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12th Chemistry Notes
12th Chemistry Notes
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CHEMISTRY
(F.Sc Part-II)
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SHORT & LONG QUESTIONS
(It includes all previous board questions)
Chapter: 1
LONG QUESTIONS:
1. State Mandeleev’s periodic law and write down the improvements made in the Mandeleev’s table? (G-
2019)
2. Discuss various periods in the modern periodic table? (G-2011)
3. Define ionization energy. How does it vary in groups and in periods generally in periodic table? (G-2017,
2018)
4. Explain periodic trend in the following physical properties: (L-2011)
(i) Atomic radius (ii) Electron affinity
5. Define hydration energy. Discuss the relation of hydration energy with size and charge on the ions? (G-
2016, 2019) (L-2010)
6. Write a brief note on halides? (G-2013) (L-2013, 2014)
7. Define hydrides. Give their classification and properties? (G-2012) (L-2014)
8. Discuss the position of hydrogen above group I-A of the periodic table by giving three similarities and
three dissimilarities? (G-2006) (L-2012, 2016)
9. Discuss the position of hydrogen over VII-A group elements? (G-2010, 2014) (L-2012)
10. Write two similarities and two dissimilarities of hydrogen with IV-A group elements? (L-2012, 2016)
Chapter: 2
S-BLOCK ELEMENTS
SHORT QUESTIONS:
16. Give preparation of portland cement as carried out by Joseph Aspdin.Why is it named so?(L-2012)
17. How gypsum is converted into plaster of paris?
18. How plaster of paris is formed. Give its two uses? (G-2012) (L-2013)
19. What is meant by dead burnt gypsum? (G-2009)
20. Why 2% gypsum is added to cement? (G-2013, 2019) (L-2013)
21. Why calcium is essential for the normal development of plants? (G-2008, 2012)
22. How lime mortar is prepared? Explain with chemical equation.(G-2010, 2012, 2014)
23. What happens when CO2 gas is passed through lime water? Also give the chemical equation. (G-2008)
(L-2009)
24. Why lime water turns milky with CO2, but become clear with excess of CO2? (G-2013, 2016, 2019) (L-
2013)
25. Why the aqueous solution of Na2CO3 is alkaline in nature? (L-2010, 2011, 2014, 2015) (G-2018)
26. Give reason that alkali metals are strong reducing agents? (G-2016)
27. Why lime is added to acidic soil? (L-2014)
28. How lime (CaO) and sand (SiO2) are used to prepare glass? (L-2015)
LONG QUESTIONS:
Chapter: 3
LONG QUESTIONS:
Chapter: 4
1. Give examples of two important oxyacids of nitrogen while giving their structures? (G-2010)(L-2016)
2. What happens, when Cu is treated with dil.HNO3 and conc.HNO3 ?Give reactions.(G-2015, 2017)
3. Describe Ring Test for the confirmation of the presence of nitrate ions in solution? (G-2008, 2010)
4. What is laughing gas?
5. “N2O supports combustion” give two reactions in favor of the statement? (G-2014)
6. How nitrogen dioxide is prepared from: (a) Lead nitrate (b) Cu + HNO3 --→ (L-2010) OR
Write two methods for preparation of NO2? (G-2019)
7. Complete and balance the following chemical equation: (G-2008)
(a) NO + P --→ (b) NO + Cl2 --→
8. Write two chemical reactions of NO in which it behaves as reducing agent? (G-2009)
9. NO2 is a strong oxidizing agent. Prove with the help of two examples? (L-2008)
10. What is the effect of temperature on NO2? (L-2009)
11. What happens when NO2 dissolved in water? (L-2014)
12. Justify that NO is an oxidizing agent? (L-2012, 2015)
13. How does HNO2 acts an oxidizing agent? (L-2012, 2015)
14. How does HNO2 acts an reducing agent? Show it with two examples. (G-2018)
15. Give the reactions of dilute nitric acid with : (a) magnesium (b) copper (L-2006) (G-2018)
16. Write reactions of two metals which evolve hydrogen upon reaction with HNO3? (G-2014) (L-2013)
17. Write balanced equations for the equations of HNO2 with: (G-2012) i) CO(NH2)2 ii) HI
18. What is Aqua Regia? How does it dissolve noble metals? (G-2011, 2012, 2013, 2015, 2019) (L-2011,
2013, 2014)
LONG QUESTIONS:
Chapter: 5
LONG QUESTIONS:
Chapter: 6
TRANSITION ELEMENTS
SHORT QUESTIONS:
1. What are typical and non typical transition elements? (L-2008, 2014)
2. How many unpaired electrons have Cr (24) and Ag (47)? (Mention also their electronic configuration) (L-
2010)
3. Define coordination number and coordination ligand. Give one example in each case.(G-2006, 2009,
2015)
4. Define central metal atom or ion? (G-2014)
5. What is ligand? Give types of ligand? (L-2015)
6. Why transition elements have variable oxidation state? (L-2015)
7. Define “paramagnetism” and “Diamagnetism”? (G-2019)
8. What is paramagnetism? What are its units? (G-2009)
9. What is the cause of paramagnetic behavior? Why Fe+3 and Mn+2 show strong paramagnetic behavior?
(G-2014)
10. Give reason that M.P and B.P show maximum value in the middle of 1st transition series? (G-2018)
11. Give the reason for the development of the colors in the compounds of transition elements? (G-2016)
(L-2014)
12. What are chelates? Give one example.(G-2010, 2017) (L-2012, 2014)
13. What is sacrificial corrosion? (G-2015) (L-2008, 2016)
14. Write formulas of chromate and dichromate ions. In which color they usually exist? (L-2012)
LONG QUESTIONS:
1. Explain the following with example: (G-2013, 2017, 2019) (L-2004, 2006, 2011, 2012, 2013)
(a) Ligand (b) Co-ordination sphere (c) Central metal atom (d) Substitutional alloy
2. How does the electronic configuration of valence shell affects the following properties of transition
elements: (a) Binding energy (b) paramagnetism (c) melting point (G-2005) (L-2013)
3. Write down the rules for naming the metal complex compounds? (L-2006)
4. Give the reactions of K2Cr2O7 with: (a) KI (b) H2S (G-2009)
5. How does potassium permanganate reacts with the followings: (G-2014) (L-2004)
(a) H2S (b) FeSO4 (c) Oxalic acid (d) KOH
6. KMnO4 acts as an oxidizing agent. Give four reactions in support your answer? (L-2014)
7. Distinguish between cathode coating and anode coating of iron for prevention of corrosion? (G-2011) (L-
2009)
8. Explain open hearth Bessemer process for the manufacture of steel? (G-2012, 2018) (L-2011, 2012,
2014)
9. Discuss chromyl chloride test along with chemical equations? (G-2008)
10. What is corrosion? How is corrosion prevented by galvanizing and zinc coating? (L-2004)
11. What is meant by “Corrosion”? Explain electrochemical theory of corrosion. (G-2019)
12. What is the difference between wrought iron and steel? Also discuss classification of steel? (L-2006)
Chapter: 7
LONG QUESTIONS:
1. Why vital force theory was rejected? What is importance of Wohler’s work in chemistry? (G-2017)
2. Write down any four features of organic compounds? (G-2019)
3. Explain cracking of petroleum? (L-2015)
4. Describe the process of reforming? (G-2011, 2014, 2018)
5. Describe the classification of organic compounds with examples? (G-2004) (L-2013)
6. Explain any five oxygen containing functional groups with examples? (G-2011, 2013)
7. Sp3 hybridization.(L-2012, 14, 16) Sp2 hybridization.(L-2012, 15) Sp hybridization,(2014, 16)
8. What is isomerism? Describe its different types with examples? (G-2009, 2012, 2015, 2016) (L-2013)
9. What is chain isomerism? Draw all the possible skeletal formula e of hexane? (G-2019)
Chapter: 8
ALIPHATIC HYDROCARBONS
SHORT QUESTIONS:
LONG QUESTIONS:
Chapter: 9
AROMATIC HYDROCARBONS
SHORT QUESTIONS:
24. How benzene can be converted into m-chloronitro benzene? (G-2013, 2019)
25. Convert benzene into: (G-2008)
i) Cyclohexane ii) maleic anhydride iii) glyoxal
26. Convert benzene into acetophenone? (G-2011)
27. Explain sulphonation with mechanism? (G-2010)
28. What happens when Cl2 is passed through benzene in: (i) Light (ii) FeCl3? (G-2010)
29. How benzene is converted into benzoic acid?
30. Why alkene is more reactive than benzene?
31. Differentiate between benzene and toluene?
LONG QUESTIONS:
Chapter: 10
ALKYL HALIDES
SHORT QUESTIONS:
LONG QUESTIONS:
Chapter: 11
LONG QUESTIONS:
Chapter: 12
LONG QUESTIONS:
1. Write one laboratory and one industrial method for preparation of acetaldehyde? (G-2019)
2. What are aldols? Explain aldol condenstion reaction mechanism for condensation of ethanal? (L-2016)
(G-2019)
3. Explain with mechanism Cannizzaro’s reaction? (G-2015, 2016)
4. Describe the mechanism of the reaction of NaHSO3 with acetone? Ehat is the utility of this reaction.
(L-2013) (G-2018)
5. Discuss Haloform reaction with one example? (L-2012)
6. Prepare acetaldehyde cyanohydrin from acetaldehyde and then convert it into 2-hydroxypropanoic
acid? (G-2012)
7. By using propanone as starting material, how would you get: (G-2017)
i) Acetic acid ii) isopropyl alcohol
8. Discuss oxidation of aldehyde with: (L-2015) i) K2Cr2O7 / H2SO4 ii) Tollen’s reagent
9. How does acetaldehyde react with following reagents: (L-2015)
i) C2H5MgI ii) HCN iii) NaHSO3 iv) I2 / NaOH
10. How does formaldehyde reacts with: (G-2013)
i) HCN ii) NaHSO3 iii) NaBH4 / H2O iv) Conc.NaOH
11. Prepare following compounds from carbonyl compounds: (L-2013)
i) Lactic acid ii) Formaldehyde iii) Croton aldehyde iv) Ethanal oxime
12. Distinguish b /w: (a) formaldehyde& acetaldehyde (b) acetaldehyde & propanone ? (L-2012)
Chapter: 13
CARBOXYLIC ACIDS
SHORT QUESTIONS:
1. Write down structural formula of Oxalic acid, Phthalic acid & Malonic acid? (L-2012)
2. How carboxylic acids can be prepared from alkyl nitriles?
3. Prepare ethane from acetic acid by reduction with (HI /P) & (NH3.Heat) ? (L-2012)
4. How carboxylic acids are prepared by the oxidative cleavage of alkenes? (L-2013)
5. How will you convert acetic acid into: (L-2013) (G-2013)
i) Methane ii) Acetic anhydride iii) Acetone
LONG QUESTIONS:
1. How would you prepare carboxylic acid from prim. Alcohols & aldehydes? (G-2014)
2. Write down mechanism of reaction b/w acetic acid and thionyl chloride? (L-2013) (G-2013)
3. How would you prepare carboxylic acid by hydrolysis of esters & from alkali nitriles? (L-2013)
4. Write down mechanism of Esterification? (L-2012)
5. Convert acetic acid into : (G-2012) (L-2014)
i) Acetyl chloride ii) Acetamide iii) Methane
6. Write a short note on acidic and basic character of amino acids? (L-2104)
7. Give two methods of preparations & two reactions of amino acids? (L-2012)
Chapter: 14
MACROMOLECULES
SHORT QUESTIONS:
30. What are fatty acids? How acid chlorides are made from them? (L-2010)
31. What are lipids? Give two physical properties? (L-2014)
32. Discuss three chemical properties of lipids with the help of reaction? (L-2010)
33. What are fats and oils? Give examples. (L-2011, 2012, 2015) (G-2011) OR Write two points of difference
between a fat and oil? (G-2019)
34. What are carbohydrates? Why are they called so? (L-2014)
35. Draw the structure of: (i) Purine (ii) Pyrimidine (G-2017)
36. Write any three differences b/w RNA & DNA? (L-2012, 2014, 2016)
Chapter: 15
23. Ammonium nitrate is a useful fertilizer for many crops except paddy rice? (G-2011)
24. Name the four argillaceous materials used for manufacturing of cement? (G-2011)
25. Name essential constituents of cement? (L-2008, 2014)
26. Give preparation of portland cement as carried out by Joseph Aspdin, why it is named so? (L-2012)
27. Pulp formed by digestion is washed at pulp washing stage. Why is it essential? (G-2011)
28. How will you prepare diammonium phosphate from ammonia? Also indicate %age of N2 and P2O5 present
in this fertilizer? (G-2010) (L-2011)
29. How ammonium nitrate is prepared. Describe the process? (L-2013)
30. Write four main non woody and woody raw materials used in the production of pulp and paper? (G-2009)
(L-2015, 2016)
31. What do you mean by “Setting of cement”? (G-2019)
32. Give reactions taking place in first 24 hours in setting of cement? (G-2008)
33. Write equations for the preparation of : (G-2008) (L-2015)
(a) Ammonium carbamate from ammonia (b) urea from ammonium carbamate
34. How diammonium hydrogen phosphate is prepared? Give its composition. (L-2009)
Chapter: 16
ENVIRONMENTAL CHEMISTRY
SHORT QUESTIONS:
LONG QUESTIONS:
1. What is smog? Give its types and conditions for the formation of a smog. (G-2008, 2012, 2013, 2017, 2019)
(L-2010, 2013, 2015)
2. Discuss acid rain. How does it affects our environment? (G-2011, 2018, 2019) (L-2006, 2009, 2013)
3. How pesticides are dangerous to human beings? Comment. (G-2014)
4. Discuss ozone as blessing. How is it destroyed by CFCs? (G-2004, 2010)
5. Name the components of environment, Give approximate composition of atmosphere and lithosphere?
(L-2014)
6. Write method for purification of water. Explain the process of disinfection of water by chlorine? (L-2004,
2012)
7. How the industrial solid wastes are incinerated? (G-2009) (L-2011)