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Do not open this Test Booklet until you are asked to do so.
Read carefully the Instructions on this Test Booklet.
Important Instructions :
1. Immediately fill in the form number on this page of the Test Booklet with Blue/Black Ball Point
Pen. Use of pencil is strictly prohibited.
2. The test is of 3 hours 20 minutes duration and this Test Booklet contains 200 questions. Each
question carries 4 marks. For each correct response, the candidate will get 4 marks. For each
incorrect response, one mark will be deducted from the total scores. The maximum marks are
720.
3. In this Test Paper, each subject will consist of two sections. Section A will consist of 35 questions
(all questions are mandatory) and Section B will have 15 questions. Candidate can choose to
attempt any 10 question out of these 15 questions. In case if candidate attempts more than
10 questions, first 10 attempted questions will be considered for marking.
4. In case of more than one option correct in any question, the best correct option will be considered
as answer.
5. On completion of the test, the candidate must hand over the Answer Sheet to the
Invigilator before leaving the Room/Hall. The candidates are allowed to take away this
Test Booklet with them.
6. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
7. On completion of the test, the candidate must hand over the Answer Sheet to the
Invigilator before leaving the Room/Hall. The candidates are allowed to take away this
Test Booklet with them.
8. The candidates should ensure that the Answer Sheet is not folded. Do not make any stray marks
on the Answer Sheet. Do not write your Form No. anywhere else except in the specified space in
the Test Booklet/Answer Sheet.
9. Use of white fluid for correction is not permissible on the Answer Sheet
10. Do not fold or make any stray marks on the Answer Sheet.
: in words ___________________________________________________________________
m mL
(1) 2 (2)
( m + M) m+M
(1) − 0.4^j − 0.8^i (2) − 0.4^j + 0.8^i
( m + M )L ( M + m)
(3) (4) (3)
m mL − 0.8^j + 0.4^i (4) None
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ALLEN
45. A reversible refrigerator operates between a 49. For free expansion of a gas which of the
low temperature reservoir at TC and a high following is true ?
temperature reservoir at TH. Its coefficient of (1) Q = W = 0 and ΔEint = 0
performance is given by :
(2) Q = 0, W > 0 and ΔEint = –W
(1) (TH – TC)/TC
(3) W = 0, Q > 0 and ΔEint = Q
(2) TC/(TH – TC)
(4) W = 0, Q < 0 and ΔEint = 0
(3) (TH – TC)/TH
50. A box (thermally insulated) has two chambers
(4) TH/(TH – TC) separated by a membrane. One of volume V
46. An ideal heat engine working between contains an ideal gas at temperature T. The
temperature T1 and T2 has an efficiency η, the 1
other of volume ( V ) is evacuated. If the
new efficiency if both the source and sink 2
temperature are doubled, will be :- membrane breaks down, the gas temperature
η will be :-
(1) (2) η
2 (1) 3/2 T
(3) 2η (4) 3η (2) 2T/3
47. A carnot engine is working between steam (3) T
point and ice point. The percentage of heat
converted into work is :- (4) None of these
(1) 26.8% (2) 100%
(3) 35% (4) 75%
48. An ideal heat engine working between
temperature TH and TL has efficiency η. If both
the temperature are raised by 100 K each, the
new efficiency of heat engine will be :
(1) equal to η
(2) greater than η
(3) less than η
(4) greater or less than h depending upon the
nature of the working substance
(1) (2)
(3) (4) (1) i > ii > iii (2) iii > ii > i
(3) iii > i > ii (4) i > iii > ii
59. Arrange the following carbanions in decreasing 63. Among the following the aromatic compound is :
order stability :
(1) (2)
(3) (4)
(1) III > I > IV > I
(2) III > II > I > IV 64. Stability order of following cations is :-
(3) I > III > II > IV
(4) III > I > II > IV
60. Select the acid with highest Ka
(1)
(2)
(1) IV > III > II > I (2) I > II > III > IV
(3) I > IV > III > II (4) I > III > IV > II
(3)
65. Which of the following will not show tautomerism
(4)
(1) (2)
61. Which of the following is not an electrophile :-
⊕
(1) BH3 (2) H 3O
⊕ ⊕
(3) (4) CH3COCH3
(3) N O2 (4) Cl
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English / 05022023 Space for Rough Work Page 10/31
ALLEN
66. Which one of the following resonating 70. Which will not show keto-enol tautomerism :-
structures of 1–methoxy–1,3–butadiene is least
stable :- (1)
(1) Θ ⊕
C H 2 − CH = CH − CH = O − CH 3
(2) Θ ⊕
CH 2 = CH − C H − CH = O − CH 3 (2)
(3) Θ ⊕
C H 2 − C H − CH = CH − O − C H 3
(4) CH 2 = CH − CH = CH − O − C H 3 (3)
67. Correct order of –I effect is :-
(1) –CN > –NO2 > –CHO
(4)
(2) –OH > –Cl > –CH3
(3) –X > –OH > –NH2 71. Most stable resonating structure of given cation is:-
(4) –Cl > –F > –Br
68. Given
(1) (2)
(3) (4)
(3) (4)
(1) 1 > 2 > 3 > 4 (2) 4 > 3 > 2 > 1 solution
(3) 2 > 3 > 1 > 4 (4) 2 > 1 > 3 > 4 (1) 2 × 10–4 M (2) 16 × 10–4 M
76. The order of stability of the following (3) 8 × 10–4 M (4) 8 × 10–8 M
tautomeric compound is :-
81. The solubility in water of a sparingly soluble
salt AB2 is 1.0 × 10–5 mol L–1. Its solubility
product will be:
(1) 1 × 10–15 (2) 1 × 10–10
(3) 4 × 10–15 (4) 4 × 10–10
82. Maximum solubility of AgBr will be in :-
(1) II > III > I (2) I > II > III (1) 0.1 M KBr (2) 0.1 M CaBr2
(3) III > II > I (4) II > I > III (3) 0.1 M AgCl (4) H2O (pure)
Nurture - I, II & III 2701CMD300122020
English / 05022023 Space for Rough Work Page 12/31
ALLEN
83. Assertion: Solubility of AgBr decreases in the SECTION-2
presence of sodium bromide. This section will have 15 questions. Candidate
Reason: Sodium bromide undergoes hydrolysis can choose to attempt any 10 questions out of
in water
these 15 questions. In case if candidate attempts
(1) If both Assertion & Reason are true and more than 10 questions, first 10 attempted
the Reason is a correct explanation of the
Assertion questions will be considered for marking.
(2) If the Assertion & Reason are true but 86. Which will lead to maximum enolisation?
Reason is not a correct explanation of the
Assertion (1) (2)
(3) If Assertion is True but the Reason is false
(4) If both Assertion & Reason are false
(3) (4)
84. Which of the following is a buffer solution ?
(1) 500 mL of 0.1 N CH3COOH + 500 mL 87. The correct statement regarding a carbonyl
of 0.1 N NaOH compound with a hydrogen atom on its alpha
(2) 500 mL of 0.1 N CH3COOH + 500 mL carbon,is :-
of 0.1 N HCl
(1) a carbonyl compound with a hydrogen
(3) 500 mL of 0.1 N CH3COOH + 500 mL atom on its alpha-carbon never
of 0.2 N NaOH equilibrates with its corresponding enol.
(4) 500 mL of 0.2 N CH3COOH + 500 mL (2) a carbonyl compound with a hydrgen atom
of 0.1 N NaOH
on its alpha-carbon rapidly equilibrates
85. Assertion : If Ksp < ionic product, precipitate is with its corresponding enol and this
formed process is known as aldehyde-ketone
Reason : Solubility product (Ksp) is the highest equilibration.
limit of ionic product of the electrolyte in
saturated solutions. (3) a carbonyl compound with a hydrogen
atom on its alpha-carbon rapidly
(1) If both Assertion & Reason are True & the
Reason is a correct explanation of the equilibrates with its corresponding enol
Assertion. and this process is known as
carbonylation.
(2) If both Assertion & Reason are True but
Reason is not a correct explanation of the (4) a carbonyl compound with a hydrogen
Assertion. atom on its alpha-carbon rapidly
(3) If Assertion is True but the Reason is equilibrates with its corresponding enol
False. and this process is known as keto-enol
(4) If both Assertion & Reason are false. tautomerism.
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ALLEN
88. Keto and enol forms of a compound are related 93. Compare bond length in the given compounds
to each other as :- across (carbon-oxygen) :-
(1) Resonance structures
(2) Conformers
(3) Configurational isomers
(4) Structural isomers
89. This molecule can be enolized involving:
(1) a > b > c
(2) b > c > a
(3) b > a > c
(4) a > c > b
(1) Hα (2) Hβ
94. {-OH, -NO2, -CHO, -OCOCH3, -COO-, -O-,
(3) Hγ (4) Cannot be enolized ⊕
− N H 3 , -SO3H}
90. Number of groups showing +M from above set is/are
(1) 6
is an example of (2) 5
(1) +E effect (2) –E effect (3) 4
(3) +M effect (4) –M effect (4) 3
91. Which is wrong electromeric effect : 95. Which of the following order is correct ?
(1)
(1) Basic strength
(2) CH3–CH=CH2
(3) –C≡N
(4) CH≡CH (2) Acidic strength
Root Shoot
Root Cap Leaf
(4) Apical Apical
Meristem primordium
Meristem Meristem
(1) Active and Passive 137. The pteridophytes are restricted to narrow
geographical regions because :-
(2) Passive and Passive
(1) The gametophytes require cool, damp and
(3) Passive and Active shady places to grow.
(4) Active and Active (2) They are vascular cryptogams.
135. Which of the following pressure is ultimately (3) They need water for fertilisation.
responsible for enlargement and extension
growth of cells ? (4) Both (1) and (3)