DAIQ Rank Booster Series for JEE MAINS PAHSE-1

Practice Sheet No. 5

Chapter: Chemical and Ionic Equilibrium Date: 24/12/2022
1. In any chemical reaction, equilibrium is supposed to be establish when
(A) Mutual opposite reactions undergo
(B) Concentration of reactants and resulting products are equal
(C) Velocity of mutual reactions become equal
(D) The temperature of mutual opposite reactions become equal
2. For the reaction PCl3 (g) + Cl2 (g) ⇌ PCl5 (g) the position of equilibrium can be shifted to the right
by
(A) Increasing the temperature
(B) Doubling the volume
(C) Addition of Cl2 at constant volume
(D) Addition of equimolar quantities of PCl3 and PCl5
3. According to law of mass action rate of a chemical reaction is proportional to
(A) Concentration of reactants (B) Molar concentration of reactants
(C) Concentration of products (D) Molar concentration of products
4. 4 moles of A are mixed with 4 moles of B. At equilibrium for the reaction A + B ⇌ C + D , 2 moles of
C and D are formed. The equilibrium constant for the reaction will be
1 1
(A) (B) (C) 1 (D) 4
4 2
5. 2 moles of PCl5 were heated in a closed vessel of 2 litre capacity. At equilibrium, 40% of PCl5 is
dissociated into PCl3 and Cl2 . The value of equilibrium constant is
(A) 0.266 (B) 0.53 (C) 2.66 (D) 5.3
6. In a reaction A + B ⇌ C + D , the concentrations of A, B, C and D (in moles/litre) are 0.5, 0.8, 0.4
and 1.0 respectively. The equilibrium constant is
(A) 0.1 (B) 1.0 (C) 10 (D) 
7. In the gas phase reaction, C2H4 + H2 ⇌ C2H6 , the equilibrium constant can be expressed in units
of
(A) litre−1 mole−1 (B) litremole−1 (C) mole2 litre−2 (D) molelitre−1
8. A mixture of 0.3 mole of H2 and 0.3 mole of I2 is allowed to react in a 10 litre evacuated flask at
500o C . The reaction is H2 + I2 ⇌ 2HI , the K is found to be 64. The amount of unreacted I2 at
equilibrium is
(A) 0.15 mole (B) 0.06 mole (C) 0.03 mole (D) 0.2 mole
9. If K c is the equilibrium constant for the formation of NH3 , the dissociation constant of ammonia
under the same temperature will be
(A) K c (B) Kc (C) K c2 (D) 1/ Kc
10. For the reaction
1
2NO2(g) ⇌ 2NO(g) + O2(g) , Kc = 1.8  10−6 at 185°C. At 185°C the Kc for NO(g) + O2(g) ⇌ NO2(g) is
2
(A) 1.95  10−3 (B) 1.95  103 (C) 7.5  102 (D) 0.9  106

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 DAIQ Rank Booster Series for JEE MAINS PAHSE-1
Practice Sheet No. 5
Chapter: Chemical and Ionic Equilibrium Date: 24/12/2022
1 1
11. If equilibrium constants of reaction, N2 + O2 ⇌ 2NO is K1 and N2 + O2 ⇌ NO is K 2 , then
2 2
1
(A) K1 = K 2 (B) K 2 = K 1 (C) K1 = 2K 2 (D) K1 = K2
2
12. G0 (HI,g)  +1.7kJ . What is the equilibrium constant at 25o C for 2HI(g)  H2 (g) + I2 (g)
(A) 24.0 (B) 3.9 (C) 2.0 (D) 0.5
13. In which of the following gaseous equilibrium an increase in pressure will increase the yield of the
products
(A) 2HI ⇌ H2 + I2 (B) 2SO2 + O2 ⇌ 2SO3
(C) H2 + Br2 ⇌ 2HBr (D) H2O + CO ⇌ H2 + CO2
14. In weak electrolytic solution, degree of ionization
(A) Will be proportional to dilution
(B) Will be proportional to concentration of electrolyte
(C) Will be proportional to the square root of dilution
(D) Will be reciprocal to the dilution
15. According to Bronsted law, water is a/an
(A) Base (B) Acid (C) Acid and base both (D) Salt
−
16. The conjugate base of H2PO is 4

(A) H3PO4 (B) P2O5 (C) PO34− (D) HPO24−

17. The solubility product of a salt having general formula MX2, in water is : 4  10−12 . The concentration
of M2+ ions in the aqueous solution of the salt is
(A) 2.0  10−6 M (B) 1.0  10−4 M (C) 1.6  10−4 M (D) 4.0  10−10 M
18. At 298 K, the solubility product of PbCl2 is 1.0  10−6 . What will be the solubility of PbCl2 in
moles/litre
(A) 6.3  10−3 (B) 1.0  10−3 (C) 3.0  10−3 (D) 4.6  10−14
19. pH of a solution is 5. Its hydroxyl ion concentration is
(A) 5 (B) 10 (C) 10−5 (D) 10−9
20. Given pH of a solution A is 3 and it is mixed with another solution B having pH 2. If both mixed then
resultant pH of the solution will be
(A) 3.2 (B) 1.9 (C) 3.4 (D) 3.5
21. The pKa of a weak acid is 4.8. What should be the ratio of [Acid]/[Salt] of a buffer if pH = 5.8 is
required
(A) 10 (B) 0.1 (C) 1 (D) 2
−14
22. Given that the dissociation constant for H2O is K w = 1 10 mole litre−2, what is the HCl of a
2

0.001molar KOH solution

(A) 10−11 (B) 3 (C) 14 (D) 11

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 DAIQ Rank Booster Series for JEE MAINS PAHSE-1
Practice Sheet No. 5
Chapter: Chemical and Ionic Equilibrium Date: 24/12/2022
23. The pH of a solution obtained by mixing 50 ml of 0.4 N HCl and 50 ml of 0.2 N NaOH is
(A) − log2 (B) − log0.2 (C) 1.0 (D) 2.0
24. When 3 mole of A and 1 mole of B are mixed in 1 litre vessel the following reaction takes place
A(g) + B(g) ⇌ 2C(g) . 1.5 moles of C are formed. The equilibrium constant for the reaction is
(A) 0.12 (B) 0.25 (C) 0.50 (D) 4.0
25. 2 mol of N2 is mixed with 6 mol of H2 in a closed vessel of one litre capacity. If 50% of N2 is
converted into NH3 at equilibrium, the value of K c for the reaction N2(g) + 3H2(g) ⇌ 2NH3(g) is
(A) 4 / 27 (B) 27 / 4 (C) 1/ 27 (D) 24
1
26. If for H2(g) + S2(S) ⇌ H2S(g) and
2
H2(g) + Br2(g) ⇌ 2HBr(g)
The equilibrium constants are K1 and K2 respectively, the reaction
1
Br2(g) + H2S(g) ⇌ 2HBr(g) + S2(S) would have equilibrium constant
2
(A) K1  K 2 (B) K1 / K 2 (C) K 2 / K1 (D) K 22 / K1
27. Which of the following equilibria will shift to right side on increasing the temperature
(A) CO(g) + H2O(g) ⇌ CO2(g) + H2(g) (B) 2SO2(g) + O2(g) ⇌ 2SO3(g)

1
(C) H2O(g) ⇌ H2(g) + (O2 )(g) (D) 4HCl(g) + O2(g) ⇌ 2H2O(g) + 2Cl2(g)
2
28. The equilibrium constant for the reaction, N2 ( g ) + O2 ( g ) 2NO ( g ) is 4.0  10−4 at 2000 K. In the
presence of a catalyst the equilibrium is attained ten times faster. Therefore, the equilibrium
constant in presence of the catalyst at 2000 K is—
(A) 4  10−4 (B) 40  10−4
(C) 4  10 −2
(D) Difficult to compute without more data
29. The equilibrium constant for a reaction A + B C + D is 1  10−2 at 298 K and is 2 at 273 K. The
chemical process resulting in the formation of C and is:
(A) Exothermic (B) Endothermic
(C) Unpredictable (D) There is no relationship between H and K
30. In a flask colourless N2O4 is in equilibrium with brown coloured NO2. At equilibrium, when the flask
is heated to 100C the brown colour deepens and on cooling, the brown colour became less
coloured. The change in enthalpy H for the system is:
(A) Negative (B) Positive (C) Zero (D) Not defined

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