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General Chemistry 2ND QTR Reviewers
General Chemistry 2ND QTR Reviewers
Quantum Model
- Developed by Erwin Schrödinger
- The possibility of placing
electrons within an atom by
describing the principal energy
level, energy level, orbital
Solid Sphere Model
(arbitrary level), and spin of.
- Developed by John Dalton
- Wave Mechanical Model
- First atomic model
- Electrons can act as a wave
- An atom is a solid sphere that
(Electron clouds)
could not be divided into smaller
particles.
QUANTUM NUMBERS:
Principal Quantum Number
Plum Pudding Model - Electron Cloud Size (n)
- Developed by J.J. Thomson - Main energy level occupied by
- Also known as Thomson’s Plum the electron
Pudding Model - Integer values n = 1, 2, 3,….
- Historical scientific model of atom - bigger n value = higher energy
- Defined by electrons surrounded - All electrons in an atom with the
by a volume of positive charge, same value of n belong to the
like negatively-charged “plums” same shell/level
embedded in a positively-charged
n Shell n Shell
“pudding” Name Name
- Electrons, Protons, and Neutrons 1 K 5 O
2 L 6 P
Planetary Model 3 M 7 Q
- Developed by Ernest Rutherford 4 N
- Electrons are arranged in
concentric circular orbits around Angular Momentum Quantum Number
the nucleus - Shape of Electron Cloud (I)
- Gold-foil experiment - Also known as sublevel or subshell
- Nucleus (atom) - Shape of the orbital within a shell
- electrons (-) are in orbits - Only integer values between 0
- protons (+) and neutrons are and n-1 are allowed
inside the nucleus - bigger l = higher energy
- Energy enters the nucleus - All electrons in an atom with the
same value of l are said to belong
Bohr Model to the same subshell
General Chemistry Reviewers: 2nd Quarter
Degenerate Orbitals
- Two or more orbitals that have the
same energy
Electron arrangement determines the
chemical behavior of atoms
- Subatomic parts are the electrons
General Chemistry Reviewers: 2nd Quarter
Ionic Bonding
- the Transfer of Electrons between
a Metal and a Nonmetal.
A CARBON DIOXIDE MOLECULE HAS TWO ● The hydrogen ion, H+, has no
CARBON-OXYGEN DOUBLE BONDS: electrons and accepts a lone pair
donated by nitrogen.
Double Covalent Bond ● After accepting the lone pair,
- Is a bond that involves two hydrogen has a full outer shell.
shared pairs of electrons.
EXCEPTIONS TO THE OCTET RULE:
Triple Covalent Bond 1. Incomplete octet
- Is a bond formed by sharing three - Rare
pairs of electrons. - Usually with B and Be
- Molecules have only 6 electrons
around central atom
Rule 6: Make sure that each atom has LONE PAIRS AND BOND PAIRS
eight electrons using double and triple Lone Pairs
bonds, if necessary. Exceptions to the - Physical larger than bonded pairs
Octet Rule are that hydrogen has only 2 - Therefore, their repulsion are
electrons, boron sometimes has only 6
greater, this tends to decrease
electrons, and phosphorus sometimes has
10 electrons. bond angles in a molecule
≤ 0.4 Non-polar
covalent
≥ 1.8 Ionic
Molecular Polarity
- Depends on geometry (shape) of
a molecule
Electronegativity
- is the ability of an atom to attract
electrons in a chemical bond
- Polar bonds result when a highly The greater the EN difference, the
electronegative atom bonds to a stronger the bond
less electronegative atom
Determining Polarity
POLARITY BASED ON SHAPE:
- A covalent bond is polar if there is
After determining the bond type,
a significant difference between
it is necessary to draw the Lewis
General Chemistry Reviewers: 2nd Quarter
Hydrocarbons
- Simplest organic compound
containing only carbon and
hydrogen
b. CH3CH = CHCH2CH3
Cycloalkanes
- GENERAL FORMULA: CnH2n
- Closed structures
d. CH3CH2CH = CH2
UNSATURATED HYDROCARBONS:
Alkenes
- Hydrocarbons that contain
carbon-carbon double bonds.
Fibrous
- Like collagen and keratin Trans Fat
- Adapt a rod like structure - Fatty acid that has been partially
hydrogenated making it more
FUNCTIONS OF PROTEINS saturated and solid.
For thousands of possible shapes,
proteins create a lot of functions with MAIN TYPES OF LIPIDS:
relation to the amino acid structures. Triglycerides
a. Support (keratin and collagen) - Three fatty acids connected to the
b. Metabolism (enzymes for glycerol
chemical reaction) - Most common type of body fat in
c. Defense (antibodies or the humans and other vertebrates
immune system) - Body’s primary long term energy
d. Transport (carriers and protein storage molecules
channels in plasma)
e. Regulation (hormones, regulatory Prostaglandins
proteins, glycogen, and insulin) - Group of 20 lipis
f. Motion (muscle contractions) - Local chemical messenger
Enzymes Phospholipids
- Speed up the rate of a chemical - One of the most important
reaction (a catalyst) by lowering molecules
the energy needed to begin the - Bilayer or cell membrane
reaction - Micelle (when formed in circular
- Re-usable shape)
- Lock and Key model → a shape - Semi permeable
must fit with the one breaking and
enzyme. Steroids
- Induced fit model → the shape - Possesses a unique skeleton of 4
does not adjust rather the one fluid rings
breaking it will. - They are also insoluble in water
- Lactose → breaks down lactose - Steroid Cholesterol → maintain
sugar the fluiding of plasma membrane
- Pepsin → breaks down proteins - Sex Hormones → testosterone
- Amylase → breaks down amylose. and progesterone.
- Thyroid Hormone →
Waxes
3. Lipids - Esther and alcohol fatty acids
- C,H,O (some phosphorus and nitrogen) chain
- A monomer that contains the subunit - Cutin → many plants have
molecules, glycerol and fatty acids wax-covered leaves to prevent
- Glycerol (hydrophilic) and fatty acid water loss.
(hydrophobic) - Protection
- Ester bond
- Fatty acid Terpenes
- Saturated Fatty Acid → single bonded, - Unique type
no double bond between carbon atoms - Don’t contain fatty acids
(ex: butter, animal fats) - Unit of isoprene
- Unsaturated Fatty Acid → double - Have distinct aroma in plants
bond between the carbon atoms (plant - Natural function at attracting
oil; except palm and coconut) pollinators and protectors against
- Polyunsaturated Fatty Acid → more herbivores and insects.
than one double bond between the
carbon atoms (corn oil, olive oil, fish oil, Prostaglandins
canola oil) - Group of 20 lipis
General Chemistry Reviewers: 2nd Quarter
4. Nucleic Acid
- 4th type
- Types: DNA and RNA
- Made up of nucleotides
- Composed of 5 carbon
sugar, phosphate group
and organic nitrogen
NITROGEN BASES:
Pyrimidines
- Cytosine
- Uracil
- Thymine
Purines
- Guanine
- Adenine
Pentose Sugar
- DNA (Deoxyribonucleic Acid)
- Material of inheritance
- Found in nucleus
- Segment of DNA is known
as gene
- RNA (Ribonucleic acid)
- Translation of genetic
information stored in DNA
into protein structure
- Phosphodiester Bond
- One nuclei to another
- Thymine pairs with Uracil, and
Adenine
- two hydrogen bond
- Double bond
- Cytosine pair with Guanine
- three hydrogen bond
- triple bond
-
3 CLASSES OF RNA:
Messenger RNA (MRNA)
- Template to make protein
History Transcription
- Central dogma of life
- Replication, Transcription,
Translation