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01 - Overview of Ceramics and Energy Consumption
01 - Overview of Ceramics and Energy Consumption
Exercises (Übungen)
Processing/Additive manufacturing
Sintering
Exercises
Index of introduction
Overview of ceramics
Classification
Energy consumption
Performance
Summary
Overview of ceramics
How much energy is consumed during the processing of ceramics? Which are the
steps that require more energy?
Ceramics cannot be forged, melted and shaped, they are not ductile and difficult to machine
Overview of ceramics
Ceramic processing
Produce a final dense ceramic component is a complex task that is based on some steps
Energy situation
Huge role of ceramics
Polymers: Flexibility
The high melting temperature (even in some cases > 3000 °C – UHTCs)
Crystallinity: degree of structural order in a solid. Long range ceramics, short range glasses
Important: salts (soluble in water) and glasses (< 30% crystalline)
They are usually moulded at room temperature from a raw material mass, followed by a
temperature treatment (which is called SINTERING) at above 800°C to consolidate the material.
As a consequence of the thermal treatment, a specific microstructure is developed, which will
determine some of the properties.
*In some cases moulding may also occur at higher temperature or by smelt casting with
subsequent crystallisation.
** Some properties are determined by the composition (density, melting point) and others by the
microstructure (mechanical, thermal, electrical properties).
Classification
Ceramics
Refractories
Functional Ceramics Structural Ceramics Bio-Ceramics
Chemical porcelain
Electro and thermal High strength, Bioinert,
Construction response toughness, melting bioactive, and
point, thermal shock, bioresorbable
Insulators reliability
Classification
Classification: According to chemical composition or „family“ of materials
Oxide ceramics: Carbides:
A-A Ti3SiC2
(Metallic)
M-X Cr2AlC
(Carbide or
nitride) Ti2AlC
A-A
(Metallic) Ti3AlC2
M-X Nb2AlC
Characteristic layered A-A Ti2AlN
microstructure …. (>150)
M-X
> 150 different compounds;
A-A
and solid solutions 500 nm
Covalent/ionic/metallic
Classification
Classification: According to chemical composition or „family“ of materials
Doping:
Fe, Ti, Mg, V…
Classification
Zirconia (ZrO2) is also one of the most studied ceramic and structural material
It is typically stabilized
Classification
- mouldability
- colour of product
- strength
- prize
Al4[(OH)8Si4O10]
(Kaolinite)
Classification
Easy!
Approx. 90 % of
Earth's crust
Continuous process
Classification
Weight
Less material
Why do bricks have holes?
Less heat during processing!!!
Materials science has been from the beginning to survive and progress
First materials were (and still are) natural: stones, wood, bones, skin, etc.
Ceramics were the first synthetic material, being a technical heritage of mankind
Needs of the time: collecting water, housing, production of other materials and decoration (!!!!)
WHY?
Ganges
Classification
25th Mill.B.C.
Classification
Housing/architecture
No this picture!!!!!
But sun-dried bricks for
houses and ovens (foods) and
later other materials
Daylife activities
Processing
Töpferscheibe Freihand-
Formgebung
Brennöfen
Trocknung
Classification
Casting of metals
Ovens
Ceramic processing
Produce a final dense ceramic component is a complex task that is based on some steps
Green body: It is the shape of the ceramic before the thermal treatment for the consolidation. The
shape should be close to the final product because machining of ceramics is difficult. At this stage the
ceramic particles (powders) are weakly bonded. It is common to use additives to form the green body.
Addition of water and additives such as binders, lubricants, etc. to form a paste/suspension/ink/etc.
AM
Energy consumption
Sintering: thermal process (might be assisted by pressure) to consolidate a powder compact into a
ceramic solid mass. Sintering is driving by the reduction or the energy of the system and it typically
implies a reduction of the porosity and consequently, a shrinkage of the body. The sintering process
defines the microstructure and consequently the properties of the ceramic material.
* Typically oven to consolidate pottery, but there
Several parameters play a role during are much more such as Spark Plasma Sintering
the densification such as heating rate,
maximal temperature, dwell time,
atmosphere, etc.
High temperatures (> 1000 °C), slow heating rates (~ 10-20 K/min) and long
isothermal holding times (hours)
Powder
Starting phase
50
Nanostructured Materials
ZnO Si3N4/CNTs
Composites
200 nm 500 nm
20 µm 5 µm
Performance
c
Defect size - Processing
2a
2c
2a
Risk
Proof-Test
Keramisches Denken
Certainly, this topic is really wide and I will explain it in a single lecture (new semesters)
Here just a brief info about that…some of this will be done in the ceramic chair.
Electronics
Energy Transition & Circular economy
Energy Transition & Circular economy
Space exploration
Novel refractories
Acquiring world leadership in waste-based ceramic materials. The use of at least 85% recycled materials
strengthens the waste market, which helps preserve natural stocks of virgin and important minerals such as
clays, limestone and feldspar and reduces imports of minerals such as zirconia, bauxite and magnesia.
Widening the market for more sustainable ceramic products to replace other materials such as concrete,
granite and marble.
Reducing in the energy consumption of the milling and firing processes (electricity and methane are the
highest factors of impact on the production cost of tile);
Improving health in the workplace thanks to the lower amount of free crystalline silica in the ceramic body.
Energy Transition & Circular economy
The ionic and covalent bonding of ceramics entails good properties such as high elastic
modulus or melting point, but limits the processing. The ceramic processing is relative
complex but determinant to control the final properties of the component.
Processing and sintering (high temp and long times) of ceramic compounds consume a
considerable amount of energy, so alternative methods (i.e. additive manufacturing or
advanced sintering techniques) are required.
Circular economy is totally required in the ceramic field – as in other fields – to reduce the
energy consumption, mining, waste and usage of materials. It has to be tackled in
different directions from processing to applications.