Chemical Engineering

Thermodynamics
(ChE31101)

Dr. Momin Elhadi Abdalla

Department of Chemical Engineering
Faculty of Engineering
University of Khartoum
B.Sc. Program
Lecture 3 1
Refrigeration Systems
and Air Conditioning

2
The vapor compression refrigeration cycle is a common method for transferring
heat from a low temperature to a high temperature.

The above figure shows the objectives of refrigerators and heat pumps. The purpose
of a refrigerator is the removal of heat, called the cooling load, from a low-
temperature medium. The purpose of a heat pump is the transfer of heat to a
high-temperature medium, called the heating load.

When we are interested in the heat energy removed from a low-temperature space,
the device is called a refrigerator. When we are interested in the heat energy
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supplied to the high-temperature space, the device is called a heat pump.
 REFRIGERATORS AND HEAT
PUMPS
The transfer of heat from a low-temperature region
to a high-temperature one requires special devices
called refrigerators.
Another device that transfers heat from a low-
temperature medium to a high-temperature one is
the heat pump.
Refrigerators and heat pumps are essentially the
same devices; they differ in their objectives only.

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for fixed values of QL and QH
 THE REVERSED CARNOT CYCLE
The reversed Carnot cycle is the most efficient refrig. cycle operating between TL and TH.
It is not a suitable model for refrigeration cycles since processes 2-3 and 4-1 are not practical
because Process 2-3 involves the compression of a liquid–vapor mixture, which requires
a compressor that will handle two phases, and process 4-1 involves the expansion of high-
moisture-content refrigerant in a turbine.

Both COPs increase as the

difference between the two
temperatures decreases,
that is, as TL rises or TH
falls.

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THE IDEAL VAPOR-COMPRESSION
REFRIGERATION CYCLE
The vapor-compression refrigeration cycle is the
ideal model for refrigeration systems. Unlike the
reversed Carnot cycle, the refrigerant is vaporized
completely before it is compressed and the turbine is
replaced with a throttling device.

This is the most

widely used cycle for
refrigerators, A-C
systems, and heat
pumps.

Schematic and T-s

diagram for the ideal
vapor-compression
refrigeration cycle. 6
 FIGURE:
The P-h diagram of
an ideal vapor-
compression
refrigeration cycle.

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10-5
The ideal vapor-compression refrigeration cycle involves an irreversible (throttling)
process to make it a more realistic model for the actual systems.
Replacing the expansion valve by a turbine is not practical since the added
benefits cannot justify the added cost and complexity.
Steady-flow
energy balance

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The ordinary household refrigerator is a good example of the application of this cycle.

Q L h1  h4
COPR  
Wnet ,in h2  h1
Q H h2  h3
COPHP  
Wnet ,in h2  h1
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Example 11-1

Refrigerant-134a is the working fluid in an ideal compression refrigeration cycle. The

refrigerant leaves the evaporator at -20oC and has a condenser pressure of 0.9 MPa.
The mass flow rate is 3 kg/min. Find COP R and COPR, Carnot for the same Tmax and
Tmin , and the tons of refrigeration.

Using the Refrigerant-134a Tables, we have

State 2 
State1  kJ 

Compressor inlet   1
h 238.41 Compressor exit kJ
kg  h2 s  278.23
 P2 s  P2  900 kPa  kg
T1  20o C   s  0.9456 kJ kJ  T2 s  43.79 C
o

x1  1.0   1 kg  K s2 s  s1  0.9456 
kg  K 

State 3  kJ State 4 
  x  0.358
Condenser exit   3 Throttle exit   4
h 101.61
kg
  kJ
P3  900 kPa   kJ T4  T1  20o C   s4  0.4053
s3  0.3738  kg  K
x3  0.0   kg  K h4  h3 
 10
 QL m(h1  h4 ) h1  h4
COPR   
Wnet , in m(h2  h1 ) h2  h1
kJ
(238.41  101.61)
kg

kJ
(278.23  238.41)
kg
 3.44

The tons of refrigeration, often called the cooling load or refrigeration effect, are

QL  m(h1  h4 ) TL
COPR , Carnot 
kg kJ 1Ton TH  TL
3 (238.41  101.61) (20  273) K
min kg 211 kJ 
min (43.79  (20)) K
 1.94 Ton  3.97
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 ACTUAL VAPOR-COMPRESSION
REFRIGERATION CYCLE
An actual vapor-compression refrigeration cycle differs
from the ideal one owing mostly to the irreversibilities
that occur in various components, mainly due to fluid
friction (causes pressure drops) and heat transfer to or
from the surroundings.
DIFFERENCES
Non-isentropic compression
Superheated vapor at evaporator exit
Subcooled liquid at condenser exit
Pressure drops in condenser and evaporator

The COP decreases

as a result of
irreversibilities.

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 SELECTING THE RIGHT REFRIGERANT
• Several refrigerants may be used in refrigeration systems such as
chlorofluorocarbons (CFCs), ammonia, hydrocarbons (propane, ethane, ethylene,
etc.), carbon dioxide, air (in the air-conditioning of aircraft), and even water (in
applications above the freezing point).
• R-11, R-12, R-22, R-134a, and R-502 account for over 90 percent of the market.
• The industrial and heavy-commercial sectors use ammonia (it is toxic).
• R-11 is used in large-capacity water chillers serving A-C systems in buildings.
• R-134a (replaced R-12, which damages ozone layer) is used in domestic refrigerators
and freezers, as well as automotive air conditioners.
• R-22 is used in window air conditioners, heat pumps, air conditioners of commercial
buildings, and large industrial refrigeration systems, and offers strong competition to
ammonia.
• R-502 (a blend of R-115 and R-22) is the dominant refrigerant used in commercial
refrigeration systems such as those in supermarkets.
• CFCs allow more ultraviolet radiation into the earth’s atmosphere by destroying the
protective ozone layer and thus contributing to the greenhouse effect that causes
global warming. Fully halogenated CFCs (such as R-11, R-12, and R-115) do the most
damage to the ozone layer. Refrigerants that are friendly to the ozone layer have been
developed.
• Two important parameters that need to be considered in the selection of a
refrigerant are the temperatures of the two media (the refrigerated space and the
environment) with which the refrigerant exchanges heat. 13
 Heat Pump Systems

 A typical heat pump system is

shown here. In the heating mode
high-pressure vapor refrigerant
is sent to the indoor heat
exchanger coil.

 The refrigerant gives up its

energy to the inside air and
condenses to a high-pressure
liquid. The liquid is throttled to a
low-pressure, low-temperature
liquid-vapor in the outdoor coil and
receives energy from the outside
air.

 The refrigerant vaporizes, enters

the compressor as a low-pressure
vapor to be compressed to the
high-pressure, and the cycle is
completed. 14
Multistage Compression When the fluid used throughout the cascade
Refrigeration Systems refrigeration system is the same, the heat exchanger
between the stages can be replaced by a mixing
chamber (called a flash chamber) since it has better
heat transfer characteristics.

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GAS REFRIGERATION CYCLES
The reversed Brayton cycle (the gas refrigeration cycle) can be
used for refrigeration.

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ABSORPTION REFRIGERATION SYSTEMS

Absorption
refrigeration is
economic when
there is a source of
inexpensive
thermal energy at
a temperature of
100 to 200°C.
Some examples
include geothermal
energy, solar
energy, and waste
heat from
cogeneration or
process steam
plants, and even
natural gas when it
is at a relatively low
price.
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The COP of actual absorption refrigeration
systems is usually less than 1.

Air-conditioning systems based on absorption

refrigeration, called absorption chillers,
perform best when the heat source can supply
heat at a high temperature with little
temperature drop.

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