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2022 CH2213 Lecture30
2022 CH2213 Lecture30
Lecture -30
DSC Analysis: Polymers & Glassy Materials
Professor Manickam Jayakannan
Department of Chemistry
IISER Pune, INDIA
E-mail: jayakannan@iiserpune.ac.in
Website: http://www.iiserpune.ac.in/~jayakannan/
1
Phase Transition in Solid State
2
Small Molecules
Normal Heat
Molten Liquid
Solid
Apply Cooling
ordered state Disorder state
Tc
∆Hc
Heat -ve Cooling
Cp ={dH/dT)p
Cool
Heating
+ve
∆Hm
Crystal Isotropic Tm
Temperature
long-chain systems
Heat
Si {SiO2}n Molten Liquid
X
O Apply Cooling Apply
Cooling
Si O Si O Si
Ma
Inf Ap y be Glass q Intermediate state
O ini ply … q Kinetically trapped
slo tes
w i
Si
Co mall Amorphous state
oli y
ng (Disorder state)
Crystal lattices
(ordered state)
Unit cell
Cool
Crystalline domain
Liq.N2
Rubber
bands
Chains are immobile
(or)
Brittle Chains are highly mobile Water tubes
at low temperature Flexible at room temperature
(Glass-like state) Allow it warm (Rubber-like state)
Temperature
6
DSC Thermograms for Amorphous polymers
1st Cooling Cycle
Exo
Tg
g io o n
Glassy state
Isothermal
Re dati
Heat
n
gra
flow
Tg
De
Endo
Temperature
q No molten state or phase transition occurs
O Tg = 156 deg C
O
n
Bisphenol-A Polycarbonate
7
Glass Transition temperature
Not Brittle
Pour hot (highly flexible)
Water
(Rubber-like state)
Chains are
immobile
(Glass-like state) Apply high
temperature
Melted
Keep it at
Thermograms for Typical Medium temperature
80-100 deg C
Semi-crystalline polymers
Temperature
8
DSC Thermograms for Crystalline polymers
Case-1: Regular trend: Melt Crystallization
TC
!HC
g io o n
Exo
Re dati
Tg
n
Heat
gra
flow Glassy state Rubbery state
De
Glass Transition
!HM
Endo
Temperature
supercooling
effect TM
Temperature