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SEMESTER 1

Assignment 3 [64]
Due date: 06 April 2020

Assignment unique number (Code): 610366

Questions

1. Give three different types of chemical bonding.

2. Draw the Lewis structure of water.

3. Determine the mass of 1.75 moles of CaCl2O2.

4. We dissolve 2.45 g of sugar in 200.0 g water. What is the mass percent of


sugar in the solution?

5. What is the molarity of 5.30 g of Na2CO3 dissolved in 400.0 mL solution?

6. If 25.0 mL of a 2.19 M solution are diluted to 72.8 mL, what is the final
concentration?

7. Given a solution of KOH with 6.50 x 10-3 M concentration.

(a) Determine whether the solution is basic or acidic.

(b) Now continue to determine its pH.

8. Balance the following chemical reactions:

(a) HgO → Hg + O2

(b) NH4NO3 → N2O + H2O


9. Determine the balanced oxidation-reduction half reactions for the below
chemical reaction:
H2 + F2 → 2HF

10. List 10 different types of alkanes and alkenes.

11. Determine the IUPAC names of the below chemical structures.

(a)

(b)

Solutions
1. Ionic, Covalent and metallic bonding. (3)

2. (3)

3. The molecular weight of CaCl2O2 is 142.983 grams /mol

from: 𝑛 (𝑚𝑜𝑙𝑒𝑠) = 𝑀𝑎𝑠𝑠 𝑖𝑛 𝑔𝑟𝑎𝑚𝑠


𝑀𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
Mass = n ×Mr

= (1.75 mol) × (142.983 grams/ mol)

= 250 grams (3)

4. mass % = (mass solute / (mass solute + mass solvent)) × 100%

= (2.45 g / (2.45 g + 200.0 g)) × 100%

= 1.21 % (3)

5. n (moles of solute) = M (molarity) × V (volume of solvent)

M = n/V
= (m/Mr) /V
= ((5.3 g) / (105.988 g/mo)) / 0.4L
= 0.125 M (4)

6. M1V1 = M2V2
(2.19 M)(25.0 mL) = M2(72.8 mL)
M2 = 0.752 M (4)

7. (a) The solution is basic

(b) pOH = -log [OH- ]

= -log(6.50 x 10-3 )

= 2.187

pH = 14 – pOH = 14 – 2.187 = 11.813 (5)

8. (a) 2 HgO → 2 Hg + 1 O2
(b) 1 NH4NO3 → 1 N2O + 2 H2O (6)

9. Oxidation half reaction: H2 → 2 H+ + 2 e-

Reduction half reaction: F2 + 2 e- → 2F- (6)

10. List 10 different types of alkanes and alkenes.


Alkanes
Methane, Ethane, Propane, butane, pentane, hexane, heptane, octane,
nonane, decane (10)

Alkenes
Ethene, Propene, 1- Butene, 2-butene, 1-pentene, 2 – pentene, 1- hexane,
2-hexene, 3-hexene, 1 – heptane, etc. (10)

11. Determine the IUPAC names of the below chemical structures.

(a) 2-Methyl-2-butene (3)


Or (2-Methyl-but – 2 – ene)

(b) 2-Bromo – 3- methyl – 2 – butene (4)


or (2-Bromo – 3 – methyl – but – 2 – ene )

Total [64]

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