QUANTA CHEMISTRY

An Institute of Chemical Sciences

CSIR-NET | IIT-GATE | IIT-JAM | Other MSc. Entrance

DPP- (4) Name Reaction (JAM)

1. Major product formed

O O
H+

O
O O O O

(a) (b) (c) (d)

O O O O
2. Major product formed
O O

H NaOH
+
NO 2
O OH O

(a) NO2 (b) NO2

O O
NO2
(c) (d)
NO2
3. Major product formed in the given reactions
O
NaOH

O
O O O
(a) (b) (c) (d)

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 DPP-(4) /Name Reaction(JAM)
4. Major product formed in the given reaction
O O
NaOH

O O O O

(a) (b) (c) (d)

5. Major product formed

O
NaOH

O
O O

(a) (b) (c) O (d) O

6. Major product formed

O O
NaOH

O O O O

(a) (b) (c) (d)

7. Major product formed

O O

NaOH

O O
O O

(a) (b) (c) (d) O

O O
O

8. Major product formed

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 DPP-(4) /Name Reaction(JAM)
O NaOH

O
CH3 O O
O O
(a) (b) (c) (d)

9. Major product formed in the given reaction is

O
KOH
COOH
O
O O O O

(a) COOH (b) COOH (c) (d) COOH

HOOC
10. Major product formed
O
KOH

O
O O
(a) (b)

O O

(c) (d)

11. Major product formed

O
1. NaOH
H 2. LiAlH4

O
O OH OH

(a) (b) (c) (d)

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 DPP-(4) /Name Reaction(JAM)
12. Major product formed

1. Hg(OAc)2, H 2O
2. PCC
3. NaOH

O O
(a) (b)

O O
(c) (d)

13. Major product

O
CH3NO2
NaOH

O NO 2 O O
NO2
(a) NO2 (b) (c) (d) NO2

14. Major product

CHO CH3NO2
NaOH, MeOH

NO2 NO2
(a) (b) (c) NO2 (d) NO2

15. Major product formed in the given reaction

NaOH
OO

(a) (b)

CH3

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 DPP-(4) /Name Reaction(JAM)
O
O
(c) (d)

16. Major product formed in the given reaction sequence is

CH3 1. O3/Me2S

CH3 2. NaOH
O O
O O
(a) (b) (c) (d)

17. The major product formed in the given reaction

1. O 3/Me 2S

2. NaOH
O O O
O

(a) (b) (c) (d)

18. The major product

CH3 1. O3/Me2S

2. NaOH
O O
O O
(a) H (b) (c) H (d)

ANSWER KEY
1. (d) 2. (b) 3. (b) 2. (d) 5. (c) 6. (c) 7. (c)
8. (b) 9. (b) 10. (b) 11. (d) 12. (a) 13. (b) 14. (b)
15. (c) 16. (c) 17. (d) 18. (b)

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 DPP-(4) /Name Reaction(JAM)

HINTS & SOLUTION

O O O O H O O H
H+
1.

O O O

O O

O O
OH
Correct option is (d)

O O O O

2. H NaOH H
+ +
NO 2 NO2

O OH O

NO 2 NaOH NO 2
H

Correct option is (b)

O O O O O O
H
3. H NaOH H 2O OH
+
HO
O O
OH

Correct option is (b)

O O
O O O O
H NaOH NaOH
6 5 4
4. 3 2
1
HO

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 DPP-(4) /Name Reaction(JAM)
Correct option is (d)

H O O
O O HO
5. NaOH NaOH NaOH
O O

Correct option is (c)

O O
O O O O
HO
H
6. NaOH

Correct option is (c)

O O

O O O O
6 HO
4 2
H
5 3 1 NaOH NaOH
7.
O O O O

Correct option is (c)

O O O O O O
NaOH NaOH
6
8. 4 2
5 3 1

HO H
O O
NaOH

Correct option is (b)

O O O
4
KOH 5 KOH
9. COOH 3
2
1 COOH COOH
O O O

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 DPP-(4) /Name Reaction(JAM)

HOOC OH
KOH HOOC
H
O O

Correct option is (b)

O
O KOH O KOH
4
5
10. 2
3 1
O O O

OH
NaOH
H
O O

Correct option is (b)

O O O O
1. NaOH NaOH
11. H 2. LiAlH4 H

O O OH

OH
LiAlH4

Correct option is (d)

OH O O O

12. Hg(OAc)2, H2O PCC NaOH

+

OH O O

Correct option is (a)

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 DPP-(4) /Name Reaction(JAM)

NO 2
O O OH
CH2 NO 2
13. CH3NO2 H2C NO2 –H2O
NaOH

Correct option is (b)

O
OH
CHO CH NO C H
14. 3 2
+ H 2C NO2 C CH 2 NO 2
H

NO 2

Correct option is (b)

H
1 O
H
15. NaOH 2 O O OH
O
O
3 OH
5
4
O
O

OH

Correct option is (c)

4
HO CH 3
5
CH3 3
O 3/Me2S NaOH
16. O O O O O
CH3 2
1

CH3
H 2O

O
Correct option is (c)

4
5
O3/Me2S 3 NaOH
17. O O O
2
1
O

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 DPP-(4) /Name Reaction(JAM)
OH
OH

H
O O
Correct option is (d)

H O O
H
CH3 O /Me S OH NaOH
3 2 NaOH O O
18. OO
H H
Correct option is (b)

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