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KCET 2014 Previous Year Paper For Chemistry
KCET 2014 Previous Year Paper For Chemistry
Questions – Chemistry
(1) 50
(2) 20
(3) 40
(4) 60
8. X
Reductive Y Z
Ozonolysis
(2)
(3)
(4)
15. P
1. CH3MgBr
2. H O + R
1. dil. NaOH
2.
4-methylpent-3-en-2-one
3
P is
(1) ethanamine
(2) ethanal
(3) propanone
(4) ethanenitrile
16. When CH2 CH O CH2 CH3 reacts with one mole of HI,
one of the products formed is
(1) ethanol
(2) ethanal
(3) ethane
(4) iodoethene
(3)
(4)
18.
The IUPAC name of „B‟ is
(1) 2-methylbutan-3-ol
(2) Pentan-2-ol
(3) 3-methylbutan-2-ol
(4) 2-methylbutan-2-ol
x
19. For Freundilich isotherm a graph of log is plotted against log
m
P. The slope of the line and its y-axis intercept, respectively
corresponds to
1
(1) log , k
n
1
(2) log ,log k
n
1
(3) ,k
n
1
,log k
(4) n
1
20. A plot of Vs. k for a reaction gives the slope 1104 K The
T
energy of activation for the reaction is
Given R 8.314 J K 1
mol1
21. The IUPAC name of the complex ion formed when gold
dissolves in aquaregia is
(1) tetrachloridoaurate (I)
(2) dichloridoaurate (III)
(3) tetrachloridoaurate (III)
(4) tetrachloridoaurate (II)
23.
Y is
(1)
(2)
(3)
(4)
24. A g P g Q g R g , follows first order kinetics with a
half life of 69.3 s at 500 C . Starting from the gas „A‟ enclosed
in a container at 500 C and at a pressure of 0.4 atm, the total
pressure of the system after 230 s will be
(1) 1.32 atm
(2) 1.12 atm
(3) 1.15 atm
(4) 1.22 atm
MnO2 HCl Ag
25. A g F2 excess
573 K
B g
B l U s
C g D g
(4) C6H5C CH
(1) a b c
(2) c b a
(3) b c a
(4) b a c
30. The compound that reacts the fastest with sodium methoxide is
(1)
(2)
(3)
(4)
37. Among the elements from atomic number 1 to 36, the number of
elements which have an unpaired electron in their s subshell is
(1) 7
(2) 9
(3) 4
(4) 6
2
(2) Ni NH3 6 is an inner orbital complex.
2
(3) CO NH3 6 is paramagnetic.
(4) COBr2 en 2 exhibits linkage isomerism.
45. A crystalline solid XY3 has ccp arrangement for its element Y.
X occupies
(1) 33% of tetrahedral voids
(2) 33% of tetrahedral voids
(3) 66% of tetrahedral voids
(4) 66% of octahedral voids
„R‟ is
(1) sulphanilamide
(2) p-bromo sulphanilamide
(3) o-bromo sulphanilic acid
(4) sulphanilic acid
(1) i d, ii b, iii c, iv a
(2) i c, ii d, iii a, iv b
(3) i c, ii a, iii d, iv b
(4) i b, ii c, iii a, iv d
50. In which one of the pairs of ion given, there is an ion that forms
a co-ordination compound with both aqueous sodium hydroxide
and ammonia and another ion that forms a co-ordination
compound only with aqueous sodium hydroxide?
(1) Zn 2 , Al3
(2) Al3 , Cu 2
(3) Pb2 , Cu 2
(4) Cu 2 , Zn 2
59. The ratio of heats liberated at 298 K from the combustion of one
kg of coke and by burning water gas obtained from kg of coke is
(Assume coke to be 100% carbon).
(Given enthalpies of combustion of CO2 , CO and H 2 as 393.5
kJ, 285 kJ, 285 kJ respectively all at 298 K).
(1) 0.69 :1
(2) 0.96 :1
(3) 0.79 :1
(4) 0.86 :1
1 2 16 2 31 4 46 4
2 4 17 1 32 2 47 3
3 4 18 3 33 1 48 2
4 1 19 4 34 3 49 4
5 2 20 2 35 4 50 1
6 4 21 3 36 3 51 4
7 1 22 4 37 4 52 3
8 1 23 3 38 4 53 1
9 3 24 2 39 1 54 3
10 2 25 1 40 4 55 4
11 2 26 1 41 1 56 3
12 1 27 4 42 2 57 2
13 1 28 2 43 3 58 3
14 3 29 1 44 2 59 1
15 4 30 4 45 2 60 2
KCET-2014-Set-A-1
Solutions – Chemistry
PM
5. Density depends upon the ratio of
RT
In the above expression, M and R remains constant for a specific
gas.
P
Therefore, density is directly proportional to
T
0.5
(1) d 0.0183
273
4
(2) d 0.0080
500
2
(3) d 0.0033
600
6
(4) d 0.00549
1092
Therefore, the density of CO2 is maximum at a condition of 4
atm and 500 K
6. The acid strength of active methylene group depends upon the
presence of electron withdrawing groups. The electron
11. For an ideal binary liquid mixture, the value of H mix and Vmix
remains zero.
Therefore,
Gmix 0
Smix 0
15. P is ethanenitrile.
x
19. A graph of log versus P is shown below.
m
1
20. In the graph of ln K vs , the slope is equal to:
T
Ea
Slope
R
Ea
1 104
8.314
E a 8.314 104 J
(2)
(3)
(4)
K sp 1.3 106
2
1.69 1012
1.74 1012
41. The species that is not hydrolysed in water is BaO2 . All other
species undergo hydrolysis in water.
42. As we move down a group in the periodic table, the ionization
enthalpy goes on decreasing. Therefore, the correct order of first
ionization enthalpy is shown below.
B Al Tl
2
43. In the complex ion CO NH3 6 , the oxidation state of Co is
51. When Na 2SO3 (X) react with dil HCl, sulphur dioxide gas (Y) is
liberated. The reaction is as follows:
Na 2SO3 X 2HCl 2NaCl H2O SO2 Y
Sulphur is obtained when hydrogen sulphide (Z) is passed into
aqueous solution of SO2 ,i.e., H 2SO3
H 2O SO2 Y H 2SO3
H 2SO3 2H 2S Z 2S 3H 2O
H 2O
2
3+ 7
0.0591 Cr
Ecell Ecell
ο
log 14
n Cr2O72 H
0.263
log50 log H
14
0.0098
Simplify the above equation,
14
26.83 log50 log H
26.83 1.6990 14 pH
25.131 14 pH
25.131
pH 2
14
60. The equivalent of weight of Cu 2 and Fe2 are 31.77 and 27.55
respectively.
22.011
Number of gram equivalents of Cu deposited
31.77
0.698
Apply Faraday‟s Law;
Q It
140 482.5 s
67550 C
At 96500 C, 31.77 g of Cu deposited.
Therefore, at 67550 C, the mass of Cu deposited is calculated
as:
31.77
Mass of Cu deposited 67550
96500
22.239 g
Hence,
22.239 g 22.011g 0.228 g
Now, the mass of Fe deposited is calculated as:
0.228
Mass of Fe deposited 27.75
31.77
0.199 g
Mass of Fe
%of Fe 100
Amount of impurity
0.199
100
22.26
0.90