CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 01: SPONTANEITY
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 1
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

1. What is a spontaneous reaction?

-A reaction that naturally occur without others intervention and also occurs without continuous energy
from an external source
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 01: SPONTANEITY
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 2
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

2.What is a nonspontaneous reaction?

-A reaction that not may occur without other intervention and also occurs with continuous energy from
an external source
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 01: SPONTANEITY
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 3
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

3. Indicate whether the following processes are spontaneous or nonspontaneous

.(a) Liquid water freezing at a temperature below its freezing point

-spontaneous
(b) Liquid water freezing at a temperature above its freezing point
-nonspontaneous
(c) The combustion of gasoline
-spontaneous
(d) A ball thrown into the air
- nonspontaneous
(e) A raindrop falling to the ground
-spontaneous
(f) Iron rusting in a moist atmosphere
-spontaneous
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 01: SPONTANEITY
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 4
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

4. A helium-filled balloon spontaneously deflates overnight as He atoms diffuse through the wall of the
balloon. Describe the redistribution of matter and/or energy that accompanies this process.

- The helium goes out in smaller confinement which is the ballon to the larger volume in
confinement which is the house.
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 01: SPONTANEITY
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 5
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

5,Many plastic materials are organic polymers that contain carbon and hydrogen. The oxidation of these
plastics in air to form carbon dioxide and water is a spontaneous process; however, plastic materials
tend to persist in the environment. Explain..

- The oxidation of plastic is spontaneous however there are kinetically stable that they break very
slow and that why they persist in our invironment
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 02: ENTROPHY
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 1
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 3

1.Indicate which substance in the given pairs has the higher entropy value. Explain your choices.

(a) C2H5OH(l)or C3H7OH(l)

-C3H7OH HAS A MORE MOLECULAR MASS
(b) C2H5OH(l)or C2H5OH(g)
- C2H5OH(g) GAS IS ALWAYS HAVE MORE ENTROPHY THAN LIQUID
(c) 2H(g)or H(g)
- 2H SINCE IT 2 MOLECULE THEREFORE DOUBLE THE ENTROPHY TOO.
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 02: ENTROPHY
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 2
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 3

2. Write the balanced chemical equation for the combustion of benzene, C6H6(l), to give carbon dioxide
and water vapor. Would you expect ΔS to be positive or negative in this process?
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 02: ENTROPHY
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 3
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 3

3. Predict the sign of the entropy change for the following processes. Give a reason for your prediction.

(a)Pb2+(aq)+S2−(aq)⟶PbS(s)
- ITS NEGATIVE BECAUSE THE ΔS IS LESS THAN ZERO AND LIQUID TO SOLID, DELTA S WILL
BE NEGATIVE
(b)2Fe(s)+O2(g)⟶Fe2O2(s)
- ITS NEGATIVE BECAUSE THE ΔS IS LESS THAN ZERO AND GAS TO SOLID, DELTA S WILL BE
NEGATIVE
(c)2C6H14(l)+19O2(g)⟶14H2O(g)+12CO2(g)
- ITS POSITIVE BECAUSE THE ΔS IS MORE THAN ZERO AND PRODUCT HAVE MORE GAS
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 03: THE SECOND AND THIRD LAW OF THERMODYNAMICS
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 1
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

1.Calculate the standard entropy change for the following process:

H2(g)+C2H4(g)⟶C2H6(g)
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 03: THE SECOND AND THIRD LAW OF THERMODYNAMICS
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 2
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

2.Calculate the standard entropy change for the following reaction:

Ca(OH)2(s)⟶CaO(s)+H2O(l)

CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT
LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS
UNIT NO. & TITLE: UNIT 03: THE SECOND AND THIRD LAW OF THERMODYNAMICS
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 3
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

3.By calculatingΔSunivat each temperature, determine if the melting of 1 mole of NaCl(s)is spontaneous at
500 °C and at 700 °C.
S°NaCl(s)=72.11𝐽𝑚𝑜𝑙.𝐾 S°NaCl(l)=95.06𝐽𝑚𝑜𝑙.𝐾 ΔH∘fusion=27.95𝑘𝐽𝑚𝑜𝑙

-What assumptions are made about the thermodynamic information (entropy and enthalpy values) used to
solve this problem?
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 03: THE SECOND AND THIRD LAW OF THERMODYNAMICS
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 4
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

4.Determine the entropy change for the combustion of gaseous propane, C 3H8,
under the standard conditions to give gaseous carbon dioxide and water.
 CHEMISTRY FOR ENGINEERS – LECTURE ANSWER SHEET FOR ACTIVITIES AND ASSESSMENT

LESSON NO. & TITLE: LESSON 05: SOLUTIONS THERMODYNAMICS

UNIT NO. & TITLE: UNIT 03: THE SECOND AND THIRD LAW OF THERMODYNAMICS
NAME:RONNICK DELA TONGA DATE OF SUBMISSION: JAN 18, 2023
ID NO.: 2022-14202-MN-0 PAGE NO: 5
YEAR/COURSE/SECTION: DMET 1-1 TOTAL NUMBER OF PAGES: 5

5.CalculateΔS°for the following changes,ΔS°valuefromtheTable

:(a)SnCl4(l)⟶SnCl4(g)
(b)CS2(g)⟶CS2(l)
(c)Cu(s)⟶Cu(g)
(d)H2O(l)⟶H2O(g)
(e)2H2(g)+O2(g)⟶2H2O(l)
(f)2HCl(g)+Pb(s)⟶PbCl2(s)+H2(g)
(g)Zn(s)+CuSO4(s)⟶Cu(s)+ZnSO4(s)