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2019 Sec 3 Sci (Chem) NA 12s
2019 Sec 3 Sci (Chem) NA 12s
SECONDARY 3
Normal Academic Exam Paper
Science Chemistry NA
1 Assumption English SA1
2 Bedok View Sec SA1
3 Canberra Sec SA1
4 Jurong West Sec SA1
5 Bartley Sec SA2
6 Beatty Sec SA2
7 Canberra Sec SA2
8 East Spring Sec SA2
9 Hillgrove Sec SA2
10 Hougang Sec SA2
11 Ken Ridge Sec SA2
12 Kranji Sec SA2
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SCIENCE (CHEMISTRY)
5105 / 03
5107 / 03
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
INSTRUCTIONS TO CANDIDATES
Do not open this booklet until you are told to do so.
Write your NAME, INDEX NUMBER and CLASS at the top of this page and on the
OAS paper. Shade your index number on the OAS paper.
There are 20 questions in this paper. Answer all questions. For each question, there
are four possible answers A, B, C and D. Choose the correct answer and record your
choice in soft or 2B pencil on the OAS paper provided. DO NOT fold or bend the
OAS paper.
At the end of the examination, hand in your OAS paper and Question Papers
separately.
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2
1 The melting and boiling points of four substances are given below in the table.
2 The graph below shows part of the cooling curve of a liquid substance.
temperature / °C
Q
R
time / min
Which row correctly identifies the states of the substance at regions P, Q and R?
P Q R
A liquid and gas liquid liquid and solid
B liquid liquid and solid solid
C gas liquid solid
D liquid liquid and gas gas
5105/5107/03/3NA/MYE/19
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3
Liquid D
A
B C
Solid Gas
4 A balloon filled with helium gas is placed in a basin of hot water. It is observed that
the balloon increases in size.
A The helium gas particles increase in size, and spaces between them
decrease.
B The helium gas particles decrease in size, and spaces between them
decrease.
C The helium gas particles remain the same size, and spaces between the
particles increase.
D The helium gas particles remain the same size, and spaces between the
particles decrease.
25 cm3
26 cm3
27 cm3
What is the volume of acid used if it started off at 0 cm3 in the burette?
A 25.70 cm3
B 25.75 cm3
C 25.80 cm3
D 25.85 cm3
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4
A X B
C D
X
X
water
What does the student check to test the purity of the crystals?
mixture 1 mixture 2
to obtain sand to obtain water to obtain salt to obtain water
A filtration distillation crystallisation filtration
B filtration filtration crystallisation distillation
C crystallisation distillation filtration filtration
D crystallisation filtration filtration distillation
5105/5107/03/3NA/MYE/19
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5
A B C D
W
X
Z
Y
metal non-metal
A W Z
B X Y
C X Z
D Z Y
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6
12 How many atoms are present in a formula unit of aluminium sulfate, Al 2 (SO 4 ) 3 ?
A 4
B 7
C 17
D 18
Which group and period of the Periodic Table does this atom belong to?
group period
A II 3
B II 5
C V 2
D V 3
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7
15 Which option shows the correct relative charges of the particles in an atom?
16 Two particles X and Y have the composition shown in the table below.
conduct electricity
melting point soluble in water
solid liquid
A high no no yes
B high yes no yes
C low no no no
D low yes yes yes
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A X2+
B X2-
C X6+
D X6-
A NH 4 CO 3
B (NH 4 ) 2 CO 3
C NH 4 (CO 3 ) 2
D (NH 4 ) 3 (CO 3 ) 2
- End of Paper 3 -
5105/5107/03/3NA/MYE/19
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Name: ……………………………………………….. ( ) Class: ……...
SCIENCE (CHEMISTRY)
5105 / 04
5107 / 04
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL ASSUMPTION ENGLISH SCHOOL
INSTRUCTIONS TO CANDIDATES
Do not open this booklet until you are told to do so.
Write your NAME, INDEX NUMBER and CLASS at the top of this page.
Write in dark blue or black pen on both sides of the paper.
You may use a soft pencil for any diagrams or graphs.
Do not use staples, paper clips, highlighters, glue or correction fluid.
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2
1 The proton (atomic) numbers of some elements are shown in the table.
[1]
(ii) Using the electronic structure in part (a)(i), explain why neon is an
unreactive gas.
………………………………………………………………………………
……………………………………………………………………………… [1]
(iii) Draw the arrangement of the particles of neon gas in the box given.
[1]
……………………………………………………………………………… [1]
………………………………………………………………………………
……………………………………………………………………………… [1]
5105/5107/04/3NA/MYE/19
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3
2 (a) A food inspector used chromatography to test a new food colouring X, for
the presence of red, blue and green dyes. The result is shown below.
pencil line
……………………………………………………………………………… [1]
………………………………………………………………………………
……………………………………………………………………………… [1]
(iii) On the diagram above, sketch the chromatogram for food colouring
X which only contains the dyes red and blue. [1]
(b) A student placed a drop of brown dye, A, and a drop of green dye, B, on a
piece of filter paper. The end of the filter paper was then dipped into a
beaker of water. The results are shown below.
A B
……………………………………………………………………………………..
……………………………………………………………………………………..
…………………………………………………………………………………….. [2]
5105/5107/04/3NA/MYE/19 [Turn over
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4
3 20.80 cm3 of ethanoic acid, CH 3 COOH, is added into a conical flask. 1.25 g of
magnesium carbonate, MgCO 3 , is then added into the flask. It is observed that
35 cm3 of carbon dioxide gas is evolved and the temperature of the mixture rose
to 42.3°C.
(a) State all suitable apparatus needed to measure the physical quantities
mentioned above.
2 x hydrogen atoms
water H2O 1 x oxygen atom
magnesium MgCO 3
carbonate
[2]
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5
Answer any two questions from this section in the spaces provided.
time / min 0 2 4 6 8 10 12 14
temperature / °C 20 50 80 110 110 110 130 150
(a) Plot a graph of temperature against time, marking each point with a cross
(×). The first two points have been done for you. Draw the heating curve of
solid X.
[2]
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6
…………………………………………………………………………………….. [1]
(c) Using the graph, determine how long it takes for solid X to be heated from
20 qC to 92 qC.
…………………………………………………………………………………….. [1]
……………………………………………………………………………………..
……………………………………………………………………………………..
……………………………………………………………………………………..
…………………………………………………………………………………….. [2]
………………………………………………………………………………
……………………………………………………………………………… [1]
compounds mixtures
5105/5107/04/3NA/MYE/19
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7
5 The table shows some of the properties of the first six members of the alkane
homologous series.
(a) Write, in the last column, the physical state of butane at 20 qC. [1]
(b) A mixture of water, pentane and hexane can be separated using the
apparatus shown.
……………………………………………………………………………… [1]
(ii) Which of the three chemicals will collect in the beaker first?
Explain your answer.
………………………………………………………………………………
……………………………………………………………………………… [2]
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8
Carbon has 15 different known isotopes. Two of the isotopes are listed in
the table below.
ଵଶ
carbon-12 ܥ
ଵସ
carbon-14 ܥ
………………………………………………………………………………
……………………………………………………………………………… [1]
………………………………………………………………………………
……………………………………………………………………………… [1]
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9
(i) does not have a fixed boiling point, and ……………………………. [1]
[2]
………………………………………………………………………………
………………………………………………………………………………
………………………………………………………………………………
……………………………………………………………………………… [2]
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10
(iii) The diagram shows how solid magnesium oxide can be tested for
electrical conductivity.
battery
light bulb
solid magnesium
oxide
crocodile clip
State the result you would expect to see. Explain your answer.
………………………………………………………………………………
………………………………………………………………………………
……………………………………………………………………………… [2]
- End of Paper 4 -
5105/5107/04/3NA/MYE/19
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ASSUMPTION ENGLISH SCHOOL
Sec 3 Normal Academic Science (Chemistry) 5105, 5107 Marking Scheme
Mid Year Examinations 2019
Paper 3 (20m)
Q1 Q2 Q3 Q4 Q5 Q6 Q7 Q8 Q9 Q10
D B D C B B A B B A
Q11 Q12 Q13 Q14 Q15 Q16 Q17 Q18 Q19 Q20
C C B C A C B A A B
1 ai 1
valencce shell
It has a full valence sh
s heelll / complete
com
comp ple
lete
te valence
val
a ence shell / noble
noble gass cconfiguration
onfi
onfiguratio
fi
aii 1
andd does not
nott need
need to
to form
orm bond.
for bo
b on
nd
d.
aiii
aiiiiii 1
bi 2.8.8
2.8.8
2.
2.8 8 1
Io
oni
niic.
Ionic.c
c.
bii 1
Potassium
Potatassiuum (metal)
iu (me
(m and fluorine (non-metal) forms an ionic bond.
etal) an
2 ai They
ey have different solubilities in the solvent. 1
cil lead is insoluble in solvent and does not affect the accuracy of the
Pencil
aii 1
chromatography results.
aiii 1
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1. Dye A is a mixture / Dye B is pure.
2. Dye B is a component / is a part of Dye A.
b 2
Award 1m for each conclusion.
3 ai Burette 1
aii thermometer 1
compound chemical formula composition of elements
2 x carbon atoms
4 x hydrogen atoms
ethanoic acid CH 3 COOH
2 x oxygen atoms
b 2
1 x magn
magnesium
nes
esiu
ium atom
iu a
magnesium MgCO 3
carbonate 1 x ca
carbon
arb
rbon
naatom
tom
3 x ox
oxygen atoms
en ato
oms
m
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Paper 4 Section B (20 m)
4 a 2
Award
Award
A d 1m m for
for correct
fo correcct points
p in
po ints
s plotted
plo
lott
tted
ed
A
Aw war
Awarda d 1m m ffor
orr graph
o ph
p h drawn
dra
awn
w
b 11
1 10 oC
110 1
c 4.8
4 8 min (accept
4. ((a
acc
cceeppt +/-
+ - of
+/ of 0.2 min)
min
in)) 1
o
At 2
At 200C C,, the
he p
he particles
a ticles
ar es are
are cclosely
losely packed in an orderly arrangement and
1
vvibrate
viib ate about
brrate
at ab
a bout their
bou
ou fixed
theiir fi
fixe
xed
xe d positions.
positi
d
At 9922oC,
C tthe
he p
particles
article are less closely packed in a disorderly arrangement
1
and
nd slide
slid
sl e over o
ide
id one another.
Purere subst
substance
ei 1
It hass a fixed melting point.
Compound - Chemical
eii Mixture - Physical 1
Award 1m only when both answers are correct
5 a Gas 1
bi Fractional distillation 1
Pentane. 1
bii
It has a lowest boiling point. 1
atom symbol number of number of number of
ci 2
protons electrons neutrons
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carbon- 6 6 6
12
carbon- 6 6 8
14
Award 1m for every 3 correct answers.
Atoms of the same element, with the same number of protons, different
cii 1
number of neutrons.
Yes.
ciii
They have the same number of electrons / electronic configuration. 1
bi 2
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BEDOK VIEW SECONDARY SCHOOL
MID-YEAR EXAMINATION 2019
CANDIDATE
NAME
REGISTER
CLASS
NUMBER
Write your index number and name on all the work you hand in. For Examiner’s use
Write in dark blue or black pen on both sides of the paper.
Section A / 20
You may use a soft pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid. 21 / 8
22 / 2
Information for Candidates
23 / 8
Section A 24 / 6
There are twenty questions in this section. Answer all questions. For each
25 / 6
question there are four possible answers A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil Total / 50
on the separate Answer Sheet.
% / Grade /
Section B
Answer all questions.
Write your answers in the spaces provided.
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2
Section A
Answer all questions in this section on the Multiple Choice Answer Sheet.
A kg B ton
C g D mg
A measuring cylinder
B burette
C beaker
D pipette
ammonia
hydrogen chloride
What deductions could you make about the properties of the two gases?
BVSS
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3
A B C D
Which of the following methods is used to obtain pure water from seawater?
6 A student tries to separate a mixture of ethanol and water by fractional distillation using
the apparatus shown.
thermometer
water out
condenser
water in
receiver
liquid
heat
8 The diagram shows the arrangement of the particles in substance X at two different
temperatures.
– 150 oC – 50 oC
A – 161 – 65
B – 161 – 49
C – 148 – 65
D – 148 – 49
temperature /oC
time /mins
C Some particles are closely packed and some particles slide past each other.
D Some particles slide past each other while some particles move freely in all
directions.
BVSS
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5
A a brown solution.
A 3 B 14 C 16 D 34
13 The diagrams below show the relative masses and charges of particles Q, R and S.
1
relative charge
relative mass
1 0
Q R S
0 -1
Q R S
Q R S
A electron proton neutron
key
proton
neutron
electron
A 3 B 4
C 7 D 10
Q R S T
key:
10 p 20 p 12 p 14 p p = proton
10 n 20 n 14 n 14 n n = neutron
Which two atoms belong to the same period in the periodic Table?
A Q and R B Q and T
C R and S D S and T
17 The element T has an electronic configuration of 2.6. Which ion will it form?
A T
B T
C T2
D T2
BVSS
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7
number of
ion
protons electrons neutrons
A 2 -
1H 1 1 2
B 18 2-
8O 10 12 8
C 27 3+
13Al 13 10 14
D 40 2+
20Ca 20 20 20
19 Which of the following takes place during the formation of an ionic bond?
Section B
Answer all questions in the spaces provided
P Q R S
3 protons 17 protons 11 protons 17 protons
5 neutrons 20 neutrons 12 neutrons 18 neutrons
T U V
12 protons 10 protons 8 protons
12 neutrons 10 neutrons 8 neutrons
Fig. 21.1
…………………………………………………………………………... [1]
…………………………………………………………………………... [1]
…………………………………………………………………………... [1]
…………………………………………………………………………... [1]
(b) Elements T and V form an ionic compound with high melting point.
[2]
BVSS
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9
(ii) Explain why the compound formed between T and V has a high melting For
examiner’s
point. use
…………………………………………………………………………...
…………………………………………………………………………...
…………………………………………………………………………...
…………………………………………………………………………... [2]
[Total:8]
Table 22.1
zinc nitrate
Zn(NO 3 ) 2
urea
CO(NH 2 ) 2
[2]
23 (a) Explain the following observations in terms of kinetic particle theory. For
examiner’s
use
(i) When ice is heated, the temperature stays constant at 0 oC until all the
ice has melted.
…………………………………………………………………………...
………………………………………………………………………….. [1]
(ii) When 1 cm3 of water is heated, the volume of steam obtained is more
than a thousand times larger.
…………………………………………………………………………...
…………………………………………………………………………... [2]
Table 23.1
Suggest how a dry sample of copper powder can be obtained from this
mixture.
…………………………………………………………………………………..
…………………………………………………………………………………..
…………………………………………………………………………………..
…………………………………………………………………………………..
………………………………………………………………………………….. [3]
1 ………………………………………………………………………………
………………………………………………………………………………
2 ………………………………………………………………………………
……………………………………………………………………………… [2]
[Total:8]
BVSS
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11
24 Chemists use paper chromatography in Fig. 24.1 to compare the food dyes present For
examiner’s
in five different jellies with two approved food dyes, Red No. 3 and Red No. 40. use
movement
of solvent
starting line
Red Red Jelly Jelly Jelly Jelly Jelly
No. 3 No. 40 A B C D E
Fig. 24.1
………………………………………………………………………………….. [1]
(b) (i) Which of the jellies contain either one of the approved food dyes?
…………………………………………………………………………... [1]
…………………………………………………………………………...
…………………………………………………………………………... [2]
………………………………………………………………………………….. [1]
………………………………………………………………………………….. [1]
[Total:6]
25 A student plans to carry out an experiment to study how temperature affects the For
examiner’s
speed of reaction between zinc and dilute hydrochloric acid. use
[4]
(b) Describe how the particles in zinc powder and dilute hydrochloric acid differ
in their arrangement and movement.
arrangement
movement
[2]
[Total:6]
End of Paper
BVSS
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13
The Periodic Table of Elements
Section A
1 2 3 4 5 6 7 8 9 10
A B D A D C A A C C
11 12 13 14 15 16 17 18 19 20
D B D A C D C C C B
Section B
Qn Answers R
Rem
Re mark
ark
rks
Remarks Marks
21ai P and R CAO
CA
AO B1
ii T CAO
CAO
O B1
iii Q and S CAO
CA
AO B1
B
iv U CAO
CAO B1
bi Corr
Correct
rrec
ectt sstructure
tructtur
uree B2
of bboth
oth
oth T an and
dV
[1]
T V Correct
Corr charge
of both T and V
[1]
bii P: It h as a g
as
has giian
ant lla
giant attttic
ic e s
lattice stru
ruct
ru ctur
ctu
ct ure
ur
u
structure. e.
B2
R: A lo ot of
lot of energy
ene
nergygy [1] 1]] is needed
ne
eeded to t overcome the strong
electrostatic
trossta
tatitic
tati
tic forces
fo
forc
ces
ces
es of of attraction
attrac between the oppositely-
charged ed io
ions.
onsns.. [1]
[1
1]
O: Thus the compoundcom
om has a high melting point.
T=8
22 B2
name and name of elements total number of
formula of present atoms present
substance
zinc nitrate Zinc, nitrogen 2 box correct
9
Zn(NO 3 ) 2 Oxygen [1m]
urea Carbon, oxygen, all correct [2m]
8
CO(NH 2 ) 2 nitrogen, hydrogen
T=2
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42
P: During melting, heat is taken in by particles
23ai B1
R: to overcome the strong forces of attraction [1]
between water molecules or particles.
O: thus temperature stays constant during melting.
P: In liquid water, the molecules/particles are close
ii B2
together [1], (R): occupying a small volume.
P: When liquid (water) change to gas (steam), the
molecules/particles are spread far apart [1] and (R):
can occupy a large volume.
O: thus the volume of steam obtained is much larger
than the same volume of water when heated.
Dissolve powder (containing the three substances) in
b B3
hot dilute sulfuric acid. [1]
Filter mixture to obtain insoluble copper as residue. [1]
Wash residue with distilled water and dry it between
filter papers [1]
c copper cannot be broken down into simper B2
substances by chemical means.[1]
copper is made up of only one type of atom.[1] [1]
T=8
T
24a B and D CAO
AO
B1
bi B, C and D (or B and
d C)) B1
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CANBERRA SECONDARY SCHOOL
Do not turn over the paper until you are told to do so.
Write in dark blue or black ink pen on both sides of the paper.
Do not use staples, paper clips, glue or correction fluid.
Answer ALL questions in Paper 3. Indicate your answers on the OTAS provided.
You are advised to spend no more than 30 minutes on Paper 3.
Answer ALL questions in Paper 4 Section A and any TWO questions in Section B.
Write all your answers on the spaces provided.
At the end of the examination, hand in your OTAS and question paper.
The number of marks is given in brackets [ ] at the end of each question or part question.
Marks Max
Section
Awarded Marks
Paper 3 20
Section A 14
Paper 4
Section B 16
Total 50
This question paper consists of 15 printed pages including the cover page.
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45
2
A beaker
B burette
C measuring cylinder
D pipette
hydrogen chloride
ammonia
What deductions can be made about the properties of the two gases?
____________________________________________________________________________________________________
Canberra Secondary School Chemistry 5105/03, 5105/04
2019 Semestral Assessment 1 Secondary 3 Normal (Academic)
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46
3
process 1 process 2
process 3 process 4
4 Which of the following statements best describes the particles in a solid as the solid is
melting?
5 Which substance has particles that are arranged in a closely packed and disorderly
manner at 78 °C?
________________________________________________________________________________________________
Canberra Secondary School Chemistry 5105/03, 5105/04
2019 Semestral Assessment 1 Secondary 3 Normal (Academic)
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47
4
6 The table shows some information about the solubilities of 3 solids, X, Y and Z.
Some of the following steps could be carried out to obtain pure Z from a mixture of the
three solids.
1 add alcohol
2 add water
3 evaporate the filtrate
4 filter
In what order should the steps be carried out to obtain pure solid Z?
A 1, 4, 3
B 1, 3, 2, 4
C 2, 4, 3
D 2, 1, 4, 3
Which of the following methods is suitable to determine the purity of the crystals?
Which row correctly describes the white powder, zinc and air?
9 Which of the following shows the correct relative charges of the subatomic particles in
an atom?
____________________________________________________________________________________________________
Canberra Secondary School Chemistry 5105/03, 5105/04
2019 Semestral Assessment 1 Secondary 3 Normal (Academic)
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48
5
4p key
5n z = electron
p = proton
n = neutron
What is the nucleon number of this element and to which Group does it belong to?
A ସ
ଽ܆
B ହ
ସ܆
C ଽ
ସ܆
D ଽ
ହ܆
A B
C D
________________________________________________________________________________________________
Canberra Secondary School Chemistry 5105/03, 5105/04
2019 Semestral Assessment 1 Secondary 3 Normal (Academic)
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49
6
A T
B T2
C T
D T2
14 Two particles P and Q have the following composition as shown in the table shown
below.
15 Which one of the following pairs of elements will form an ionic compound?
A 8
B 14
C 16
D 26
____________________________________________________________________________________________________
Canberra Secondary School Chemistry 5105/03, 5105/04
2019 Semestral Assessment 1 Secondary 3 Normal (Academic)
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50
7
A XY
B XY 2
C X2Y
D YX 2
19 The equation represents the reaction between silver nitrate and magnesium chloride.
x y
A 1 1
B 2 2
C 1 2
D 2 1
A antimony
B lead
C sodium
D vanadium
End of Paper 3
________________________________________________________________________________________________
Canberra Secondary School Chemistry 5105/03, 5105/04
2019 Semestral Assessment 1 Secondary 3 Normal (Academic)
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8
Paper 4
Section A (14 marks)
A B C
D E F
……………………………………………………………………………………… [1]
A2 Magnesium oxide is used to make refractory linings for blast furnaces because of
its high melting point.
(a) (i) Write the symbols for magnesium ion and oxide ion.
……………………………………………………………………………….. [1]
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9
(b) Draw the ‘dot and cross’ diagram to show the bonding in magnesium oxide.
[2]
(c) In terms of structure and bonding, explain why magnesium oxide has a high
melting point.
………………………………………………………………………………………
………………………………………………………………………………………
……………………………………………………………………………………… [2]
………………………………………………………………………………………
……………………………………………………………………………………… [1]
A3 Solid calcium hydroxide, Ca(OH) 2 , reacts with dilute hydrochloric acid, HCl, to
form aqueous calcium chloride, CaCl 2 , and water.
(a) Balance the chemical equation for the reaction and fill in the missing state
symbols.
……. Ca(OH) 2 (s) + ……. HCl ( ) Æ ……. CaCl 2 (aq) + ……. H 2 O ( ) [2]
End of Section A
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10
Paper 4
Section B (16 marks)
B1 The ‘dot and cross’ diagram shows the arrangement of all the electrons in a
molecule of compound Z.
1p
key
6p x and z = electron
1p 1p p = proton
1p
(a) Using the Periodic Table, write the chemical formula of Z. ………………… [1]
……………………………………………………………………………………… [1]
temperature / qC
time / min
R S
-162
P Q
-182
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………………………………………………………………………………..
………………………………………………………………………………..
……………………………………………………………………………….. [1]
PQ …………………………………………………….
QR ……………………………………………………. [2]
(d) Carbon dioxide, CO 2 , has the same type of bonding as Z. Draw a ‘dot and
cross’ diagram to show the arrangement of all the electrons in a molecule of
carbon dioxide.
[2]
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12
B2 Eucalyptol is one of the active ingredients found in eucalyptus oil which is used as
an essential oil for aromatherapy. Chromatography was done on four different
brands of essential oils, A, B, C and D, using alcohol as the solvent. The results
are shown in the chromatogram below.
start line
eucalyptol A B C D
(a) State the essential oil(s) containing eucalyptol as one of the ingredients.
……………………………………………………………………………………… [1]
(b) State and explain whether essential oil D is a pure substance or a mixture.
………………………………………………………………………………………
……………………………………………………………………………………… [2]
(c) Explain why the start line must be drawn using a pencil instead of a pen.
………………………………………………………………………………………
……………………………………………………………………………………… [1]
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(d) Eucalyptol has a melting and boiling point of 5 °C and 176 °C respectively.
It is separated from eucalyptus oil using the following separation technique
shown in the diagram below.
thermometer
water out
X condenser
fractionating
column
water in
conical
round-bottom flask
flask
Y
eucalyptus oil
boiling
chips
heat
……………………………………………………………………………….. [1]
(iii) In the boxes below, draw diagrams to show how the particles are
arranged at positions X and Y.
position X Y
diagram of
particles
[2]
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14
R 38 2, 8, 6
S 16 32
T 19 38
U 30 2, 8, 5
……………………………………………………………………………………… [1]
(c) Using the Periodic Table and the table above, name the element that atom
T represents.
……………………………………………………………………………………… [1]
……………………………………………………………………………………… [1]
………………………………………………………………………………..
……………………………………………………………………………….. [1]
……………………………………………………………………………….. [1]
………………………………………………………………………………………
……………………………………………………………………………………… [1]
End of Paper 4
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15
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Answer Scheme
Do not turn over the paper until you are told to do so.
o.
Write in dark blue or black ink pen on both sides
es of the pappaper.
perr.
orrectio
io fluid.
ion
io
Do not use staples, paper clips, glue or correction d..
At the end
he end off tthe
en examination,
he exa
ami
m na
atio , hand
tion nd in
nd in your
yyourr OTAS
ou TAS and
OTA nd question
an estion paper.
ques
ques
The number
er of
mbe
be marks
of mar
arks
ark is gi
given
giv
ve
en in
nbbrackets
rackets [ ] at tthe
ack he end of each question or part question.
Marks Max
Section
Awarded Marks
Paper 3 20
Section A 14
Paper 4
Section B 16
Total 50
This question paper consists of 15 printed pages including the cover page.
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61
2
A beaker
B burette
C measuring cylinder
D pipette
hydrogen chloride
ammonia
am
mmo
moni
na
ctions can
What deductions can be
ca b made
mad
ad
ade about
ab
abou
out the
th
he properties
prrop
p operrttiies of the
e two
tw ga
gases?
ase
ses?
s?
am
mmo
moni
na
ammonia hydroge
hy
hydrogen chloride
density
dens
density
ns y solubility
so
s olu
olu
lubi
b liity
ty iin
n wa
w
water
ate
ter de
density solubility in water
le dense
less d than
A denser
de
dens
nser than
than
ha
an airr insoluble
insollublle insoluble
air
less dense than
B denser
de
dens
n er than
tha
an air
aiir
a soluble
solu
solubl
be soluble
air
les
less
lesss dense
den
nse
se tthan
han
C insoluble
ins denser than air insoluble
airr
a
ai
de
ens
nse
less dense e th
than
D soluble denser than air soluble
airr
ai
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3
process 1 process 2
process 3 process 4
5 Which
hich substance
Wh su
ubsta
an ce has
nc h s particles
ha partic les that
iccle tthat are
hat e arranged
arre arr ed in a closely
rrange closel packed and disorderly
manner
ma
ann e at
nner
nner at 78 °C
°C?
C?
melting
me
elting
gp point
pooiin
nt / °C
°C boiling
oiling point / °C
bo
A -185
-18
18
18
855 8
B --63
6
63 67
C 0 81
D 98 214
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4
6 The table shows some information about the solubilities of 3 solids, X, Y and Z.
Some of the following steps could be carried out to obtain pure Z from a mixture of the
three solids.
1 add alcohol
2 add water
3 evaporate the filtrate
4 filter
In what order should the steps be carried out to obtain pure solid
olid Z?
A 1, 4, 3
B 1, 3, 2, 4
C 2, 4, 3
D 2, 1, 4, 3
7 ystals in tthe
A student found some crystals he
he labor
raattor
o y.
laboratory.
owing met
Which of the following methods
etth
e ho
o
ods is
is suitable
suitititab
su able to
ab o determine
d termine the
de th
he purity
purity
y off the
th
he cr
crys
crystals?
y tals?
A Measu
su
ure the
Measure he
he size
siz
ize of the hee crystals.
cryyssttal
a s.
B Measure
Mea
e su r the
sure e mass
maasss of of the he crystals.
the crry
ystal allss..
C Measure
Measu e the
urre e solubility
sol
olub
ubilililitity o
off tthe
hee crystals.
cryst
rry
yst
sta allss..
D Measure
Measure
re
e the
the
e melting
melting p point
on
oi ntt of
of the
tth
he cr
he ccrystals.
rystalslss.
8 A whit
itte po
white p wder is
powder s fformed
orrm
o meed wh
when zzinc
when incc is
in i co
ccompletely
mpl burned in air.
h row
Which ro
ow correctly
corr
corrrec
ectl
tly describes
desc
scri
scribe
ribe
bes the white
w powder, zinc and air?
e po
white powd
wder
wd
powder zinc air
A compound
co
omp
mpound element mixture
B compound
comp mixture element
C element compound mixture
D mixture element compound
9 Which of the following shows the correct relative charges of the subatomic particles in
an atom?
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5
4p key
5n z = electron
p = proton
n = neutron
What is the nucleon number of this element and to which Group does it belong to?
A ସ
ଽ܆
B ହ
ସ܆
C ଽ
܆
ସ
D ଽ
ହ܆
ହ
12 The
e electronic
e ec
ele tr
tron
onic
ic structures
strructure
res of
re of four
fou
our atoms are
are shown
sh below.
b
ich atom
Which ato
at om
m iss chemically
ch
c hem
miicca
allllyy unr
nrrea
eact
ctiv
ct ive?
iv
unreactive? ?
A B
C D
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6
A T
B T2
C T
D T2
14 Two particles P and Q have the following composition as shown in the table shown
below.
16 Wh
Which
i h of
hic of the
the following
he fol
o lo
owi
w ng
n iss m
mo
most
ost
st likely
lik
i ely to b
be
e an iionic
o ic co
on compound?
me
m eltting
melting g point
po
poiin
nt / °°C
C boilililin
bo
boiling ing
ing point / °C electrical conductivity in solid state
A -20
-205
20
2
205
05 -183
-18 poor
B --153
15
153 50 good
C 105757 2050 poor
D 1798
179
7988 2978 good
A 8
B 14
C 16
D 26
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7
A XY
B XY 2
C X2Y
D YX 2
x y
A 1 1
B 2 2
C 1 2
D 2 1
20 A mo
m
molecule
le
ecu
ule CH
H3C
CO
O 2 X has a relative
rela
relati
tivve
e molecular
mol
olec
ecular m
mass
asss of
as o 82.
82
What
at iss the
at th
he identity
iid
de
en
ntiity
t of e
el
le
em
men
nt X?
element X?
A an
a nti
timoony
antimonyny
B le
ead
ad
lead
C sodi
diu
diium
sodiumum
D anadium
vanadiumum
m
End of Paper 3
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8
Paper 4
Section A (14 marks)
A B C
D E F
(a) m whic
State the diagram ich be
which best
st repre
ese
ent
represent
(ii) a pu
pure
ure
e co
ccompound;
omp
mpou
un
nd
d; F [1]
((iii)
(iii) a mixture
m xt
mixu urre of e
elements.
le
eme
menttss.. B [1]
(b)
(b
b) A is
is a dia
ia
atomi
to
om c g
diatomic ga
as while
gas whiille E is
wh i am onat
on ato
at omic g
monatomic gas. Suggest a possible identity
of EE..
helium
h
he lium / n
li neon argon
eon / a
eo ar
rgo
g n/k krypton
kr
ryp on / x
ypto xenon / radon
………………………………………………………………………………………
……
… ……………
……
… ………… …………… ……………
…… [1]
A2 Magnesium m oxide
esium oxid
ox ide
ide is used
use to make refractory linings for blast furnaces because of
its high mel
melting
ltin point.
ting poi
(a) (i) Write the symbols for magnesium ion and oxide ion.
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9
(b) Draw the ‘dot and cross’ diagram to show the bonding in magnesium oxide.
Mg O
key
y – electron of Mg
x – electron of O
(d)
(d
(d) M olten
Moltennm aggne
nesium oxide
magnesium oxi
xide
de is
is able
ab
able
le to
to conduct
cond
duc
uctt electricity.
electric
el Explain why.
M
Moolten m
Molten ag
gne
n sium
magnesium um
um oxide
oxixide contains
con
o taain
ins mobile
mo
m obi
b le iions that can carry charges/
………………………………………………………………………………………
…… ……… …………… ……
… ………
……………… ………
… ……
ions
/ have ioons tthat
ns ha
h are
at ar ffree
re fr eee tto
ommove
moove to carry charges.
………………………………………………………………………………………
…
…… ……
… ………
……………………… ………
…… ………… [1]
A3 Solid calcium
m hy
hydr
dro
dr oxide Ca(OH) 2 , reacts with dilute hydrochloric acid, HCl, to
hydroxide,
form aqueous
ueou
ouss calcium
calciu chloride, CaCl 2 , and water.
(a) n the chemical equation for the reaction and fill in the missing state
Balance
symbols.
M r of Ca(OH) 2 = 40 + 2(16 + 1) = 74
0 m – no working
relative formula mass = 74 [1]
End of Section A
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10
Paper 4
Section B (16 marks)
B1 The ‘dot and cross’ diagram shows the arrangement of all the electrons in a
molecule of compound Z.
1p
key
y
6p x and z = el
ele
electron
ectro
1p 1p p = pr
proton
prot
oton
on
1p
(b) Wh
W at type
What typ
y e off bonding
bondi
on
nd
diing
ng is pres
ese
esen
nt in
present nZ ?
Z?
c
covale
lent
lent b
covalent on nding
bonding
………………………………………………………………………………………
… ……… ……………………… ……
… ………………… ………
………… [1]
em
emp
mpper
p urre / qC
temperature
te eratur
er
eratur
u C
time / min
R S
-162
P Q
-182
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11
……………………………………………………………………………….. [1]
QR liquid [2]
(d) Carbon dioxide, CO 2 , has the same type of bonding as Z. D Draw a ‘dot and
cross’ diagram to show the arrangement of all the electrons
trons in a molecule of
carbon dioxide.
C O
O
key
ke
k y
electron
x = elecctrron off C
on o
y = el
e
electron
leec
c
ctr
tron
tr o of
of O
[2]
1m–c correct
coo
orr
rrrect sharing
ec sh
sharinng of
of electrons
electro
1m–c correct
coorr
rre
rrec
ec arrangement
ct ar
rrang
ra
ang ement of electrons
gem
-1
1 – showing
sh
howin only
ng onnly valence electrons
y valen
(A:
A: no key)
(A key
eyy)
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12
B2 Eucalyptol is one of the active ingredients found in eucalyptus oil which is used as
an essential oil for aromatherapy. Chromatography was done on four different
brands of essential oils, A, B, C and D, using alcohol as the solvent. The results
are shown in the chromatogram below.
start line
eucalyptol A B C D
(c) E
Ex plai
plaiin wh
a
Explain whyhy thhe st
the sstart
ta
arrt lliline
in
neem usst b
must be
ed raw
rawn
drawn n using
gap enciil in
en
pencil instead of a pen.
P
Pe
Pen n in
inkk coonttai
a ns a m
contains mi
mixtureixt
xtu
urre of
of dy
dyes
e which
dyes whic
ch wi
w
wil
will
ill sep
separate out with the
………………………………………………………………………………………
………… ……………………… ……… ……… …… …
………
……
… …………
………………
solvent
so
s olv e t and
lven and interfere
an inte
terf
te erre with
rfe with thee results.
res
esul
ults
t .
………………………………………………………………………………………
………… … …… ……… ………… …… …………… …………
…… … … [1]
(R:
((R affect,
R: af
a fe
ec smudge,
ctt, sm
smu uddge, spread)
sp pre
ead
ad)
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13
(d) Eucalyptol has a melting and boiling point of 5 °C and 176 °C respectively.
It is separated from eucalyptus oil using the following separation technique
shown in the diagram below.
thermometer
water out
X condenser
fractionating
column
n
water in
conical
round-bottom flask
flask
Y
eucalyptus oil
boilin
boiling
ng
chipss
heat
he
ea
att
(i) Name
me tthe
me h sep
he separation
epa
eparrat atio
ion
on technique
tecch
te hniq
qu
ue
e used
used
sse
ed to obtain
obt
btai
bt ain
ain eucalyptol.
eu
uca
caly
lypt
ly pto
pt ol.
fractional
frac
cti
t on al distillation
onal disti
tiillllatio
on
………………………………………………………………………………..
…
……………………… ……… …………… ……… …… ………
… ………… ……………
…… [1]
((ii)
ii) State
St
S tat the
ate th temperature
he temp per
ea ure observed
attur obse
ob r ed on
serv on the
the thermometer
t erm
th when eucalyptol
iss being
be
eiing
ng co
collected
ollle
ec
cte
ted in the
he con
he conical
on
nical
iccal fflask.
lask.
la
176
temperature
tem = …………………………. °C [1]
(iii)
(iii
(iiiii) In
n the
the boxes
th bo
oxe
xess below,
be draw diagrams to show how the particles are
arranged
arrang
ngged at
at positi
positions X and Y.
positi
position X Y
diagram of
particles
[2]
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14
R 16 38 2, 8, 6
S 16 32 2, 8, 6
T 19 38 2, 8, 8, 1
U 15 30 2, 8, 5
(c) abo
bo
ove
ve, name
Using the Periodic Table and the table above, name
name the
e element
ele
leme
men
ment that atom
T represents.
potassium
………………………………………………………………………………………
……… …………………
… …… ………
… …… ……… ………
………… ………………… … … [1]
Whhicch atom
Which om ((R,
om R, S,
S, T or
or U)
U) is
is in the sam
ssame
saame
me group
group a
as
s at
atom
om Q?
Q?
U
………………………………………………………………………………………
… …… ……………
……………… ………… ……
…………… ……………………… ………
…… ……… [1]
(e)
(e
e) (i)
((ii)
i) Define
De n the
effiine e term
errm ‘isotopes’.
te ‘i‘iso
s topes’..
Isotopes
Isotop
Is ope
op s are
es re atoms
are atoms off tthe
at he same element with the same number
he
………………………………………………………………………………..
…
…… ……… …………………… …………
……
of p
of protons
rrotons but
oto bu different
ut diff
d
di f erent number of neutrons.
iff
………………………………………………………………………………..
… ……… ………
… …… [1]
(ii) Which
Whic
Wh ich
ic h two atoms are isotopes?
R and S
……………………………………………………………………………….. [1]
……………………………………………………………………………………… [1]
End of Paper 4
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Class Index Number
Name:
Write your name, class and index number on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams, graphs, tables or rough working.
Do not use staples, paper clips, glue or correction fluid.
There are twenty questions. Answer all questions. For each question there are four possible
answers A, B, C and D. Choose the one you consider correct and record your choice in soft
pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very
carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong
answer. Any rough working should be done in this question paper.
A C
B D
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3
Acid Solution
A Burette Pipette
B Pipette Burette
C Measuring cylinder Pipette
D Burette Measuring Cylinder
A C
B D
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4
Heat
Which of the following shows the colour and solubility in water of the two
solids present in the mixture?
Solid 1 Solid 2
A Green Insoluble White Soluble
B Green Soluble White Insoluble
C Green Insoluble White Insoluble
D Green Soluble White Soluble
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5
W X Y Z S1 S2
A W contains S 1 and S 2 .
B X is the artificial colouring, S 1 .
C Y is a pure substance.
D Z contains S 1 .
N is a liquid which forms carbon dioxide and water when burnt in air.
M N
A Element Compound
B Compound Compound
C Compound Mixture
D Element Mixture
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6
A I and II only
B I and III only
C II and III only
D I, II and III
13 Which of the following is correct regarding the relative mass of the sub-atomic
particles of an atom?
A Z+
B Z-
C Z2+
D Z2-
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A ZnN
B Zn 3 N 2
C Zn(NO 3 ) 2
D Zn 3 (NO 3 ) 2
A A covalent compound Y 2 X.
B A covalent compound YX 2 .
C A ionic compound Y 2 X.
D A ionic compound YX 2 .
18 Which of the following will form a simple covalent compound with oxygen?
A Aluminium
B Lithium
C Neon
D Nitrogen
A LiF
B F2
C O2
D H2O
End of Paper
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Class Index Number
Name:
Write your name, class and index number on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams, graphs, tables or rough working.
Do not use staples, paper clips, glue or correction fluid.
Section A
Answer all questions in the spaces provided.
Section B
Answer all questions in the spaces provided.
The number of marks is given in brackets [ ] at the end of each question or part question.
A copy of the Periodic Table is printed on page 8.
A B C
D E F
Fill in the table below by stating the diagram(s) that matches with the
description.
Description Diagram (A to F)
A pure element
2 The table below shows the melting and boiling points of nitrogen and
hydrogen.
Movement: ………...……………………………………………………
Arrangement: ...……………………………………………………………
[2]
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3
(b) When cooled from -100oC to -256oC, state whether nitrogen or hydrogen
will condense first. Explain your answer.
…………………………………………………………………………………..
[1]
…………………………………………………………………………………..
[1]
(d) Nitrogen and hydrogen reacts to form ammonia, NH 3 , during the Haber
process.
[2]
The dot-and-cross diagram below shows the arrangement of all the electrons
in a molecule of compound Z.
Y X Y
…………………………………….……………………………………………
[1]
(b) Use the Periodic Table to identify elements X and Y.
X: …………..…………………………..
Y: …………..…………………………..
[1]
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4
……………….…………………………………………………………….
……………….…………………………………………………………….
[1]
[2]
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5
4 Fig. 4.1. shows the heating curve of a mixture containing substance Y, in liquid
state, contaminated with some impurities.
Temperature / oC
200
179
172
30
Time / min
Fig. 4.1.
(a) Based on the heating curve, suggest why the mixture is impure.
……………………………………………………………………………………….
[1]
(b) Tick(3) the box which shows the boiling point of pure substance Y.
Tick (3)
171oC
174oC
180oC
199oC
[1]
(c) The mixture can be purified using the method shown in Fig. 4.2. below.
Condenser
Boiling chips
Fig. 4.2
JWSS Mid-Year Examinations 2019 Science (Chemistry) 5105/5107/04 Secondary 3NA
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6
…....………………….…………………………………………………………
[1]
(ii) Draw arrows on Fig. 4.2. to indicate the direction of flow of water in the
condenser by drawing arrows. Label ‘water in’ and ‘water out’.
[1]
…....……….……………………………………………………………………
[1]
…....……….……………………………………………………………………
[1]
…....……….……………………………………………………………………
…....……….……………………………………………………………………
[1]
(iii) When separating solution of C, the student has forgotten to test for
saturation. He continued heating until all the solvent has evaporated.
Explain why.
…....……….……………………………………………………………………
[1]
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7
(a) Complete the table below for the formula and number of electrons for
magnesium and chloride ions.
Chloride ion
[2]
[3]
(c) (i) Magnesium chloride has high melting and boiling points.
Explain why.
………..........………………………………………………………………….
………..........………………………………………………………………….
………..........………………………………………………………………….
[2]
………..........………………………………………………………………….
[1]
End of Paper
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2019 MYE 3N(A) Paper 3 MS
1 2 3 4 5
B C C A C
6 7 8 9 10
D D B D D
11 12 13 14 15
A A D B B
16 17 18 19 20
C C D B A
[Total: 3]
H N H
H
x pair
airr off el
3 pa electrons
e ectron shared
ns sshhaarred
ed [1]
(For each
( or e
(F ach pair
ac r: 1 e- fr
pair: ffrom
om H, 1 e- fr
m H, from
fro
om N)
x 1 lone
ne
eppair
aiir off e
a electrons
lectro
le ons o
onn nitro
nitrogen [1]
Maximum 1 mark
if no dot-and-cross
to differentiate
electrons from
nitrogen/hydrogen
atoms
[Total: 6]
water in
[Total: 8]
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2019 Sec 3 NA Science Chemistry SA2
Bartley Sec 2
Answer all the questions in this section. Write your answers in the separate Multiple Choice Answer Sheet
Which letter represents a mixture of solid and liquid states of the substance?
temperature/ oC
D
C
time/ min
0
A 3
B 4
C 6
D 8
BSS/ 2019/ End-of-Year Examination/ 3NA Sc(Chem)
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3
A 3-
B 3+
C 5-
D 5+
8 Element X forms the ion X2+ while element Z forms the ion Z-.
What is the chemical formula of the compound formed when element X reacts with element Z?
A XZ
B XZ 2
C XZ 3
D X2Z
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4
A 2 g of hydrogen gas, H 2
B 14 g of nitrogen gas, N 2
C 20 g of argon, Ar
D 24 g of carbon, C
A Br B K C N D Ne
12 What is a trend of the elements from the left to the right of the Periodic Table?
group period
A I 1
B I 4
C VII 1
D VII 4
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14 A piece of potassium is placed in a trough of cold water added with a few drops of Universal Indicator.
A explosion
B potassium darts around the surface of the water
C Universal Indicator turns from green to red
D vigorous effervescence
16 What are the products of the reaction between magnesium and steam?
18 What is the observation when a piece of silver is added to dilute hydrochloric acid?
A effervescence
B explosion
C no visible change
D solution turns greenish-yellow
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6
A ductile
B malleable
C soft
D sonorous
20 The observations made when three unknown metals, X, Y and Z are separately added to water, is
shown in the table below.
X explosion
Y no visible change
Z effervescence
A X, Y, Z
B X, Z, Y
C Y, X, Z
D Y, Z, X
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7
1 The table shows four elements and some information about them.
(a) Complete the table above to describe the different elements. [4]
(b) Draw the ‘dot and cross’ diagram to represent the arrangement of electrons in a
molecule of carbon dioxide, CO 2 .
[2]
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8
2 Sodium, Na, is a highly reactive metal found in Group I of the Periodic Table. Fluorine, F 2 , is a pale
yellow gas found in Group VII of the Periodic Table.
_____________________________________________________________________ [1]
_____________________________________________________________________ [1]
(c) Sodium and fluorine reacts in a highly explosive reaction to produce the salt sodium
fluoride, NaF, as the only product.
11.5 g of excess sodium reacts with fluorine to produce 0.2 moles of sodium fluoride.
(i) What is the number of moles of sodium that is added in this reaction?
3 In ancient Egypt, copper was added to gold to form an alloy called red-gold. Besides giving the
gold a nice red hue, it made the gold stronger.
[2]
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9
4 (a) A water-soluble ink, X, is made up of several dyes. A student carried out an investigation
to determine the types of dyes found in ink X. The set-up for the experiment is shown
below.
cover
beaker
solvent
________________________________________________________________ [1]
(ii) Two mistakes were made in her experimental set-up. Suggest the changes she will
need to make.
change 1: _______________________________________________________
_______________________________________________________
change 2: _______________________________________________________
_______________________________________________________
[2]
(iii) Some sand was found in the liquid ink X. Suggest the separation method that is
required to remove the sand from the mixture.
___________________________________________________________________ [1]
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10
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11
5 The table below lists a set of elements and their electronic configurations.
aluminium 2, 8, 3
calcium 2, 8, 8, 2
fluorine 2, 7
hydrogen 1
lithium 2, 1
(a) Metals and non-metals can react with one another to form compounds with high melting
points.
(i) Name two elements that can combine to form a compound with high melting point.
(ii) Give the chemical formula of the compound formed from the elements named in
(a)(i).
___________________________________________________________________ [1]
(iii) State the type of bonding found in the compound formed when metals and nom-
metals react.
___________________________________________________________________ [1]
___________________________________________________________________ [1]
(b) A non-metal can react with another non-metal to form a compound with low melting point.
(i) Name two elements from the table that will react to form a compound with low
melting point.
(ii) Write the chemical equation for the formation of the compound from the elements
named in (b)(i).
___________________________________________________________________ [2]
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12
___________________________________________________________________
___________________________________________________________________ [1]
6 (a) Fluorine, chlorine, bromine and iodine are elements from Group VII of the Periodic Table.
___________________________________________________________________ [1]
(ii) Describe the trend in the colour of Group VII elements down the group.
___________________________________________________________________ [1]
(iii) When fluorine is bubbled into a solution of potassium iodide, a brown solution is
formed. Explain this observation.
___________________________________________________________________
___________________________________________________________________
___________________________________________________________________ [2]
(b) You are provided with three unlabelled metals. It is known that the three metals are
calcium, iron and gold and they can be identified using an acid.
(i) Give an example of an acid that you can use to identify the metals.
___________________________________________________________________ [1]
(ii) Circle the observation for each of the metal with the substance having pH 1.
END OF PAPER
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BLANK PAGE
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3N Sc(Chem) End of Year Examinations 2019
Section A
1 B 2 D 3 B 4 A 5 B
6 B 7 C 8 B 9 B 10 D
11 D 12 D 13 B 14 C 15 C
16 C 17 C 18 C 19 B 20 D
Section B
Question 1
(a) Every 2 correct 1 mark
carbon C 6 6 2,4
oxygen O 8 8 2,6
magnesium Mg 12 12
2 2,8,2
Chlorine Cl 17
17 17 2,8,7
2,
Question
Ques on 2
sttiion
(a) It
It has
h s 1 valence
ha vvaalencce eel
electron;
lec
ectrroonn;
n;
(b)) Soft/low
Sof
offt/lo
tt//lo
low density/low
low ddeens
nsit
ityy//lloow me
melt
melting
ltin
ltingg and bboiling point/good conductor of heat or
in
electricity/malleable/ductile/shiny;
lectr
tric
tr icitty/
ic y/malllea
eabl
ble/
bl e/du
e/ dduuctil
(c) (i) No. of
o moles
oles = 11.5/23;
mol 11
= 0.5 mol;
(ii) Mass = 0.2 x (23 + 19);
= 8.4 g;
Question 3
Correct ratio;
Correct representation of alloy (Min 3 layers, closely-packed);
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Section C
Question 4
(a) (i) Chromatography;
(ii) Place start line above solvent;
Draw start line with pencil;
(iii) Filtration;
(b) (i) pipette;
(ii) electronic stopwatch;
(iii) electronic balance; Reject ‘electric balance’
(iv) thermometer;
Question 5
(a) (i) Any metal (Al, Ca, Li) + Any non-metal
metal (F, H)
H);;
(ii) Correct formula;
(iii) ionic bonding;
(iv) Conducts only
ly in molten/aqueous
mol
olte
lte
ten/
n/aqu ous state;
aque staatte;
st
(b) (i) Fluorine hydrogen;
ne andd hydro
rro
oge
gen;
n;
(ii)
i) H 2 + F 2 ĺ
ĺ+)
+
+)
Correct
Co
C rrreecct formula;
fo
orrm
mul
ula;
a
a;
Balanced
Balanc d eequation;
ceed qquuation;;
(iii)
ii ) Small
(iii
(i Smaalll am
Sm aamount
oun of eenergy
unnt of neerg required
rgy requ
quir
qu ed tto
ired
ir overcome weak intermolecular forces;
o ove
Questionn 6
(a) (i) Halogen;
Halo
l geen;
(ii) Darkens;
arke
k ns;
(iii) Fluorine is more reactive than iodine;
And will displace iodine from a solution of its ions;
(b) (i) Sulfuric/hydrochloric/nitric acid;
(ii) calcium: vigorous effervescence;
iron: mild effervescence;
gold: no visible change;
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BEATTY SECONDARY SCHOOL
END OF YEAR EXAMINATION 2019
_________________________________________________________________________________
Write your name, class and register number on all the work you hand in.
Write in dark blue or black pen.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
At the end of the examination, hand in your answers to Paper 3 and Paper 4 separately.
The number of marks is given in brackets [ ] at the end of each question or part question.
Section Marks
A / 14
B / 16
Total / 30
_________________________________________________________________________________
This paper consists of 12 printed pages (including this cover page).
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2
Section A
1 The diagrams below represent the particles in three different substances A, B and C at room
temperature.
A B C
……….………………………………………………………………………………………………..[1]
(b) mixture.
……….………………………………………………………………………………………………..[1]
2 Using water as the solvent, Amber carried out chromatography on three substances I, II and III.
The chromatogram obtained is shown below.
………………….……………………………………………………………………………...…….......
………………….……………………………………………………………………………...……...[1]
(b) Describe two other conclusions that can be made from the chromatogram.
………………….……………………………………………………………………………...…….......
………………….……………………………………………………………………………...…….......
………………….……………………………………………………………………………...……...[2]
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3
3 Five metallic elements, which belong to the same group in the Periodic Table, are given special
symbols. The special symbols and the order of reactivity of these metals are shown below.
Aa Bb Cc Dd Ee Ff
It is further given that Aa combines spontaneously with oxygen present in air to form a compound
with the formula Aa2O.
.…………………………………..……………..…………………………………..………………… [1]
(b) State the group that these elements belong to in the Periodic Table.
.……...…………………………..……………………………………..……………………………… [1]
(c) Write down the formula of the compound formed between the elements Ee and chlorine.
…..……………………………………………………………………………………..……………… [1]
(d) Suggest the name of the elements given the special symbols Aa and Ff.
Aa
Ff
[1]
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4
4 The apparatus shown is used to collect the hydrogen gas produced from the reaction of lithium
metal and cold water.
reactants water
(a) Write down a balanced chemical equation, including state symbols, for the reaction between
lithium metal and cold water.
…..……………….………………………………………………………….………..……………… [2]
(b) Effervescence is observed in the reaction. Describe another observation that you would expect
to see in the reaction flask.
…..……………….………………….………………………………………………..……………… [1]
…..………..….…………………………………………………………………..………….…… [1]
(ii) State the physical property of the gas that allows it to be collected by this method.
….………….………………………...…………………………………………..………….…… [1]
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5
Section B
Answer any two questions from this section in the spaces provided.
5 Heptanol is an organic compound with the chemical formula C7H15OH. It has a pleasant smell and
is sometimes used in cosmetics due to its fragrance.
(a) The figure below shows the heating curve of heptanol from –50 °C to 200 °C.
……………………………………….……………………………………….…………………....
…………………………………………………………………………….………………….....[2]
(iii) In the box below, draw a diagram to represent the arrangement of the heptanol particles
at –100 °C.
[1]
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6
(iv) Describe the changes in the arrangement and movement of the heptanol particles as the
temperature decreases from 200 °C to 0 °C.
…………………………………….…………………………………….…………………...........
.………………………………………………………………………….…………………...........
….……………………………………………………………………….………………….......[2]
(b) When heptanol was heated, it reacted with oxygen in air to form carbon dioxide and water
vapour.
.………………………………………………………………………….………………….......[1]
Mr = …………………… [1]
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7
6 The figure shows the electronic structures of four elements drawn by a student.
(a) One of the electronic structures in the figure above was drawn wrongly. Explain which element
has a wrong electronic structure.
.……...……………….…………..……………………………………..…………….……………… [1]
(b) State the two elements which belong to the same period, and the period that they belong to.
.……...……………….…………..……………………………………………………………… [1]
(ii) Draw a ‘dot and cross’ diagram of the compound formed between element 3 and element
4 showing only the outer shell electrons.
[2]
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8
(d) (i) Determine the type of compound formed between element 1 and 3.
.……...……………….…………..……………………………………..…………….……….… [1]
(ii) Draw a ‘dot and cross’ diagram of the compound formed between element 1 and element
3 showing only the outer shell electrons.
[2]
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9
7 Petrol is a mixture of hydrocarbons (compounds containing carbon and hydrogen atoms only)
containing between 5 and 10 carbon atoms and is used as a fuel for internal combustion engines.
A B
C D
.……...……………….…………..……………………………………..…………….……….…
.……...……………….…………..……………………………………..…………….……… [2]
.……...……………….…………..……………………………………..…………….……… [1]
(b) The table shows the boiling points of some of the hydrocarbons in the petrol fraction.
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10
(i) On the grid, plot a graph to show how the boiling point changes with the number of
carbon atoms in these hydrocarbons. Draw a best-fit curve through the points.
180
boiling point
/ °C
160
140
120
100
80
60
40
number of
carbon atoms
[2]
(ii) Use your graph to deduce the boiling point of the hydrocarbon with 7 carbon atoms.
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11
(c) (i) Suggest a method of separation that can be used to separate the hydrocarbons A, B, C
and D.
...…...……………….…………..…………………………………..………………….……… [1]
.……...………………...………..…………………………………..………………….……… [1]
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BEATTY SECONDARY SCHOOL
END OF YEAR EXAMINATION 2019
_________________________________________________________________________________
There are twenty questions on this paper. Answer all questions. For each question there are four
possible answers, A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the separate Answer
Sheet.
_________________________________________________________________________________
This paper consists of 8 printed pages (including this cover page).
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2
1 The four pieces of apparatus shown below can be used to measure volumes. Which
apparatus is the most suitable to measure 20.5 cm3 of liquid?
A B C D
2 A student intends to measure the volume of carbon dioxide gas produced from the reaction
between 10 cm3 of hydrochloric acid and excess calcium carbonate. The list of apparatus
available is shown below.
A 1 and 2
B 3 and 4
C 2 only
D 4 only
first last
A dissolve evaporate crystallise filter
B dissolve filter evaporate crystallise
C filter dissolve evaporate crystallise
D filter crystallise evaporate dissolve
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3
thermometer
electric mixture
heater
1 boiling 2 condensation
3 freezing 4 melting
A 1 and 2
B 1 and 4
C 2 and 3
D 2 and 4
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4
F G H
A compound element mixture
B compound compound element
C mixture element compound
D mixture element mixture
9 The nucleon number of an isotope of copper is 60. How many protons, neutrons and
electrons are present in an atom of this isotope?
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5
W X Y Z
4 protons 5 protons 5 protons 6 protons
5 neutrons 5 neutrons 6 neutrons 7 neutrons
12 Non-metals can form both covalent bonds and ionic bonds. Element X can be found in
Group VI in the Periodic Table. How many covalent bonds does it form in total and what is
the charge on an ion of X when it forms an ionic bond?
13 A metal X and a non-metal Y react together to form an ionic compound X 2Y. Which
statement is correct when this compound is formed?
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6
14 Aspirin is an oral medication that is used to reduce fever and relieve muscle aches,
toothaches, common cold, and headaches. The structural formula of aspirin is shown
below.
A C9O4H8N2
B CH4COC6H4COH
C CH3CO2C6H4CO2H
D CH3CO2C6H4N2CO2H
17 Which statement is incorrect about the trends of Group VII elements on descending the
group?
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7
18 Which row shows the correct properties of the Group VII elements?
A 60
B 80
C 120
D 216
20 The relative molecular mass (Mr) of a compound with the formula FexO4 is 232. What is
the value of x?
A 2
B 3
C 4
D 6
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3NA EOY 2019 Answer Key
5105/03
1 2 3 4 5 6 7 8 9 10
A B B C B C A C B C
11 12 13 14 15 16 17 18 19 20
D A D C B B D C C B
5105/04
1 (a) A, C 1
(b) B 1
2 (a) Substance II is more soluble in water as the spot has travelled a further distance on the 1
chromatogram.
(b) Substance I is a mixture made up of three components.
nts. 2
The same substance is present in substances I and II.
Substance II and/or III is/ are pure.
(Any two)
Aa
a Fran
an
anci
cium
um
Francium
F
Ff Lith
thiu
thium
Lithium
4 (a) 2Li(s)
(s) + 2H
2H2O (l) Æ 2 2LiOH
LiiOH
L OH (aq(aq)
q) + H2 (g
((g)) 2
1 mark:rk: Balanced
Bala
Ba anceded cchemical
hemica
he ca al e
eqqua
u ti
t on
equation
1 mark: k: St
tat
ate symbol
State sy
s y ol
symbolsols ((pprro
ovided correct balanced chemical equation)
(provided
(b) Li dissolves
ves in wa
water/
ateer/
r/ 1
Li floats onn water
wa er / darts
atte dart on water surface.
(c) (i) Displacement
acem of water 1
(ii) Insoluble in water 1
(ii) The temperature [1] at which a substance changes from the solid state into liquid 1
state [1].
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2
(iii) 1
(iv) At 200 °C, the particles were far apart [1 mk pt] and moved rapidly in all 2
directions [1 mk pt].
At 0 °C, the particles are closely packed [1 mk pt] and slide over one another
[1 mk pt]
1 ma
mark:
ark
rkk:: co
ccorrect
orrecct charges
char
ch arge
arg s and number of ions
1 mark: correct
corr
co rrec
rr ectt electronic
ec electro structure
(d) (i) Covalent
vale
ent compound.
compo 1
(ii) 2
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3
7 (a) (i) Relative molecular mass, Mr, is the average mass of an molecule [1] of the 2
1
substance when compared with the mass of of an atom of the carbon-12
12
isotope [1], 126 C.
(ii) B 1
(b) (i) Correctly plotted points [1] 2
Smooth curve [1]
(ii) 98 °C (Accept value from student’s graph) 1
(c) (i) Fractional distillation. 1
(ii) A, B, C and D are miscible liquids / have different boiling points. 1
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CANBERRA SECONDARY SCHOOL
Do not turn over the paper until you are told to do so.
Write in dark blue or black ink pen on both sides of the paper.
Do not use staples, paper clips, glue or correction fluid.
Answer ALL questions in Paper 3. Indicate your answers on the OTAS provided.
You are advised to spend no more than 30 minutes on Paper 3.
Answer ALL questions in Paper 4 Section A and any TWO questions in Section B.
Write all your answers on the spaces provided.
At the end of the examination, hand in your OTAS and question paper.
The number of marks is given in brackets [ ] at the end of each question or part question.
Marks Max
Section
Awarded Marks
Paper 3 20
Section A 14
Paper 4
Section B 16
Total 50
This question paper consists of 17 printed pages including the cover page.
Setter: Ms Rebecca Ng
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141
2
1 The following steps were taken by a student to investigate a reaction between zinc and
dilute hydrochloric acid.
1. Measure and pour 20.0 cm3 of dilute hydrochloric acid into a beaker.
2. Measure the initial temperature of the acid.
3. Weigh 2 g of zinc granules and add it into the acid.
4. Measure the time taken for the reaction to complete.
2 Which of the following statements is true about particles in the solid state?
3 Chromatography was used to test for food colourings which have been banned.
The results are shown in the diagram.
Which of the three drinks tested contains both of the banned colourings?
A Fizzo only
B Juicy only
C Fizzo and Sparkle only
D Juicy and Sparkle only
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3
A B C D
8 Which of the following options contains only electronic configuration of metal atoms?
A 1 2,2 2,8,3
B 2 2,4 2,8,5
C 2,8 2,8,1 2,8,2
D 2,8,2 2,8,8,1 2,8,8,2
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4
Which of the following shows the correct chemical formula and type of compound
formed from the elements?
chemical formula
type of compound
of compound
A XW 2 ionic
B X2W ionic
C WX covalent
D WX 2 covalent
electrical conductivity
melting point / °C boiling point / °C
in solid state in molten state
A -183 -162 poor poor
B 15 104 poor poor
C 657 997 poor good
D 2040 3654 good good
12 The table shows the results of adding dilute hydrochloric acid and aqueous sodium
hydroxide to an oxide.
result of adding
dilute hydrochloric acid dilute sodium hydroxide
A no reaction no reaction
B no reaction reaction
C reaction no reaction
D reaction reaction
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5
1 metal + acid
2 metal oxide + acid
3 metal carbonate + acid
4 metal hydroxide + acid
Which method(s) will lead to the production of a gas as the other product?
A 1 only
B 1 and 3 only
C 2 and 4 only
D 2, 3 and 4 only
What is P?
A ammonium sulfate
B hydrochloric acid
C sodium hydroxide
D sodium sulfate
16 Which of the following correctly matches the gas and its identification test?
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6
I II III IV V VI VII 0
T U W
X Y
halogen appearance
fluorine pale yellow gas
chlorine yellowish-green gas
bromine red-brown liquid
iodine dark purple solid
astatine ?
A brown gas.
B black solid.
C grey liquid.
D white solid.
End of Paper 3
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7
Paper 4
Section A (14 marks)
For each statement, (a) to (c), select from the list the substance described.
…………………………………………………………………………………………… [1]
…………………………………………………………………………………………… [1]
(c) This substance when dissolved in water, turns blue litmus paper red.
…………………………………………………………………………………………… [1]
A2 The table below gives information about an atom of hydrogen and an atom of oxygen.
hydrogen 1
oxygen 2,6
(a) With reference to the Periodic Table, complete the table above. [1]
(b) Hydrogen and oxygen can react to form a compound which boils at 100 oC.
Draw the ‘dot and cross’ diagram to show the bonding in the compound formed.
Show all electrons.
[2]
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8
(c) With reference to its structure and bonding, explain why the compound in (b)
has a low boiling point.
……………………………………………………………………………………………
……………………………………………………………………………………………
…………………………………………………………………………………………… [2]
The diagram below shows the first three steps used to prepare crystals of this salt.
……………………………………………..……………………………………..
……………………………………………..…………………………………….. [1]
(ii) Name the processes being used in step 2 and step 3 respectively.
(b) The solution left in step 3 is allowed to cool for some time to allow crystals to
grow. Describe the remaining steps required to obtain a sample of pure and dry
magnesium chloride crystals.
……………………………………………………………………………………………
……………………………………………………………………………………………
…………………………………………………………………………………………… [2]
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9
(c) A student plans to prepare the salt, silver chloride, using the same method
above.
Do you expect the student to be successful in preparing the salt? Explain your
answer.
……………………………………………………………………………………………
……………………………………………………………………………………………
…………………………………………………………………………………………… [2]
End of Section A
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10
Paper 4
Section B (16 marks)
The table below shows the boiling points of the three alcohols respectively.
In order to obtain pure samples of each alcohol, the chemist set up the experiment as
shown below.
Y
[2]
(b) Suggest an apparatus that could be added to the set up to ensure a more
efficient separation of the three alcohols.
…………………………………………………………………………………………… [1]
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11
(c) Of the three alcohols present in the mixture, which alcohol will be collected last?
Explain your answer.
……………………………………………………………………………………………
…………………………………………………………………………………………… [2]
……………………………………………………………………………………………
…………………………………………………………………………………………… [1]
(e) (i) In the box below, draw a diagram to show the arrangement of particles in
P.
[1]
……………………………………………..……………………………………..
……………………………………………..…………………………………….. [1]
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12
B2 (a) John was washing his hair when some shampoo accidentally entered his mouth.
He rinsed his mouth immediately as it left a bitter taste in his mouth. After his
shower, John checked the label of the shampoo bottle. Part of the shampoo’s
ingredients list is shown below.
(i) The chemical that caused the bitter taste in John’s mouth is an alkali that
is also responsible for the soapy feel of the shampoo.
From the ingredient list above, state the ingredient that has caused the
bitter taste in John’s mouth.
……………………………………………..…………………………………….. [1]
(ii) John brought a small sample of the shampoo to the science laboratory
and diluted it with water. With the permission of his science teacher, he
added one drop of Universal Indicator into the diluted shampoo.
State the colour change that the student will expect to see in the drop of
Universal Indicator.
……………………………………………..…………………………………….. [1]
(iii) Under supervision, John did further tests and found out that a typical
1 litre bottle of shampoo contains 30 g of the salt, sodium chloride, NaCl.
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13
Seven further 2.0 cm3 portions of hydrochloric acid are added. Each time, the
mixture is stirred and the highest temperature reached is measured and
recorded.
The results for the experiment are shown in the table below.
volume of
acid added / 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0
cm3
temperature
of the mixture 21.0 24.2 27.4 30.7 32.9 31.2 29.4 27.6
/ oC
Four points from the results above have been plotted on the grid below and a
best-fit line for the four points has been drawn.
(i) On the grid, plot the remaining four points using the results above. Mark
each point with a cross (x). [1]
(ii) Draw a best-fit line for these four points in (b)(i). Extend this line to
intersect (cross) the line already drawn. [1]
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14
(iii) The acid and the alkali exactly neutralise each other at the point where
the two graph lines intersect (cross).
(iv) Write an ionic equation to show what is meant by the term neutralisation.
Include state symbols.
……………………………………………..…………………………………….. [1]
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15
B3 (a) The table shows the relative atomic masses, A r , and the melting points of some
Group I metals.
(i) Plot a graph of melting point against relative atomic mass, marking each
point with a (x). [1]
(ii) Draw a curved line of best fit, taking into account all your plotted points. [1]
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16
………………….………….. oC [1]
……………………………………………..……………………………………..
……………………………………………..……………………………………..
……………………………………………..…………………………………….. [2]
(b) Halogens exist as diatomic molecules and are all found in Group VII of the
Periodic Table.
(i) Write down a balanced chemical equation for the reaction that occurs
between chlorine and the potassium iodide solution.
……………………………………………..…………………………………….. [1]
(ii) Describe an observation that you would make in this chemical reaction.
Give an explanation for the observation.
……………………………………………..……………………………………..
……………………………………………..…………………………………….. [2]
End of Paper 4
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17
157
85 88 89 91 93 96 - 101 103 106 108 112 115 119 122 128 127 131
55 56 57 – 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba lanthanoids
Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 - - -
87 88 89 - 103 104 105 106 107 108 109 110 111 112 114 116
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Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium actinoids Rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
- - - - - - - - - - - - -
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 - 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
- 232 231 238 - - - - - - - - - - -
3
The volume of one mole of any gas is 24 dm at room temperature and pressure (r.t.p.)
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158
CANBERRA SECONDARY SCHOOL
Do not turn over the paper until you are told to do so.
o.
es of the paper.
Write in dark blue or black ink pen on both sides pap
perr.
Do not use staples, paper clips, glue or correction
io fluid.
orrectio
ion
io d..
estions in
Answer ALL questions in Paper
Pa
P ape
p r 4 Se
S ctio
on A and
Section da
anny TWO
any TW
T WO questions
ques
estion
ns in Section
Sectio B.
Se
Write all your answers
ans wers on
nsswe n the
tth spaces
he sp
pac e provided.
aces pro
ro v
viided.
d.
d.
At the
he end
en
e nd off the
the examination,
exa
ami
m na
ati o , hand
tion nd in
nd in your
yo
y urr OTAS
ou TAS and
OTA nd question
an estion paper.
ques
qu es
The number
mbe
be off mar
er o marks
arks
ar given
ks is gi
g iv
veen in
nbbrackets
rackets [ ] at the
ack the end of each question or part question.
Marks Max
Section
Awarded Marks
Paper 3 20
Section A 14
Paper 4
Section B 16
Total 50
This question paper consists of 17 printed pages including the cover page.
Setter: Ms Rebecca Ng
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159
2
1 The following steps were taken by a student to investigate a reaction between zinc and
dilute hydrochloric acid.
1. Measure and pour 20.0 cm3 of dilute hydrochloric acid into a beaker.
2. Measure the initial temperature of the acid.
3. Weigh 2 g of zinc granules and add it into the acid.
4. Measure the time taken for the reaction to complete.
3 C
Ch
hroma
ro
oma
mato
t graphy
Chromatography hy was
was
as used to
to ttest
esst fo
or ffo
for ood
d ccolourings
food olou
ol ouri
ou ring
rings whi
ng which have been banned.
The
e results
re
essu
ult
lts are
arre shown
a sh
how
o n in
n the
the
he diagram.
diia
agr
g am.
Which of the three drinks tested contains both of the banned colourings?
A Fizzo only
B Juicy only
C Fizzo and Sparkle only
D Juicy and Sparkle only
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3
A B C D
7 e statem
Three em
ments a
statements bo
b out
aboutut iisotopes
soto
so oppe
es are
are give
ar ven.
ve n
given.
1 Issotopes
Isotopes ess of
of the
th
he same e element
elleemme
ent
nt have
haavve the
t e same
th sa
ame number
num
mbe of protons.
2 Isotopes
Is otopes of
sot of the
he same
th e element
me ele
lemen have
ntt h avee different
diff
di ffer
ff ent number
eren
er en num of neutrons.
3 Isotopes
IIs
sot
ot o
op es of
pes of the
t e same
th sa
s a
amme
meeelement
lle
ement havhaveve different
diff
di fferent atomic masses.
Which
ich of
of the
he following
th ffo
olllllo
owiin
ow ng is
is true?
true?
e?
?
A All statements
sttat
s ateem
ments s are
are correct
correct and statement 1 explains statement 2.
B All statements
statem
st men
ents
ts are
are correct
co and statement 2 explains statement 3.
C Statement
atem menentt 1 and 2 is correct but statement 3 is not correct.
D Statement
tement 3 is correct but statement 1 and 2 is not correct.
8 Which of the following options contains only electronic configuration of metal atoms?
A 1 2,2 2,8,3
B 2 2,4 2,8,5
C 2,8 2,8,1 2,8,2
D 2,8,2 2,8,8,1 2,8,8,2
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4
Which of the following shows the correct chemical formula and type of compound
formed from the elements?
chemical formula
type of compound
of compound
A XW 2 ionic
B X2W ionic
C WX covalent
D WX 2 covalent
electrical
el
lec triicall cconductivity
ectr
tr ond
on ductivity
y
melting point / °C
C boiling
bo
b ing point
oililin point / °C
po C
in solid
d state
sta
tate in molten
mol
olte
ten
te n state
A -183
83 -16
-162
16
1 62 poor
pooor
or poor
B 15 104
104
10 poor
pooor poor
p
C 657 997
99 7
99 poor good
D 2040
20
20 3654
3654
36 4 good
good good
12 The
e ta
ttable
ab
blle shows
sh
show
o s th
the
he re
results
es
suulltts off adding di
dilu
dilute
lute
lu te h
hydrochloric
ydroc acid and aqueous sodium
hydroxide
ydrroxidde to
oxiid
ox o an
an oxide.
oxid
de.
Which
ch of
of the
he following
the fol
olllo
o
owi
wiiing
w ng
n ts indicates
g results ndiicates that the oxide is acidic?
ind
result of adding
dilute
dilu
di lute
lu te hydrochloric
hydr acid dilute sodium hydroxide
A no reaction no reaction
B no reaction reaction
C reaction no reaction
D reaction reaction
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5
1 metal + acid
2 metal oxide + acid
3 metal carbonate + acid
4 metal hydroxide + acid
Which method(s) will lead to the production of a gas as the other product?
A 1 only
B 1 and 3 only
C 2 and 4 only
D 2, 3 and 4 only
What is P?
A ammonium sulfate
B hydrochloric acid
C sodium hydroxide
D sodium sulfate
gas
gaas test
test and result
re
A am
a
ammonia
mmom n niia mo
moist
oisst red
red litmus
litmus paper remains red
B carbon
carb
bon
on dioxide
dio
i xidede
de lighted
liighted splint extinguishes
C hydrogen
hyydr
d ogge
en n bubble
bubb
bble
bb le gas
gas
a into
int limewater, effervescence observed
D oxygen
oxxyyg
geenn glowing splint relights
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6
I II III IV V VI VII 0
T U W
X Y
halogen
h
haalo
logen
n appearance
ap
ppe
pe a
arran
an c
cee
fluorine
fluo
uo
ori
rine
n pale
pale
pa e yellow
yellow gas
ga
as
chlorine
chlori
rine
ri ne
e yellowish-green
yellllow
ye o issh-gr
gree
een
ee n gas
bromine
b
brrom
min
ine re
red-brown
ed-
d-br
brrow
b o n liq
liquid
iiodine
io dine
ne
ne dark
da k purple
da pu solid
astatine
as
statiin
nee ?
Astatine would be
be expected
exp
ex pected to be a
A brown gas.
wn gas
B black solid.
C grey liquid.
D white solid.
End of Paper 3
1 2 3 4 5 6 7 8 9 10
B A B C D D B C D B
11 12 13 14 15 16 17 18 19 20
A B D B C D C B A B
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7
Paper 4
Section A (14 marks)
For each statement, (a) to (c), select from the list the substance described.
(a) metho
od.
This substance can be prepared using the titration method.
NaCl [1]
CaCO
Ca 3 [1]
(c) n dissolved
This substance when disso
iis
sso
solvve
edd in water,
wa
ate
t r, turns blue
e llitmus
itm
tmus p
tm aper red..
ap
paper
SO 2 [1]
A2 ta
abblle below
The table be
elo
low gives
giiv
vees information
info
inform
fo rmat
a ion about
ab
a bou
out an
n atom
atto
om of hydrogen
hyd
ydro
r gen and
a an atom of oxygen.
attom
atomm n mb
nu ber o
number off pr
prot
oton
ot o s
protons electronic configuration
hydrogen
hy
yddrrog
og e
enn 1 1
oxygen
o
oxxygen
n 8 2,6
(a) With
h reference
ref
efer
erence to the Periodic Table, complete the table above. [1]
(b) Hydrogen and oxygen can react to form a compound which boils at 100 oC.
Draw the ‘dot and cross’ diagram to show the bonding in the compound formed.
Show all electrons.
[2]
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8
(c) With reference to its structure and bonding, explain why the compound in (b)
has a low boiling point.
The diagram below shows the first three steps used to prepare crystals
ys of this salt.
(a) (i)
(i
i) Explain
E
Ex p aiin why
xpl why a
wh an excess
ne s of
xcess of powdered
powde
ow
o wde
derre magnesium
ed ma
agn esiium carbonate
gne ca is used.
ensure
To e
ennsure
su
s that
ur th
hat all
at a
alll th
ll tthe
eaacid
cid iis
ac s used
us
u sed up/fully reacted.
ed up/fu
……………………………………………..……………………………………..
……
………
………
………
………
… ……
…………
…………
…… [1]
(ii)
i)) Name
N me
Na me tthe processes
he p roce
ro sses being
cess
ce ss be used in step 2 and step 3 respectively.
process
proc
oces s used
ess used in
i step 2 is filtration
(b) The solution left in step 3 is allowed to cool for some time to allow crystals to
grow. Describe the remaining steps required to obtain a sample of pure and dry
magnesium chloride crystals.
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9
(c) A student plans to prepare the salt, silver chloride, using the same method
above.
Do you expect the student to be successful in preparing the salt? Explain your
answer.
[2]
End of Section A
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10
Paper 4
Section B (16 marks)
The table below shows the boiling points of the three alcohols respectively.
(a) Co
omp
mple
lete
Completete tthe
he ttable
he able bel
elow
el ow.
ow
below.
Y condenser condensation
[2]
4 correct [2], 2-3 correct [1]. 0-1 correct [0]
(b) Suggest an apparatus that could be added to the set up to ensure a more
efficient separation of the three alcohols.
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11
(c) Of the three alcohols present in the mixture, which alcohol will be collected last?
Explain your answer.
Butanol [1]
…………………………………………………………………………………………… [1]
(e) (i) In the box below, draw a diagram to show the arrangement of particles in
P.
[1]
Partic
cle
es sl
Particles s ide over o
slide ne
onee anoth
her
er th
another hroughout tthe
throughout he lliquid.[1]
he iquid.[1]
iq
……………………………………………..……………………………………..
…
……………
… ……
… …………
……
… … ………
……
………
……
……………..…
.………
.…… … [1]
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169
12
B2 (a) John was washing his hair when some shampoo accidentally entered his mouth.
He rinsed his mouth immediately as it left a bitter taste in his mouth. After his
shower, John checked the label of the shampoo bottle. Part of the shampoo’s
ingredients list is shown below.
(i) The chemical that caused the bitter taste in John’s mouth is an alkali that
is also responsible for the soapy feel of the shampoo.
redient
nt tthat
From the ingredient list above, state the ingredient hat ha
ha has caused the
bitter taste in John’s mouth.
(ii) samp
John brought a small sample ple
le of the e shampoo
sham
sh amp pooo to the he sscience
cience laboratory
ci labo
Wiitth the
and diluted it with water. With th
he permission
pe
p ermmisssi
sion
sion
on of
of his
hiis science
scie
sc ience teacher,
ie teache he
added one dropop of Universal
Un
niv
iver
e sal Indicator
I dica
In atto
or into
into
in to the
th
hee diluted
dililut
uted
ut ed shampoo.
sha
hampoo.
e the colo
State our
u cha
colour hange
ha e th
change hat the
that he
e sstudent
tudent willl expect
ex ctt to
to see
se
ee in tthe
h drop
he dro of
Univer
errs
sa
Universalal Indi
dica
di cato
tor .
Indicator.
Green
n tto
Green ob lu
ue/
e pu
purp
rple
blue/purplele [1]
( iii)
(i
(iii) Unde
Un
Under de su
der
de upervissio
on,
supervision, n John
Joh
ohn di
d
didd further
furthe
er te
test
sts and found out that a typical
st
tests
1 lilitre
itre
tre bottle
tr bo
b ottle of
of shampoo
s a
sh am
mpo
oo contains
c nttai
co a ns 3
300 g of th
the salt, sodium chloride, NaCl.
Ca
C lccul
Calculate ulat
atte
e thethe number
th n mb
nu berr o
off mo
m les of sodium chloride present in a typical
moles
1 litre
lilittrre
re bottle
bottttlle
bo e of shampoo.
sham
sh ampo
ampoo. Round
po Ro off your answer to 3 decimal places.
M r of N
NaCl
aCl
aC
Cl = 2
233+3
35.5 = 58.5 [1]
Molle
Mole
Mo e = 30 / 58.5 = 0.513 mol
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13
Seven further 2.0 cm3 portions of hydrochloric acid are added. Each time, the
mixture is stirred and the highest temperature reached is measured and
recorded.
The results for the experiment are shown in the table below.
volume of
acid added / 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0
cm3
temperature
of the mixture 21.0 24.2 27.4 30.7 32.9
32.9 31
31.2 2
29.4 27.6
/ oC
i)
(ii) Draw w a b es
e st-fit lilline
best-fit ine ffor or these ffour
or ou
o ur po
p ints in (b
points (b)(
)(i)). E
(b)(i). xtend this line to
Extend
in
nte
t rsec
ect (cross)
ect
ec
intersect (cro
(c
(cro
oss
sss)) the
tthhe line
liliine
ne already
ne alr
lrrea
lrea
eady
dy drawn.
drra
aw
wnn. [1]
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2019 Semestral Assessment Secondary 3 Normal (Academic)
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14
p (iii) The acid and the alkali exactly neutralise each other at the point where
the two graph lines intersect (cross).
(iv) Write an ionic equation to show what is meant by the term neutralisation.
Include state symbols.
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15
B3 (a) The table shows the relative atomic masses, A r , and the melting points of some
Group I metals.
(i) Plot a graph of melting point against relative atomic mass, marking each
point with a (x). [1]
(ii) Draw a curved line of best fit, taking into account all your plotted points. [1]
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16
76 (+/- 2) oC [1]
Effervescence observed
Sodium darts on the surface of water and melts away
Mixture turns from green to blue/purple
Yellow flame observed
[2]
Any 2 of the 4
(b) Halogens exist as diatomic molecules and are all found in Group VII of the
Periodic Table.
Cl
Cl 2 + 2KI
2K
2 KI ї 2KCl
2K
2 KCl + I 2 [1]
((i
ii)
i)
(ii) De
es sccri
rb
Describe be
e an observation
obse
ob serrv
vat
a io
on tth
hatt yyou
that ou would
would make
m in this chemical reaction.
G
Gi
ivve
Givee an
an explanation
exxp
plla
annat
a io
on for thee observation.
obse
ob servatio
se
Co
Colo
lourle
lour
urle
urles
Colourlessss
ss olut
uttio
u on ttu
solution urns b
turns brown. [1]
C
Ch
hlorine
lo n
lo
Chlorinenee be
bein
ein
beinging mo
more reactive than iodine, displaces iodine from the [2]
solution.
solu
uttiio
onn. [1
[[1]]
End of Paper 4
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17
175
85 88 89 91 93
3 96
96 - 101
1 103
103 106
1 06
06 108
10 112 115
1 119 122 128 127 131
55 56 57 – 71 72 73
73 74
74 75
5 76
6 77 78
78 79
79 80 81
81 82 83 84 85 86
Cs Ba lanthanoids
noids
Hff Ta W Re
Re Os
O s Irr Ptt
P Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium
um
u m tantalum
um
m tungsten
st
st rhenium
m osmium
osmi
smi
ssm
mium
iu iridium
iirid
ir
rrid
diium
iu
u platinum
plat
pla
p la
atinum
a gold
d mercury
m
merc ury thallium lead bismuth polonium astatine radon
133 137 1788 181 184
84
4 186 19
190
190
9 0 192
19
192
9 2 195
195 197 201 204 207 209 - - -
87 88 89 03
3
9 - 103 104
04
04 105 106
6 107 08
0
108 8 109
09
09 110 11
111 112
11 114 116
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Fr Ra R
Rf D
Db Sg
Sg Bh
h Hs
Hs M
Mt Ds Rg Cn Fl Lv
francium radium actinoids
oids Rutherfordium
Ruthe
herford
rford
diium
um
m dubnium
dubn
ubn
bniu
bn ium
ium
um seaborgium
se
s
seab
eab
eaborgi
o um
or bohrium
boh
bohr
bo
b oh
ohr
o h ium
ium
m hassium
ha
hass
asssium
a i meitnerium
m darmstadtium
darmstadti
darms tadtium
ta
tadti roentgenium
roentge copernicium flerovium livermorium
- - - - - - - - - - - - -
57
7 58
58 9
59 60
60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce
e Prr
P Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum
hanum cerium
ceriu
ceri
cer um praseodymium
prase
prase
eod
o
odymi
ody um neodymium
neod
dymiu
ymiumm promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139
39 140
0 141 144 - 150 152 157 159 163 165 167 169 173 175
89 90
90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th
T h Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium
protacti
protac nium uranium
ur neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
- 232
32
2 231 238 - - - - - - - - - - -
3
The volume of one mole of any gas is 24 dm
d at room temperature and pressure (r.t.p.)
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East Spring Secondary School
Towards Excellence and Success
Name: …………………………………………………………………………………… ( )
Class: ……………………
INSTRUCTIONS TO CANDIDATES
There are 20 questions on this paper. Answer all questions. For each question there are 4
possible answers A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the OTAS.
Calculators and mathematical sets are allowed.
20
This question paper consists of 8 printed pages including the cover page.
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2
1 Which of the following laboratory apparatus should be used to measure 27.20 cm3
of dilute hydrochloric acid?
A pipette B burette
C D
A 2 B 3 C 11 D 12
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3
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4
7 What happens to the molecules in a liquid when it turns into a solid at its freezing
point?
melting point / °C
A 32
B 25 to 28
C -20 to -30
D -35
96
9 An atom of molybdenum is represented as 42 Mo.
A B C D
key
2p 2p 1p 1p = electron
2n 1n 2n 1n p = proton
n = neutron
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5
1 2
A shared high
B shared low
C transferred high
D transferred low
13 Hydrogen reacts with nitrogen to form ammonia as shown by the chemical equation
below:
x H 2 (g) + y N 2 (g) Æ z NH 3 (g)
What are the values for x, y and z needed to balance the equation?
x y z
A 1 2 2
B 2 2 1
C 3 1 2
D 3 2 2
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6
15 When aluminium, sulfur and calcium burn in oxygen, oxides are formed.
Which row identifies the type of oxides that is formed by each one of them?
16 A student was given dilute hydrochloric acid and the four solids listed below.
1 magnesium
2 magnesium carbonate
3 magnesium sulfate
4 magnesium oxide
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7
Z is a red liquid.
19 Lithium, sodium and potassium are all in the same group of the Periodic Table.
B They all have the same number of electrons in their outer shell.
D They all have the same total number of protons plus neutrons in the nuclei of
their atoms.
A 10cm3
B 20cm3
C 40cm3
D 200cm3
End of Paper 3
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East Spring Secondary School
Towards Excellence and Success
Name: …………………………………………………………………………………… ( )
Class: ……………………
INSTRUCTIONS TO CANDIDATES
Write your name, class and register number in the spaces provided above, and on all the
work you hand in.
Write in dark blue or black pen.
You may use a soft pencil for any diagrams, graphs, tables or rough working.
The use of an approved scientific calculator is expected, where appropriate
Do not use staples, paper clips, highlighters, glue or correction fluid.
Section A
Answer all questions.
Write your answers in the space provided on the question paper.
Section B
Answer any two questions.
Write your answers in the space provided on the question paper.
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2
……………………………………………………………………………………………..……[1]
(c) Name another gas pollutant that has the same effect as sulfur dioxide on the
environment.
…………………………………………………………………………………….……….……[1]
(d) Acid rain can cause the soil in community gardens to be too acidic for plant growth.
(i) Name the chemical that can be added to the soil to make it suitable for plant
growth.
………………………………………………………………………..…………………[1]
(ii) Explain, in terms of the chemistry involved, the effect the chemical in (d)(i) has on
the soil.
………………………………………………………………………………….………….
……………………………………………………………………………….…….……[1]
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3
Figure 2.1
(b) a compound,
……………………………………………………………………………………………….[1]
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4
3 (a) A teacher uses the apparatus in Figure 3.1 to bubble chlorine gas through colourless
lithium bromide solution.
chlorine gas
lithium bromide
solution
Figure 3.1
(i) Describe an observation that can be made during this chemical reaction.
…………………………………………………………………………………....….…[1]
(ii) Explain why a reaction can occur between chlorine gas and lithium bromide
solution.
………………………………………………………………………….…….…..….……
………………………………………………………………………….…….…..….…[1]
(b) Table 3.2 shows the observation of three Group I metals when they were placed in a
beaker of water.
Metal observation
Table 3.2
(i) With reference to Table 3.2, arrange the metals in the order of increasing
reactivity.
………………………………………………………………………………..…..……[1]
(ii) One of the metals that was added to water was sodium. Sodium react with water
to form sodium hydroxide and hydrogen gas.
Write a balanced chemical reaction, with state symbols, for the reaction between
sodium and water.
…………………………………………………………………………….…...…….…[2]
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5
(iii) Describe what you would observe when a few drops of Universal Indicator is
added to the reaction mixture.
………………………………………….……………………………………………....[1]
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6
4 A student carried out an experiment to determine how fast magnesium carbonate reacts with
hydrochloric acid by measuring the volume of gas X formed at regular intervals.
The equation for the reaction is as follows:
hydrochloric acid + magnesium carbonate ĺmagnesium chloride + water + gas X
(a) Describe the test and observation for gas X that is formed.
test: ………………………………………..………………………………………………...…..
observation: …………………………………………………………………………………….
……………………………………………………………………………………………...…[2]
(b) Magnesium hydroxide is also able to react with hydrochloric acid to form
magnesium chloride and water.
Write an ionic equation, with state symbols for the reaction between
magnesium hydroxide and hydrochloric acid.
…………………………………………………………………………………………………[1]
(c) When preparing salts by this method, just enough hydrochloric acid is added to react
exactly with all the magnesium hydroxide.
What is the pH of the solution formed at the end of the reaction to produce
magnesium chloride?
pH = …………………………….[1]
(d) Draw a ‘dot-and-cross’ diagram to show the arrangement in magnesium chloride.
Show the outer electrons only.
[2]
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7
(e) State and explain whether magnesium chloride has a high or low melting point.
……………………………………………………………………………………………………
……………………………………………………………………………………………………
…………………………………………………………………………………………………[2]
5 Table 5.1 gives information about a fluorine atom and an atom of element Y.
number of protons 6
number of electrons 9 6
(c) Draw a diagram to show the electronic configuration of the fluorine atom.
[1]
(d) Describe, in terms of electrons, how a fluorine atom becomes a fluoride ion.
…………………………………………………………………………………………………....
…………………………………………………………………………………………………[1]
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8
temperature/°C
time/min
[2]
(ii) Describe how the arrangement and movement of the particles in compound Y
changes as it is heated from -200°C to -150°C.
………………………………………………………………………………………………..
……………………………………………………………………………………………….
……………………………………………………………………………………………….
………………………………………………………………………………….………...[2]
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9
Table 6.1
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10
(d) Silver nitrate can also be used as an additive in chromatography to separate organic
compounds. Figure 6.2 shows a chromatogram comparing a sample with five known
substances after a silver nitrate chromatography.
sample A B C D E
Figure 6.2
(i) State the substance(s) that are present in the sample.
…….…………………………………………………………………………………….[1]
(ii) State one conclusion that can be made about substances A, B, C and D.
…………..………………………………………………………………………………….
………………….……………………………………………………………………….[1]
End of paper 4
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11
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ESSS 2019 3NA Science Chemistry SA2
Paper 3
1 2 3 4 5 6 7 8 9 10
B B D C B B C A A D
11 12 13 14 15 16 17 18 19 20
C B C D B B A B B C
Paper 4
2a B 1
2b A 1
2c E 1
4a Test: bu
bubble
ubb
b le th
the
he ga
gass into li
limewater. 1
Observation:
vatio
on: A wh
w
white
ite p
precipitate is formed. 1
4b H+ (aq) + O
OHH-DT
DTĺ+ 2 O (l) 1
4c 7 1
4d Mg – 1
both Cl –
- xx 2+ - 1
Cl x x Mg x Cl x
x x
xx
- electron of Cl
X – electron of Mg
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4e Magnesium chloride has a high melting point. 1
Large amount of energy is required to overcome strong electrostatic 1
forces of attraction between oppositely-charged ions/strong ionic
bonds between ions.
-100
-128
8
-18
18
84
-184
-200
-20
00
time / min
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6a Precipitation 1
6b Calcium chloride 1
6c Filter the mixture to obtain silver nitrate as residue. 1
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HILLGROVE SECONDARY SCHOOL
END-OF-YEAR EXAMINATION 2019
SECONDARY 3 (NORMAL ACADEMIC)
CANDIDATE ( ) CLASS
NAME 3 -
CENTRE INDEX
NUMBER S NUMBER
Section A
There are fifteen questions in this section. Answer all questions. For each question there are four
possible answers A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the separate answer
sheet (OTAS).
Section B and C
Answer all questions.
Write your answers in the space provided on the question paper.
The number of marks is given in brackets [ ] at the end of each question or part question.
A copy of the Periodic Table is printed on page 11.
A 15
B 11
C 14
Parent’s/ Guardian’s Signature: ___________________ TOTAL 40
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2
1 Which method is used to obtain glass pieces from aqueous sodium chloride?
A chromatography
B crystallisation
C distillation
D filtration
A air
B ammonia
C carbon monoxide
D chlorine
4 What decides the order of arrangement of the elements in the Periodic Table?
A density
B number of neutrons
C number of protons
D relative atomic mass
5 Which is/are the main particle(s) that contribute to the mass of an atom?
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202
3
6 The diagram shows the arrangement of electrons in the atoms of four different elements.
Which element is the least reactive?
Distilled water is then added to the beaker and the lamp lights up.
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203
4
10 Which equation for the reaction between sodium carbonate and dilute hydrochloric acid is correct?
A carbon
B gold
C oil
D sodium chloride
A blue
B orange
C red
D violet
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5
13 The diagram shows the soil pH range over which a vegetable grows well.
Why is slaked lime (calcium hydroxide) added to this soil before planting the vegetable?
The oxide of element Y forms a solution that turns Universal Indicator blue.
element X element Y
A metal metal
B metal non-metal
C non-metal metal
D non-metal non-metal
When vinegar is added to powdered chalk, bubbling of a colourless gas is observed. This gas forms
a white precipitate with limewater.
A carbon dioxide
B hydrogen
C nitrogen
D oxygen
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6
Section B
Answer all questions in the space provided.
Fig. 1.1
(ii) has atoms that share two pairs of electrons with each other, …………………
(b) With reference to its structure, explain why substance B has a low melting point.
[1]
[Total: 4]
2 The incomplete diagram shows the outer shell of electrons in a chlorine molecule, Cl2.
Complete the electronic structure with dots and crosses. Show only the outer shell electrons.
[Total: 2]
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7
Table 3.1 shows some reactions of acids and bases and the salts formed. The first row has
been completed for you.
Table 3.1
[Total: 2]
4 Table 4.1 shows the concentration of some ions present in a sample of seawater.
Table 4.1
(a) Which positive ion in Table 4.1 has the lowest concentration?
[1]
(b) Give the name of the ion with the formula I–.
[1]
(c) Which two ions in Table 4.1 are formed from elements in Group II of the Periodic Table?
[1]
[Total: 3]
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8
Section C
Answer all questions in the space provided.
5 Iron is a commonly used metal. It can react with many types of substances.
Table 5.1
number of particle relative charge
particle present on the particle
electron
neutron 0
proton 26
[2]
(b) Iron reacts with hydrochloric acid to form iron(II) chloride and a gas which ‘pops’ with a
lighted splint.
Complete the chemical equation with appropriate numbers and chemical formulae for this
reaction.
(c) Fig. 5.1 shows a measuring cylinder containing FeCl2 solution, as shown below.
Fig. 5.1
[1]
(ii) Suggest another measuring instrument that can take more accurate volume
measurement in the laboratory.
[1]
[Total: 6]
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9
6 A student wants to find out if flower petals contain one coloured substance or two. He follows
the procedure shown in Fig. 6.1.
Fig. 6.1
(a) When he puts the chromatography paper in ethanol, suggest and explain whether the
starting line should be above or below the surface of the ethanol.
[2]
(b) The student concludes that there are two substances in the petal colour.
On Fig. 6.2, show what the chromatography paper looks like after the experiment.
Fig. 6.2
[2]
[Total: 4]
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10
Fig. 7.1
[1]
(b) Use arrows to indicate on the diagram where water should enter and exit the condenser.
[1]
(c) On Fig. 7.1, draw and label what should be added to the setup to make boiling smooth.
[1]
(d) Suggest the name of the apparatus that must be added to the setup to separate a mixture
of water and ethanol.
[1]
[Total: 4]
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11
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3NA CHEM EOY 2019 MARK SCHEME
1 2 3 4 5 6 7 8 9 10
D D A C C B C A B A
11 12 13 14 15
D B A C A
1 a I A;
Ii B;
iii A;
b Weak intermolecular forces of attraction / van der Waals forces + low energy required to
overcome ;
2 2 electrons in the shared space ;
6 electrons in the unshared space in the shell of the chlorine atom
om on
o the right ;
3 Nitric ;
Magnesium
esium oxide
oxxide / magnesium
o magn
ma gnes
esiuium hydroxide
hydr
hy drox de ;
oxiid
2++
2
4 a Calcium ion / Ca
Ca ;
b Io
Iodide
odi
d de
de ;
c Caa2+ an
C and M 2+
nd Mg 2
(A
(A:
A: name
names
mes o
me off ion
ions)
ns)
s) ;
5 A number
nu
n u
umb
mber o
mb off particle
part
pa rtic
rticlle pre
ic present relative charge on the
paarrtticlee
p
particle particle
elec
eelectron
el
leeccttrro
onn 26 -1
neutron
ne
n euuttron 32 0
proton on 26 +1
Mark
Mar rk by
rk by column
colu
lumn
lu mn ;;
b H 2 in the
the llast
ast blank ;
as
fficiients: 2 and 1 (A: no number in front of H 2 . R: if wrong or no formula is filled instead
Coefficients:
of H 2 an
and the equation is not balanced with the coefficients) ;
c i 55 cm3 ;
ii Burette ;
6 a Line above ethanol ;
Prevent spot of colour from dissolving in ethanol and not travel up the chromatography
paper ;
b Original spot of colour shown in the same position ;
Two spots shown (vertically) above the spot of colour ; R: two spots horizontally aligned
7 a Y;
B Arrow indicating water in at the bottom inlet + water out at the upper outlet (words not
necessary, reject if words conflict with arrows) ;
c Drawing + label of boiling chips at the bottom of the flask ;
d Fractionating column ; R: other spellings like fractional
1
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NAME: ( ) CLASS: 3A
There are twenty questions on this paper. Answer all questions. For each question there are four
possible answers, A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the OTAS provided.
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2
2 Ganymede is the largest moon of the planet Jupiter and has a surface temperature of -179 qC.
The table shows the substances found on the surface of Ganymede.
What substance(s) is/are likely to exist in liquid state on the surface of Ganymede?
X water
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3
o
4 Which technique can be used to separate a mixture of ethanol (boiling point 79 C) and methyl
o
benzene (boiling point 111 C)?
A crystallisation
B evaporation
C filtration
D fractional distillation
Z magnesium oxygen
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4
P Q R S
A P and Q
B P and S
C Q and R
D Q and S
9 Which of the following statements about sodium atoms and sodium ions is true?
Cl
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5
Statement 1
Ionic compounds can conduct electricity in the molten state but not in the solid state.
Statement 2
Ionic compounds contain free-moving ions when molten or dissolved in water but not in
the solid state.
X Y Z
X Y Z
A hydrogen ammonia water
B hydrogen water ammonia
C ammonia hydrogen water
D water ammonia hydrogen
14 The equation shows the reaction that occurs when ethene is burnt in air.
C 2 H 4 + xO 2 ĺyCO 2 + zH 2 O
x y z
A 3 1 1
B 3 2 2
C 4 1 2
D 4 2 1
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6
A 2Al + 3H 2 O Æ Al 2 O 3 + 2H 2
B Mg + O 2 Æ MgO 2
C 4Na + O 2 Æ 2Na 2 O
D S + O 2 Æ SO3
A 70
B 71
C 124
D 142
What volume of carbon dioxide gas is produced at room temperature and pressure?
A 12 dm3
B 24 dm3
C 36 dm3
D 48 dm3
19 Ammonium chloride is heated with substance Q and the reaction produces ammonia gas.
What type of substance is Q?
A acid
B base
C metal
D salt
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7
20 The diagram shows the pH values of the soil in two parts of the garden of a house, X and Y.
The house owner wishes to use lime to neutralise the soil in one part of the garden.
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8
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1
NAME: ( ) CLASS: 3A
Write your name, register number and class on all the work you hand in.
Write in dark blue or black pen on both sides of the paper.
You may use an HB pencil for any diagrams or graphs.
Do not use staples, paper clips, glue or correction fluid.
At the end of the examination hand in your answers to Paper 3 and Paper 4 separately.
The number of marks is given in brackets [ ] at the end of each question or part question.
20 24 16 60
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2
Section A
Which of these separation techniques is used to separate each of the underlined substance
from the stated mixture?
.…………………………………………….. [1]
................…………………………………. [1]
…………………………………………….. [1]
2 The set of apparatus is used in the preparation of crystals of the salt, copper(II) chloride,
CuCl 2 .
Y
Z
X
gentle heat
X …………………………..………
Y …………………………………..
Z ………………………………….. [2]
(b) What is the name of an apparatus that can be used to measure accurately the
volume of a liquid?
……………………………………………………………………………………………….. [1]
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3
(b) A student claims that an impure sample of an element melted at a fixed temperature of
65 oC during an experiment.
..……………………………………………………………………………………………….
………………………………………………………………………………………………… [1]
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4
lithium
2, 1
neon
10
potassium
19
oxygen
2, 6
(b) Which elements belong to the same group? Explain your answer.
…………………..…………………………………………………………………………….
………………………………………………………………………………………………… [1]
[1]
(d) Unlike the other three elements, neon does not bond with other atoms. Explain why.
……………………………………………………………………………………………….. [1]
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5
6 X is an unknown element. It has been determined that 0.2 mole of XO has a mass of 8 g.
…………………………………………………………………………………………………
………………………………………………………………………………………………… [1]
(b) Calculate the relative atomic mass of element X and suggest its identity.
7 Mrs Kay wants to grow cucumbers in her garden. Cucumbers require soil that is slightly
alkaline.
(a) Explain why the soil in this garden is not suitable for growing cucumbers.
……………………………………………………………………………………………… [1]
(b) Name a chemical that she can add to the soil to make it suitable for planting
cucumbers.
……………………………………………………………………………………………… [1]
(c) Describe a test to check the change of pH after adding the chemical stated in (b).
……………………………………………………………………………………………… [1]
End of Section A
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6
Section B
Answer any two questions from this section in the spaces provided.
(a) Describe, in terms of electrons, how a chlorine atom becomes a chloride ion.
…………………………………………………………………………………………………
………………………………………………………………………………………………… [1]
(b) The diagram shows the arrangement of sodium ions and chloride ions in a crystal
of sodium chloride.
Cl
Na
…………………………………………………………………………………………
………………………………………………………………………………………… [2]
(ii) Give another physical property of sodium chloride other than the one
mentioned in b(i).
…………………………………………………………………………………………. [1]
(iii) Draw a ‘dot and cross’ diagram in the space below to show the arrangement
of the electrons in NaCl. You are required to show only the valence electrons.
[2]
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7
Draw a ‘dot and cross’ diagram in the space below to show the arrangement of the
electrons in Cl 2 . You are required to show only the valence electrons.
[2]
9 (a) The salt, magnesium chloride, is commonly used in fire extinguishers and can be
obtained by the reaction of magnesium hydroxide and hydrochloric acid.
(i) Name the type of reaction between magnesium hydroxide and hydrochloric
acid.
………………………………………………………………………………………… [1]
(ii) Magnesium chloride can also be made from the reaction of magnesium
carbonate and hydrochloric acid.
Name the gas produced in this reaction and describe a test to identify this
gas.
test ……………………………………………………………………………………
…………………………………………………………………………………………
observation ………………………………………………………………………….
………………………………………………………………………………………… [3]
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8
Typical analysis
ions mg/dm3
(i) How many diffferent metal ions are present in the mineral water?
………………………………………………………………………………………… [1]
(ii) Iron(II) sulfate is an essential body mineral. Iron can be obtained from the
food that we eat.
………………………………………………………………………………………… [1]
What colour would you expect to see and what does the pH tell you about the
mineral water?
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9
A B C D
A …………………………………
C ………………………………… [2]
1……………………………………………………………………………………….
………………………………………………………………………………………..
2……………………………………………………………………………………….
………………………………………………………………………………………… [2]
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10
temperature/ oC
D
C
time / min
(i) Benzene has a melting point of 5 qC and a boiling point of 80 qC. Predict the
temperature at region A.
………………………………………………………………………………………… [1]
[1]
(iii) In terms of the kinetic particle theory, explain the changes that happened to
the benzene particles, in terms of the arrangement and movement of the
particles as benzene is heated from 0 °C to 15 °C.
…………………………………………………………………………………………
…………………………………………………………………………………………
………………………………………………………………………………………… [2]
End of Paper 4
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SA2_2019
Sec 3NA Science (Chemistry) 5105
Answer Key
Paper 3 [20 marks]
er 4 (40
Paper (40
40 marks)
marks)
ma
Se
Sectio
on A [24
Section [2
24 ma
marks] Marks E/M/H
1 (a) Crystallisation
Crry
yssta
talllissa
attiio
on 1 E
(b) Ch
Chromatography
hrro
oma
matograp aphy
ap hy 1 E
(c) Fractional
Fraction nal distillation
disisti
t llatio 1 E
[3]
2 (a) X – beaker
beake 1 m – one/two
Y – filter
t funnel correct E
Z – evaporating dish 2 m - all correct
(b) Pipette or burette 1 E
[3]
3 (a) i air 1 M
ii zinc 1 M
iii water 1 E
(b) An impure sample of the element will not melt at a fixed 1 M
temperature/ An impure sample of the element will melt at a
lower temperature / An impure sample of the element will
melt within a range of temperature.
[4]
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4 (a) 2 H 2 O 2 (l) Æ 2 H 2 O (l) + 1 O 2 (g) 1 E
(b) 1 Cl 2 (g) + 2 KBr (aq) Æ 2 KCl (aq) + 1 Br 2 (g) 1 E
(c) 1 C 3 H 8 (g) + 5 O 2 (g) Æ 3 CO 2 (g) + 4 H 2 O (g) 1 M
[3]
5 (a) element proton number arrangement of electrons
E
lithium 3 2, 1
2,8 1 –each
neon 10
correct pair
potassium 19 2, 8, 8, 1
Tot:2
oxygen 8 2, 6
(c)
1 E
Oxygen atom
Correct no of
O shells &
correct
ectt number
correc
ec numbe
of electrons
ele
lectron
(d)
d) N
Ne
Neon
eon nh has
as a completely
co
omple
mp ple
lete
tely
l filled
fil
illed
d outer
oute
ou t rs sh
shell
heelll of electrons/
ele
lect
le ctro
ct ons/ ha
has a 1 M
full
ull valence
fu val
alle
enncee shell
shell
sh
[Reject:
[Rej
[R e ect: Neone n iis
Neo s a noble
nob
ob
o le gas/unreactive/has
ble gas//u
unnrreacctt ve/
c
ctiv e/ha
has
ha s a stable
stab
electronic
elle
e eccctr
tron
tr onicc shell]
shell]]
[5]
6 (a) Relative
Re
R elaati
t ve
ve atomic
ato
ommiic m
ma
mass
ass iis
s the
the average
averag mass of one atom of
av
an
an element
eleeme nt compared
ent co
c omppar ed to
ared to 1/12 the
t mass of a carbon-12 1 E
atom
atto
omm
(b) Mola
Molar
lla
lar
a mass ss of XO
XO = 88/0.2 = 40 1 H
X + 166 = 40
X = 24
1
X is Magnesium
[3]
7 (a) The soil is acidic whereas cucumbers need a slightly 1 M
alkaline condition to grow.
(b) Calcium hydroxide / calcium oxide/calcium carbonate 1 E
Lime/slaked lime/quicklime
[Reject: limewater]
(c) Dissolve some soil in water /make a soil solution and 1 H
use a pH meter or Universal indicator to test the soil
condition
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[Reject: use universal indicator/litmus paper even if the
observations are mentioned in the answer]
[3]
24
1 – correc
correct
Cl number of
of valen
valence
electrons
elec
electr
tro
ons
iii Good
Go
G oodd cconductor
on
o n ucttor
ndu o off e
el
electricity
lec
ectr
tric
icitty when
wh
when
en molten
mol
oltten orr in
in aqueous
aq 1 E
state/
s ate/
st (any one)
Soluble
luble in
Solu
So n water
wat
at er
(c)) 1 – correct M
number of bonded
electrons
1 – correct
number of non-
bonding electrons
[Minus
us mark if all the electrons are not drawn in dots or cross]
[8]
9 (a) i neutralisation 1 E
ii Carbon dioxide 1 E
Bubble the gas into limewater 1 M
White precipitate is formed in limewater 1 H
(b) i 4 1 M
ii FeSO 4 1 H
iii Bluu- green /blue 1 M
Slightly alkaline /weakly alkaline/ alkaline 1
[8]
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10 (a) i A: Water / carbon dioxide (or any appropriate answer) 2 E
C: any diatomic molecule
ii Compounds can be separated into its components by M
chemical methods but mixtures are separated by physical 2
methods. Any two
1
E
liquid
d
A
Ar rangememmen
Arrangement: en t :
At 0OC
At C,, th
the
he pparticle
artic
iccle
le in
in the
the solid state
th stat
ate
at e are
are closely
close packed in
an
a orderly
orrd
deerly mamanner.
m nnerr. When
ann Wh
W hen heated
hea
eaate
tedd to 15 C
OC, the particles are
now
no
n ow slslightly
s ig
gh y far
httly fa apart
arr a p rt in
pa disorderly
n a di s rder manner.
diso
[8]
total [24]
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KENT RIDGE SECONDARY SCHOOL
END-OF-YEAR EXAMINATION 2019
PAPER 3
ADDITIONAL MATERIALS
Multiple Choice Answer Sheet
There are twenty questions on this paper. Answer all questions. For each question, there are
four possible answers A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the separate
Answer Sheet.
Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any
rough working should be done in this booklet.
You may proceed to answer Paper 4 as soon as you have completed Paper 3.
_____________________________________________________________________________________
This Question Paper consists of 8 printed pages, including this page.
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240
Section A
The total mark for this section is 20.
1 A student wishes to add exactly 20.15 cm3 of acid to exactly 25.0 cm3 of an alkali in a titration
experiment.
acid alkali
A pipette measuring cylinder
B pipette burette
C measuring cylinder burette
D burette pipette
2 The graph shows the change in temperature with time when ice at -20oC is heated to 120oC?
Which row correctly describes the change taking place when ice is heated?
points change
A P to Q average energy of particles remains constant
B Q to R ice melting
C R to S the volume of steam is increasing
D T to U water boiling
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3 A piece of dry ice becomes smaller very quickly when left in the open air without any trace
of liquid unlike normal ice.
Which diagram shows the correct change in the arrangement of the carbon dioxide
molecules in dry ice when left in the open air?
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6 A student placed some substances into three different boxes as shown below.
I II III
I II III
A air water vapour oxygen
B oxygen air water vapour
C oxygen water vapour air
D water vapour air oxygen
property classification
A black powder burns in air to form a colourless gas element
B colourless solution produces two colourless gases when an element
electric current is passed through it
8 Benzoic acid has the molecular formula of C 7 H 6 O 2 . How many atoms are present in a
molecule of benzoic acid?
A 3
B 9
C 10
D 15
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9 What is the correct relative mass of each particle in an atom?
e- e-
e- - e-
e- e e- e-
e- e-
A an atom of carbon
B an atom of neon
C an ion of boron
D an ion of nitrogen
A 2, 5
B 2, 8, 2
C 2, 8, 6
D 2, 8, 8
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12 The diagram shows the molecule of a compound.
Which pair of elements could Y and Z be?
Z Y Z
X – electron of Y
– electron of Z
Y Z
A calcium chlorine
B carbon oxygen
C sodium chlorine
D sulfur chlorine
conducts electricity
melting point / °C
when liquid in aqueous solution
A -114 none none
B -114 none good
C 180 none insoluble
D 808 good good
14 Aluminium sulfate reacts with calcium hydroxide according to the chemical equation below.
w x y z
A 1 1 1 2
B 1 3 2 3
C 2 3 2 3
D 2 3 3 1
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15 The graph below shows the colour ranges of the acid-base indicators methyl orange,
bromothymol blue and phenolphthalein.
A few drops of different indicators were added into a solution separately. The colour of the
solution turned yellow in methyl orange, yellow in bromothymol blue and colourless in
phenolphthalein.
A 2.5 to 3.5
B 4.5 to 5.5
C 7.5 to 8.5
D 9.5 to 10.5
16 Workers in a factory accidently spilled some sulfuric acid on the floor. Which of the following
would leave an alkaline mixture when added in excess?
A calcium hydroxide
B copper(II) nitrate
C magnesium carbonate
D silver powder
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18 A noble gas Z is used to fill weather balloons.
A 1 diatomic molecule
B 1 single atoms
C 2 single atoms
D 2 diatomic molecules
19 The chart below shows the melting points of the elements in Group I of the Periodic Table.
The melting point for potassium is missing.
temperature/°C
200
Li
150
100
Na
50
Rb
Cs
0
A 0 °C
B 63 °C
C 98 °C
D 180 °C
End of Paper 3
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KENT RIDGE SECONDARY SCHOOL
END-OF-YEAR EXAMINATION 2019
PAPER 4
Write your name, class and index number in the spaces provided at the top of this page.
Write in dark blue or black pen on both sides of the paper.
You may use a soft pencil for any diagrams or graphs.
Do not use staples, paper clips, highlighters, glue or correction fluid.
Section A
Answer all questions. FOR EXAMINER’S USE
Section B PAPER 3
Answer any two questions. 20
Write your answers in the spaces provided on the question
paper. PAPER 4
Section A 14
In calculations, you should show all the steps in your working,
giving your answer at each stage.
PAPER 4
Enter the numbers of the Section B questions you have Section B 16
answered on the dotted lines in the grid. A copy of the Periodic
Table can be found on page 11. Q………
Q………
TOTAL
50
_____________________________________________________________________________________
This Question Paper consists of 11 printed pages, including this page.
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248
Section A
Answer all the questions.
The total mark for this section is 14.
1 Part of the Periodic Table is shown in Fig. 1.1. The letters A to G are not real symbols
of the elements.
Fig. 1.1
[2]
[2]
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2 The formulae of ionic compounds can be deduced from the charges on the ions
present. The following list shows the symbols of some common ions.
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3 Plants make a variety of coloured pigments. A student extracted blue colouring from
four different plants, R, S, T and U. The student put a spot of each colouring on a
piece of filter paper. The filter paper was dipped into a solvent and left for 30 minutes.
Fig. 3.1
[1]
[1]
[1]
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4 Phosphorus is a non-metal. Fig. 4.1 shows a molecule of phosphorus oxide.
Fig. 4.1
(a) Complete Table 4.1 to show the number of electrons, neutrons and protons in a
phosphorus atom.
Table 4.1
(b) With reference to Fig. 4.1, what is the molecular formula of phosphorus oxide?
[1]
[1]
Draw a ‘dot and cross’ diagram of phosphorus hydride. Only show the outer
shell electrons.
[2]
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Section B
Fig. 5.1
(i) Complete the equation, by stating the name of the salt and gas produced.
magnesium hydrochloric
+ Æ +
metal acid
test:
result: [4]
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253
(b) A farmer wanted to plant a new crop which only grows well on neutral soil. He
took a sample of the soil from his land and varied the pH of the soil by adding
different amount of lime to it.
Fig 5.2 shows the graph of how the pH of the sample of soil changes as lime is
added.
Fig. 5.2
(ii) What is the pH of soil required by the farmer to plant the new crop?
(iii) What mass of lime must then be added to the soil so that it is suitable for
growing the new crop?
(iv) After adding 4.0 g of lime to the soil sample, a small amount of the soil was
removed and added to water. A few drops of Universal indicator were then
added to the mixture.
[4]
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6 (a) Fluorine, chlorine, bromine, iodine and astatine are elements in Group VII.
(ii) Going down the group, from fluorine to astatine, describe two trends in their
properties.
[4]
Table 6.1
sodium Na 11
potassium K 2,8,8,1
(i) Complete the table with the atomic number and electronic structure for the
elements in Group I.
(ii) Using data from Table 6.1, suggest the reason why lithium, sodium and
potassium are found in the same group?
(iii) Caesium is another element in Group I. Write the formula of a caesium ion.
[4]
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7 (a) The pie chart in Fig. 7.1 shows the composition of air.
other gases
gas B
gas A
Fig. 7.1
[1]
(ii) Name two gases that are classified under ‘other gases’.
[1]
(b) The graph in Fig. 7.2 shows the amount of carbon monoxide in the air of a large
city.
Fig. 7.2
(ii) The peak period in a city is typically between 7 to 8 am and 6.30 to 7.30 pm.
Suggest why the level of carbon monoxide is the highest at these times.
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(iii) Carbon monoxide is an air pollutant. What is the effect of carbon monoxide
on human health?
(iv) Name another pollutant that can commonly be found in the air sample of the
city.
[4]
End of Paper
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Secondary 3 Normal (Academic) 11 5105/04 Science (Chemistry)
Kent Ridge Secondary School End-of-Year Examination 2019
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CONFIDENTIAL
1 2 3 4 5 6 7 8 9 10
D B B B A C B D A D
11 12 13 14 15 16 17 18 19 20
B B D B B A D C B C
Qn no Remarks
1 (a)(i) B and C 1
(a)(ii) D 1
(b)(i) True 1
(b)(ii) True 1
Q1: [4]
Q
2 (a) CaOO 2 correct:
(b) MgCl 2 1m
(c)) CaSO
Ca
CaSO 4
(d) Al(NO
Al(N
NO 3 ) 3 Max: 2m
Q2: [2]
3 (a)
(a
a) water
wa
w ate
t r/e
et
ethanol
th
haanol 1
(b) S 1
(c)
c) R an
a
anddT 1
Q3: [3]
4 (a) 3 correct:
number
n umbe of number of number of 1m
symbol
symb
bol
electrons
el neutrons protons
ଷଵ
Max: 1m
ଵହܲ 15 16 15
(b) P4O6 1
(c) Covalent 1
(d) 1m:
shared
electrons
H P H
1m:
valence
electrons
H
Max: 2m
Q4: [5]
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CONFIDENTIAL
Qn no Remarks
5 (a)(i) Salt: magnesium chloride 1
1
Gas: hydrogen
(a)(ii) Test: Lighted splint 1
Result: Flame extinguished with a ‘pop’ sound. 1
(b)(i) Acidic, pH less than 7. 1
(b)(ii) pH 7 1
(b)(iii) 2.0 g 1
Accept: 2 g
Reject: if no unit
(b)(iv) Green to blue 1
Reject: purple
Q5: [8]
6 (a)(i) halogen 1
Any
y one
on
o ne point
p iin
po nt
(b)(i)
((b
(b)(
b)(
)(i)
(i 2 correct:
element
ellem
emen
e t symbol
sy
s yymb
mb
mbol
bo atomic
atom number
micc n um
umber
um electronic structure 1m
lithium
lith
tth
hiu
i um Li
L 3 2,1 Max: 2m
sodium
so
s od
odi
diium Na 11 2,8,1
pota
potassiu
ass
ssiu
iu
K 19 2,8,8,1
m
(b)(ii) All of the elements have one electron in their outer shell. 1
Max: 1m
(b)(i) 8 am and 7.30 pm 1
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CONFIDENTIAL
Qn no Remarks
(b)(ii) These are the times where many there are much incomplete 1
combustion of carbon containing fuels in cars/transport
Allow:
- More transportation for people to go to work and return
home
- There are more cars on the road at that time.
de
Reject: carbon dioxide
(c)(i) 28 1
(c)(ii) 9.8/28 = 0.35 mol
mo
ol 1
Reject: iff no
no unit
un
u nit
Q6: [8]
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2019 Sec 3 NA Science Chemistry SA2
Kranji Secondary School
Section A: Multiple Choice Questions (20 marks)
For each question, there are four possible answers, A, B, C and D. Choose the one you consider
correct and record your choice in soft pencil on the OMR sheet provided.
1 Which of the following apparatus can be used to measure 24.3 cm3 of solution most
accurately?
A burette
B conical flask
C measuring cylinder
D pipette
The graph shows the temperature of the metal during this process.
A melting point
B colour of crystals
C size of crystals
D solubility
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264
5 Which stages occur in distillation?
6 A mixture of two sugars was compared with four different sugars using chromatography.
The results are shown in the diagram.
A 1 and 2
B 1 and 4
C 2 and 3
D 2 and 4
Which method of separation could be used to obtain each of the required products from each
mixture?
mixture 1 mixture 2
to obtain sand to obtain water to obtain salt to obtain water
A crystallisation distillation filtration filtration
B crystallisation filtration filtration distillation
C filtration distillation crystallisation filtration
D filtration filtration crystallisation distillation
3
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8 The diagrams show the nuclei of four different atoms.
A Q and R
B Q and T
C R and S
D S and T
A An electron is added.
B An electron is removed.
C A proton is added.
D A proton is removed.
A CCl2
B CCl4
C CaCl2
D CaCl4
Al SO4
A -2 +3
B +2 -3
C -3 +2
D +3 -2
4
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13 The diagram shows a molecule of hydrogen fluoride.
14 A compound has a molecular formula of X2O and a relative molecular mass of 44.
A 9
B 14
C 18
D 28
15 The colour of Universal Indicator in each of four solutions is shown in the table.
16 Which of the following does not react with dilute sulfuric acid?
A magnesium hydroxide
B magnesium metal
C magnesium nitrate
D magnesium carbonate
Which type of chemical reaction takes place when farmers add calcium hydroxide to the soil?
A decomposition
B neutralisation
C precipitation
D saturation
5
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18 The following gases are present in car exhaust fumes.
• nitrogen
A nitrogen only
B nitrogen and water vapour only
C nitrogen, carbon dioxide and water vapour only
D nitrogen, carbon monoxide, carbon dioxide and water vapour only
19 A steel works and a chemical works are built near to a city. The limestone (calcium carbonate)
buildings in the city begin to crumble.
A carbon dioxide
B carbon monoxide
C oxygen
D nitrogen dioxide
20 The diagram shows steel wool inside a test-tube. The test-tube is inverted in water, trapping
air inside. Steel requires oxygen and water to rust.
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Section B: Structured Questions (14 marks)
1 The diagrams A, B, C, D, E and F in Fig. 1.1 represent the particles in different substances.
Fig.1.1
(a) Write in the table, which of the diagrams A, B, C, D, E and F, best represents the
descriptor in the table. Each diagram can only be used once.
descriptor diagram
liquid element
gaseous compound
solid mixture
liquid mixture
[2]
(i) Complete the table to show the relative charges and relative masses of a
proton, a neutron and an electron.
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(ii) Using information from the Periodic Table on page 13. State the number of
protons, electrons and neutrons on one atom of argon.
particle number
proton
neutron
electron
[2]
……………………………….…………………………………………………………
……………………………….………………………………………...……………[1]
……………………………….……..………………………………...……………[1]
(ii) Explain why potassium chloride does not conduct electricity at 25°C.
……………………………….……..………………………………...……………[1]
(iii) Draw the dot and cross diagram to show the bonding in potassium chloride.
Show only valence electrons.
[2]
(b) (i) Potassium chloride is a salt that can be prepared by an acid-alkali method
of preparation.
…………………………………..…………………………………...……………[1]
(ii) Name the acid and the alkali used to prepare potassium chloride.
Acid : …………………………………....……………
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Section C: Free Response Questions (16 marks)
sulfur
Fig.3.1
As a result of the reaction, the piece of sulfur changed into an acidic gas, sulfur dioxide.
The student breathe in and suffered irritation to the eyes and lungs and he remembered that
sulfur dioxide is an air pollutant.
....................................................................................................................................
.............................................................................................................................. [1]
(ii) Other than irritation to the eyes and lungs, state another problem that sulfur
dioxide causes.
....................................................................................................................................
.............................................................................................................................. [1]
The student decided to replace sulfur with zinc and heated since in air. Zinc reacts with
oxygen in the air to produce zinc oxide.
(b) (i) Write a balanced chemical equation of the reaction between zinc with oxygen.
.............................................................................................................................. [1]
(ii) The zinc oxide produced is able to react and dissolve in both acid and alkali. What
type of oxide is zinc oxide?
.............................................................................................................................. [1]
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The student then added some zinc to some dilute sulfuric acid contained in test-tube A. He
also added some of the zinc oxide produced by the reaction earlier to some dilute sulfuric
acid in test-tube B as shown in Fig. 3.2.
zinc
zinc oxide
Fig.3.2
test-tube : …………………………………………….
explanation : ………………….……………………………………………………………
....................................................................................................................................
.............................................................................................................................. [2]
test : ……………………………………………………………………………..………….
result : ………………….……………………………...……………………………………
.............................................................................................................................. [2]
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4 Lead(II) chloride is used to make white pigment in white paint. It has been banned as lead
compounds are toxic.
Lead(II) chloride is prepared in the laboratory by mixing aqueous lead(II) nitrate and aqueous
sodium chloride together.
.............................................................................................................................. [1]
(ii) State the method used to prepare lead(II) chloride in the laboratory
.............................................................................................................................. [1]
(b) The reaction between aqueous lead(II) nitrate and aqueous sodium chloride is shown
below.
The lead(II) chloride formed was then filtered from the mixture and dried with filter paper
and weighed.
(ii) Calculate the number of moles of lead(II) chloride used if 5.56 g of lead(II) chloride
was used to make the solution for the reaction.
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(iii) Calculate the moles of sodium chloride used.
(c) Lead(II) chloride has a high melting point. Explain, in terms of bonding, why it has a high
melting point.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
END OF PAPER
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The Periodic Table of Elements
Group
I II III IV V VI VII 0
1 2
H He
hydrogen helium
Key 1 4
3 4 proton (atomic) number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 - 101 103 106 108 112 115 119 122 128 127 131
275
55 56 57 – 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba lanthanoids Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89 – 103 104 105 106 107 108 109 110 111 112 114 116
actinoids
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Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium Rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –
3
The volume of one mole of any gas is 24 dm at room temperature and pressure (r.t.p)
13
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KRANJI SECONDARY SCHOOL
Sec 3NA 5105 EYE Answer Key / 2019
1 A 6 D 11 B 16 C
2 C 7 D 12 D 17 B
3 B 8 A 13 A 18 C
4 A 9 B 14 B 19 D
5 C 10 D 15 C 20 D
(b)(i) +1 (first row), 1 (second row), -1, 1/1840 (third row)) [1M for any
an
ny 2]] 2
(iii)
Legend:
nd:: X – el
e
electron
leecctrron of K
O – electron
ellectron of Cl
e
(b)(i) Titration 1
3 (a)(i) Volcanic activities/Combustion of fossil fuels such as coals from power stations 1
(a) (ii) Forms acid rains that corrode marble buildings, kills aquatic wildlife as ponds and 1
lakes become too acidic and causes poor plant growth
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(b) (ii) Amphoteric oxide 1
(c) (ii) Test : Pushed lighted splint into gas (Allow ECF of 2 marks from (c)(i)) 1
Results : Gas extinguishes lighted splint with a pop sound. 1
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