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Solar Energy Materials & Solar Cells 95 (2011) 1188–1192

Contents lists available at ScienceDirect

Solar Energy Materials & Solar Cells


journal homepage: www.elsevier.com/locate/solmat

On the ultra-miniaturization of concentrator solar cells


Alexis Vossier 1, Baruch Hirsch 1, Eugene A. Katz 2, Jeffrey M. Gordon n,3
Department of Solar Energy and Environmental Physics, Jacob Blaustein Institutes for Desert Research, Ben-Gurion University of the Negev, Sede Boqer Campus 84990, Israel

a r t i c l e i n f o a b s t r a c t

Article history: The trend of cell miniaturization in concentrator photovoltaics (CPV) – currently in mm-scale and
Received 28 September 2010 motivated by efficiency improvements linked to reduced series resistance – begs the question whether
Received in revised form fundamental energetic considerations limit ultra-miniaturization. Mitigating factors subsume the
28 December 2010
busbars and metallization grid, the contributions of which embody subtle tradeoffs and vary non-
Accepted 29 December 2010
Available online 15 January 2011
trivially as cell size is reduced – evaluated via a distributed circuit simulation model, with some
supporting experimental evidence. Concurrently, the influence of cell size on how metal grid design can
Keywords: lower series resistance is assessed, prompted by micro-concentrators that completely eliminate grid
Photovoltaics shadowing and allow far greater metallization coverage.
Concentrator
& 2011 Elsevier B.V. All rights reserved.
Miniaturization
Solar
Multijunction
Metallization

1. Introduction (typically optimized for irradiance values of order 102–103 suns,


with 1 sun¼1 mW/mm2)? If so, to what degree of miniaturiza-
Series resistance losses constrain concentrator solar cell per- tion? The architecture considered is that of current state-of-the-
formance at high irradiance [1], with smaller cells incurring lower art ultra-efficient (  40%) III–V alloy 3-junction cells (e.g., [4]).
losses (since cell current scales with active area). Do basic
energetic considerations limit cell ultra-miniaturization? The
dominant factors in addressing this question are: (a) busbars 2. Description of the model
consume a progressively larger fraction of gross cell (chip) area at
smaller photo-active areas, with the affiliated parasitic loss from The solar cell model here is based on distributed elementary
the unilluminated area and (b) the metal grid that embodies a circuit units [5,6] (Fig. 1), each treated as an equivalent non-ideal
tradeoff between shadowing losses and series resistance [2,3]. photodiode, for which the current density J as a function of
The latter prompts revisiting the value of micro-concentrators that voltage V can be expressed as
attach to the cell surface and can completely obviate grid shadowing  qðV þ IRs Þ  V þIR
by redistributing the flux between the metal fingers. They were also J ¼ Jph Jo e nkT 1  ð1Þ
viewed to allow cells to be redesigned for higher metallization Rsh
coverage (at no incremental optical loss) in order to reduce cell series where T is cell temperature, k is Boltzmann’s constant, q is
resistance [2]. But the competition between diminished series resis- the electron’s charge, Jph is the photo-generated current density
tance and greater parasitic dark regions beneath the widened metal (proportional to irradiance), Jo is the dark current density, n is the
fingers remained unresolved, and will also be scrutinized here. diode ideality factor and Rs and Rsh refer to lumped-parameter series
Will cell efficiency improve by decreasing cell area well below and shunt resistances, respectively. The approximation of a single
the 1 mm2 value to which commercial CPV has evolved value of Jo and a single value of n is valid as long as the voltage drop
across the cell surface is small compared to kT/q (E25–30 mV for
CPV). The input parameters are diodes, resistors and current gen-
n
Corresponding author. erators, rather than the explicit material properties required for the
E-mail address: jeff@bgu.ac.il (J.M. Gordon). alternative finite-element approach, which are based on solving the
1
These authors contributed equally to this work. basic semiconductor equations after one defines device architecture.
2
Also at: The Ilse Katz Institute for Nanoscale Science and Technology, The three types of elementary units in the model are (Fig. 2):
Ben-Gurion University of the Negev, Beersheva 84105, Israel.
3
Also at: The Pearlstone Center for Aeronautical Engineering Studies,
Department of Mechanical Engineering, Ben-Gurion University of the Negev, (1) Illuminated area, with inhomogeneous flux maps simulated
Beersheva 84105, Israel. by varying Jph among sub-elements. Ohmic losses have two

0927-0248/$ - see front matter & 2011 Elsevier B.V. All rights reserved.
doi:10.1016/j.solmat.2010.12.053
A. Vossier et al. / Solar Energy Materials & Solar Cells 95 (2011) 1188–1192 1189

Fig. 1. Model of the 3-junction cell based on three types of distributed circuit units (busbar, illuminated area and fingers). R denotes resistance, Iph is the photocurrent and
D a diode. For clarity, only the equivalent circuits associated with the top InGaP junction plus the busbar and fingers are shown. The equivalent circuits for the lower
junctions are similar, with the electrical connection between them via resistors representing the tunnel diodes.

Fig. 2. Surface geometry of square, nominally 1, 0.2 and 0.1 mm cells, all with two 0.1 mm-wide busbars. Imposing a typical metal finger width and spacing of 0.010 and
0.090 mm, respectively, constrains a cell’s actual active width (Tables 2 and 3).

Table 1
Materials and resistances in the 3-junction InGaP/InGaAs/Ge cell model.

Layer Material Dopant Dopant density Thickness, Resistivity, Lateral resistance, Vertical contribution,
(cm  3) t (mm) r (O mm) r/t (O) rt (O mm2)

Metallization Ag/Au/AuGe N/A N/A 5 E0 E0 1  10  3


Window AlInP N 4  1017 0.025 1.2 4808 3  10  6
Emitter GaInP N 2  1018 0.100 0.31 313 3.1  10  6
Base GaInP P 1.5  1017 0.500 120 23 810 6  10  3
Emitter GaAs N 1  1018 0.100 0.074 74 7.4  10  7
Base GaAs P 18  1016 3.500 20 558 6.8  10  3
Emitter Ge N 2  1019 0.200 0.0082 4 1.6  10  7
Base Ge P 3  1017 140 1.1 0.8 1.6  10  2
1190 A. Vossier et al. / Solar Energy Materials & Solar Cells 95 (2011) 1188–1192

vertical (Rvert_base, Rvert_emitter) and two lateral components to the other loss mechanisms. Furthermore, the minimal cell
(Rlat_base, Rlat_emitter) with an additional window resistance size deduced below would only increase when edge recombina-
Rwindow for the top (InGaP) layer. A single diode simulates all tion is not insubstantial because its relative contribution (peri-
recombination losses. meter-to-area ratio) increases as the cell is miniaturized.
(2) Busbars: The resistive network (devoid of current generation) (b) Adequacy of a 2D simulation: The chief advantage of a 3D
is similar to that for the illuminated area, but with an simulation would be superior accounting for resistive losses
additional resistance Rfront_contact to account for the voltage in the fingers. For mm-scale (or smaller) cells, finger resistive
drop at the metal-semiconductor interface. Lateral current in losses are usually modest because of low current per finger
the busbar flows through resistor Rbusbar. and short finger length. Typically, the voltage drop along the
(3) Fingers: similar to the units used for the busbar, but exchan- fingers will not exceed 5–10 mV for a 1 mm2 cell even at
ging Rbusbar with resistor Rfinger to simulate current flow along 10,000 suns. Consequently, invoking a lumped finger resis-
the fingers. tance rather than a distributed one (i.e., using a 2D instead of
a 3D model) will not affect the results significantly.
(c) The voltage drop for current flow through a tunnel diode is
The choice of material properties and component resistances,
taken to vary linearly with current density, with an equivalent
summarized in Table 1, was guided by [7], and is commensurate
resistance calculated from the slope of its current–voltage
with champion cell efficiencies of  40% at 500 suns for an active
curve in the tunneling regime. Here, a value of 0.4 O mm2 is
area of  25 mm2 [4]. The template considered here has a square
used for both tunnel junctions, and cell current densities are
active region, with two 0.1 mm-wide busbars (see Fig. 3).
assumed not to exceed the tunnel diode threshold [8].
(Throughout, ‘‘active’’ area refers to the irradiated region that
includes the metal fingers but does not include the busbars.)
The additional modeling assumptions are:
3. Impact of cell size
(a) Negligible edge recombination: primarily based on the cells
operating at high irradiance where edge losses are small relative First, the width and spacing of the fingers were taken as fixed
parameters typical of commercial CPV cells: 0.010 and 0.090 mm,
respectively (Fig. 2). The simulated efficiency and fill factor (FF being
0.5 the solar cell parameter most sensitive to series resistance) of a
3-junction cell are plotted in Fig. 3 as a function of flux concentra-
tion for a nominal cell linear dimension from 10 down to 0.1 mm.
0.4
The peak performance values are listed in Table 2.
The basis for improved performance (Fig. 3) is fundamentally
0.1 mm
0.3 0.2 mm different at the larger and smaller ends of the size scale. As cell size
Efficiency

0.5 mm decreases from 10 to 1 mm, the efficiency gain derives mainly from
1 mm
5 mm lower resistive losses, as reflected in the reduction in FF at irradiance
0.2 10 mm values above the order of 102 suns. However, the insensitivity of FF to
cell size below 1 mm indicates that the area-dependent contribution
of series resistance becomes negligible compared to other contribu-
0.1 tions (e.g., resistances associated with the bulk or tunnel junction).
Stipulating 0.1 mm-wide busbars imposes a substantial non-
0.0 active area for the smallest cells. Simulations for the sub-mm cells
revealed an insensitivity of efficiency to busbar widths as narrow as
1 10 100 1000 10000
Flux concentration (suns)
Table 2
Peak performance for assorted cell sizes covering 6 orders of magnitude in active
1.0 cell area.

Nominal active Actual active cell Number of Metal grid Maximum


cell width (mm) width (mm) metal fingers shadowing efficiency
0.8
0.1 mm 10 9.990 99 0.099 0.382*
0.2 mm 5 4.990 49 0.098 0.387
0.6 0.5 mm 1 0.990 9 0.091 0.393
Fill factor

1 mm 0.5 0.490 4 0.082 0.398


5 mm 0.2 0.190 1 0.053 0.416
10 mm 0.1 0.100 0 0 0.443
0.4
n
Ratio of short-circuit current to solar input power ¼0.164 A/W.

0.2
Table 3
Front-contact grid geometries simulated for a nominal active cell width of 1 mm.
0.0 The base case analyzed in Section 3 is Design B.
1 10 100 1000 10000
Case Photo-active Finger width Inter-finger Metal grid
Flux concentration (suns) width (mm) (mm) spacing (mm) coverage

Fig. 3. (a) Efficiency and (b) FF of the 3-junction cell as a function of flux concentration A 0.995 0.005 0.095 0.045
for a broad range of cell sizes. Efficiency first improves with concentration because of B 0.990 0.010 0.090 0.091
the fundamental increase of open-circuit voltage with irradiance, but then worsens C 0.975 0.025 0.075 0.231
when high irradiance amplifies resistive losses. At fixed flux concentration, efficiency D 0.950 0.050 0.050 0.474
and FF consistently improve (but then plateau) as the cell is miniaturized.
A. Vossier et al. / Solar Energy Materials & Solar Cells 95 (2011) 1188–1192 1191

0.02 mm. Hence the 0.1 mm busbar width was retained for uni- chief contribution to cell series resistance [9]), but, for the 1 mm2
formity of comparison, cognizant that far higher ratios of net-to- cell, the calculations show the energetic benefit to be negligible
gross area should not introduce perceptible performance penalties. up to  1000 suns. Efficiency actually worsens at higher flux
As cell dimension further decreases to the order of 0.1 mm, the density, deriving almost completely from a reduced FF. The
principal energetic benefit of miniaturization stems from lower insensitivity of cell performance to thicker metal fingers (at least
shadowing losses of the active area (Table 3, Fig. 2, and recall that up to 1000 suns) might actually be beneficial by relaxing the
the metal finger width and spacing are fixed). Since the need for tolerances in front-contact deposition processes.
the metal grid vanishes when cell size reaches  0.1 mm (and The results for the 1 mm2 cell indicate that the cell’s resistive
since the benefit of reduced series resistance with miniaturization losses (proportional to the square of the current, and heightened
asymptotes at cell widths of  1 mm), there appears to be no at high irradiance due to the increase in local concentration with
incentive for yet smaller cells. micro-concentrators) dominate at averaged concentration values
above 1000 suns, and militate against the benefit of greater
metal coverage.
4. Influence of metal grid dimensions The scale dependence of the problem reveals different conclu-
sions for the 100 mm2 cell, where increased metal coverage can
The geometry of the front-contact grid signifies the tradeoff reduce overall resistive losses non-negligibly. To wit, cell effi-
between shadowing and resistive losses. However, the introduc- ciency at 500 suns improves noticeably (10% relative) as metal
tion of micro-concentrators that obviate essentially all grid coverage increases from 5% to 10%, but with no improvement for
shadowing by redistributing the concentrated flux on photo- greater coverage (Fig. 4c and d). This relative improvement
active regions between the metal fingers [2] (without modifying increases with irradiance, and actually peaks at a metal coverage
the total cell flux) focuses the analysis on the non-optical aspects of  25% at flux concentration values of order 103—a consequence
of grid design. Micro-concentrators create the possibility of of the tradeoff between reduced grid resistance versus greater
redesigning for higher metallization coverage. The issue is non- dark current area. (It should be noted that practical consi-
trivial because expanded metallization both reduces series resis- derations related to passive heat rejection capabilities and
tance and incurs losses due to more parasitic dark area. accommodating exceptionally high amperage will likely restrict
To isolate the impact of higher metal coverage, a second set of 100 mm2 cells to flux concentration values not exceeding
simulations was run for a cell with a nominal active area of 1 mm2,  103 suns.)
comprising 9 metal fingers of variable width and spacing, as
summarized in Table 3. The simulated conversion efficiency and FF
of these 4 configurations are plotted in Fig. 4(a) and (b) as a function
of averaged flux concentration, i.e., total flux divided by total active 5. Summary and conclusions
cell area (which includes the metal fingers but not the busbars).
Decreasing the spacing between the fingers leads to an The principal finding is how a balance of energetic incentives
improvement in the sheet emitter resistance (that comprises a favors cell miniaturization, but not below active cell linear

0.5 1.0
nominal 1 mm active width nominal 1 mm active width
0.4 0.8
metal coverage:
Efficiency

Fill factor

0.3 0.6 0.045


metal coverage: 0.045 0.091
0.091 0.231
0.2 0.231 0.4 0.474
0.474
0.1 0.2

0.0 0.0
1 10 100 1000 10000 1 10 100 1000 10000
Averaged flux concentration (suns) Averaged flux concentration (suns)

0.5 1.0
nominal 10 mm active width nominal 10 mm active width
0.4 0.8
Efficiency

Fill factor

0.3 0.6
metal coverage: 0.050 metal coverage: 0.050
0.2 0.099 0.4 0.099
0.248 0.248
0.497 0.497
0.1 0.2

0.0 0.0
1 10 100 1000 10000 1 10 100 1000 10000
Averaged flux concentration (suns) Averaged flux concentration (suns)

Fig. 4. Performance sensitivity to metal coverage for an InGaP/InGaAs/Ge 3-junction cell. In all instances, a micro-concentrator totally obviates grid shadowing losses,
which is why the efficiencies in Fig. 4 are higher than corresponding values in Fig. 3. (a) Efficiency and (b) FF for the nominal 1 mm2 cell as a function of averaged flux
concentration for the 4 metal grid geometries noted in Table 3. Cell performance is insensitive to metal coverage up to  1000 suns and then worsens as metal coverage
increases. The sensitivity of open-circuit voltage to metal coverage (not shown) turned out to be insignificant up to 1000 suns and barely a 3% (relative) effect at
10,000 suns. (c) and (d) The same exercise performed for the 100 mm2 cell, illustrating a tangible benefit of increased metallization.
1192 A. Vossier et al. / Solar Energy Materials & Solar Cells 95 (2011) 1188–1192

dimensions of  0.1 mm, deriving from the combination of the fingers, as well as the increased current density in the
irradiated strips, was evaluated. Although greater metal coverage
(a) the reduction in cell resistive losses asymptoting with minia- can benefit cm-scale cells, for mm-scale (or smaller) cells, no
turization at a cell width of  1 mm, energetic benefit was found and, at flux concentration values of
(b) the optical gain due to the lessening of grid shadowing losses order 103 suns, cell efficiency actually worsens with greater metal
with miniaturization, but with coverage.
(c) the need for a metal grid becoming insignificant below an
active cell width of  0.1 mm.
Acknowledgment
Evaluating the economics of cell miniaturization as part of a
full CPV system analysis can be performed with software Baruch Hirsch is the recipient of a Howard and Lisa Wenger
packages such as Ref. [10]. Usually, the relative costs of system graduate scholarship.
components (and hence conclusions about nominally optimal
configurations) are case-specific [11]. At high concentration, References
where the cells comprise a small fraction of total system cost,
an increase in that fraction may not impact the economic balance. [1] K. Nishioka, T. Takamoto, T. Aguib, M. Kaneiwa, Y. Uraoka, T. Fuyuki,
However, as cells are miniaturized, in addition to the worsening Evaluation of InGaP/InGaAs/Ge triple-junction solar cell and optimization of
solar cell’s structure focusing on series resistance for high-efficiency con-
ratio of active-to-gross (chip) area and greater waste in the centrator photovoltaic systems, Sol. Energy Mater. Sol. Cells 90 (2006)
process of cutting smaller cells from parent wafers, the number 1308–1321.
of lead wires, micro-wire bonds, bypass diodes, heat-sink bonds [2] O. Korech, E.A. Katz, J.M. Gordon, D. Feuermann, N. Eisenberg, Efficiency
enhancement in concentrator solar cells by dielectric micro-concentrators,
and optical components increases in proportion to the reciprocal Opt. Lett. 32 (2007) 2789–2791.
of active cell area, which may represent non-negligible incre- [3] G.S. Kinsey, M. Haddad, R.R. King, R.A. Sherif, N.H. Karam, Optimization of
mental costs, in particular when cell area decreases to the order of high-concentration multijunction solar cells, in: Proceedings of the Interna-
tional Conference on Solar Concentrators for the Generation of Electricity or
10  1–10  2 mm2. Conversely, miniaturization also creates the
Hydrogen, Publ. NREL/CD-520–38172 (2005).
possibility of more compact, less expensive concentrator optics, [4] W. Guter, J. Schöne, S.P. Philipps, M. Steiner, G. Siefer, A. Wekkeli, E. Welser,
with less expensive optical fabrication and packaging E. Oliva, A.W. Bett, F. Dimroth, Current-matched triple-junction solar cell
technologies—crucial because the optics can constitute about half reaching 41.1% conversion efficiency under concentrated sunlight, Appl. Phys.
Lett. 94 (2009) 223504.
of total system cost [11]. Accordingly, while noting these con- [5] K. Nishioka, T. Takamoto, T. Agui, M. Kaneiwa, Y. Uraoka, T. Fuyuki, Evalua-
siderations, this study focuses on the energetic pros and cons of tion of InGaP/InGaAs/Ge triple-junction solar cell under concentrated light by
cell miniaturization. simulation program with integrated circuit emphasis, Jpn. J. Appl. Phys. 43
(2004) 882–889.
To our knowledge, there have been no systematic fabrication [6] B. Galiana, C. Algora, I. Rey-Stolle, I. Garcı́a-Vara, A 3D model for concentrator
studies along these lines; but recent data illuminate the trends. solar cells based on distributed circuit units, IEEE Trans. Electron Dev. 52
Specifically, for concentrator cells where the basic cell architec- (2005) 2552–2558.
[7] C.G. Zimmermann, Utilizing lateral current spreading in multi-junction solar
ture was maintained, but active cell area was reduced from 100 to cells: an alternative approach to detecting mechanical defects, J. Appl. Phys.
1 mm2: (1) the irradiance at which efficiency peaks increased 100 (2006) 023714.
from  300 to 1000 suns and (2) peak efficiency rose by a few [8] A. Braun, B. Hirsch, E.A. Katz, J.M. Gordon, W. Guter, A.W. Bett, Localized
irradiation effects on tunnel diode transitions in multi-junction concentrator
percent relative [12–14] (note the corresponding predictions in
solar cells, Sol. Energy Mater. Sol. Cells 93 (2009) 1692–1695.
Fig. 3a). [9] C. Algora, V. Diaz, Influence of series resistance on guidelines for manufacture
In contrast, recent findings [15,16] for thin-film Cu(In,Ga)Se2 of concentrator p-on-n GaAs solar cells, Prog. Photovoltaics 8 (2000)
211–225.
(CIGS) photovoltaics indicate that both cell efficiency and the
[10] P. Gilman, N. Blair, M. Mehos, C. Christensen, S. Janzou, C. Cameron, Solar
irradiance at which efficiency peaks increase even as cell size is Advisor Model User Guide for Version 2.0, National Renewable Energy
reduced to the scale of microns – albeit at flux densities and Laboratory Technical Report NREL/TP-670-43704, Golden, CO, 2008.
efficiencies far below those of the concentrator cells addressed [11] G.D. Conley, S.J. Horne, SolFocus Inc., 510 Logue Ave., Mountain View, CA
94043, personal communications and company technical reports, 2008.
above. The series resistance of CIGS cells is dominated by the [12] O. Korech, B. Hirsch, E.A. Katz, J.M. Gordon, High flux characterization of
limited conductivity of the transparent conducting oxide window ultrasmall multi-junction concentrator solar cells, Appl. Phys. Lett 91 (2007)
layer, so the vertical contribution to series resistance is negligible 064101.
[13] E.A. Katz, J.M. Gordon, W. Tassew, D. Feuermann, Photovoltaic characteriza-
compared to the lateral one. However, the vertical component of tion of concentrator solar cells by localized irradiation, J. Appl. Phys. 100
series resistance is not negligible in the high-irradiance cells (2006) 044514.
analyzed here – due to contributions from the tunnel diodes [14] R.R. King, R.A. Sherif, G.S. Kinsey, C.M. Fetzer, K.M. Edmonson, D.C. Law, H.L.
Cotal, D.D. Krut, J.H. Ermer, N.H. Karam, Bandgap engineering in high-
and the Ge sub-cell – such that miniaturization below 0.1 mm efficiency multijunction concentrator cells, in: Proceedings of the Interna-
offers no energetic advantage. tional Conference on Solar Concentrators for the Generation of Electricity or
A related issue was whether exploiting micro-concentrators Hydrogen, Scottsdale, AZ, NREL/CD-520-38172, 2005.
[15] M. Paire, L. Lombez, J.F. Guillemoles, D. Lincot, Toward microscale
(flux redistributors that attach to the cell surface and can
Cu(In,Ga)Se2 solar cells for efficient conversion and optimized material
completely eliminate grid shadowing losses) to increase metalli- usage: theoretical evaluation, J. Appl. Phys. 108 (2010) 034907.
zation coverage can improve cell efficiency by reducing series [16] M. Paire, L. Lombez, N. Péré-Laperne, S. Collin, J.L. Pelouard, J.F. Guillemoles,
resistance, as posited in Ref. [2]. The non-trivial tradeoff between D. Lincot, Microscale Cu(In,Ga)Se2 solar cells for concentration: a path to 30%
efficiency—theoretical evaluation and first experimental results, in: Proceed-
the benefit of more front-contact metal (at no shadowing loss) ings of the 25th European Photovoltaic Solar Energy Conference, 2010,
and the penalty of a larger dark current from the regions beneath 2872–2876.

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