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Experiment B
Experiment B
The aim of the experiment was to determine the effect of pre-prepared cmc
powder on different height, diameter and flow curves of different capillary tubes
and to determined the viscosity that appears as a function of the cutting speed.
The prepared solution was poured into the tygon tube. Different capillary and
different diameter values of the flow to be non-newtonian or newtonian was
determined.
ii
TABLE OF CONTENTS
TABLE OF CONTENTS............................................................................ii
LIST OF FIGURES................................................................................iii
LIST OF TABLES..................................................................................iv
1. INTRODUCTION...............................................................................1
2. THEORETICAL BACKGROUND...............................................................2
3. EXPERIMENTAL SET UP AND CHEMICALS...................................................5
3.1. APPARATUS...............................................................................5
3.2. CHEMICALS...............................................................................5
4. PROCEDURE...................................................................................6
5. CALCULATIONS AND EXPERIMENTAL RESULTS............................................7
5.1. CALCULATIONS..........................................................................7
5.2 EXPERIMENTAL RESULTS..............................................................11
6. DISCUSSION..................................................................................12
7. CONCLUSİON AND RECOMENDATION .....................................................14
7.1. CALCULATIONS.........................................................................14
7.2. CALCULATIONS.........................................................................14
REFERENCES..................................................................................15
APPENDIX.....................................................................................16
APPENDIX A.................................................................................16
APPENDIX B.................................................................................21
iii
LIST OF FIGURES
LIST OF TABLES
INTRODUCTION
In the case of simple sliding at constant pressure and constant temperature, the
degree of slip was correlated with the shear rate. The dynamic constant was the
dynamic constant. Such fluids were "newtonian fluids" classified according to the
laws open, such as water, oil and air. These liquids were elastic and have a
viscosity constant. Liquids with a viscous consistency and significantly elastic were
classified as "non-newtonian fluids".
In the theory part of this experiment classified several fluids. The properties of
CMC powder solution were mentioned. Shear stress formula and its importance. It
was mentioned whether liquids were elastic. It was mentioned that the capillary
viscosity depends on a certain pressure drop and volumetric flow rate. In procedure
part of the experiment was made in three different diameters. These were 3 mm, 4
mm and 5 mm. Water fill to a certain extent and the flow of water flowing through
the gap calculate in how many seconds its was gone.
In the calculation part of the experiment, the volumetric flow rate "Q" of a
newtonian fluid in a fixed horizontal capillary tube of "newton fluids" was
determined. The diameter of the prepared solder was determined by the length of
the capillary tubes and by the effect of the open air pressure.
In the discussion part of this experiment, if there was an error in the procedure
The volumetric flow rate “Q” of a newtonian fluid in a horizontal capillary tube
under steady, fully developed and laminar conditions, is decribed by the equation;
4 '
π R (−P ) (2.3)
Q=
8σ
With
dP ∆P (2.4)
−P' = =constant =
dX L
Where, σ ,
∆ P , L and R are the viscosity, pressure drop across capillary, length and Radius of
the capillary repectively.The pressure drop across the capillary tube is also given
by;
∆ P=ρgh ( t ) (2.5)
Where “ ρ ” is the liquid density “g” is the acceleration due to gravity. In the
experimental set up which consist of vertical burette feeding the capillary
tubing,h(t) is the change of height of flowing liquid through the burette as shown in
figüre 3.1. The change of “h” with respect to time can be expressed as:
Where “A” is the cross sectional area of burette. Integration of Equation 2.6 gives:
4
π R (ρg) Bρ (2.7)
ln ( h ( t ) )= +C= t +C=mt +C
8 LAσ σ
3
Where
π R4 g (2.8)
B=
8 LA
Log(h(t)) vs. t plots for such liquids are expected to be linear having negative
slopes which may be used to estimate viscosity for “Newtonian fluids” (4).
In the case of “non-newtonian fluid”, the shear stress, τ , is not linearly related to
the shear rate, γ , and the “apparent” viscosity is aa funtion of shear rate. “ τ W
(shear stress and γ w (shear rate) at capillary wall atn any time t are given by
equations :
R ∆P (2.10)
τ w=
2L
Which gives,
h (t) (2.14)
ln =−kt+¿
h0
Where h 0 is the height of the meniscus at time t=0 and k, a, b are constants. By
fitting the second order polynomial curve (y=m x 2+nx+r) of log(h(t)/h 0) vs time
graph, the constants can be reached;
2
a =r
2
b =m 2 × ( a × b )−k=n
1 γ w −m 1 dm (2.15)
= = (1+ )
σ a (γ w ) τ w Bρ 4 m dt
2
Where ;
3.EXPERIMENTAL SET UP
Beaker
Funnel
6
String rods
d= 0.8 mm
L=20 cm d= 1.2 mm
d= 1.7 mm
d= 0.8 mm
L=30 cm d= 1.2 mm
d= 1.7 mm
d=0.8 mm
L=39.6 cm d= 1.2 mm
d= 1.7 mm
3.2.CHEMICALS
Water
7
4.PROCEDURE
10 g of CMC powder was added to the beaker and 1500 ml of water was
added. The beaker was placed in a magnetic stirrer and allowed to dissolve
the solution in water overnight.
A 20 mm long, 0.8 mm diameter capillary was removed and attached to a 50
mL burette.
The burette was filled with the pre-prepared solution and noted the height
of the solution, h (0).
The valve of the burner was opened and the timer was started at the same
time.
The duration of the solution was decreased for each 2 mL level.
The above procedure was reported for capillaries having a diameter of 0.8
mm and length 30 and 39.6 cm and capillaries each of 1.2 mm and 1.7 mm
and each of 20, 30 and 39.6 cm.
8
1.4
1.2
f(x) = − 2.147555659E-08 x² − 0.000660773012 x
1 + 1.219570202725
ln(h(t)/h(0))
0.8 R² = 0.998731461084654
0.6
0.4
0.2
0
0 200 400 600 800 1000 1200 1400 1600 1800 2000
Time (s)
−8 2
y=(−2 ×10 ) x −(0.0007) x+ 1.2196
Equaiton of graph was taken and a,b and k values were calculated by (....),(...),
(...),
a 2=1.2196
a=1.1044
9
2 −8
b =2× 10
b=1.414 ×10−4
2 ×(a ×b)−k=n
−4
2 ×(1.1044 ×1.414 ×10 )−k =0.0007
k =3.877 ×10−4
m=−k +2 b × ( a+ bt )
Since t=0
m=−7.54 ×10−5
dm
=2b 2
dt
dm
=2× ¿
dt
( )
γ w −m 1 dm
= 1+
τ w Bρ 4 m dt
2
−(−7.54 × 10 ) (5..)
( )
−5
γw 1 −8
= 1+ ×3.9988 × 10
( )(
τw −8
)
3
−9 m kg 2.27 ×10
2.49 ×10 2
× 1008.4 3
s m
γ w =295.922 s−1
10
1
=82.84
ηa ( 295.922 s )
−1
−5
η a=4.0790 ×10
0.000045
0.00004
Apparent Viscosity (pa.s)
0.000035
0.00003
0.000025
0.00002
0.000015
0.00001
0.000005
0
0 200 400 600 800 100012001400160018002000
Time (s)
0.000045
0.00004
Apparent viscosity (Pa.s)
0.000035
0.00003
0.000025
0.00002
0.000015
0.00001
0.000005
0
0 500 1000 1500 2000 2500 3000 3500
Shear rate (1/s)
Appendix
Appendix A
mL Time(s)
2 3
4 6
6 9
8 13
10 16
12 19
14 23
16 27
18 31
20 36
22 40
24 45
26 50
28 55
30 60
32 63.6
34 67.2
36 70.8
38 75
40 79.8
12
42 84
44 88.8
46 94.2
48 124.2
50 131.4
h( t)=71.5 cm
ΔP=7073.068 Pa
R=0.00085
R ΔP
τ w=
2L
τ w =7.5910 Pa
4
πR g
B=
8 LA
−8 3 2
B=5.078 ×10 m / s
13
1.4
1.2
f(x) = 0.00001185630015 x² − 0.0107482162778 x
1 + 1.260488248469
ln(h(t)/h(0))
R² = 0.984072457552789
0.8
0.6
0.4
0.2
0
0 20 40 60 80 100 120 140
Time (s)
Equaiton of graph was taken and a,b and k values were calculated by (....),(...),
(...),
2
a =1.2605
a=1.1227
b 2=1× 10−5
−3
b=3.1623 ×10
2 ×(a ×b)−k=n
−3
k =−3.6 ×10
m=−k +2 b × ( a+ bt )
Since t=0
m=0.0107
dm 2
=2b
dt
dm
=2× ¿
dt
( )
γ w −m 1 dm
= 1+ 2
τ w Bρ 4 m dt
( )
γw −( 0.0107 ) 1 −5 (5..)
= 1+ × 2× 10
( )(
τw −5
)
3
−8 m kg 4.9× 10
5.078 ×10 2
× 1008.4 3
s m
γ w =1664.07 s−1
1
=219.216
ηa ( 1664.07 s )
−1
−5
η a=2.7413 ×10
15
0.000003
0.0000025
0.0000015
0.000001
0.0000005
0
0 20 40 60 80 100 120 140
Time (s)
0.000003
0.0000025
Apparent viscosity (Pa.s)
0.000002
0.0000015
0.000001
0.0000005
0
1000 2000 3000 4000 5000 6000 7000 8000
Shear rate (1/s)
mL Time (s)
2 2
4 5
6 7
8 10
10 13
12 16
14 20
16 23
18 26
20 30
22 34
24 38
26 42
28 46
30 50
32 55
34 60
36 63.6
38 66.6
40 70.2
42 74.4
44 78.6
17
46 83.4
48 89.4
50 95.4
RΔP
τ w=
2L
τ w =15.0302 Pa
4
πR g
B=
8 LA
4 2
π ×(0.00085 m) ×( 9.81m/ s )
B=
8( 0.20 m)× ( 10 m )
−4
B=1.005 ×10−7 m3 / s2
18
1.4
1.2
f(x) = − 3.93940807622481E-05 x² − 0.00796811858915598 x + 1.20061149705912
R² = 0.998559103733232
1
ln(h(t)/h(0))
0.8
0.6
0.4
0.2
0
0 20 40 60 80 100 120
Time (s)
Equaiton of graph was taken and a,b and k values were calculated by (....),(...),
(...),
a 2=1.2006
m=0.0415
dm 2
=2b
dt
dm
=2× ¿
dt
( )
γ w −m 1 dm
= 1+
τ w Bρ 4 m 2 dt
19
( )
γw − ( 0.0415 ) 1 −5 (5..)
= 1+ ×8 ×10
( s ) (
τw −3
m )
−7 m
3
kg 6.89 ×10
1.005× 10 2
× 1008.4 3
−1
γ w =6250.41 s
1
=415.857
ηa ( 6250.41 s )
−1
−7
η a=3.8472× 10
0.00000045
0.0000004
0.00000035
Apparent Viscosity
0.0000003
0.00000025
0.0000002
0.00000015
0.0000001
0.00000005
0
0 10 20 30 40 50 60 70 80 90 100
Time (s)
0.00000045
0.0000004
0.00000035
Apparent Viscosity
0.0000003
0.00000025
0.0000002
0.00000015
0.0000001
0.00000005
0
6000 6200 6400 6600 6800 7000 7200 7400 7600
Shear rate
20
Appendix B
h(t) ∆P τw h(t ) m γw γw ηa
ln ( ) ( )
h (0) τw
h( t) ∆P τw h(t) m γw γw ηa
ln ( ) ( )
h (0) τw
h( t) ∆P τw h(t ) m γw γw ηa
ln ( ) ( )
h (0) τw
REFERENCES
http://www.uobabylon.edu.iq/eprints/publication_12_15796_137.pdf
http://www.wikizero.biz/index.php?
q=aHR0cHM6Ly9lbi53aWtpcGVkaWEub3JnL3dpa2kvQ2FyYm94eW1ldGh5bF9jZ
WxsdWxvc2U
http://www.physics.iitm.ac.in/~compflu/Lect-notes/chhabra.pdf
https://www.quora.com/What-is-the-shear-stress-formula
25
https://www.google.com/search?
rlz=1C1NDCM_trTR786TR786&biw=1536&bih=706&tbm=isch&sa=1&ei=Z8a9XM
6qIeWBk74PmYy20A4&q=shear+stress+graph&oq=shear+stress+g&gs_l=img.1.
0.0i19l3j0i5i30i19l4j0i8i30i19l3.1602951.1608162..1608927...2.0..0.179.2269
.0j16......0....1..gws-wiz-img.......0j0i67j0i30.m2XZo3GeR-
0#imgrc=MWDVD1DdHjmriM:
https://www.researchgate.net/figure/Structural-unit-of-carboxymethyl-
cellulose-CMC_fig1_265467174
NOMENCLATURE
26