ( II ) CH3 CH CH3
sp2 sp2 sp 3 sp2 sp 3
( III ) CH3 CH CH3 ( IV ) H2C C CH2
sp 3 sp3 sp 3 sp2 sp sp 2
23. D
Sol. (I) CO (II) N2 (III) CN- (IV) NO+
–
All are iso electronic (contain 14e ) thus have same bond order
24. D
Sol. All has equal dipole moment
25. BCD
Sol. (A) XeF2 sp3d Linear

Br 3 sp3d Linear
(B) CO2 sp Linear
I3 sp3d Linear
(C) XeF4 sp3d2 square planar
[Ni(CN)4]-2 dsp2 square planar
(D) H2O sp3 bend
SO2 sp2 bend
26. CD
Sol.  Si > Mg > Al > Na
The I.E1 of Mg is greater than Al due to more penetrating nature of 3s orbital than 3p
orbital of Al.
7
F>N>O>C
Due to half-filled electronic configuration of ‘N’ its I.E 1 is greater than that of oxygen.
27. AB
Sol.  As the radius of cations increase, the size of hydrated radii decreases because the
ions are less hydrated on moving down group – 1
 Ionization energy decreases due to increase in atomic size and decrease in nuclear
charge.
28. ABCD
Sol. All of these are characteristics of carbocation.
29. AD
Sol. No place of symmetry so optically active
30. AC
Sol. (A) BCl  BCl (B) NH3  NH4
3 4
sp2  sp3 sp3  sp3

(C) BF3  BF3 , NH3 (D) SO2Cl2  H2SO 4
sp2  sp3 sp3  sp3
SECTION – C
31. 00006.69
(Range 6.69 – 6.70)
Sol. [OH–] = 2  10–7
pOH = -log2  10–7 = 7 – 0.3010 = 6.69
32. 00099.50
Sol. P1 = 12 atm, T1 = 300 K
P2 = 14.9 atm, T2 = ?
P1 P2 PT
  T2  2 1
T1 T2 P1
14.9  300
  372.5K  99.5o C
12
33. 00003.26
Sol. pH = 3  [H+] = 10–3
pH = 4  [H+] = 10–4
103  104
Final [H+] =   5.5  10 4
2
pH = -log 5.5  10–4 = 3.26
34. 00001.00
Sol. K = 2  10–2 mol–1sec–1
t = 25, [At] = 0.5 M, [Ao] = ?
 Ao  1 M
8
35. 00079.80
 PV 
 
ngas  RT gas TH2
Sol.  
nH2  PV  Tgas
 RT 
 H2
5.4 2 390
 
Mgas 0.14 300
5.4  2  30
Mgas   79.8
0.14  29
36. 00027.31
Sol. Rate = t[A]1/2
t75 = t½ + t3/4 = 16 + 11.31 = 27.31
of reaction
9
Mathematics PART – III
SECTION – A
37. D
1 1 2  3  sin 2  sin2  N
Sol.    (say)
1  3 sin2 1  3 sin 2 1  9 sin2 sin2  3  sin 2  sin2  D
N  2  3  sin2  sin2   2  6 sin      cos       2  2cos2       2 sin2     

D  1  3  sin 2  sin2   9 sin 2 sin2
9
 2sin2       1 
2
 cos 2       cos 2      
 2sin2       1  9 cos2       9 cos2     
 8  7cos2       9 sin2     
 8 sin2     
N 1

D 4
38. D
1
Sol. R
sin30o
1
r
tan30o
R 2
Now  sec 30o 
r 3
39. A

i
Sol. z  e4
10
1
z 5  iz  1  i  i  1   2i
2
 cos   0
40. C
Sol. 2B  A  C
 A  B  C  180o
 B  60 o
b c
From sine rule, 
sinB sinC
1 b 3
    2
sinC c sinB 3
2
2
C  45o , A  180o  B  C 
5
 75o 
12
41. C
Sol.  y  x and y   x are angle bisectors of B and C respectively
 Image of A about y = x and y = – x i.e. (7, 5) and (–7. –5) must lie on line joining B
and C
10
 equation of BC is  y  5    x  7  7y  5x
14
42. C
A
Sol.  tan 6 tan 42 tan 66 tan78
B
tan 6 tan  60  6  tan  60  6  tan18 tan  60  18  tan  60  18 
 
tan 54 tan18
tan  3  6  tan  3  18 
  1
tan 54 tan18
43. AB
1 1

Sol. x 10  x  1   x  5 2  4
1 2
1
x 10  x 
44. BD
Sol. Let the circle be x 2  y 2  2gx  2fy  c  0
given : 2f  2g  9  0  2f  2g  9 and c  4  0  c  4
 Circle is x 2  y2  2gx   2g  9  y  4  0
  x 2  y 2  9y  4   2g  y  x   0
11
 Circle passes through points of intersection of  x 2  y 2  9y  4   0 and

2g  y  x   0
On solving : y  4, 1
2
 Points are (–4, 4) and   1 , 1 
2 2  
45. ACD
2 2
 1   2  5 x  12 y  1
Sol. x    y    a 1
 13   13  13
If this represents an ellipse then
0 < |a -1| < 1
46. AB
Sol. We know, that A.M.  G.M.
a1  a2  ..........  an1  2an
 a1a 2 ......2 an 
1/n
n
a1  a2  ......  an 1  2an
  2c 
1/n
n
 a1  a2  ......  2an  n.  2c  a
1/n
 Minimum value of a1  a2  .....  an1  2an is n.  2c 

1/n
47. AB
Sol. Let S   5, 12  and S '   24, 7 
and Let P   0, 0 
 24  5    7  12
2 2
Now, SS ' 
  361  25    386 
For ellipse SP  S 'P  2a
 13  25  2a
 2a  38
 SS '  2ae
SS '  386 
 e 
2a 38
For hyperbola SP  S 'P  2a
 2a  25  13  12  a  6
SS '  2ae  12e
386  12e
386
e
12
12
48. AD
Sol. Slope of I curve  2x  a
at (1, 0), 2 + a = m1 (say)
Slope of II curve = c – 2x
at (1, 0), c – 2 = m2 (say)
For touch, m1 = m2
2ac2 …(i)
and (1, 0) is on both the curves
0  1  a  b and 0 = c – 1 ...(ii)
Solving Eqs. (i) and (ii), we get
a = –3, b = 2, c = 1
SECTION – C
49. 00000.50
A B C
4R sin .sin .sin
r 2 2 2
Sol. 
r1 4R sin A .cos B .cos C
2 2 2
B C 1
 tan .tan 
2 2 2
A B C
Now, tan  tan  tan 
2 2 2
A B A C
 tan . tan  tan . tan
2 2 2 2
B C 1 1
 1  tan . tan  1  
2 2 2 2
50. 00000.12
n 
Sol. As there is just one middle term, n must be even and middle term is   1 th term, and
2 
n/2
 1
 
n n/2
it is given by Tn/21 n Cn/2 x 2 x
 
n Cn/ 2 x n/2
Now, n Cn/ 2 x n/ 2  924 x 6
n
  6  n  12
2
[Also, note that 12 C6  924 ]
51. 00019.00
Sol. k1p  7  330
k 2p  11  486
k 3p  15  604
k1p  323  19 17 
13
k 2p  475  19  25 
k 3p  589  19  31
Hence p is 19
52. 06305.00
Sol. Sum of the coefficient of the terms not containing c is 38 and of the term not containing
b and c both is 28 , so required sum  38  28 .
53. 01533.00
Sol. x  7, y  3
xy  73
54. 00025.00
25 25 25
Sol. z  z   24  z 
z z z
25 2
 24  z   24 or 24 z  z  25  24 z
z
2 2
 z  24 z  25  0 and z  24 z  25  0
  z  25  z  1  0 and  z  25  z  1  0
 z  1  0 and z  25  0
Hence 1  z  25
or 1  z  0  25

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ALL INDIA INTEGRATED TEST SERIES

HALF COURSE TEST – III

ANSWERS, HINTS & SOLUTIONS

sp2 sp2 sp 3 sp2 sp 3

( III ) CH3 CH CH3 ( IV ) H2C C CH2

sp2  sp3 sp3  sp3

Mathematics PART – III

N  2  3  sin2  sin2   2  6 sin      cos       2  2cos2       2 sin2     

 Circle passes through points of intersection of  x 2  y 2  9y  4   0 and

 Minimum value of a1  a2  .....  an1  2an is n.  2c 

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