PROCESS ISOBARIC ISOMETRIC ISOTHERMAL ISENTROPIC POLYTROPIC

PVT (P = C) (V = C) (T = C) (S = 0) (PVn = C)
𝑃1 𝑉1 k= 𝑃2 𝑉2 k 𝑃1 𝑉1 n= 𝑃2 𝑉2 n
𝑇1 𝑉1 1-k 𝑇1 𝑉1 1-n
𝑉1 𝑇1 𝑃1 𝑇1 = =
RELATIONS = = 𝑃1 𝑉1 = 𝑃2 𝑉2 𝑇2 𝑉2 𝑇2 𝑉2
𝑉2 𝑇2 𝑃2 𝑇2
𝑇1 𝑃1 k-1/k 𝑇1 𝑃
= = 𝑃1 n-1/n
𝑇2 𝑃2 𝑇2 2

𝑉
NON-FLOW Wn = 𝑃1 𝑉1 ln 𝑉2 𝑘(𝑃2 𝑉2−𝑃1𝑉1) 𝑛(𝑃2 𝑉2−𝑃1𝑉1 )
Wn = P (V2 – V1) Wn = 0 1 Wn = Wn =
WORK 1−𝑘 1−𝑛
Wn = Ws
𝑃
STEADY Wn = 𝑃1 𝑉1 ln 𝑃1 Ws = Ws =
Ws = 0 Ws = V (P1 – P2) 2
FLOW WORK
Ws = Ws Ws = kWs Ws =kWs
∆INTERNAL
∆U = mCv∆T ∆U = mCv∆T ∆U = 0 ∆U = mCv∆T ∆U = mCv∆T
ENERGY

∆ENTHALPY ∆H = mCp∆T ∆H = mCp∆T ∆H = 0 ∆H = mCp∆T ∆H = mCp∆T

HEAT Q = Wn = Ws Q = T∆S
Q = mCp∆T Q = mCv∆T Q = mCn∆T
TRANSFER Q = T∆S Q=0

𝑇 𝑇 𝑉 𝑇
∆ENTROPY ∆S = mCp ln 𝑇2 ∆S = mCp ln 𝑇2 ∆S = mR ln 𝑉2 ∆S = 0 ∆S = mCn ln 𝑇2
1 1 1 1