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General Chemistry Reviewers: 2nd Quarter

- Developed by Niels Bohr


LESSON #1: QUANTUM NUMBERS - Electrons orbit the nucleus at
AND ELECTRON CONFIGURATION
fixed energy levels
MODELS OF AN ATOM: - Electrons can gain more energy

Quantum Model
- Developed by Erwin Schrödinger
- The possibility of placing
electrons within an atom by
describing the principal energy
level, energy level, orbital
Solid Sphere Model
(arbitrary level), and spin of.
- Developed by John Dalton
- Wave Mechanical Model
- First atomic model
- Electrons can act as a wave
- An atom is a solid sphere that
(Electron clouds)
could not be divided into smaller
particles.
QUANTUM NUMBERS:
Principal Quantum Number
Plum Pudding Model - Electron Cloud Size (n)
- Developed by J.J. Thomson - Main energy level occupied by
- Also known as Thomson’s Plum the electron
Pudding Model - Integer values n = 1, 2, 3,….
- Historical scientific model of atom - bigger n value = higher energy
- Defined by electrons surrounded - All electrons in an atom with the
by a volume of positive charge, same value of n belong to the
like negatively-charged “plums” same shell/level
embedded in a positively-charged
n Shell n Shell
“pudding” Name Name
- Electrons, Protons, and Neutrons 1 K 5 O
2 L 6 P
Planetary Model 3 M 7 Q
- Developed by Ernest Rutherford 4 N
- Electrons are arranged in
concentric circular orbits around Angular Momentum Quantum Number
the nucleus - Shape of Electron Cloud (I)
- Gold-foil experiment - Also known as sublevel or subshell
- Nucleus (atom) - Shape of the orbital within a shell
- electrons (-) are in orbits - Only integer values between 0
- protons (+) and neutrons are and n-1 are allowed
inside the nucleus - bigger l = higher energy
- Energy enters the nucleus - All electrons in an atom with the
same value of l are said to belong
Bohr Model to the same subshell
General Chemistry Reviewers: 2nd Quarter

-orbital azimuthal quantum Spin Quantum Number


number - Direction of spin (s)
Spectroscopists use the following notation - Spin makes the electron behave
for subshells like tiny magnets
l Subshell Name
- Opposite spin attracts e-
0 s (sharp)
to each other & helps
1 p (principal) overcome the negative
2 d (diffuse) repulsion they have for
3 f (fundamental) each other
- Allows them to exist in the
It is possible for an atomic orbital to exist
beyond s, p, d, f orbital. Like g, h, i … same orbitals
orbital. - Spin can be clockwise or
counterclockwise
Magnetic Quantum Number
- Orientation in space of orbitals - Can have values of +½ or -½
EXAMPLE:
(ml)
- Orientation of orbitals within a
subshell
- Does not affect orbital energy
(except in magnetic fields)
- Only integer values between –l
and +l are allowed 4p5
↑↓ ↑↓ ↑
l Possible Values # Orbitals n = l = ml = ms =
of ml 4 1 0 -½
0
(s) 0 1=2 -1 0 +1

n= energy level (4)


1 (p) -1, 0, +1 3=6
l = p(l) which means p(1)
2
(d) -2, -1, 0, +1, +2 5 = 10 ml = between -l and +l (0)
ms = when the last arrow is facing down
3 (f) -3, -2, -1, 0, +1, 7 = 14 automatically the answer should be -½
+2, +3

Atomic Orbitals Orbital Diagram


- Shows the spin of electrons
- Region in space where there is a
- Arrow up is +½
high probability of finding an - Arrow down is -½
electron
Ground State
- Shapes
- Lowest energy state of an atom
- s – spherical
- p – dumbbell-shaped Excited State
- d & f – complex shapes - An atom has a higher potential
energy

Degenerate Orbitals
- Two or more orbitals that have the
same energy
Electron arrangement determines the
chemical behavior of atoms
- Subatomic parts are the electrons
General Chemistry Reviewers: 2nd Quarter

- Can receive or gain - Contain unpaired electrons or spins and


are attracted by a magnet
Orbital Notation ● Diamagnetic Materials
- Orbital is represented by aline, - Contain paired spins are repelled by a
with the orbital’s name written magnet
under the line and the electrons
are represented by arrows

ELECTRON CONFIGURATION (RULES) Representing Electron Configuration


- Electron configuration notation
Pauli’s Exclusion Principle - Highest occupied level
- Wolfgang Pauli ○ Electron-containing main
- No two electrons can have the energy level with the
same set of quantum numbers highest principal quantum
- An atomic orbital contains a number
maximum of two electrons with ○ Similar chemical properties
opposite spin come from similar valence
○ Last quantum number will electrons
be different - Inner shell electrons
○ Must have one up arrow ○ Electrons that are not in
and one down arrow the highest occupied
○ Arrows should be up and energy level
down
Electron configurations can be written
Aufbau Principle in terms of noble gases
- Niels Bohr I. Instead of writing out the long
- When predicting an atoms ground configurations that some of the
state electron configuration, larger elements would have, you
electrons will occupy the lowest can abbreviate by using the
energy orbital available first closest smaller noble gas to the
- Diagonal Diagram element in question to replace
- “Building Up” most of the electron configuration.
- Lowest to highest energy
- Order of energies: s < p < d < f II. Only noble gases can be used.
Exceptions to Rules
a. A full level is the next stable thing
Hund’s Rule
to a full level
- Friedrich Hund
b. Some atoms will violate our
- “The most stable arrangement of
predictions in order to achieve
electrons in the subshells is the
stability. This can occur in the
one with the most number of
transition metals when the
parallel spins”
predicted configuration ends in a
- “Empty bus seat rule”
d4 or d9
● Paramagnetic Materials c. It will steal a single electron from
the ful s shell that came before it
General Chemistry Reviewers: 2nd Quarter

to obtain 2 half full shells or one - Electron Dot Structure


half and one full shell. - is a quick and easy diagram that
d. s2 d4 becomes s1 d5 and s2 d9 shows the valence electrons in an
becomes s1 d10 element.
- the nucleus of the element is
IMPORTANT DATA THAT COULD BE represented by its symbol.
GATHERED FROM THE SHORTENED E
CONFIG: - The valence electrons are
represented by dots placed
Valence Configuration around the symbol in pairs.
- Electronic configuration
HOW TO DRAW A LEWIS STRUCTURE:
representing the outermost
1. Look at the element you want to
subshells
draw the structure dot and see
what group it is in
Valence Electrons
2. Draw dots around the symbol
- Number of electrons in the
according to how many valence
outermost subshells
electrons it has
- Group number = valence electrons
Rule#1: No side can have more than two
dots because each orbital can only hold
two electrons.

Rule#2: When filling the sides of the


element symbol each side gets one dot
before doubling up. Exceptions are
hydrogen and helium.

ELECTRON DOT DIAGRAMS OF IONS:

LESSON #2: LEWIS DOT STRUCTURE


- Gilbert Lewis
○ noticed something
interesting about elements
that were very stable.
- Complete period of orbitals
- 8 valence electrons ● Dots are less for cations & more
- Nobles gases for anions than the corresponding
- Core electrons atom.
EXAMPLE:
○ Electrons not in the
outermost shell

Noble Gas Stability


- Atoms want to gain stability
- Atoms will try to gain or lose
electrons to have a full valence
shell
- Metals try to lose electrons
- Non-metals try to gain electrons
Lewis Theory
-
- G.N. Lewis (1875-1946) recognized
Oxidation number
atoms tend to acquire a noble-gas
- Represents the number of
electronic configurations and
electrons an atom will typically
valence (outmost) electrons is
gain or lose to achieve the octet
fundamental for bonding:
Lewis Dot Structure
General Chemistry Reviewers: 2nd Quarter

- electron transfer resulting ● Two atoms held together by


in ionic bonds sharing a pair of electrons are
- sharing electrons resulting joined by a single covalent bond.
in covalent bonds
Octet Rule
- says that atoms like to have full
outer shells of only eight electrons.
- Atoms will lose or gain valence
electrons to make their outer
shells full with eight electrons, and
they do this by bonding with other
atoms.

Non-bonding/ Unshared/ Lone pairs


- Some electrons are already paired
up within a single atom and are DRAWING LEWIS STRUCTURES:
not shared. 1. Add valence e–’s of all atoms.
(Number of valence electrons are
ADDING OR REMOVING ELECTRONS: found on the Periodic Table)
- You always want to do the least
amount of effort. Choose to add
or remove electrons based on how
many electrons you would need to
move to get to 8.

2. Surround Central Atom with


Outer Atoms.

Central atom is the least electronegative


atom. (The element furthest to the left on
the Periodic Table; except Hydrogen… H
can never be the central atom)
Covalent Bonding
- the Sharing of Electrons between
Nonmetals.

3. Connect all atoms to the central


atom with single bonds.

Ionic Bonding
- the Transfer of Electrons between
a Metal and a Nonmetal.

4. Fill the octets of the outer


atoms.
General Chemistry Reviewers: 2nd Quarter

- The atom which contributes the


5. Place the remaining electrons electron pair is called the donor,
on the central atom to fill its
octet. while the atom which accepts it is
called the acceptor.

● The nitrogen atom in ammonia


has a full outer shell, with a lone
pair which it can donate.
6. If you run out of e–’s before the ● The boron atom in boron
central atom has an octet… trifluoride is short of two electrons
…form multiple bonds until which it accepts to attain a full
it does. outer shell.

Multiple bonds are formed EXAMPLES OF DATIVE COVALENT BOND:


FORMATION OF AMMONIUM ION
by moving unshared electrons into
a sharing position.

A CARBON DIOXIDE MOLECULE HAS TWO ● The hydrogen ion, H+, has no
CARBON-OXYGEN DOUBLE BONDS: electrons and accepts a lone pair
donated by nitrogen.
Double Covalent Bond ● After accepting the lone pair,
- Is a bond that involves two hydrogen has a full outer shell.
shared pairs of electrons.
EXCEPTIONS TO THE OCTET RULE:
Triple Covalent Bond 1. Incomplete octet
- Is a bond formed by sharing three - Rare
pairs of electrons. - Usually with B and Be
- Molecules have only 6 electrons
around central atom

2. Odd numbered electrons


- Relatively rare
- Quite unstable
- Reactive
- E.g. NO = 11 VE
- NO2 = 17 VE
Co-ordinate / Dative Covalent Bond
- special type of covalent bond in 3. Expanded Octets
which both the shared electrons - Elements in period 3 and beyond
(P, As, S, Se, Te, Cl, Br, I, At)
are contributed by one atom only.
- The covalent bond is
represented by an arrow (→)
pointing towards the acceptor
atom.
General Chemistry Reviewers: 2nd Quarter

LEWIS STRUCTURES OF POLYATOMIC IONS: - Affects physical and chemical


properties of molecules, and so is
their reactivity
- It can be determined by
experiment (x-ray diffraction)
- Simple molecules can be predicted
without experimentation, however
it is only qualitative
- Scientist use the VSEPR Theory to
predict the shape of molecules
Molecular Shape
VSEPR Theory assumes that the shape
of molecule is determined by the
repulsion of electron pairs
Valence Shell Electron Pair Repulsion
Theory
RULES FOR WRITING LEWIS DOT
STRUCTURES: 1. Shared and unshared pairs repel.
2. Lone pairs repel stronger than
Rule 1: Count the valence electrons.
shared pairs.
Rule 2: Place the least electronegative 3. Double and triple bonds are
element at the center except for H, which viewed as single; for structure only.
is always an outer atom.
4. The resultant shape of the
Rule 3: Add covalent bonds between the molecule is a result of shared and
center atom and the outer atoms. lone pairs being as far apart as
Rule 4: Add the lone pairs to the outer possible.
atoms. “The best arrangement of a given number
of things is the one that minimizes the
Rule 5: Add lone pairs to the center
repulsions among them.”
atom.

Rule 6: Make sure that each atom has LONE PAIRS AND BOND PAIRS
eight electrons using double and triple Lone Pairs
bonds, if necessary. Exceptions to the - Physical larger than bonded pairs
Octet Rule are that hydrogen has only 2 - Therefore, their repulsion are
electrons, boron sometimes has only 6
greater, this tends to decrease
electrons, and phosphorus sometimes has
10 electrons. bond angles in a molecule

LESSON #3: MOLECULAR POLARITY


& GEOMETRY
Molecular Geometry
- 3D arrangement of atoms in a
molecule
General Chemistry Reviewers: 2nd Quarter

the electronegativities of the two


atoms

Electronegativity Type of Bond


Difference

≤ 0.4 Non-polar
covalent

Between 0.5 - 1.8 Polar covalent

≥ 1.8 Ionic

- If there is symmetry with the


charge, then the compound is
nonpolar.

- If the charges are asymmetrical


and there are dipoles, the
compound is polar.
TYPES OF BONDS:
Metallic
- sharing free electrons among
positively charged ions (bet.
metals)
Ionic
- transfer of electron from one
atom to another (between metal
& non-metal) Fluorine has a stronger attraction for the
Covalent electrons. They are still shared, but spend
- sharing of electrons between more time around the fluorine giving
atoms (between nonmetals) partial opposite charges to opposite ends
a. non-polar covalent – equal of the bond (a dipole)
sharing of e-
b. polar covalent – unequal sharing NONPOLAR BOND (NO DIPOLE) VS. POLAR
of e- BOND (DIPOLE)

DETERMINING POLARITY OF MOLECULES:


Bond Polarity
- Depends on EN difference

Molecular Polarity
- Depends on geometry (shape) of
a molecule

Electronegativity
- is the ability of an atom to attract
electrons in a chemical bond
- Polar bonds result when a highly The greater the EN difference, the
electronegative atom bonds to a stronger the bond
less electronegative atom

Determining Polarity
POLARITY BASED ON SHAPE:
- A covalent bond is polar if there is
After determining the bond type,
a significant difference between
it is necessary to draw the Lewis
General Chemistry Reviewers: 2nd Quarter

Structure to determine the shape of the SATURATED HYDROCARBONS:


molecule. Alkanes
● If there is symmetry with the - Carbon - carbon
charge, then the compound is
- Paraffins = Parum Affinis
nonpolar.
● If the charges are asymmetrical - “Slight” affinity
and there are dipoles, the - Every carbon atoms participates
compound is polar. in 4 single bonds
- GENERAL FORMULA: CnH2n+2

LESSON #4: ORGANIC CHEMISTRY


Is the chemistry of compounds
containing carbons

3 FORMS OF PURE CARBON:


1. Diamond
2. Graphite Constitutes a Homologous Series,
3. Buckminsterfullerene “BuckyBalls” in which one compound differs from a
preceding one by a fixed group of atoms.
[These 3 are most often referred to as
Allotropes, which are other known
variations of carbon]

WHAT MAKES CARBON BONDINGS UNIQUE:


● The bonding capabilities
“It can bond with other carbon atoms and
form chains and rings at various lengths”
Ex: Asphalt, Polyethylene.

Hydrocarbons
- Simplest organic compound
containing only carbon and
hydrogen

3 MAIN GROUPS OF HYDROCARBONS:


● Saturated Hydrocarbons
● Unsaturated Hydrocarbons*
Alkanes in which carbons are
● Aromatic Hydrocarbons
connected in a straight chain are called
Normal Alkanes.
*ALIPHATIC COMPOUNDS - ARE DEFINED AS
ANY CARBON ATOMS JOINED BY A BOND
WITHOUT BENZENE*

Alkanes that are branched are called


branched chain alkanes.
General Chemistry Reviewers: 2nd Quarter

Constitutional (Structural) Isomers Geometric Isomer


- When two or more molecules - Isomers in which the atoms are
share the same molecular formula, joined to one another in the same
but have different atomic way but differ because some
connections (structural formula). atoms occupy different relative
positions in space.
Conformational Isomer - Identified either as Cis or Trans
- 3 dimensional models for n-butane
EXAMPLES: DETERMINING THE POSSIBILITY
OF CIS-TRANS ISOMERS
- Rotating the central
carbon-carbon bond a. CH3CH2CH = C(CH3)2

- All share the same structural


formula.

b. CH3CH = CHCH2CH3

Switching from one conformation


to another does not require the breaking
and making of covalent bonds. c. CH3CH = CHCH2CH2CH3

Cycloalkanes
- GENERAL FORMULA: CnH2n
- Closed structures

d. CH3CH2CH = CH2

UNSATURATED HYDROCARBONS:
Alkenes
- Hydrocarbons that contain
carbon-carbon double bonds.

- Olefins (greek word for oil /


usually forms oily substances.) Alkynes
- Contains at least 1 carbon-carbon
- GENERAL FORMULA: CnH2n
triple bond.
- Linear Geometry
Aromatic Compounds
- Unsaturated
- Looks like Alkenes
- Alternating pattern within a ring
General Chemistry Reviewers: 2nd Quarter

- Benzene 5. When there are two or more different


alkyl branches, the name of each branch,
with its position number, precedes the
base name. Branch names are placed in
alphabetical order.
FOR CYCLOALKANES:
(cis/trans + position no. + alkyl groups +
NAMING HYDROCARBONS: cyclo-parent chain)
Organic chemists use a systematic
FOR ALKENES:
set of rules, called the IUPAC rules, to
Position no. + Alkyl group + double bond
name organic molecules based on their
position no. + parent
structural formulas instead of their
name (-ene)
chemical formulas.
FOR ALKYNES:
1. Determine the longest continuous Position no. + Alkyl group + triple bond
(not necessarily straight) chain of position no. + base name (-yne)
carbon atoms in the molecule.
- The base name of the FOR AROMATIC COMPOUNDS:
branched-chain alkane is that of 1. Name of the group as prefix + benzene
the straight-chain alkane. as the suffix.

Number of Atoms Prefix


2. When two groups are on a benzene
ring. Isomers are distinguished by prefixes
1 Meth- ortho (o-), meta (m-), para (p-).
2 Eth-
3 Prop- 3. When two or more groups are present
4 But-
5 Pent- on the benzene ring.
6 Hex-
7 Hept- HYDROCARBON DERIVATIVES:
8 Oct- ● Alcohol
9 Non-
10 Dec- - R-OH

2. Any chain branching off the longest ● Ether


chain is named as an alkyl group. An - ROR’
alkyl group is an alkane less than one
hydrogen atom. ● Aldehyde
(e.g. Methane group becomes methyl - R-CHO
group, Ethane becomes ethyl group)
● Ketone
3. The complete name of a branch - R-CO-R’
requires a number that locates the
branch on the longest chain. For this ● Carboxylic Acid
purpose, you number each carbon atom - R-COOH or R-CO₂H
on the longest chain in the direction that
gives the smaller numbers for the ● Ester
locations of all branches - R-COO-R’
4. When there are more than one alkyl
branch of the same kind (say, two methyl ● Amine
groups), this number is indicated by a - R-NH₂
prefix, such as di-, tri-, or tetra-, used
with the name of the alkyl group. ● Amide
- R-CO-NH
General Chemistry Reviewers: 2nd Quarter

- Chitin → strong and flexible


● Propionic Acid surgical thread found in
- Naturally occurring exoskeletons of arthropods.
carboxylic acid with the 2. Proteins
chemical formula: - C,H,O and N (and some sulfur)
CH₃CH₂CO₂H - Amino Acids → the basic building
block of protein
- C₃H₆O₂ - Formed by formation of amino acids to
polypeptides
- Peptide bond
LESSON #5: BIOLOGICAL - There are 20 amino acids (9 essentials;
MACROMOLECULES 11 non essentials.)
- 3 out of 4 macromolecules can be CONDITIONAL AMINO ACIDS:
found in foods (fat, protein, There are times wherein they
carbohydrates) become essential when certain conditions
- The 4th macromolecule is the are not met by your body. (you may get
nucleic acid. them from foods)
- DNA / RNA
Complete Protein
1. Carbohydrates - Contains all 9 essential amino
- C,H,O acids
- Meat, Egg, Tofu
a. Simple Carbohydrates
- Main source of energy Incomplete Protein
- Simple sugar → monosaccharide - Does not contain all 9 essential
- Short Chain → oligosaccharide amino acids
- two to ten monosaccharides - Grains, Legumes, Veggies
- short chain of monosaccharides
- Ex: Glucose, Fructose, Galactose STRUCTURE OF PROTEINS:
- Glucose + Glucose = Maltose - Primary, secondary, tertiary and
- Glucose + Fructose = Sucrose quaternary
- Glucose + Galactose = Lactose
Primary Protein Structure
b. Complex Carbohydrates - Chain of amino acid
- long term energy storage - 1 chain
- insoluble in water due to large - Peptide bond
molecular size
- Polysaccharides → straight/branched Secondary Protein Structure
chain of sugars - Local folding of the polypeptide
EXAMPLES: chain into sheets
- Starch → storage of energy in
plants Tertiary Protein Structure
- Glycogen → stored glucose in - 3D folding pattern of protein due
animals to side chain interaction
- Glycogen → located at the liver
and skeletal muscles; more highly Quaternary Protein Structure
branched than starch. - Consisting of more than one
- Glycosidic Bond → bonding of amino acid chain
monomers
- Cellulose → structural *different shapes = different jobs*
component of cell walls; dietary
timer in humans to maintain Globular
regular elimination. - Rounded or irregular 3D
General Chemistry Reviewers: 2nd Quarter

Fibrous
- Like collagen and keratin Trans Fat
- Adapt a rod like structure - Fatty acid that has been partially
hydrogenated making it more
FUNCTIONS OF PROTEINS saturated and solid.
For thousands of possible shapes,
proteins create a lot of functions with MAIN TYPES OF LIPIDS:
relation to the amino acid structures. Triglycerides
a. Support (keratin and collagen) - Three fatty acids connected to the
b. Metabolism (enzymes for glycerol
chemical reaction) - Most common type of body fat in
c. Defense (antibodies or the humans and other vertebrates
immune system) - Body’s primary long term energy
d. Transport (carriers and protein storage molecules
channels in plasma)
e. Regulation (hormones, regulatory Prostaglandins
proteins, glycogen, and insulin) - Group of 20 lipis
f. Motion (muscle contractions) - Local chemical messenger

Enzymes Phospholipids
- Speed up the rate of a chemical - One of the most important
reaction (a catalyst) by lowering molecules
the energy needed to begin the - Bilayer or cell membrane
reaction - Micelle (when formed in circular
- Re-usable shape)
- Lock and Key model → a shape - Semi permeable
must fit with the one breaking and
enzyme. Steroids
- Induced fit model → the shape - Possesses a unique skeleton of 4
does not adjust rather the one fluid rings
breaking it will. - They are also insoluble in water
- Lactose → breaks down lactose - Steroid Cholesterol → maintain
sugar the fluiding of plasma membrane
- Pepsin → breaks down proteins - Sex Hormones → testosterone
- Amylase → breaks down amylose. and progesterone.
- Thyroid Hormone →
Waxes
3. Lipids - Esther and alcohol fatty acids
- C,H,O (some phosphorus and nitrogen) chain
- A monomer that contains the subunit - Cutin → many plants have
molecules, glycerol and fatty acids wax-covered leaves to prevent
- Glycerol (hydrophilic) and fatty acid water loss.
(hydrophobic) - Protection
- Ester bond
- Fatty acid Terpenes
- Saturated Fatty Acid → single bonded, - Unique type
no double bond between carbon atoms - Don’t contain fatty acids
(ex: butter, animal fats) - Unit of isoprene
- Unsaturated Fatty Acid → double - Have distinct aroma in plants
bond between the carbon atoms (plant - Natural function at attracting
oil; except palm and coconut) pollinators and protectors against
- Polyunsaturated Fatty Acid → more herbivores and insects.
than one double bond between the
carbon atoms (corn oil, olive oil, fish oil, Prostaglandins
canola oil) - Group of 20 lipis
General Chemistry Reviewers: 2nd Quarter

- Local chemical messenger

4. Nucleic Acid
- 4th type
- Types: DNA and RNA
- Made up of nucleotides
- Composed of 5 carbon
sugar, phosphate group
and organic nitrogen

NITROGEN BASES:
Pyrimidines
- Cytosine
- Uracil
- Thymine

Purines
- Guanine
- Adenine

Pentose Sugar
- DNA (Deoxyribonucleic Acid)
- Material of inheritance
- Found in nucleus
- Segment of DNA is known
as gene
- RNA (Ribonucleic acid)
- Translation of genetic
information stored in DNA
into protein structure
- Phosphodiester Bond
- One nuclei to another
- Thymine pairs with Uracil, and
Adenine
- two hydrogen bond
- Double bond
- Cytosine pair with Guanine
- three hydrogen bond
- triple bond
-
3 CLASSES OF RNA:
Messenger RNA (MRNA)
- Template to make protein

Ribosomal RNA (RNA)


- Makes up ribosomes

Transfer RNA (TRNA)


- Matches AA to mRNA to help
make protein

History Transcription
- Central dogma of life
- Replication, Transcription,
Translation

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