Professional Documents
Culture Documents
10 1021@acsreagents 4012
10 1021@acsreagents 4012
pubs.acs.org/doi/book/10.1021/acsreagents
ABSTRACT
This monograph for Aluminum Sulfate, Hydrated provides, in addition to common physical constants, a general
description including typical appearance, applications, change in state (approximate), and aqueous solubility. The
monograph also details the following specifications and corresponding tests for verifying that a substance meets ACS
Reagent Grade specifications including: Assay, Insoluble Matter, Chloride, Calcium, Magnesium, Potassium, Sodium,
Heavy Metals, and Iron.
Note: This reagent is available in degrees of hydration ranging from 14 to 18 molecules of water.
GENERAL DESCRIPTION
SPECIFICATIONS
Maximum Allowable
Insoluble matter . . . . . . . . . . . . . . . . . . . . . 0.01%
Chloride (Cl) . . . . . . . . . . . . . . . . . . . . . . . 0.005%
DOI:10.1021/acsreagents.4012
© 2017 American Chemical Society A ACS Reagent Chemicals, Part 4
ACS Reagent Chemicals Monograph
pubs.acs.org/doi/book/10.1021/acsreagents
TESTS
Assay
(By indirect complexometric titration of AlIII). Weigh accurately 8 g and transfer to a 250 mL volumetric flask. Dissolve in
about 75 mL of water, add 5 mL of hydrochloric acid, dilute to volume with water, and mix. Place a 25.0 mL aliquot of this
solution in a 250 mL beaker, add 50 mL of water, mix, and then add 40.0 mL of standard 0.1 M EDTA and 20 mL of ammonium
acetate–acetic acid buffer solution. Heat the solution to near boiling for 5 min and cool. (The pH should be 4.0–5.0 and
should be maintained in that range by adding more buffer during the titration if necessary.) Add 50 mL of alcohol and 2 mL
of dithizone indicator solution, and titrate the excess of EDTA with 0.1 M zinc chloride volumetric solution until the color
changes from a green-violet to a rose-pink. One milliliter of 0.1 M EDTAcorresponds to 0.02972 g of Al2(SO4)3 · 14H2O,
0.03152 g of Al2(SO4)3 · 16H2O, and 0.03332 g of Al2(SO4)3 · 18H2O.
where F = 29.72 for 14H2O, 31.52 for 16H2O, and 33.32 for 18H2O.
Insoluble Matter
[Part 2: Gravimetric Methods; Insoluble Matter]. Use 20 g dissolved in 150 mL of water containing 5 mL of 25% sulfuric acid.
Chloride
[Part 2: Colorimetry and Turbidimetry; Chloride]. Use 0.20 g.
S a m p l e S t o c k S o l u t i o n . Dissolve 10.0 g of sample in 80 mL of water, add 2 mL of nitric acid (1:1), transfer to a 100
mL volumetric flask, dilute to the mark with water, and mix (1 mL = 0.10 g).
DOI:10.1021/acsreagents.4012
© 2017 American Chemical Society B ACS Reagent Chemicals, Part 4
ACS Reagent Chemicals Monograph
pubs.acs.org/doi/book/10.1021/acsreagents
Heavy Metals
[Part 2: Colorimetry and Turbidimetry; Heavy Metals (as Lead); Procedure for Heavy Metals, Method 1]. Dissolve 4.0 g in 40
mL of water, and dilute with water to 48 mL. Use 36 mL to prepare the sample solution, and use the remaining 12 mL to
prepare the control solution.
Iron
[Part 2: Colorimetry and Turbidimetry; Iron; Procedure for Iron, Method 1 (Ammonium Thiocyanate)]. Dissolve 1.0 g in 40 mL
of water; use 20 mL of this solution, and 1 mL of hydrochloric acid.
DOI:10.1021/acsreagents.4012
© 2017 American Chemical Society C ACS Reagent Chemicals, Part 4